A novel application of horseradish peroxidase （HRP） in the oxidation of alcohol ethoxylate to alkylether carboxylic acid in the present of H2O2 was reported in this paper. We propose the mechanism for the catalytic ...A novel application of horseradish peroxidase （HRP） in the oxidation of alcohol ethoxylate to alkylether carboxylic acid in the present of H2O2 was reported in this paper. We propose the mechanism for the catalytic oxidation reaction is that the hydrogen transfers from the substrate to the ferryl oxygen to form the α-hydroxy carbon radical intermediate. The reaction offers a new approach for further research structure and catalytic mechanism of HRP and production of alkylether carboxylic acid.展开更多
基金the National Science and Technology Support Project of China (No.2007BAE52B03) for the financial support.
文摘A novel application of horseradish peroxidase （HRP） in the oxidation of alcohol ethoxylate to alkylether carboxylic acid in the present of H2O2 was reported in this paper. We propose the mechanism for the catalytic oxidation reaction is that the hydrogen transfers from the substrate to the ferryl oxygen to form the α-hydroxy carbon radical intermediate. The reaction offers a new approach for further research structure and catalytic mechanism of HRP and production of alkylether carboxylic acid.
