基于遗传算法和蚁群算法的LEACH改进协议

针对无线传感器网络低功耗自适应集簇分层(Low Energy Adaptive Clustering Hierarchy,LEACH)路由协议因能耗不均衡导致节点过早死亡的问题,提出了一种基于遗传算法和蚁群算法改进的LEACH路由协议。在分簇阶段,通过遗传算法选举合理的簇头节点并根据节点的分布划分簇群;在数据传输阶段,通过蚁群算法使簇头节点尽可能选择能量充足且距离较短的路径进行数据传输。仿真结果表明,与传统的分簇路由协议LEACH和LEACH-C相比,改进算法可以使网络的能量消耗更加均衡,并延长网络的生命周期。

SYNTHESIS AND CHARACTERIZATION OF A NOVEL ALCOHOL-SOLUBLE POLYORGANOSILOXANE CONTAINING AMINO SIDE GROUPS

A novel alcohol-soluble polyorganosiroxane containing amino side groups, poly[3-(4-aminophenoxy)-aminophenoxy) propylmethylsiloxane] (2), was first prepared by the reduction of nitro groups on 4-nitrophenoxypropyl side chains of poly[3-(4-nitrophenoxy)propylmethylsiloxane] (1). The reaction proceeded easily with nearly 100% conversion. The synthesized alcohol-soluble polymer 2, which has potential application as a precursor for preparing advanced functional polymers, was characterized by FTIR, H-1-NMR, C-13-NMR, Si-29-NMR, VPO and GPC, respectively.

Selective leaching of lithium from spent lithium-ion batteries using sulfuric acid and oxalic acid

Traditional hydrometallurgical methods for recovering spent lithium-ion batteries(LIBs)involve acid leaching to simultaneously extract all valuable metals into the leachate.These methods usually are followed by a series of separation steps such as precipitation,extraction,and stripping to separate the individual valuable metals.In this study,we present a process for selectively leaching lithium through the synergistic effect of sulfuric and oxalic acids.Under optimal leaching conditions(leaching time of 1.5 h,leaching temperature of 70°C,liquid-solid ratio of 4 mL/g,oxalic acid ratio of 1.3,and sulfuric acid ratio of 1.3),the lithium leaching efficiency reached89.6%,and the leaching efficiencies of Ni,Co,and Mn were 12.8%,6.5%,and 21.7%.X-ray diffraction(XRD)and inductively coupled plasma optical emission spectrometer(ICP-OES)analyses showed that most of the Ni,Co,and Mn in the raw material remained as solid residue oxides and oxalates.This study offers a new approach to enriching the relevant theory for selectively recovering lithium from spent LIBs.

Recovery of Li, Ni, Co and Mn from spent lithium-ion batteries assisted by organic acids: Process optimization and leaching mechanism

The proper recycling of spent lithium-ion batteries(LIBs)can promote the recovery and utilization of valuable resources,while also negative environmental effects resulting from the presence of toxic and hazardous substances.In this study,a new environmentally friendly hydro-metallurgical process was proposed for leaching lithium(Li),nickel(Ni),cobalt(Co),and manganese(Mn)from spent LIBs using sulfuric acid with citric acid as a reductant.The effects of the concentration of sulfuric acid,the leaching temperature,the leaching time,the solid-liquid ratio,and the reducing agent dosage on the leaching behavior of the above elements were investigated.Key parameters were optimized using response surface methodology(RSM)to maximize the recovery of metals from spent LIBs.The maxim-um recovery efficiencies of Li,Ni,Co,and Mn can reach 99.08%,98.76%,98.33%,and 97.63%.under the optimized conditions(the sulfuric acid concentration was 1.16 mol/L,the citric acid dosage was 15wt%,the solid-liquid ratio was 40 g/L,and the temperature was 83℃ for 120 min),respectively.It was found that in the collaborative leaching process of sulfuric acid and citric acid,the citric acid initially provided strong reducing CO_(2)^(-),and the transition metal ions in the high state underwent a reduction reaction to produce transition metal ions in the low state.Additionally,citric acid can also act as a proton donor and chelate with lower-priced transition metal ions,thus speeding up the dissolution process.

Hydrometallurgical processing of chalcopyrite:A review of leaching techniques

Copper,an essential metal for the energy transition,is primarily obtained from chalcopyrite through hydrometallurgical and pyrometallurgical methods.The risks and harmful impacts of these processes pose significant concerns for environmental and human safety,highlighting the need for more efficient and eco-friendly hydrometallurgical methods.This review article emphasizes current pro-cesses such as oxidative leaching,bioleaching,and pressure leaching that have demonstrated efficiency in overcoming the complicated chalcopyrite network.Oxidative leaching operates under benign conditions within the leaching media;nevertheless,the introduction of oxidizing agents provides benefits and advantages.Bioleaching,a non-aggressive method,has shown a gradual increase in copper extrac-tion efficiency and has been explored using both primary and secondary sources.Pressure leaching,known for its effectiveness and se-lectivity in copper extraction,is becoming commercially more viable with increased research investments.This research also provides im-portant data for advancing future research in the field.

Study on synergistic leaching of potassium and phosphorus from potassium feldspar and solid waste phosphogypsum via coupling reactions

To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this paper.The study investigates the features of P and F in PG,and explores the decomposition of PF using hydrofluoric acid(HF)in the sulfuric acid system for K leaching and leaching of P and F in PG.The impact factors such as sulfuric acid concentration,reaction temperature,reaction time,material ratio(PG/PF),liquid–solid ratio,PF particle size,and PF calcination temperature on the leaching of P and K is systematically investigated in this paper.The results show that under optimal conditions,the leaching rate of K and P reach more than 93%and 96%,respectively.Kinetics study using shrinking core model(SCM)indicates two significant stages with internal diffusion predominantly controlling the leaching of K.The apparent activation energies of these two stages are 11.92 kJ·mol^(-1)and 11.55 kJ·mol^(-1),respectively.

Effect of Saline Water on Soil Acidity, Alkalinity and Nutrients Leaching in Sandy Loamy Soil in Rwamagana Bella Flower Farm, Rwanda

The necessity to saline and sodic waters is sometimes used for irrigating agricultural activities under certain circumstances, but it is important to note that the use of these waters comes with specific considerations and limitations. One way to decrease undesirable effects of sodic waters on the physical and chemical properties of soils is to apply organic and chemical amendments within the soil. This study aimed to assess the effectiveness of saline water on soil acidity, alkalinity and nutrients leaching in sandy loamy soil at Bella flower farm, in Rwamagana District, Rwanda. The water used was from the Muhazi Lake which is classified as Class I (Saline water quality). Column leaching experiments using treated soils were then conducted under saturated conditions. The soil under experimental was first analyzed for its textural classification, soil properties and is classified as sandy loamy soil. The t-test was taken at 1%, 5% and 10% levels of statistical significance compared to control soil. The results indicated that the application of saline water to soils caused an increase in some soil nutrients like increase of Phosphorus (P), Potassium (K+), Magnesium (Mg2+), Sulphur (S), CN ratio and Sodium (Na+) and decreased soil texture, physical and chemical properties and remained soil nutrients. Consequently, the intensive addition of saline water leachates to soil in PVC pipes led to decreased of soil EC through leaching and a raiser Soluble Sodium Percentage (SSP). The rate of saline water application affected the increase accumulation of SAR and Na% in the top soil layers. The study indicated that saline water is an inefficient amendment for sandy soil with saline water irrigation. The study recommends further studies with similar topic with saline water irrigation, as it accentuated the alkalinity levels.

Experimental investigation of dynamic characteristics of leaching tubing for solution mining of salt cavern carbon and energy storage

Salt caverns are extensively utilized for storing various substances such as fossil energy,hydrogen,compressed air,nuclear waste,and industrial solid waste.In China,when the salt cavern is leached through single-well water solution mining with oil as a cushion,engineering challenges arise with the leaching tubing,leading to issues like damage and instability.These problems significantly hinder the progress of cavern construction and the control of cavern shape.The primary cause of this is the flowinduced vibration instability of leaching tubing within a confined space,which results in severe bending or damage to the tubing.This study presents a model experimental investigation on the dynamic characteristics of leaching tubing using a self-developed liquid-solid coupling physical model experiment apparatus.The experiment utilizes a silicone-rubber pipe(SRP)and a polycarbonate pipe(PCP)to examine the effects of various factors on the dynamic stability of cantilevered pipes conveying fluid.These factors include external space constraint,flexural rigidity,medium outside the pipe,overhanging length,and end conditions.The experiments reveal four dynamic response phenomena:water hammer,static buckling,chaotic motion,and flutter instability.The study further demonstrates that the length of the external space constraint has a direct impact on the flutter critical flow velocity of the cantilevered pipe conveying fluid.Additionally,the flutter critical flow velocity is influenced by the end conditions and different external media.

Extraction of Valuable Metals from Titanium-bearing Blast Furnace Slag by Acid Leaching

To realize the resource utilization of the valuable metals in the titanium-containing blast furnace slag,the process route of “hydrochloric acid leaching-electrolysis-carbonization and carbon dioxide capture-preparation of calcium carbonate” was proposed.In this study,the influences of process conditions on the leaching rates of calcium,magnesium,aluminum,and iron and the phases of the leaching residue were investigated for the leaching process.The experimental results show that the HCl solution could selectively leach the elements from the titanium-containing blast furnace slag.The better leaching conditions are the HCl solution concentration of 4 mol/L,the leaching time of 30 min,the ratio of liquid volume to solid gas of 10 mL/g,and the stirring paddle speed of 300 r/min.Under the conditions,the leaching rates of calcium,magnesium,aluminum,and iron can reach 85.87%,73.41%,81.35%,and 59.08%,and the leaching rate of titanium is 10.71%.The iron and the aluminum are removed from the leachate to obtain iron-aluminum water purification agents,and the magnesium is removed from the leachate to obtain magnesium hydroxide.The leaching residue phase is dominated by perovskite,followed by magnesium silicate and tricalcium aluminate,and the titaniumrich material could be obtained from the leaching residue by desiliconization.

Preparation of sodium molybdate from molybdenum concentrate by microwave roasting and alkali leaching

The preparation process of sodium molybdate has the disadvantages of high energy consumption,low thermal efficiency,and high raw material requirement of molybdenum trioxide,in order to realize the green and efficient development of molybdenum concentrate resources,this paper proposes a new process for efficient recovery of molybdenum from molybdenum concentrate and preparation of sodium molybdate by microwave-enhanced roasting and alkali leaching.Thermodynamic analysis indicated the feasibility of oxidation roasting of molybdenum concentrate.The effects of roasting temperature,holding time,and power-to-mass ratio on the oxidation product and leaching product sodium molybdate (Na_(2)MoO_(4)·2H_(2)O) were investigated.Under the optimal process conditions:roasting temperature of 700℃,holding time of 110 min,and power-to-mass ratio of 110 W/g,the molybdenum state of existence was converted from MoS_(2) to Mo O3.The process of preparing sodium molybdate by alkali leaching of molybdenum calcine was investigated,the optimal leaching conditions include a solution concentration of 2.5 mol/L,a liquid-to-solid ratio of 2 mL/g,a leaching temperature of 60℃,and leaching solution termination at pH 8.The optimum conditions result in a leaching rate of sodium molybdate of 96.24%.Meanwhile,the content of sodium molybdate reaches 94.08wt%after leaching and removing impurities.Iron and aluminum impurities can be effectively separated by adjusting the pH of the leaching solution with sodium carbonate solution.This research avoids the shortcomings of the traditional process and utilizes the advantages of microwave metallurgy to prepare high-quality sodium molybdate,which provides a new idea for the highvalue utilization of molybdenum concentrate.

Process engineering of demineralisation of moderate to high ash Indian coals through NaOH‑HCl leaching and HF leaching

Chemical leaching of coals would be required to produce cleaner coals for some special applications where physical benefi-ciation may not be effective enough.This would also help in recovering Li and rare earth metals besides in the sequestration of CO_(2).About 20 Indian coals having complexly distributed moderate to high ash contents were sequentially treated with various alkali–acid such as NaOH-HCl,HF,HCl,HCl-HF,and NaOH-HCl-HF leaching.This aimed to establish and design the best stepwise sequential process for the highest degree of demineralisation through a chemical leaching process.Kinetics and process intensification studies were carried out.More than 80%demineralisation of Madhaipur and Neemcha coals was observed using the best sequential treatment designed presently.The repeated stepwise treatment of the alkali and the acid was also studied,which was found to significantly enhance the degree of demineralisation of coals.The integrated process of alkali–acid leaching followed by solvent extraction(Organo-refining)and vice versa of the treated coal was also studied for producing cleaner coals.

Study on metal recovery process and kinetics of oxidative leaching from spent LiFePO_(4)Li-batteries

A green environmental protection and enhanced leaching process was proposed to recover all elements from spent lithium iron phosphate(LiFePO_(4)) lithium batteries.In order to reduce the influence of Al impurity in the recovery process,NaOH was used to remove impurity.After impurity removal,the spent LiFePO_(4) cathode material was used as raw material under the H_(2)SO_(4) system,and the pressure oxidation leaching process was adopted to achieve the preferential leaching of lithium.The E-pH diagram of the Fe-P-Al-H_(2)O system can determine the stable region of each element in the recovery process of spent LiFePO_(4)Li-batteries.Under the optimal conditions(500 r·min^(-1),15 h,363.15 K,0.4 MPa,the liquid-solid ratio was 4:1 ml·g^(-1)and the acid-material ratio was 0.29),the leaching rate of Li was 99.24%,Fe,Al,and Ti were 0.10%,2.07%,and 0.03%,respectively.The Fe and P were precipitated and recovered as FePO_(4)·2H_(2)O.The kinetic analysis shows that the process of high-pressure acid leaching of spent LiFePO_(4) materials depends on the surface chemical reaction.Through the life cycle assessment(LCA)of the spent LiFePO_(4) whole recovery process,eight midpoint impact categories were selected to assess the impact of recovery process.The results can provide basic environmental information on production process for recycling industry.

无线传感器网络LEACH协议的改进

为提高经典LEACH路由协议的功能表现,解决因选取过程中簇头节点过于集中带来的相关问题,对LEACH协议中簇首的选取以及簇首到基站的通信进行优化。从原理上详细分析LEACH的算法原理,并在此基础上提出改进的LEACH路由算法。改进算法在簇首选取过程中考虑节点的剩余能量和空间位置,在数据稳定传输阶段采用多跳方式传递数据。通过MATLAB进行仿真实验,结果显示改进后的LEACH算法有助于减少节点的能量消耗,延长了网络节点的生命周期。

无线传感器网络LEACH协议能耗均衡改进

LEACH(lowenergy adaptive clustering hierarchy)路由协议是无线传感器网络中被广泛应用的分层协议,但它存在簇头选择不合理和节点能耗不均衡的缺点。通过对LEACH协议节点能耗建模和分析,提出了一种均衡节点能耗的改进协议LEACH-B。最后用NS2对改进后的协议进行仿真,仿真结果表明,改进后的协议能均衡节点的能耗,有效地延长了整个网络的生存期。

基于LEACH协议的簇头多跳(LEACH-M)算法

为了延长网络的生存时间,需要设计能量有效的协议,适应传感器网络的特点。成簇算法是传感器网络中减少能量消耗的一种关键技术,它能够增强网络的扩展性和延长网络的生存时间。早先提出的LEACH协议是无线传感网中的低功耗自适应分层路由算法,但节点通过一跳通信将数据传送给簇头,簇头也通过一跳通信将聚合后的数据传送给基站,这样会造成簇头节点负载过重,在LEACH协议中引入簇头多跳算法,使得簇头之间形成一个多跳的最优路径通向基站,从而减少了簇头节点能量的消耗,延长了传感网的寿命。实验表明此方法行之有效。

一种基于LEACH的改进WSN路由算法

针对无线传感器网络中网络能量损耗不均的问题,提出了一种基于LEACH的改进节能路由协议LEACH-PSOC。本文针对LEACH算法中的簇首选举方法进行了改进,首先利用粒子群算法良好的收敛性和全局优化能力将整个网络区域合理分割成多个子区域,然后在子区域内通过考虑节点剩余能量的因素进而选举出簇首。实验结果表明:与经典路由协议LEACH相比,该协议能够更加有效的平衡网络负载,提高了能量的利用率,延长了网络的生命周期。

一种基于LEACH协议改进的簇间多跳路由协议

为了均衡无线传感器网络的能量消耗,延长网络的生存时间,在研究几种基于均匀分簇和非均匀分簇的路由协议基础上,提出一种基于LEACH协议改进的簇间多跳路由协议。该协议引入能量因子和距离因子修正了LEACH协议的阈值函数。在簇间通信过程,簇头节点与Sink节点之间采用多跳通信方式,簇头与簇头之间形成一条通向Sink节点的优化路径。实验结果表明,相比于LEACH协议和EEUC协议,本文提出的新协议能够有效的均衡网络的能量消耗,延长无线传感器网络的寿命。

Environmental availability and ecological risk assessment of heavy metals in zinc leaching residue

Four different methods,namely mineralogical analysis,three-stage BCR sequential extraction procedure,dynamic leaching test and Hakanson Potential Ecological Risk Index Method were used to access the environmental activity and potential ecological risks of heavy metals in zinc leaching residue.The results demonstrate that the environmental activity of heavy metals declines in the following order：CdZnCuAsPb.Potential ecological risk indices for single heavy metal are CdZnCuAsPb.Cd has serious potential ecological risk to the ecological environment and contributes most to the potential toxicity response indices for various heavy metals in the residue.

无线传感器网络路由协议LEACH的研究与改进

无线传感器网络(WSN)数据传输离不开路由协议,路由协议是其组网的基础.由于WSN是一种资源受限网络,尤其是能量的受限,因此路由协议必须维持较小的路由信息并尽可能的减少能耗.文中从其体系结构、协议栈、网络层次等几个方面分析介绍了无线传感器网络,在对传感器网络路由协议作了充分了解的基础上深入研究了经典的聚类路由算法——LEACH(Low Energy Adaptive Clustering Hierarchy),提出了对它的改进方案并用OPNET对改进前后的算法进行了仿真比较.仿真结果证明了改进后算法的有效性,并且在能耗和网络生存时间上比LEACH有了提高.

WSN中LEACH路由协议簇头数优化研究

基于簇的LEACH路由协议在大规模无线传感器网络中有着良好的适应性,但在具体的网络分簇过程中由于每轮选择簇头节点时并没有考虑簇头节点的数量从而造成被选簇头节点的数量过多或过少,导致传感器节点因为不必要的数据融合或数据传输距离过长而消耗过多的能量,缩短了整个网络的寿命。为克服这些问题,提出了一种优化簇头数的方法,计算出一个区域内最佳的簇头数范围,通过控制簇头的数量来改善网络的性能。仿真结果证明该算法能够提高网络的整体性能,延长网络的生存时间。