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Copper Hydride-Catalyzed Conjugate Reduction-Aldol Addition Domino Reaction of α,β-Unsaturated Carboxylates with Ketones
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作者 Zengchang Li Lan Jiang +1 位作者 Zhengning Li Huiying Chen 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2013年第4期539-544,共6页
Copper hydride-catalyzed conjugate reduction-intermolecular aldol addition domino reactions were realized using α,β-unsaturated carboxylates as hydride acceptors and a silane as the reducing reagent. High diastereos... Copper hydride-catalyzed conjugate reduction-intermolecular aldol addition domino reactions were realized using α,β-unsaturated carboxylates as hydride acceptors and a silane as the reducing reagent. High diastereoselec- tivities were achieved with 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene as the ligand and tert-butyl acrylate as the hydride acceptor. 展开更多
关键词 REDUCTION aldol addition domino reaction copper hydride CATALYSIS
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Catalytic, Conjugate Reduction-Aldol Addition Reaction of β'Oxoal kyl α, β-Unsatu rated Carboxylates
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作者 郑爱军 姜岚 李争宁 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第10期2587-2590,共4页
Intramolecular conjugate reduction-aldol addition reactions of β'-oxoalkyl a,fl-unsaturated carboxylates were performed in the presence of copper catalysts generated in situ from copper salts, phosphine ligands and ... Intramolecular conjugate reduction-aldol addition reactions of β'-oxoalkyl a,fl-unsaturated carboxylates were performed in the presence of copper catalysts generated in situ from copper salts, phosphine ligands and silanes. Moderate to good yields and high diastereoselectivities were obtained in 15 min to 3 h using bis[(2-diphenyl- phosphino)phenyl] ether as the ligand. 展开更多
关键词 conjugate reduction aldol addition domino reaction copper hydride CATALYSIS
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Proline Catalyzed Asymmetric Aldol Reaction between Methyl Ketones and a-Ketoesters
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作者 王亚军 沈宗旋 +1 位作者 李斌 张雅文 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2006年第9期1196-1199,共4页
Direct asymmetric aldol additions of acetone/and butanone to a-ketoesters were achieved using L-proline as a chiral catalyst. Various optically active a-hydroxyesters were obtained in the yields of 43%-93% with enanti... Direct asymmetric aldol additions of acetone/and butanone to a-ketoesters were achieved using L-proline as a chiral catalyst. Various optically active a-hydroxyesters were obtained in the yields of 43%-93% with enantioselectivities up. to 81% e.e. The steric effect seems to be an important factor which influences the activity and the selectivity of the reaction. Acetone showed higher reactivity than butanone while the latter provided better enantioselectivity in some cases. 展开更多
关键词 PROLINE CATALYSIS ASYMMETRIC aldol addition α-ketoester
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