We present a systematic analysis of the exciton-recombination zone within all-quantum-dot （QD） multilayer films using sensing QD layers in QD-based light-emitting diodes （QLEDs）, and demonstrate the a11-QD multila...We present a systematic analysis of the exciton-recombination zone within all-quantum-dot （QD） multilayer films using sensing QD layers in QD-based light-emitting diodes （QLEDs）, and demonstrate the a11-QD multilayer films with different sequences of layers prepared by inserting a sensing blue QD layer denoted as B at various positions within four red QD multilayers denoted as R. We also use different hole transporting layers （PVK, CBP as well as poly-TPD） to prevent the formation of leakage current and to improve the luminance. The results show that the total EL emission is mostly at the fourth （60%） and fifth （40%） QD monolayers, adjacent to ITO. This presents both decreasing current density and increasing brightness with different hole transporting layers, thus resulting in more efficient performance.展开更多
为了改善全光波长转换器的转换性能进而提高输出信号质量,研究了波长转换器的Q因子特性。采用牛顿迭代法和四阶龙格库塔法解光场传输方程和跃迁速率方程,分析了输入信号光功率、脉冲宽度、最大模式增益和有源区长度4个因素对全光波长转...为了改善全光波长转换器的转换性能进而提高输出信号质量,研究了波长转换器的Q因子特性。采用牛顿迭代法和四阶龙格库塔法解光场传输方程和跃迁速率方程,分析了输入信号光功率、脉冲宽度、最大模式增益和有源区长度4个因素对全光波长转换器的Q因子特性的影响,并将得到的结果与相同条件下的输出消光比比较。结果表明:增大输入信号光功率,Q因子先增大后减小,并且在-12 d Bm时取得最大值8.819 d B;Q因子随着脉冲宽度的增加而不断下降;增大最大模式增益和有源区长度,Q因子增大。在实现波长转换的基础上,优化各参数数值,得到的Q因子达到16.680 d B,输出信号质量较好。要同时获得高的消光比和Q因子,提高输出信号的质量,必须选取适当的输入信号光功率、脉冲宽度、最大模式增益和有源区长度。展开更多
近年来,全无机铯铅卤素钙钛矿(CsPb X 3,X=Cl,Br,I)量子点由于其色纯度高、具有可调谐的发射波长(410~760 nm)、窄的半峰宽(12~42 nm)和较高的荧光量子产率(最高可达95%以上)以及可全溶液处理等优势而受到人们的高度关注,在显示和照明...近年来,全无机铯铅卤素钙钛矿(CsPb X 3,X=Cl,Br,I)量子点由于其色纯度高、具有可调谐的发射波长(410~760 nm)、窄的半峰宽(12~42 nm)和较高的荧光量子产率(最高可达95%以上)以及可全溶液处理等优势而受到人们的高度关注,在显示和照明领域有着较为广阔的应用前景。本文首先介绍了近年来发展起来的全无机钙钛矿量子点的液相合成方法,如高温热注射法、一步反应法、阴离子交换法和过饱和重结晶法等;其次介绍了全无机钙钛矿量子点的形貌、尺寸和晶型调控及材料组分、反应温度和杂质离子对其发光性能的影响,进而总结了无铅全无机钙钛矿量子点的研究进展;然后介绍了全无机钙钛矿量子点在发光二极管方面的应用进展;最后概述了全无机钙钛矿量子点在未来发展中存在的挑战和机遇。展开更多
To ensure the infiltration of spiro-OMeTAD into the quantum dot-sensitized photoanode and to consider the limit of the hole diffusion length in the spiro-OMeTAD layer, a rutile TiO2 nanorod array with a length of 200 ...To ensure the infiltration of spiro-OMeTAD into the quantum dot-sensitized photoanode and to consider the limit of the hole diffusion length in the spiro-OMeTAD layer, a rutile TiO2 nanorod array with a length of 200 nm, a diameter of 20 nm and an areal density of 720 ram 2 was successfully prepared using a hydrothermal method with an aqueous-grown solution of 38 mM titanium isopropoxide and 6 M hydrochloric acid at 170 ℃ for 75 min. PbS quantum dots were deposited by a spin coating-assisted successive ionic layer adsorption and reaction （spin-SILAR）, and all solid-state PbS quantum dot-sensitized TiO2 nanorod array solar cells were fabricated using spiro-OMeTAD as electrolytes. The results revealed that the average crystal size of PbS quantum dots was -78 nm using Pb（NO3）2 as the lead source and remain unchanged with the increase of the number of spin-SILAR cycles. The all solid-state PbS quantum dot-sensitized TiO2 nanorod array solar cells with spin-SILAR cycle numbers of 20, 30 and 40 achieved the photoelectric conversion efficiencies of 3.74%, 4.12% and 3.11%, respectively, under AM 1.5 G illumination （100 mW/cm2）.展开更多
基金Supported by the National High Technology Research and Development Program of China under Grant No 2013AA032205the National Natural Science Foundation of China under Grant Nos 11474018,51272022 and 61575019+1 种基金the Specialized Research Fund for the Doctoral Program of Higher Education of China under Grant Nos 20120009130005 and 20130009130001the Technological Development Contract under Grant No HETONG-150188-04E008
文摘We present a systematic analysis of the exciton-recombination zone within all-quantum-dot （QD） multilayer films using sensing QD layers in QD-based light-emitting diodes （QLEDs）, and demonstrate the a11-QD multilayer films with different sequences of layers prepared by inserting a sensing blue QD layer denoted as B at various positions within four red QD multilayers denoted as R. We also use different hole transporting layers （PVK, CBP as well as poly-TPD） to prevent the formation of leakage current and to improve the luminance. The results show that the total EL emission is mostly at the fourth （60%） and fifth （40%） QD monolayers, adjacent to ITO. This presents both decreasing current density and increasing brightness with different hole transporting layers, thus resulting in more efficient performance.
文摘为了改善全光波长转换器的转换性能进而提高输出信号质量,研究了波长转换器的Q因子特性。采用牛顿迭代法和四阶龙格库塔法解光场传输方程和跃迁速率方程,分析了输入信号光功率、脉冲宽度、最大模式增益和有源区长度4个因素对全光波长转换器的Q因子特性的影响,并将得到的结果与相同条件下的输出消光比比较。结果表明:增大输入信号光功率,Q因子先增大后减小,并且在-12 d Bm时取得最大值8.819 d B;Q因子随着脉冲宽度的增加而不断下降;增大最大模式增益和有源区长度,Q因子增大。在实现波长转换的基础上,优化各参数数值,得到的Q因子达到16.680 d B,输出信号质量较好。要同时获得高的消光比和Q因子,提高输出信号的质量,必须选取适当的输入信号光功率、脉冲宽度、最大模式增益和有源区长度。
文摘近年来,全无机铯铅卤素钙钛矿(CsPb X 3,X=Cl,Br,I)量子点由于其色纯度高、具有可调谐的发射波长(410~760 nm)、窄的半峰宽(12~42 nm)和较高的荧光量子产率(最高可达95%以上)以及可全溶液处理等优势而受到人们的高度关注,在显示和照明领域有着较为广阔的应用前景。本文首先介绍了近年来发展起来的全无机钙钛矿量子点的液相合成方法,如高温热注射法、一步反应法、阴离子交换法和过饱和重结晶法等;其次介绍了全无机钙钛矿量子点的形貌、尺寸和晶型调控及材料组分、反应温度和杂质离子对其发光性能的影响,进而总结了无铅全无机钙钛矿量子点的研究进展;然后介绍了全无机钙钛矿量子点在发光二极管方面的应用进展;最后概述了全无机钙钛矿量子点在未来发展中存在的挑战和机遇。
基金supported by the National Natural Science Foundation of China(51272061,51472071)
文摘To ensure the infiltration of spiro-OMeTAD into the quantum dot-sensitized photoanode and to consider the limit of the hole diffusion length in the spiro-OMeTAD layer, a rutile TiO2 nanorod array with a length of 200 nm, a diameter of 20 nm and an areal density of 720 ram 2 was successfully prepared using a hydrothermal method with an aqueous-grown solution of 38 mM titanium isopropoxide and 6 M hydrochloric acid at 170 ℃ for 75 min. PbS quantum dots were deposited by a spin coating-assisted successive ionic layer adsorption and reaction （spin-SILAR）, and all solid-state PbS quantum dot-sensitized TiO2 nanorod array solar cells were fabricated using spiro-OMeTAD as electrolytes. The results revealed that the average crystal size of PbS quantum dots was -78 nm using Pb（NO3）2 as the lead source and remain unchanged with the increase of the number of spin-SILAR cycles. The all solid-state PbS quantum dot-sensitized TiO2 nanorod array solar cells with spin-SILAR cycle numbers of 20, 30 and 40 achieved the photoelectric conversion efficiencies of 3.74%, 4.12% and 3.11%, respectively, under AM 1.5 G illumination （100 mW/cm2）.
