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Side-chain symmetry-breaking strategy on porphyrin donors enables high-efficiency binary all-small-molecule organic solar cells
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作者 Wentao Zou Xu Zhang +12 位作者 Haojiang Shen Wenqing Zhang Xinyue Jiang Liaohui Ni Can Shen Longlong Geng Xiaotao Hao Yingguo Yang Xunchang Wang Renqiang Yang Yanna Sun Yuanyuan Kan Ke Gao 《SusMat》 SCIE EI 2024年第3期204-213,共10页
Side-chain symmetry-breaking strategy plays an important role in developing photovoltaic materials for high-efficiency all-small-molecule organic solar cells(ASM OSCs).However,the power conversion efficiencies(PCEs)of... Side-chain symmetry-breaking strategy plays an important role in developing photovoltaic materials for high-efficiency all-small-molecule organic solar cells(ASM OSCs).However,the power conversion efficiencies(PCEs)of ASM OSCs still lag behind their polymer-based counterparts,which can be attributed to the difficulties in achieving favorable morphology.Herein,two asymmetric porphyrin-based donors named DAPor-DPP and DDPor-DPP were synthesized,presenting stronger intermolecular interaction and closer molecular stacking compared to the symmetric ZnP-TEH.The DAPor-DPP:6TIC blend afforded a favorablemorphologywith nanoscale phase separation and more ordered molecular packing,thus achievingmore efficient charge transportation and suppressed charge recombination.Consequently,the DAPor-DPP:6TIC-based device exhibited superior photovoltaic parameters,yielding a champion PCE of 16.62%higher than that of the DDPor-DPP-based device(14.96%).To our knowledge,16.62%can be ranked as one of the highest PCE values among the binary ASM OSC filed.Thiswork provides a prospective approach to address the challenge ofASM OSCs in improving film morphology and further achieving high efficiency via side-chain symmetry-breaking strategy,exhibiting great potential in constructing efficient ASM OSCs. 展开更多
关键词 all-small-molecule organic solar cells asymmetric side-chain engineering power conversion efficiency small molecule donors
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Enhanced Performance via π-Bridge Alteration of Porphyrin-Based Donors for All-Small-Molecule Organic Solar Cells 被引量:1
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作者 Haojiang Shen Yi Ren +7 位作者 Jianfeng Li Yixuan Xu Chenyang Han Wentao Zou Huajun Xu Yanna Sun Yuanyuan Kan Ke Gao 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2023年第6期644-650,共7页
All-small-molecule organic solar cells (ASM OSCs) are promising for commercial application due to the well-defined chemical structures, convenient purifying process and low batch-to-batch variation. However, the simil... All-small-molecule organic solar cells (ASM OSCs) are promising for commercial application due to the well-defined chemical structures, convenient purifying process and low batch-to-batch variation. However, the similarity of molecule structures between small molecule donors and acceptors makes a hard regulation of their blend morphology, which will limit the efficiency. 展开更多
关键词 all-small-molecule organic solar cells Porphyrin-based small molecule donor Binary device π-bridge engineering Morphology tuning
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P-doped all-small-molecule organic solar cells with power conversion efficiency of 17.73%
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作者 Wanying Feng Kangqiao Ma +10 位作者 Guangkun Song Tianyin Shao Huazhe Liang Shudi Lu Yu Chen Guankui Long Chenxi Li Xiangjian Wan Zhaoyang Yao Bin Kan Yongsheng Chen 《Science China Chemistry》 SCIE EI CAS CSCD 2023年第8期2371-2379,共9页
All-small organic solar cells(ASM OSCs)inherit the advantages of the distinct merits of small molecules,such as well-defined structures and less batch-to-batch variation.In comparison with the rapid development of pol... All-small organic solar cells(ASM OSCs)inherit the advantages of the distinct merits of small molecules,such as well-defined structures and less batch-to-batch variation.In comparison with the rapid development of polymer-based OSCs,more efforts are needed to devote to improving the performance of ASM OSCs to close the performance gap between ASM and polymer-based OSCs.Herein,a well-known p-dopant named fluoro-7,7,8,8-tetracyano-p-quinodimethane(FTCNQ)was introduced to a highefficiency system of HD-1:BTP-e C9,and a high power conversion efficiency(PCE)of 17.15%was achieved due to the improved electrical properties as well as better morphology of the active layer,supported by the observed higher fill factor(FF)of 79.45%and suppressed non-radiative recombination loss.Furthermore,combining with the further morphology optimization from solvent additive of 1-iodonaphthalene(IN)in the blend film,the HD-1:BTP-e C9-based device with the synergistic effects of both FTCNQ and IN demonstrates a remarkable PCE of 17.73%(certified as 17.49%),representing the best result of binary ASM OSCs to date. 展开更多
关键词 organic solar cells all-small-molecule power conversion efficiency p-dopant
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Step‑by‑Step Modulation of Crystalline Features and Exciton Kinetics for 19.2%Efficiency Ortho‑Xylene Processed Organic Solar Cells 被引量:1
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作者 Bosen Zou Weiwei Wu +10 位作者 Top Archie Dela Pena Ruijie Ma Yongmin Luo Yulong Hai Xiyun Xie Mingjie Li Zhenghui Luo Jiaying Wu Chuluo Yang Gang Li He Yan 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期258-272,共15页
With plenty of popular and effective ternary organic solar cells(OSCs)construction strategies proposed and applied,its power conversion efficiencies(PCEs)have come to a new level of over 19%in single-junction devices.... With plenty of popular and effective ternary organic solar cells(OSCs)construction strategies proposed and applied,its power conversion efficiencies(PCEs)have come to a new level of over 19%in single-junction devices.However,previous studies are heavily based in chloroform(CF)leaving behind substantial knowledge deficiencies in understanding the influence of solvent choice when introducing a third component.Herein,we present a case where a newly designed asymmetric small molecular acceptor using fluoro-methoxylated end-group modification strategy,named BTP-BO-3FO with enlarged bandgap,brings different morphological evolution and performance improvement effect on host system PM6:BTP-eC9,processed by CF and ortho-xylene(o-XY).With detailed analyses supported by a series of experiments,the best PCE of 19.24%for green solvent-processed OSCs is found to be a fruit of finely tuned crystalline ordering and general aggregation motif,which furthermore nourishes a favorable charge generation and recombination behavior.Likewise,over 19%PCE can be achieved by replacing spin-coating with blade coating for active layer deposition.This work focuses on understanding the commonly met yet frequently ignored issues when building ternary blends to demonstrate cutting-edge device performance,hence,will be instructive to other ternary OSC works in the future. 展开更多
关键词 organic solar cells Ternary design Solvent selection Flouro-methoxylated end group Morphological ordering
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Manipulating the Macroscopic and Microscopic Morphology of Large-Area Gravure-Printed ZnO Films for High-Performance Flexible Organic Solar Cells 被引量:1
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作者 Zhenguo Wang Jingbo Guo +6 位作者 Yaqin Pan Jin Fang Chao Gong Lixin Mo Qun Luo Jian Lin Changqi Ma 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期229-239,共11页
Gravure printing is a promising large-scale fabrication method for flexible organic solar cells(FOSCs)because it is compatible with two-dimension patternable roll-to-roll fabrication.However,the unsuitable rheological... Gravure printing is a promising large-scale fabrication method for flexible organic solar cells(FOSCs)because it is compatible with two-dimension patternable roll-to-roll fabrication.However,the unsuitable rheological property of ZnO nanoinks resulted in unevenness and looseness of the gravure-printed ZnO interfacial layer.Here we propose a strategy to manipulate the macroscopic and microscopic of the gravure-printed ZnO films through using mixed solvent and poly(vinylpyrrolidone)(PVP)additive.The regulation of drying speed effectively manipulates the droplets fusion and leveling process and eliminates the printing ribbing structure in the macroscopic morphology.The additive of PVP effectively regulates the rheological property and improves the microscopic compactness of the films.Following this method,large-area ZnO∶PVP films(28×9 cm^(2))with excellent uniformity,compactness,conductivity,and bending durability were fabricated.The power conversion efficiencies of FOSCs with gravure-printed AgNWs and ZnO∶PVP films reached 14.34%and 17.07%for the 1 cm^(2)PM6:Y6 and PM6∶L8-BO flexible devices.The efficiency of 17.07%is the highest value to date for the 1 cm^(2)FOSCs.The use of mixed solvent and PVP addition also significantly enlarged the printing window of ZnO ink,ensuring high-quality printed thin films with thicknesses varying from 30 to 100 nm. 展开更多
关键词 flexible organic solar cell gravure printing large-area flexible interfacial layer rheology properties zinc oxide
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H-and J-aggregation of conjugated small molecules in organic solar cells
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作者 Qiaoqiao Zhao Feng He 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期174-192,I0005,共20页
As H-and J-aggregation receive more and more attention in the research of organic solar cells(OSCs),especially in small molecular systems,deep understanding of aggregation behavior is needed to guide the design of con... As H-and J-aggregation receive more and more attention in the research of organic solar cells(OSCs),especially in small molecular systems,deep understanding of aggregation behavior is needed to guide the design of conjugated small molecular structure and the fabrication process of OSC device.For this end,this review is written.Here,the review firstly introduced the basic information about H-and J-aggregation of conjugated small molecules in OSCs.Then,the characteristics of H-and J-aggregation and the methods to identify them were summarized.Next,it reviewed the research progress of H-and J-aggregation of conjugated small molecules in OSCs,including the factors influencing H-and J-aggregation in thin film and the effects of H-and J-aggregation on OPV performance. 展开更多
关键词 H-AGGREGATION J-AGGREGATION organic solar cells Small molecules EFFICIENCY STABILITY
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End-group modulation of phenazine based non-fullerene acceptors for efficient organic solar cells with high open-circuit voltage
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作者 Yahui Zhang Yafeng Li +7 位作者 Ruixiang Peng Yi Qiu Jingyu Shi Zhenyu Chen Jinfeng Ge Cuifen Zhang Zheng Tang Ziyi Ge 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期461-468,I0011,共9页
Phenazine-based non-fullerene acceptors(NFAs)have demonstrated great potential in improving the power conversion efficiency(PCE)of organic solar cells(OSCs).Halogenation is known to be an effective strategy for increa... Phenazine-based non-fullerene acceptors(NFAs)have demonstrated great potential in improving the power conversion efficiency(PCE)of organic solar cells(OSCs).Halogenation is known to be an effective strategy for increasing optical absorption,refining energy levels,and improving molecular packing in organic semiconductors.Herein,a series of NFAs(Pz IC-4H,Pz IC-4F,Pz IC-4Cl,Pz IC-2Br)with phenazine as the central core and with/without halogen-substituted(dicyanomethylidene)-indan-1-one(IC)as the electron-accepting end group were synthesized,and the effect of end group matched phenazine central unit on the photovoltaic performance was systematically studied.Synergetic photophysical and morphological analyses revealed that the PM6:Pz IC-4F blend involves efficient exciton dissociation,higher charge collection and transfer rates,better crystallinity,and optimal phase separation.Therefore,OSCs based on PM6:Pz IC-4F as the active layer exhibited a PCE of 16.48%with an open circuit voltage(Voc)and energy loss of 0.880 V and 0.53 e V,respectively.Accordingly,this work demonstrated a promising approach by designing phenazine-based NFAs for achieving high-performance OSCs. 展开更多
关键词 organic solar cells Non-fullerene acceptor PHENAZINE Central core End group
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Recent progress of hybrid cathode interface layer for organic solar cells
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作者 Jianru Wang Dan Zhou +9 位作者 Zhentian Xu Yujie Pu Senmei Lan Fang Wang Feiyan Wu Bin Hu Yongfen Tong Ruizhi Lv Honglin Chu Lie Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期383-406,共24页
Organic solar cells(OSCs)have gained conspicuous progress during the past few decades due to the development of materials and upgrading of the device structure.The power conversion efficiency(PCE)of the single-junctio... Organic solar cells(OSCs)have gained conspicuous progress during the past few decades due to the development of materials and upgrading of the device structure.The power conversion efficiency(PCE)of the single-junction device had surpassed 19%.The cathode interface layer(CIL),by optimizing the connection between the active layer and the cathode electrode,has become a momentous part to strengthen the performances of the OSCs.Simultaneously,CIL is also indispensable to illustrating the working mechanism of OSCs and enhancing the stability of the OSCs.In this essay,hybrid CILs in OSCs have been summarized.Firstly,the advancement and operating mechanism of OSCs,and the effects and relevant design rules of CIL are briefly concluded;secondly,the significant influence of CIL on enhancing the stability and PCE of OSCs is presented;thirdly,the characteristics of organic hybrid CIL and organic-inorganic hybrid CIL are introduced.Finally,the conclusion and outlook of CIL are summarized. 展开更多
关键词 organic solar cells Theoperation mechanism organic hybrid cathode interface layer organic-inorganic hybrid CIL
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Rational molecular engineering towards efficient heterojunction solar cells based on organic molecular acceptors
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作者 张凯彦 宋朋 +1 位作者 马凤才 李源作 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期575-587,共13页
The selection of photoactive layer materials for organic solar cells(OSCs) is essential for the photoelectric conversion process.It is well known that chlorophyll is an abundant pigment in nature and is extremely valu... The selection of photoactive layer materials for organic solar cells(OSCs) is essential for the photoelectric conversion process.It is well known that chlorophyll is an abundant pigment in nature and is extremely valuable for photosynthesis.However,there is little research on how to improve the efficiency of chlorophyll-based OSCs by matching chlorophyll derivatives with excellent non-fullerene acceptors to form heterojunctions.Therefore in this study we utilize a chlorophyll derivative,Ce_(6)Me_(3),as a donor material and investigate the performance of its heterojunction with acceptor materials.Through density functional theory,the photoelectric performances of acceptors,i ncluding the fullerene derivative PC_(71)BM and the terminal halogenated non-fullerene DTBCIC series,are compared in detail.It is found that DTBCIC-C1 has better planarity,light absorption,electron affinity,charge reorganization energy and charge mobility than others.Ce_(6)Me_(3) has good energy level matching and absorption spectral complementarity with the investigated acceptor molecules and also shows good electron donor properties.Furthermore,the designed Ce_(6)Me_(3)/DTBCIC interfaces have improved charge separation and reorganization rates(K_(CS)/K_(CR)) compared with the Ce_(6)Me_(3)/PC_(71)BM interface.This research provides a theoretical basis for the design of photoactive layer materials for chlorophyll-based OSCs. 展开更多
关键词 organic solar cells density functional theory chlorophyll derivative non-fullerene acceptors
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Molecular Structure Tailoring of Organic Spacers for High‑Performance Ruddlesden–Popper Perovskite Solar Cells
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作者 Pengyun Liu Xuejin Li +6 位作者 Tonghui Cai Wei Xing Naitao Yang Hamidreza Arandiyan Zongping Shao Shaobin Wang Shaomin Liu 《Nano-Micro Letters》 SCIE EI CAS 2025年第2期314-357,共44页
Layer-structured Ruddlesden–Popper(RP)perovskites(RPPs)with decent stability have captured the imagination of the photovoltaic research community and bring hope for boosting the development of perovskite solar cell(P... Layer-structured Ruddlesden–Popper(RP)perovskites(RPPs)with decent stability have captured the imagination of the photovoltaic research community and bring hope for boosting the development of perovskite solar cell(PSC)technology.However,two-dimensional(2D)or quasi-2D RP PSCs are encountered with some challenges of the large exciton binding energy,blocked charge transport and poor film quality,which restrict their photovoltaic performance.Fortunately,these issues can be readily resolved by rationally designing spacer cations of RPPs.This review mainly focuses on how to design the molecular structures of organic spacers and aims to endow RPPs with outstanding photovoltaic applications.We firstly elucidated the important roles of organic spacers in impacting crystallization kinetics,charge transporting ability and stability of RPPs.Then we brought three aspects to attention for designing organic spacers.Finally,we presented the specific molecular structure design strategies for organic spacers of RPPs aiming to improve photovoltaic performance of RP PSCs.These proposed strategies in this review will provide new avenues to develop novel organic spacers for RPPs and advance the development of RPP photovoltaic technology for future applications. 展开更多
关键词 Ruddlesden-Popper perovskites Low-dimensional perovskite solar cells organic spacers Molecular structure Design strategies
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Highly efficient and stable organic solar cells with SnO_(2)electron transport layer enabled by UV-curing acrylate oligomers
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作者 Mwende Mbilo Du Hyeon Ryu +7 位作者 Seungjin Lee Muhammad Haris Julius Mwakondo Mwabora Robinson Juma Musembi Hang Ken Lee Sang Kyu Lee Chang Eun Song Won Suk Shin 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期124-131,共8页
The interfaces between the inorganic metal oxide and organic photoactive layer are of outmost importance for efficiency and stability in organic solar cells(OSCs).Tin oxide(SnO_(2))is one of the promising candidates f... The interfaces between the inorganic metal oxide and organic photoactive layer are of outmost importance for efficiency and stability in organic solar cells(OSCs).Tin oxide(SnO_(2))is one of the promising candidates for the electron transport layer(ETL)in high-performance inverted OSCs.When a solution-processed SnO_(2)ETL is employed,however,the presence of interfacial defects and suboptimal interfacial contact can lower the power conversion efficiency(PCE)and operational stability of OSCs.Herein,highly efficient and stable inverted OSCs by modification of the SnO_(2)surface with ultraviolet(UV)-curable acrylate oligomers(SAR and OCS)are demonstrated.The highest PCEs of 16.6%and 17.0%are achieved in PM6:Y6-BO OSCs with the SAR and OCS,respectively,outperforming a device with a bare SnO_(2)ETL(PCE 13.8%).The remarkable enhancement of PCEs is attributed to the optimized interfacial contact,leading to mitigated surface defects.More strikingly,improved light-soaking and thermal stability strongly correlated with the interfacial defects are demonstrated for OSCs based on SnO_(2)/UV cross-linked resins compared to OSCs utilizing bare SnO_(2).We believe that UV cross-linking oligomers will play a key role as interfacial modifiers in the future fabrication of large-area and flexible OSCs with high efficiency and stability. 展开更多
关键词 organic solar cells SnO_(2) Surface defects Ultraviolet resins Stability Cross-linking oligomers Non-halogenated solvent
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Improved Efficiency and Stability of Organic Solar Cells by Interface Modification Using Atomic Layer Deposition of Ultrathin Aluminum Oxide
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作者 Ai Lan Yiqun Li +8 位作者 Huiwen Zhu Jintao Zhu Hong Lu Hainam Do Yifan Lv Yonghua Chen Zhikuan Chen Fei Chen Wei Huang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期282-290,共9页
The interfacial contacts between the electron transporting layers(ETLs)and the photoactive layers are crucial to device performance and stability for OSCs with inverted architecture.Herein,atomic layer deposition(ALD)... The interfacial contacts between the electron transporting layers(ETLs)and the photoactive layers are crucial to device performance and stability for OSCs with inverted architecture.Herein,atomic layer deposition(ALD)fabricated ultrathin Al_(2)O_(3)layers are applied to modify the ETLs/active blends(PM6:BTP-BO-4F)interfaces of OSCs,thus improving device performance.The ALD-Al_(2)O_(3)thin layers on ZnO significantly improved its surface morphology,which led to the decreased work function of ZnO and reduced recombination losses in devices.The simultaneous increase in open-circuit voltage(V_(OC)),short-circuit current density(J_(SC))and fill factor(FF)were achieved for the OSCs incorporated with ALD-Al_(2)O_(3)interlayers of a certain thickness,which produced a maximum PCE of 16.61%.Moreover,the ALD-Al_(2)O_(3)interlayers had significantly enhanced device stability by suppressing degradation of the photoactive layers induced by the photocatalytic activity of ZnO and passivating surface defects of ZnO that may play the role of active sites for the adsorption of oxygen and moisture. 展开更多
关键词 atomic layer deposition interface modification organic solar cells STABILITY
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Enhancing efficiency and stability of organic solar cells through a simplified four-step synthesis of fully non-fused ring electron acceptor
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作者 Chenyang Han Huanhuan Gao +7 位作者 Yanna Sun Yuanyuan Kan Zhaozhao Bi Wei Ma Yani Zhang Juan Antonio Zapien Yingguo Yang Ke Gao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期601-608,I0015,共9页
Design and synthesis of superior cost-effective non-fullerene acceptors(NFAs)are still big challenges for facilitating the commercialization of organic solar cells(OSCs),yet to be realized.Herein,two medium bandgap fu... Design and synthesis of superior cost-effective non-fullerene acceptors(NFAs)are still big challenges for facilitating the commercialization of organic solar cells(OSCs),yet to be realized.Herein,two medium bandgap fully non-fused ring electron acceptors(NFREAs,medium bandgap,i,e.,1,3-1,8 eV),namely PTR-2Cl and PTR-4Cl are synthesized with only four steps by using intramolecular noncovalent interaction central core,structured alkyl side chain orientation linking units and flanking with different electron-withdrawing end group.Among them,PTR-4C1 exhibits increased average electrostatic potential(ESP)difference with polymer donor,enhanced crystallinity and compactπ-πstacking compared with the control molecule PTR-2CI.As a result,the PTR-4Cl-based OSC achieved an impressive power conversion efficiency(PCE)of 14.72%,with a much higher open-circuit voltage(V_(OC))of 0.953 V and significantly improved fill factor(FF)of 0.758,demonstrating one of the best acceptor material in the top-performing fully NFREA-based OSCs with both high PCE and V_(OC).Notably,PTR-4Cl-based cells maintain a good T_80lifetime of its initial PCE after over 936 h under a continuous thermal annealing treatment and over1300 h T_(80)lifetime without encapsulation.This work provides a cost-effective design strategy for NFREAs on obtaining high V_(OC),efficient exciton dissociation,and ordered molecular packing and thus high-efficiency and stable OSCs. 展开更多
关键词 organic solar cells Fully non-fused ring acceptors End group engineering Morphology regulation High efficiency
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An Unprecedented Efficiency with Approaching 21%Enabled by Additive‑Assisted Layer‑by‑Layer Processing in Organic Solar Cells
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作者 Shuai Xu Youdi Zhang +6 位作者 Yanna Sun Pei Cheng Zhaoyang Yao Ning Li Long Ye Lijian Zuo Ke Gao 《Nano-Micro Letters》 SCIE EI CAS 2025年第2期372-375,共4页
Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network act... Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer deposition.This optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture capability.This approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs. 展开更多
关键词 organic solar cells Additive-assisted layer-by-layer processing Three-dimensional fibril morphology Bulk p-i-n structure Optical management
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π-Extended giant dimeric acceptor as a third component enables highly efficient ternary organic solar cells with efficiency over 19.2%
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作者 Mengran Peng Haotian Wu +7 位作者 Liming Wu Jianhua Chen Ruijie Ma Qunping Fan Hua Tan Weiguo Zhu Hongxiang Li Junqiao Ding 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期263-270,I0006,共9页
Ternary strategy with a suitable third component is a successful strategy to improve the photovoltaic performance of organic solar cells(OSCs).Very recently,Y-series based giant molecule acceptors or oligomerized acce... Ternary strategy with a suitable third component is a successful strategy to improve the photovoltaic performance of organic solar cells(OSCs).Very recently,Y-series based giant molecule acceptors or oligomerized acceptors have emerged as promising materials for achieving highly efficient and stable binary OSCs,while application as third component for ternary OSCs is limited.Here a novelπ-extended giant dimeric acceptor,GDF,is developed based on central Y series core fusion and rigid BDT as linker,and then incorporated into the state-of-the-art PM1:PC6 system to construct ternary OSCs.The GDF has a near planar backbone,resulting in increasedπ-conjugation,excellent crystallinity,and good electron transport capacity.When GDF is introduced into the PM1:PC6 system,it ensues in a cascade like the lowest unoccupied molecular orbitals(LUMO)energy level alignment,a complementary absorption band with PM1 and PC6,higher and balanced hole and electron mobility,slightly smaller domain size,and a higher exciton dissociation probability for PM1:PC6:GDF(1:1.1:0.1)blend film.As a consequence,the PM1:PC6:GDF(1:1.1:0.1)ternary OSC achieves a champion PCE of 19.22%,with a significantly higher open-circuit voltage and short-circuit current density,compared to 18.45%for the PM1:PC6(1:1.2)binary OSC.Our findings show that employing aπ-extended giant dimeric acceptor as a third component significantly improves the photovoltaic performance of ternary OSCs. 展开更多
关键词 Giant dimeric acceptor Third component Ternary organic solar cells
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Alkyl chain modulation of asymmetric hexacyclic fused acceptor synergistically with wide bandgap third component for high efficiency ternary organic solar cells
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作者 Shufang Li Huilan Guan +4 位作者 Can Zhu Chaoyuan Sun Qingya Wei Jun Yuan Yingping Zou 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第7期1713-1719,共7页
Herein,two asymmetric hexacyclic fused small molecule acceptors(SMAs),namely BP4F-HU and BP4F-UU,were synthesized.The elongated outside chains in the BP4F-UU molecule played a crucial role in optimizing the morphology... Herein,two asymmetric hexacyclic fused small molecule acceptors(SMAs),namely BP4F-HU and BP4F-UU,were synthesized.The elongated outside chains in the BP4F-UU molecule played a crucial role in optimizing the morphology of blend film,thereby improving charge mobility and reducing energy loss within the corresponding film.Notably,the PM6:BP4F-UU device exhibited a higher open-circuit voltage(V_(oc))of 0.878 V compared to the PM6:BP4F-HU device with a V_(oc)of 0.863 V.Further,a new wide bandgap SMA named BTP-TA was designed and synthesized as the third component to the PM6:BP4F-UU host binary devices,which showed an ideal complementary absorption spectrum in PM6:BP4F-UU system.In addition,BTP-TA can achieve efficient intermolecular energy transfer to BP4F-UU by fluorescence resonance energy transfer(FRET)pathway,due to the good overlap between the photoluminescence(PL)spectrum of BTP-TA and the absorption region of BP4F-UU.Consequently,ternary devices with 15wt%BTP-TA exhibits broader photon utilization,optimal blend morphology,and reduced charge recombination compared to the corresponding binary devices.Consequently,PM6:BP4F-UU:BTP-TA ternary device achieved an optimal power conversion efficiency(PCE)of 17.83%with simultaneously increased V_(oc)of 0.905 V,short-circuit current density(J_(sc))of 26.14 mA/cm^(2),and fill factor(FF)of 75.38%. 展开更多
关键词 asymmetric hexacyclic acceptor outside chain wide bandgap acceptor ternary organic solar cells
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Molecular packing tuning via chlorinated end group enables efficient binary organic solar cells over 18.5%
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作者 Yafeng Li Zhenyu Chen +1 位作者 Xingzheng Yan Ziyi Ge 《Carbon Energy》 SCIE EI CAS CSCD 2024年第3期196-203,共8页
Designing novel nonfullerene acceptors(NFAs)is of vital importance for the development of organic solar cells(OSC).Modification on the side chain and end group are two powerful tools to construct efficient NFAs.Here,b... Designing novel nonfullerene acceptors(NFAs)is of vital importance for the development of organic solar cells(OSC).Modification on the side chain and end group are two powerful tools to construct efficient NFAs.Here,based on the high-performance L8BO,we selected 3-ethylheptyl to substitute the inner chain of 2-ethylhexyl,obtaining the backbone of BON3.Then we introduced different halogen atoms of fluorine and chlorine on 2-(3-oxo-2,3-dihydro-1Hinden-1-ylidene)malononitrile end group(EG)to construct efficient NFAs named BON3-F and BON3-Cl,respectively.Polymer donor D18 was chosen to combine with two novel NFAs to construct OSC devices.Impressively,D18:BON3-Cl-based device shows a remarkable power conversion efficiency(PCE)of 18.57%,with a high open-circuit voltage(V_(OC))of 0.907 V and an excellent fill factor(FF)of 80.44%,which is one of the highest binary PCE of devices based on D18 as the donor.However,BON3-F-based device shows a relatively lower PCE of 17.79%with a decreased FF of 79.05%.The better photovoltaic performance is mainly attributed to the red-shifted absorption,higher electron and hole mobilities,reduced charge recombination,and enhanced molecular packing in the D18:BON3-Cl films.Also,we performed stability tests on two binary systems;the D18:BON3-Cl and D18:BON3-F devices maintain 88.1%and 85.5%of their initial efficiencies after 169 h of storage at 85°C in an N2-filled glove box,respectively.Our work demonstrates the importance of selecting halogen atoms on EG and provides an efficient binary system of D18:BON3-Cl for further improvement of PCE. 展开更多
关键词 binary organic solar cell chlorinated end group molecular packing
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Synergistic high efficiency and low energy loss of all-small-molecule organic solar cells based on benzotriazole-basedπ-bridge unit 被引量:2
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作者 Jing Guo Ke Hu +6 位作者 Beibei Qiu Dengchen Yang Xiaojun Li Jinyuan Zhang Lei Meng Zhanjun Zhang Yongfang Li 《Science China Materials》 SCIE EI CAS CSCD 2022年第12期3382-3391,共10页
Reducing energy loss(V_(loss))is one of the most crucial challenges in organic photovoltaic cells.The V_(loss),determined by the differences between the optical band gap(E_(g))of the active layer material and the open... Reducing energy loss(V_(loss))is one of the most crucial challenges in organic photovoltaic cells.The V_(loss),determined by the differences between the optical band gap(E_(g))of the active layer material and the open-circuit voltage(V_(oc))of the device,is generally alleviated by lowering the energy difference between the lowest unoccupied molecular orbital(LUMO)and highest occupied molecular orbital(HOMO)level of the donor(D)and acceptor(A).In this work,we synthesized two A-π-D-π-A-type small-molecule donors(SMDs)SM-benzotriazole(BTz)-1 and SM-BTz-2 by introducing a BTzπ-bridge unit and terminal regulation.The BTzπ-bridge unit significantly lowers the HOMO energy level of SMDs,resulting in high V_(oc)and high mobility,achieving a balance of low energy loss(<0.5 eV)and high efficiency.Ultimately,the organic solar cells based on SM-BTz-2 as the donor and Y6 as the acceptor obtain a high V_(oc)of 0.91 V,J_(sc) of 22.8 mA cm^(−2),fill factor of 68%,and power conversion efficiency(PCE)of 14.12%,which is one of the highest efficiencies based on the SMDs with triazoleπ-bridges to date.What’s more,the BTzπ-bridge unit is a potential unit that can improve mobility and reduce energy loss. 展开更多
关键词 small-molecule donor materials all-small-molecule organic solar cells benzotriazoleπ-bridge energy loss
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Fluorination-substitution effect on all-small-molecule organic solar cells 被引量:3
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作者 Qiong Wu Dan Deng +7 位作者 Jianqi Zhang Wenjun Zou Yang Yang Zhen Wang Huan Li Ruimin Zhou Kun Lu Zhixiang Wei 《Science China Chemistry》 SCIE EI CAS CSCD 2019年第7期837-844,共8页
Due to the strong crystallinity and anisotropy of small molecules, matched molecular photoelectric properties and morphologies between small molecules and non-fullerene acceptors are especially important in all-small-... Due to the strong crystallinity and anisotropy of small molecules, matched molecular photoelectric properties and morphologies between small molecules and non-fullerene acceptors are especially important in all-small-molecule organic solar cells(OSCs).Introducing fluorine atoms has been proved as an effective strategy to achieve a high device performance through tuning molecular energy levels, absorption and assembly properties. Herein, we designed a novel benzodithiophene-based small molecule donor BDTF-CA with deep highest occupied molecular orbital(HOMO) energy level. All-small-molecule OSCs were fabricated by combing non-fullerene acceptor IDIC with different fluorine-atom numbers. Two or four fluorine atoms were introduced to the end-capped acceptor of IDIC, which are named as IDIC-2 F and IDIC-4 F, respectively. With the increase of fluorination from IDIC to IDIC-4 F, the open circuit voltage(Voc) of the devices decreased, while hole and electron mobilities of the active layers increased by one order of magnitude. Contributed to the most balanced Voc, short-circuit current(Jsc) and fill factor(FF), the device based on BDTF-CA/IDIC-2 F achieved the highest power conversion efficiency of 9.11%. 展开更多
关键词 organic solar cells all-small-molecule FLUORINATION BLEND morphology energy LEVELS
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15.3% efficiency all-small-molecule organic solar cells enabled by symmetric phenyl substitution 被引量:5
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作者 Jinzhao Qin Cunbin An +13 位作者 Jianqi Zhang Kangqiao Ma Yang Yang Tao Zhang Sunsun Li Kaihu Xian Yong Cui Yabing Tang Wei Ma Huifeng Yao Shaoqing Zhang Bowei Xu Chang He Jianhui Hou 《Science China Materials》 SCIE EI CSCD 2020年第7期1142-1150,共9页
Synergistic optimization of donor-acceptor blend morphologyis a hurdle in the path of realizing efficient non-fullerene small-molecule organic solar cells(NFSMOSCs)due to the anisotropic conjugated backbones of both d... Synergistic optimization of donor-acceptor blend morphologyis a hurdle in the path of realizing efficient non-fullerene small-molecule organic solar cells(NFSMOSCs)due to the anisotropic conjugated backbones of both donor and acceptor.Therefore,developing a facile molecular design strategy to effectively regulate the crystalline properties of photoactive materials,and thus,enable the optimization of blend morphology is of vital importance.In this study,a new donor molecule B1,comprising phenyl-substituted benzodithiophene(BDT)central unit,exhibits strong interaction with the non-fullerene acceptor BO-4 Cl in comparison with its corresponding thiophene-substituted BDT-based material,BTR.As a result,the B1 is affected and induced from an edgeon to a face-on orientation by the acceptor,while the BTR and the acceptor behave individually for the similar molecular orientation in pristine and blend films according to grazing incidence wide angle X-ray scattering results.It means the donor-acceptor blend morphology is synergistically optimized in the B1 system,and the B1:BO-4 Cl-based devices achieve an outstanding power conversion efficiency(PCE)of 15.3%,further certified to be 15.1%by the National Institute of Metrology,China.Our results demonstrate a simple and effective strategy to improve the crystalline properties of the donor molecule as well as synergistically optimize the morphology of the all-small-molecule system,leading to the high-performance NFSM-OSCs. 展开更多
关键词 organic solar cells all-small-molecule non-fullerene CRYSTALLINITY intermolecular interaction
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