A highly enantioselective allylic substitution reaction of anthrones with aromatic or aliphatic allyl carbonates was realized by using iridium catalyst prepared from [Ir（COD）CI]2 and BHPphos. Substituted 10-allylant...A highly enantioselective allylic substitution reaction of anthrones with aromatic or aliphatic allyl carbonates was realized by using iridium catalyst prepared from [Ir（COD）CI]2 and BHPphos. Substituted 10-allylanthrones were obtained in excellent yields and with excellent enantioselectivity and regioselectivity （up to 98% yield, 99700 ee） under mild conditions.展开更多
基金the National Basic Research Program of China (973 Program, No. 2015CB856600)National Natural Science Foundation of China (Nos.21572252, 21332009, 21421091) for generous financial support
文摘A highly enantioselective allylic substitution reaction of anthrones with aromatic or aliphatic allyl carbonates was realized by using iridium catalyst prepared from [Ir（COD）CI]2 and BHPphos. Substituted 10-allylanthrones were obtained in excellent yields and with excellent enantioselectivity and regioselectivity （up to 98% yield, 99700 ee） under mild conditions.
