Effectiveness of Sodium Silicate on the Corrosion Protection of AA7075-T6 Aluminium Alloy in Sodium Chloride Solution

The influence of sodium silicate on the corrosion behaviour of aluminium alloy 7075-T6 in 0.1 M sodium chloride solution was studied by open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) techniques. Scanning electron microscopy (SEM) was used to characterize the AA7075-T6 surface. Silicate can significantly reduce corrosion deterioration and the inhibition efficiency increases with the concentration of Na2SiO3. The corrosion inhibition mechanism involves the formation of a protective film over the alloy surface by adsorption of aluminosilicate anions from solution, as has also been suggested by others in literature.

CORROSION BEHAVIOR OF A ZIRCONIUM-TITANIUM BASED PHOSPHONIC ACID CONVERSION COATING ON AA6061 ALUMINIUM ALLOY

The conversion coating was formed by dipping AA6061 in a fluorotitanate/zirconate acid and amino trimethylene phosphonic acid （ATMP） solution at room temperature. The formation process and the anti-corrosion performance of the conversion coating were investigated using electrochemical test and salt spray test （SST）, respectively. The electrochemical test shows that the Zr/Ti and ATMP coating improves the corrosion resistance of AA6061 as good as the chromate （VI） coating. But the results of SST show that the corrosion resistance of Zr/Ti and ATMP coating is not as good as the chromate （VI） coating. The corrosion area is less than 2% after 72 h.

DEFORMATION BEHAVIOR OF AA6063 ALUMINIUM ALLOY AFTER REMOVING FRICTION EFFECT UNDER HOT WORKING CONDITIONS

The hot deformation behavior of AA6063 aluminium alloy has been investigated by means of compression tests at temperatures between 400 and 520℃, and strain rates ranging from 2.5 to 10 s^-1. Owing to the barreling, the theoretical model on the basis of Hills general method is used to calculate the flow stress of a cylindrical specimen under uniaxial simple compression so as to consider the friction effect at the die-specimen interface. A method of evaluating the friction coefficient by combining compression tests with the finite element method is presented. The real flow behavior of AA6063 aluminium alloy can be described with sinh-Arrhenius equation. The hot deformation activation energy Q derived from the corrected stress and strain data is 232. 350 kJ/mol.

Experimental and numerical investigation on under-water friction stir welding of armour grade AA2519-T87 aluminium alloy

Friction stir welding(FSW) is a promising welding process that can join age hardenable aluminium alloys with high joint efficiency. However,the thermal cycles experienced by the material to be joined during FSW resulted in the deterioration of mechanical properties due to the coarsening and dissolution of strengthening precipitates in the thermo-mechanical affected zone(TMAZ) and heat affected zone(HAZ). Under water friction stir welding(UWFSW) is a variant of FSW process which can maintain low heat input as well as constant heat input along the weld line. The heat conduction and dissipation during UWFSW controls the width of TMAZ and HAZ and also improves the joint properties. In this investigation, an attempt has been made to evaluate the mechanical properties and microstructural characteristics of AA2519-T87 aluminium alloy joints made by FSW and UWFSW processes. Finite element analysis has been used to estimate the temperature distribution and width of TMAZ region in both the joints and the results have been compared with experimental results and subsequently correlated with mechanical properties.? 2016 China Ordnance Society. Production and hosting by Elsevier B.V. All rights reserved.

Mechanical and metallurgical properties of friction stir welded dissimilar joints of AZ91 magnesium alloy and AA 6082-T6 aluminium alloy

In the present research work,AZ91 magnesium alloy and AA6082-T6 aluminium alloy were joined by friction stir welding process.The comparison of microstructure and mechanical properties between different joints by varying the different materials on advance and retreating sides were mainly studied.Four different welds have been prepared to find the material mixing between the similar and dissimilar joints.The joint interfaces of the welds have been investigated by employing an optical microscope and scanning electron microscope.When Mg was placed on advancing side(AS),more aluminium content was soluble in nugget zone than the case where Mg was placed on the retreating side(RS).Thin intermetallic layer in the joint interface of Mg/Al and thick intermetallic layer with poor adhesion of the aluminium and magnesium have been observed in the dissimilar joints varying the sides.The highest UTS of 172.3 MPa was found for Mg-Al when Mg was placed on AS and lower UTS of 156.25 MPa was obtained when Mg was placed on RS.Hardness of 86 Hv and 89 Hv were observed in the Stir zone for the dissimilar AZ91 Mg alloy and AA6082-T6 Al alloy when AZ91Mg alloy was placed on the AS and on the RS respectively.Fractography was also carried out to find the mode of failure.

Effect of Process Parameters on Tensile Strength of Friction Stir Welded Cast LM6 Aluminium Alloy Joints

This paper reports the effect of friction stir welding （FSW） process parameters on tensile strength of cast LM6 aluminium alloy. Joints were made by using different combinations of tool rotation speed, welding speed and axial force each at four levels. The quality of weld zone was investigated using macrostructure and microstructure analysis. Tensile strength of the joints were evaluated and correlated with the weld zone hardness and microstructure. The joint fabricated using a rotational speed of 900 r/min, a welding speed of 75 mm/min and an axial force of 3 kN showed superior tensile strength compared with other joints. The tensile strength and microhardness of the welded joints for the optimum conditions were 166 MPa and 64.8 Hv respectively.

Effect of Post-weld Heat Treatment on Microstructure and Mechanical Properties of Friction Stir Welded SSM7075 Aluminium Alloy

7XXX series aluminium alloys generally present low weldability by fusion welding methods because of the sensitivity to weld solidification cracking, vaporization of strengthening alloys and other defects in the fusion zone. Friction stir welding（FSW） can be deployed successfully with aluminium alloys. We presented the effect of post-weld heat treatment（PWHT） on the microstructure and mechanical properties of SSM7075 joints. Semi solid plates were butt-welded by FSW at a rotation speed of 1110 r/min, welding speeds of 70 and 110 mm/min. Solution treatment, artificial aging, and T6（solution treatment and artificial aging combined） were applied to the welded joints, each with three samples. It was found that the T6 joints at the speed of 70 mm/min yielded the highest tensile strength of 459.23 MPa. This condition best enhanced the mechanical properties of FSW SSM7075 aluminium alloy joints.

EFFECT OF ELECTRIC CURRENT PULSE ON SUPERPLASTICITY OF ALUMINIUM ALLOY 7475

The superplastic deformation of aluminium alloy 7475 applied electric current pulse has been studied.The results presented that applying a high density current pulse raises both the elongation rate and the m value,and makes supperior superplastic properties at high strain rate of 10^(-2)s^(-1),the optimum deformation temperature could move from 530℃to 480~510℃,TEM observation showed the superplastic deformation of the alloy is the results of grain boundary slips and dislocation slips in grains under function of the electron wind;the intergranular tear is a main behavior of fracture of the alloy.

Microstructure and Mechanical Property of 2024 Aluminium Alloy Prepared by Rapid Solidification and Mechanical Milling

Rapidly solidified 2024 aluminium alloy powders were mechanically milled, then consolidated to bulk form. The microstructural changes of the powders in mechanical milling (MM) and consolidation process were characterized by X-ray diffraction analyses and transmission electron microscopy observations. The results showed that mechanical milling reduced the grain size to nanometer, dissolved the Al2Cu intermetallic compound into the aluminium matrix and produced an aluminium supersaturated solid solution. During consolidation process. the grain size increased to submicrometer, and the Al2Cu and Al2(Cu, Mg, Si, Fe, Mn) compounds precipitated owing to heating. Increasing consolidation temperature and time results in obvious grain growth and coarsening of second phase particles. The tensile yield strength of the consolidated alloy with submicrometer size grains increases with decreasing grain size, and it follows the famous HallPetch relation

Mechanism of Nickel-Aluminium Alloy Electroplating

The effect of operating conditions on the aluminium content of Ni-Al alloy deposit and the catalytic function of NaF on electrodeposition in the nonaqueous solution containing aluminium are investigated.The results indicate that the plated aluminuim content will be increased with the rise of current density in a given range.When the current density is 2.5A/dm 2,nickle aluminium alloy containing 13.1 wt% aluminium will be deposited.The plated aluminium content will be increased by 2wt% as 0.1mol/L NaF is added to the bath.

THE PRODUCTION OF FOAM ALUMINIUM ALLOY BY LOW-PRESSURE INFILTRATION METHOD

The influence of technical parameters on the infiltrating height of the moltenmetal in the process of Producing aluminium alloy foam by low-pressure infiltration method were investigated.Experiments indicated that the height increases with the preheating temperature of granules,theexternal pressureand the pouring temperature of molten alloy,among which the action of pre heating temperature of granules is more effective.There exists a critical pre heating temperature for different size of granules.

Ballistic behavior of boron carbide reinforced AA7075 aluminium alloy using friction stir processing-An experimental study and analytical approach

High strength-to-weight ratio of non-ferrous alloys, such as aluminium, magnesium and titanium alloys, are considered to be possible replacement of widely accepted steels in transportation and automobile sectors. Among these alloys, magnesium is self explosive and titanium is costlier, and aluminium is most likely to replace steels. Application of aluminium or its alloys is also thought of as an appropriate replacement in defence field, especially to enhance the easiness in mobility of combat vehicles while maintaining the same standard as that of conventional armour grade steels. Hence most of the investigations have been confined to aluminium or its alloys as base material and open an era of developing the newer composite materials to address the major limitation, i.e. tribological properties. The surface composites can be fabricated by incorporating the ceramic carbides like silicon carbide, carbides of transition metals and oxides of aluminium using surface modification techniques, such as high energy laser melt treatment, high energy electron beam irradiation and thermal spray process which are based on fusion route. These techniques yield the fusion related problems, such as interfacial reaction, pin holes, shrinkage cavities or voids and other casting related defects, and pave the way to need of an efficient technique which must be based on solid state. Recently developed friction stir processing technique was used in the present investigation for surface modification of AA7075 aluminum alloy, which is an alternative to steels. In the present investigation, 160 μm sized boron carbide powder was procured and was reduced to 60 μm and 30 μm using high energy ball mill. Subsequently these powders were used to fabricate the surface composites using friction stir processing.Ballistic performance testing as per the military standard(JIS.0108.01) was carried out. In the present work, an analytical method of predicting the ballistic behavior of surface composites was developed. This method was based on energy balance, i.e., the initial energy of impact is same as that of energy absorbed by multi layers. An attempt also has been made to validate the analytical results with the experimental findings. Variation between the analytical and experimental results may be accounted due to the assumptions considering such as isotropic behavior of target and shearing area of contact as cylindrical instead of conical interface As the analytical model yields the ballistic performance in the closer proximity of experimentally obtained, it can be considered to be an approximation to evaluate the ballistic performance of targets.

Modified Layer-Removal Method for Measurement of Residual Stress in Pre-stretched Aluminium Alloy Plate

Residual stress is one of the factors affecting the machining deformation of monolithic structure parts in the aviation industry. Thus,the studies on machining deformation rules induced by residual stresses largely depend on correctly and efficiently measuring the residual stresses of workpieces. A modified layer-removal method is proposed to measure residual stress by analysing the characteristics of a traditional layer-removal method. The coefficients of strain release are then deduced according to the simulation results using the finite element method( FEM). Moreover,the residual stress in a 7075T651 aluminium alloy plate is measured using the proposed method,and the results are then analyzed and compared with the data obtained by the traditional methods. The analysis indicates that the modified layer-removal method is effective and practical for measuring the residual stress distribution in pre-stretched aluminium alloy plates.

Experimental investigation on friction stir welding of 2A12 aluminium alloys

Friction stir welding experiments were conducted to study the effects of the process parameters on the weld quality of 2A12 aluminium alloys. Through appropriate selection of the shoulder press amount （axial force）, tool rotation speed and welding speed, good joints were obtained for the test pieces with thickness of 6 ram. The microstructures in weld nugget zone, thermo-mechanical affected zone and heat-affected zone were analyzed. It is found that the ratio of the tool rotation speed to the welding speed should be optimized for a suitable shoulder press amount.

Inhibition Behaviour of 2-butinel,4diol and Tartrate Salt,and Their Synergistic Effects on Corrosion of AA3003 Aluminium Alloy in 0.5% NaCl Solution

This work intends to investigate the inhibition behaviour of 2-butine 1, 4diol and potassium sodium tartrate and their synergistic effects on 3003 aluminium alloy corrosion in 0.5% NaCl solution. Experiments were carried out by electrochemical impedance spectroscopy （EIS） and Tafel polarization method in a three-electrode cell. It was concluded that the inhibition efficiencies increased with an increase in the concentrations of inhibitors. For 2-butinel, 4diol and tartrate salt, the optimum in the inhibition efficiency, at room temperature and neutral pH, was observed for concentrations close to 10-3 mol/L and 1.5×10^-3mol/L, respectively. The electrochemical results illustrated that 2-butinel, 4diol and tartrate salt, have significant synergistic inhibition effects on corrosion of 3003 aluminium alloy in 0.5% NaCl solution. The optimum ratio of concentrations for tartrate to alcohol was 2：1.

The Rare Earth Aluminium Alloys in China

The development and application of rare earth aluminium alloys began in the 1960s in China.The represen- tative work was the usage of rare earth metals in alumino-silicon alloys for piston.In the 1970s,its initial stage. rare earths were used in enhanced AIMgSi alloy transmission line and FeCr Al alloy electric heating wire.During its developing period(from 1980 to 1985),in the field of smelting,after the electrolytic preparation of RE-Al master alloys at relatively low temperature,a new technique was invented that rare earth compounds were added to commercial aluminium electrowinning cell to produce RE-Al alloys directly.It opened the way for the appli- cation of rare earths in industry on a large scale.In the field of application,it was found that the addition of rare earths could improve the conductivity and processing property of aluminium alloys.The application of rare earths to aluminium conductors and products had made a breakthrough progress.Since 1986,its golden age,the study,production and application of aluminium alloys containing rare earths have been developing at an amazing speed,running neck and neck with the application of RE in agriculture,textile dyeing,and cast iron.

Hydrogen Fixation Effect of Rare Earths in Pure Aluminium and Aluminium Alloys

The areal distribution of some elements in the rare earth bearing spheroidal phases in pure aluminium and Al-Mn alloys was studied by SIMS(secondary ion mass spectrometry).The results show that cerium,iron. silicon and hydrogen are significantly segregated in the phases.Thus the existence of hydrogen-rich rare earth bearing eompounds is confirmed.It indicates that the rare earths have a hydrogen fixation effect in aluminium and aluminium alloys.

Assessment of mechanical properties of aluminium alloy welded joint using small punch test

The small punch test technique （SPT） was used to evaluate the mechanical properties of various materials and the basic method to test material tensile mechanics peqeormance from an inverse finite element （ FE） arithmetic with SPT was put forward. The research shows that specific tensile mechanical behavior and strain-stress distribution of each district of weld seam can be accurately determined by small punch test. Therefore, mechanical behavior of the inhomogeneous joint can be predicted by a numerical model. The simulation comes to good agreement with experimental data.

Prediction of Earing in Deep Drawing of Roll-cast Aluminium Alloy Sheets

Commercial aluminium alloy sheets are presently sem ic ontinuously, direct chill casting billets that are hot and cold rolled to the fi nal gauge. Interest has been shown in continuous methods which eliminate the ho t rolling step through rapid solidification of the molten metal to the final sla b. Accordingly, sheets are produced by homogenization, cold rolling, intermedia te and final annealing of these roll-cast slabs. The problem of earing is of gr eat concern as it causes frequent interruption of production runs and leads to m aterial wastage. Therefore, it is quite desirable that earing can be predic ted and consequently necessary measures be taken to minimize or eliminate this u nwanted phenomenon. It is accepted generally that, the principal source of earing is the crystallogr aphic anisotropy arising from non-random distribution of crystal orientations i n the material. Accordingly, several attempts have been made to correlate the m echanical and crystallographic properties of the materials to the earing behavio ur for predictive purposes. Some of these are based on continuum concepts which concentrate on the macroscopic rather than the microscopic aspects of the mater ials. To accommodate the microstructural features of the material, some models have been developed. A more recent approach which provides a connection between texture and plastic anisotropy parameters of the material is the Continuum Mech anics of Textured Polycrystals (CMTP) method proposed by Lin et al. A simplifie d version of this method has been suggested by Chan with promising accuracy for aluminium and copper sheets. AA3105 and AA8011 aluminium alloy sheets were used in this investigation. The a s-cast slabs were cold rolled to the final thickness of 1.0 mm. Different anne aling temperatures in the range of 420 ℃ to 540 ℃ produced a range of R-value s. Circular blanks of 60 mm diameter were machined and deep drawn using a cylind rical flat-bottom punch of 33 mm diameter. The heights of the drawn cups were measured at 0, 45 and 90° to the rolling direction, with the aid of a microme ter accurate to 10 -2 mm. The earing percentage was then calculated usin g the following formula: % earing=h p-h v1/2(h p+h v)(1) where h p is the distance between the bottom of the cup and the peak of ear , and h v is the distance between the bottom of the cup and the valley of t he ear. For the measurement of plastic strain ratios (R-values), tensile specimens cut at 0, 45 and 90° to the rolling direction were photogridded with 1mm square s. These specimens were then stretched in the range of uniform deformation and the dimensional changes were measured with the aid of a travelling microscope. The strain ratios, whether R 0, R 45 or R 90 were determined from the following equation: R θ=dε wdε t=dε wdε l+dε w(2) where Θ refers to the specimen orientation and dε w and dεl refer to the transverse and longitudinal strains of the gauge section, respectively. The av erage strain ratio, R, and the parameter ΔR were then calculated from: R=14(R 0+2R 45+R 90)(3) ΔR=12(R 0-2R 45+R 90)(4) where R 0, R 45 and R 90 values are determined using specimen s cut at 0, 45 and 90° to the rolling direction, respectively. Finally, a continuum mechanics approach using different yield criteria is employ ed for the prediction of earing behaviour under different conditions of the mate rials. Instead of using texture data, the yield stress values are obtained by d ifferent anisotropic yield criteria such as; Hosford, Hill, and Zhou. The predicted earing profiles are compared to the experimental data and the suit ability of different yield criteria is discussed.

Investigation of the Effect of Grain Refinement on the Mechanical Properties of 6082 Aluminium Alloy

In this study, it is aimed to investigate effect of the grain refinement on the mechanical properties of the AA 6082. The micro structure which plays crucial role in determining the mechanical properties of the alloys is varied according to grain size, chemical composition and cooling rate. The prescription was prepared by determining the chemical composition range according to the standard (TSE-EN-573). The casting experiments were performed on the 6082 aluminium alloy which belongs to Al-Mg-Si system with different percentages of grain refinement (AlTi5B1) and chemical composition. Heat treatment that is homogenization and artificial aging was applied after casting and extrusion process, respectively. The microstructure analysis and mechanical tests were done on the produced samples in order to understand the structural and mechanical strength of the material. The experimental results showed that using the grain refinements is contributed to increasing the mechanical properties. It was observed that the mechanical strength values increased by 17% after the reduction of the grain size by 69% with the 0.11% addition of the AlTi5B1 master alloy.