The alumina solubility in the title system within the composition range of KR{m（K3AlF6）/[m（K3AlF6）＋ m（Na3AlF6）]} 10%―50%, a ternary Na3AlF6-K3AlF6-AlF3 molten system with 23%―29%（mass fraction） AlF3 was inv...The alumina solubility in the title system within the composition range of KR{m（K3AlF6）/[m（K3AlF6）＋ m（Na3AlF6）]} 10%―50%, a ternary Na3AlF6-K3AlF6-AlF3 molten system with 23%―29%（mass fraction） AlF3 was investigated by measuring the mass loss of a rotating sintered corundum disc. And the following empirical equation was derived when superheat degree was no more than 60 °C： w（Al2O3）sat=A×（T/1000）B, where A= –1.85774＋ 26.754234w（AlF3）–0.3683–0.00783KR2.363＋0.010266KR2.3048＋0.7902w（AlF3）0.00652, B=112.4625–53.2567w（AlF3）0.4236＋ 5.1079w（AlF3）0.9241＋0.01542w（AlF3）1.3540. Considering both higher alumina solubility and not too high superheat de gree are required, alumina solubility of different compositions at not the same temperature but the same superheat degree was studied, which will be more industrial helpful for selecting prospective compositions. The results show that the composition deserved to be further tested in lower temperature cells is 10%―30% KR and 23%―26%（mass fraction） AlF3.展开更多
基金Supported by the National Basic Research Program of China(No.2005CB623703)the National High-Tech Research and Development Program of China(No.2008AA030503)
文摘The alumina solubility in the title system within the composition range of KR{m（K3AlF6）/[m（K3AlF6）＋ m（Na3AlF6）]} 10%―50%, a ternary Na3AlF6-K3AlF6-AlF3 molten system with 23%―29%（mass fraction） AlF3 was investigated by measuring the mass loss of a rotating sintered corundum disc. And the following empirical equation was derived when superheat degree was no more than 60 °C： w（Al2O3）sat=A×（T/1000）B, where A= –1.85774＋ 26.754234w（AlF3）–0.3683–0.00783KR2.363＋0.010266KR2.3048＋0.7902w（AlF3）0.00652, B=112.4625–53.2567w（AlF3）0.4236＋ 5.1079w（AlF3）0.9241＋0.01542w（AlF3）1.3540. Considering both higher alumina solubility and not too high superheat de gree are required, alumina solubility of different compositions at not the same temperature but the same superheat degree was studied, which will be more industrial helpful for selecting prospective compositions. The results show that the composition deserved to be further tested in lower temperature cells is 10%―30% KR and 23%―26%（mass fraction） AlF3.
