With the aids of SEM,XPS measurements,localized plasmon resonance light scattering(PRLS) spectrometry and light scattering imaging,investigations on the amalgamation process of both cetyltrimethylammonium bromide(CTAB...With the aids of SEM,XPS measurements,localized plasmon resonance light scattering(PRLS) spectrometry and light scattering imaging,investigations on the amalgamation process of both cetyltrimethylammonium bromide(CTAB) and citrate-coated gold nanoparticles(AuNPs) in the presence of Hg2+ showed that the Au-Hg amalgam process of gold nanoparticles is surface coating dependent in aqueous medium,and the scattering light color change of AuNPs under a dark-field microscope is blue-shifted from red-orange into yellow-orange or even yellow.The former one involves the reduction of Hg2+ to Hg0 species and adsorption of Hg0 on the surfaces of AuNPs,while the later one indicates the shape-evolution of AuNPs.展开更多
基金supported by the National Natural Science Foundation of China (21035005)Postgraduate Science and Technology Innovation Program of Southwest China University (2009004)
文摘With the aids of SEM,XPS measurements,localized plasmon resonance light scattering(PRLS) spectrometry and light scattering imaging,investigations on the amalgamation process of both cetyltrimethylammonium bromide(CTAB) and citrate-coated gold nanoparticles(AuNPs) in the presence of Hg2+ showed that the Au-Hg amalgam process of gold nanoparticles is surface coating dependent in aqueous medium,and the scattering light color change of AuNPs under a dark-field microscope is blue-shifted from red-orange into yellow-orange or even yellow.The former one involves the reduction of Hg2+ to Hg0 species and adsorption of Hg0 on the surfaces of AuNPs,while the later one indicates the shape-evolution of AuNPs.
