Fluidization characteristics of silicon particle system are studied by the pressure fluctuation method.The existence of fine particles in the system can improve fluidization. Silicon particles with a wide size distrib...Fluidization characteristics of silicon particle system are studied by the pressure fluctuation method.The existence of fine particles in the system can improve fluidization. Silicon particles with a wide size distribution,preferably with some fines, behave as Group A particles according to Geldart classification, although the system belongs to Group B actually. The system is also approved to be suitable for organochlorosilane monomer production using a fluidized bed reactor. Experimental data obtained in this work are important for the design and operation of commercial fluidized bed reactors for the production of organochlorosilane monomers.展开更多
Experiments on the behavior of airborne microparticle sediments and their adhesion on glass slides were conducted in a laboratory located on the first floor of a teaching building. Clean tiles and glass slides were pl...Experiments on the behavior of airborne microparticle sediments and their adhesion on glass slides were conducted in a laboratory located on the first floor of a teaching building. Clean tiles and glass slides were placed at different angles （0°, 45° and 90°） with respect to the horizontal plane in the laboratory. The sedimentation of microparticles was investigated at certain time intervals （1 d, 3 d, l0 d and 30 d）. The results of testing, at day 30, show that the diameters of particles on the horizontal tiles varied from 20 to 80 μm; few particles with diameter less than 0.5 μm or greater than 100 μm were found. The amount of particle sediment on all the slides increased along over time, while the average diameter of particles was not correlated with time, nor with the angle of placement. The maximum particle size, the total particle surface area, the total perimeter of all particles and the cover ratio of light （the proportion of total area of particles to the observed area of the slides surfaces） did not change significantly within the first 10 days. Inspection of all the samples for the last 20 days, however, showed that these variables increased substantially with the passage of time and were in reverse proportion to the placement angles, which indicates a concentration of particles, as well as physical and chemical changes.展开更多
The performances of four optical particles counters, Aerosol Spectrometer (Grimm 1.108), Enviro Check (Grimm 1.107), DustMonit and ParticleScan, were evaluated in laboratory tests employing monodisperse aerosol partic...The performances of four optical particles counters, Aerosol Spectrometer (Grimm 1.108), Enviro Check (Grimm 1.107), DustMonit and ParticleScan, were evaluated in laboratory tests employing monodisperse aerosol particles. The study focused on how commercial instruments perform during routine measurements respect to OPC scientific understanding, because it is important for users of such instruments to be aware of their limitations. Measurements were performed using aerosol generated by a Monodisperse Aerosol Generator (MAGE), which produced carnauba wax particles of diameter (1.00 ± 0.08) μm and (1.40 ± 0.15) μm, and monodisperse Polystyrene Latex (PSL) aerosol with nominal diameter of 1.0mm. The results show comparable total particle number concentrations for all the counters, when the count of the first size channel (0.3 - 0.4 μm) for the 1.108 Grimm counter was left out. In the said channel the Grimm counter 1.108 always showed much higher particle counts than those inferred from the tested aerosols. The overcount was proved by the fact that the aerosol sampled in each test on a Nuclepore filter showed no particles in the 0.3 - 0.4 μm range when examined under Scanning Electronic Microscope (SEM). The presence of an artefact produced by the counter was assumed as a likely explanation. For all the counters, the Count Median Diameters (CMDs) of aerosol size distributions, were far below the expected value for the aerosol used. The nearest CMD values to the expected ones were shown by the Grimm 1.107 counter.展开更多
Knowledge of particle number size distribution（PND） and new particle formation（NPF）events in Southern China is essential for mitigation strategies related to submicron particles and their effects on regional air q...Knowledge of particle number size distribution（PND） and new particle formation（NPF）events in Southern China is essential for mitigation strategies related to submicron particles and their effects on regional air quality,haze,and human health.In this study,seven field measurement campaigns were conducted from December 2013 to May 2015 using a scanning mobility particle sizer（SMPS） at four sites in Southern China,including three urban sites and one background site.Particles were measured in the size range of15-515 nm,and the median particle number concentrations（PNCs） were found to vary in the range of 0.3× 10~4-2.2 × 10~4 cn^（-3） at the urban sites and were approximately 0.2 × 10~4 cm^（-3） at the background site.The peak diameters at the different sites varied largely from 22 to 102 nm.The PNCs in the Aitken mode（25-100 nm） at the urban sites were up to 10 times higher than they were at the background site,indicating large primary emissions from traffic at the urban sites.The diurnal variations of PNCs were significantly influenced by both rush hour traffic at the urban sites and NPF events.The frequencies of NPF events at the different sites were0%-30%,with the highest frequency occurring at an urban site during autumn.With higher SO_2 concentrations and higher ambient temperatures being necessary,NPF at the urban site was found to be more influenced by atmospheric oxidizing capability,while NPF at the background site was limited by the condensation sink.This study provides a unique dataset of particle number and size information in various environments in Southern China,which can help understand the sources,formation,and the climate forcing of aerosols in this quickly developing region,as well as help constrain and validate NPF modeling.展开更多
During the 2012 Lanzhou International Marathon, the local government made a significant effort to improve traffic conditions and air quality by implementing traffic restriction measures. To evaluate the direct effect ...During the 2012 Lanzhou International Marathon, the local government made a significant effort to improve traffic conditions and air quality by implementing traffic restriction measures. To evaluate the direct effect of these measures on urban air quality, especially particle concentrations and their size distributions, atmospheric particle size distributions （0.5-20μm） obtained using an aerodynamic particle sizer （model 3321, TSI, USA） in June 2012 were analyzed. It was found that the particle number, surface area and volume concentrations for size range 0.5-10 μm were （15.0±2.1） cm-3, （11.8±2.6） μm2/cm3 and （1.9±0.6） μm2/cm3, respectively, on the traffic-restricted day （Sunday）, which is 63.2%, 53.0% and 47.2% lower than those on a normal Sunday. For number and surface area concentrations, the most affected size range was 0.5-0.7 and 0.5-0.8 μm, respectively, while for volume concentration, the most affected size ranges were 0.5-0.8, 1.7-2.0 and 5.0-5.4 μm. Number and volume concentrations of particles in size range 0.5-1.0μm correlated well with the number of non-CNG （Compressed Natural Gas） powered vehicles, while their correlation with the number of CNG-powered vehicles was very low, suggesting that reasonable urban traffic controls along with vehicle technology improvements could play an important role in improving urban air quality.展开更多
ISO 16890:2016一般通风用空气过滤器标准是在欧美现有标准的基础上创建的用以确定空气过滤器对细颗粒物PM2.5等的计重过滤效率为目标的标准。该标准认为在给定的粒径范围内空气动力学当量直径可视为等同于光学当量直径,据此以空气过滤...ISO 16890:2016一般通风用空气过滤器标准是在欧美现有标准的基础上创建的用以确定空气过滤器对细颗粒物PM2.5等的计重过滤效率为目标的标准。该标准认为在给定的粒径范围内空气动力学当量直径可视为等同于光学当量直径,据此以空气过滤器对人工气溶胶的计径计数效率和典型大气气溶胶体积分布数学模型,计算得到对PM2.5等的计重过滤效率。欧洲并拟以此标准取代EN 779等现行标准。对ISO 16890:2016标准的相关问题进行了探讨,并对我国制定相关标准提出了一些看法和建议。展开更多
文摘Fluidization characteristics of silicon particle system are studied by the pressure fluctuation method.The existence of fine particles in the system can improve fluidization. Silicon particles with a wide size distribution,preferably with some fines, behave as Group A particles according to Geldart classification, although the system belongs to Group B actually. The system is also approved to be suitable for organochlorosilane monomer production using a fluidized bed reactor. Experimental data obtained in this work are important for the design and operation of commercial fluidized bed reactors for the production of organochlorosilane monomers.
基金Projects 50474050 supported by the National Natural Science Foundation of China 20040533011 by the Doctoral Fund of Ministry of Education of China
文摘Experiments on the behavior of airborne microparticle sediments and their adhesion on glass slides were conducted in a laboratory located on the first floor of a teaching building. Clean tiles and glass slides were placed at different angles （0°, 45° and 90°） with respect to the horizontal plane in the laboratory. The sedimentation of microparticles was investigated at certain time intervals （1 d, 3 d, l0 d and 30 d）. The results of testing, at day 30, show that the diameters of particles on the horizontal tiles varied from 20 to 80 μm; few particles with diameter less than 0.5 μm or greater than 100 μm were found. The amount of particle sediment on all the slides increased along over time, while the average diameter of particles was not correlated with time, nor with the angle of placement. The maximum particle size, the total particle surface area, the total perimeter of all particles and the cover ratio of light （the proportion of total area of particles to the observed area of the slides surfaces） did not change significantly within the first 10 days. Inspection of all the samples for the last 20 days, however, showed that these variables increased substantially with the passage of time and were in reverse proportion to the placement angles, which indicates a concentration of particles, as well as physical and chemical changes.
文摘The performances of four optical particles counters, Aerosol Spectrometer (Grimm 1.108), Enviro Check (Grimm 1.107), DustMonit and ParticleScan, were evaluated in laboratory tests employing monodisperse aerosol particles. The study focused on how commercial instruments perform during routine measurements respect to OPC scientific understanding, because it is important for users of such instruments to be aware of their limitations. Measurements were performed using aerosol generated by a Monodisperse Aerosol Generator (MAGE), which produced carnauba wax particles of diameter (1.00 ± 0.08) μm and (1.40 ± 0.15) μm, and monodisperse Polystyrene Latex (PSL) aerosol with nominal diameter of 1.0mm. The results show comparable total particle number concentrations for all the counters, when the count of the first size channel (0.3 - 0.4 μm) for the 1.108 Grimm counter was left out. In the said channel the Grimm counter 1.108 always showed much higher particle counts than those inferred from the tested aerosols. The overcount was proved by the fact that the aerosol sampled in each test on a Nuclepore filter showed no particles in the 0.3 - 0.4 μm range when examined under Scanning Electronic Microscope (SEM). The presence of an artefact produced by the counter was assumed as a likely explanation. For all the counters, the Count Median Diameters (CMDs) of aerosol size distributions, were far below the expected value for the aerosol used. The nearest CMD values to the expected ones were shown by the Grimm 1.107 counter.
基金supported by the National Natural Science Foundation of China(Nos.U1301234,21277003)the Shenzhen Science&Technology Plan,and the Ministry of Science and Technology of China(No.2013CB228503)
文摘Knowledge of particle number size distribution（PND） and new particle formation（NPF）events in Southern China is essential for mitigation strategies related to submicron particles and their effects on regional air quality,haze,and human health.In this study,seven field measurement campaigns were conducted from December 2013 to May 2015 using a scanning mobility particle sizer（SMPS） at four sites in Southern China,including three urban sites and one background site.Particles were measured in the size range of15-515 nm,and the median particle number concentrations（PNCs） were found to vary in the range of 0.3× 10~4-2.2 × 10~4 cn^（-3） at the urban sites and were approximately 0.2 × 10~4 cm^（-3） at the background site.The peak diameters at the different sites varied largely from 22 to 102 nm.The PNCs in the Aitken mode（25-100 nm） at the urban sites were up to 10 times higher than they were at the background site,indicating large primary emissions from traffic at the urban sites.The diurnal variations of PNCs were significantly influenced by both rush hour traffic at the urban sites and NPF events.The frequencies of NPF events at the different sites were0%-30%,with the highest frequency occurring at an urban site during autumn.With higher SO_2 concentrations and higher ambient temperatures being necessary,NPF at the urban site was found to be more influenced by atmospheric oxidizing capability,while NPF at the background site was limited by the condensation sink.This study provides a unique dataset of particle number and size information in various environments in Southern China,which can help understand the sources,formation,and the climate forcing of aerosols in this quickly developing region,as well as help constrain and validate NPF modeling.
基金supported by the Hundred Talents Program of Chinese Academy of Sciences (No. 29O827631)
文摘During the 2012 Lanzhou International Marathon, the local government made a significant effort to improve traffic conditions and air quality by implementing traffic restriction measures. To evaluate the direct effect of these measures on urban air quality, especially particle concentrations and their size distributions, atmospheric particle size distributions （0.5-20μm） obtained using an aerodynamic particle sizer （model 3321, TSI, USA） in June 2012 were analyzed. It was found that the particle number, surface area and volume concentrations for size range 0.5-10 μm were （15.0±2.1） cm-3, （11.8±2.6） μm2/cm3 and （1.9±0.6） μm2/cm3, respectively, on the traffic-restricted day （Sunday）, which is 63.2%, 53.0% and 47.2% lower than those on a normal Sunday. For number and surface area concentrations, the most affected size range was 0.5-0.7 and 0.5-0.8 μm, respectively, while for volume concentration, the most affected size ranges were 0.5-0.8, 1.7-2.0 and 5.0-5.4 μm. Number and volume concentrations of particles in size range 0.5-1.0μm correlated well with the number of non-CNG （Compressed Natural Gas） powered vehicles, while their correlation with the number of CNG-powered vehicles was very low, suggesting that reasonable urban traffic controls along with vehicle technology improvements could play an important role in improving urban air quality.
