As the novel ligands for the separation of trivalent actinides from lanthanides for spent nuclear fuel reprocessing,the amide-substituted 1,10-phenanthroline derivations were found to have high selectivity on Am(III) ...As the novel ligands for the separation of trivalent actinides from lanthanides for spent nuclear fuel reprocessing,the amide-substituted 1,10-phenanthroline derivations were found to have high selectivity on Am(III) and Eu(III) in nitric acid media[1;2]. However, the origin of their extraction abilities is still an open question.展开更多
文摘As the novel ligands for the separation of trivalent actinides from lanthanides for spent nuclear fuel reprocessing,the amide-substituted 1,10-phenanthroline derivations were found to have high selectivity on Am(III) and Eu(III) in nitric acid media[1;2]. However, the origin of their extraction abilities is still an open question.