Recycle Adsorption of Cu2＋ on Amine-functionalized Mesoporous Silica Monolithic

3-Aminopropyltriethoxysilane functionalized worm-like mesoporous silica monolithic（WMSM-NH2） was prepared and used as a new regenerable adsorbent for the removal of Cu2＋ ions. The analysis results show that the WMSM-NH2 monolithic had a high efficiency value of 99.3% for Cu2＋ remediation when the Cu2＋ solution was at an initial concentration of 10.32 mg/L. The regeneration study of the WMSM-NH2 monolithic presented that the adsorp- tion efficiency of 89.0% was remained and a mass of 92.0% was left after seven adsorption-desorption cycles were executed. The monolithic material with high resistance to the acid and good mechanical stability can facilitate the operations of adsorption and regeneration of the adsorbent.

Palladium nanoparticles supported on amine-functionalized glass fiber mat for fixed-bed reactors on the effective removal of hexavalent chromium by catalytic reduction

Palladium nanoparticles were deposited on the amine-grafted glass fiber mat （GFM-NH2） catalyst support by a conventional impregnation process followed by the borohydride reduction in aqueous solution at room temperature to create the designed Pd/GFM-NH2 catalyst. By the use of large size glass fiber mat without nano/mesopores as the catalyst support, the internal mass transfer limitations due to the existence of nano/mesopores on the catalyst support were eliminated and the Pd/GFM-NH2 catalyst could be easily separated from treated water due to the large size of the catalyst support. Batch experiments demonstrate its good catalytic reduction performance of Cr（VI） with formic acid as the reducing agent. It also demonstrated an efficient Cr（VI） removal and stability in a lab-prepared, packed fixed-bed tube reactor for the continuous treatment of Cr（VI）-containing water. Thus, it has a good potential for the catalytic reduction of Cr（VI） in the water treatment practice.

Ultrafine PdAg alloy nanoparticles anchored on NH2-functionalized 2D/2D TiO_(2) nanosheet/rGO composite as efficient and reusable catalyst for hydrogen release from additive-free formic acid at room temperature

A 2 D-2 D titanium dioxide nanosheet-reduced graphene oxide(TNS-r GO)composite with better electronic conductivity and hydrophilicity was prepared by the hydrothermal method.The as-obtained TNS-r GO composite was further functionalized with 3-aminopropyltriethoxysilane(APTES)to provide a large amount of-NH2 groups on the surface for anchoring ultrafine Pd Ag alloy nanoparticles with an average particle size of 1.69 nm by a facile wet reduction approach.Benefiting from the combined effects of well-dispersed Pd Ag alloy nanoparticles,facilitated electron transfer from TNS-r GO to Pd,and increased electron density of active sites,the Pd8 Ag_(1)/NH_(2)-TNS-r GO catalyst exhibited excellent activity towards dehydrogenation of formic acid without adding any additives at 298 K,corresponding to an initial turn over frequency as high as 1090 h-1,which is much higher than that of most other state-of-theart catalysts.

Impacts of nano-scale pore structure and organic amine assembly in porous silica on the kinetics of CO_(2) adsorptive separation

Nano structure including pore structure and amine assembly is critical for improving sorption and desorption kinetics for adsorptive CO_(2) separation.The present work delineates(1)the influence of the nano-scale pore structure of amine-functionalized solid sorbents,and(2)effect of changing the assembly of amine molecules on surface of nano-porous SiO_(2) on the rates of adsorption and desorption of CO_(2).50PEI-MSN sorbent with inverted cone-shaped pores was prepared by using mesoporous silica nanospheres(MSN)with inverted cone-shaped pores for the loading of polyethyleneimine(PEI).Co-structure-directing(CSD)method was used to synthesize the sorbent with arranged amine assembly at nano-scale(2N-CSD).By comparison with 50PE卜SBA15 as a benchmark sorbent,both sorbents have improved sorption and desorption kinetics.There are significant effects of nano pore structure and amine assembly on the sorption and desorption kinetics.The inverted cone-shaped pores in MSN allow loading polymeric amines in their narrower ends and leaving larger pore mouths open for the transport of CO_(2);50PEI-MSN shows a maximum sorption rate of 81.4 mg·g^(-1)·min^(-1) with average sorption rate of 25.4mg·g^(-1)·min^(-1) at 80℃ which are 34%and 59%higher than the corresponding values for 50PEI-SBA15;a maximum desorption rate of 38.4mg·g^(-1)·min^(-1) with average desorption rate of 11.8 mg·g^(-1)·min^(-1) ramping from 30 to 95℃ which are 37%and 156%higher than the corresponding values for 50PEI-SBA15.The arranged monolayer-like amine assembly on surface of nanoporous SiO_(2) likely provides high amine sorption sites through improved accessibility of amine,and 2N-CSD shows a maximum sorption rate of 60.5 mg·g^(-1)·min^(-1),with average sorption rate of 12.8mg·g^(-1)·min^(-1) at 300C which are 108%and 205%higher than the corresponding values for 50PEI-SBA15;a lower maximum desorption rate of 9.7 mg g'1min"1 and average desorption rate of 9.8mg·g^(-1)·min^(-1) ramping from 30 to 95℃ which is 250%higher than the corresponding value for 50PEI-SBA15.The present work demonstrates the importance of tailoring nano-scale pore structure and amine assembly for significantly improving sorption and desorption kinetics of adsorptive CO_(2) separation.

Facile assembly of mesoporous silica nanoparticles with hierarchical pore structure for CO2 capture

In the work,we propose an efficient one-pot approach for synthesis of a new type of mesoporous silica nanoparticles(MSNs).That can be successfully realized by using tetraethylorthosilicate(TEOS) and N-[3-(trimethoxysilyl)propyl]ethylenediamine(TSD) as the silica precursors and cetyltrimethylammonium bromide(CTAB) as the structure-directing agent through a facile assembly process.The as-synthesized MSNs possess a spherical morphology with about 230 nm,a relatively high surface area of133 m^2/g,and a hierarchical pore size distribution.When applied as the sorbents,the amine-functioned MSNs demonstrate the enhanced adsorption capacity for CO2 capture(at 1 bar,15 vol% CO2,up to80.5 mg/g at 75℃),high selectivity,and good cycling durability,benefiting from the suitable modification of polyethyleneimine.