The mapping method is a forward-modeling method that transforms the irregular surface to horizontal by mapping the rectangular grid as curved; moreover, the wave field calculations move from the physical domain to the...The mapping method is a forward-modeling method that transforms the irregular surface to horizontal by mapping the rectangular grid as curved; moreover, the wave field calculations move from the physical domain to the calculation domain. The mapping method deals with the irregular surface and the low-velocity layer underneath it using a fine grid. For the deeper high-velocity layers, the use of a fine grid causes local oversampling. In addition, when the irregular surface is transformed to horizontal, the flattened interface below the surface is transformed to curved, which produces inaccurate modeling results because of the presence of ladder-like burrs in the simulated seismic wave. Thus, we propose the mapping method based on the dual-variable finite-difference staggered grid. The proposed method uses different size grid spacings in different regions and locally variable time steps to match the size variability of grid spacings. Numerical examples suggest that the proposed method requires less memory storage capacity and improves the computational efficiency compared with forward modeling methods based on the conventional grid.展开更多
A Hybrid Coordinate Ocean Model (HYCOM) is used to simulate the sea surface temperature of the Tropical and North Pacific. Based on the different combinations of two air-Sea flux data sets (COADS and ECMWF) and tw...A Hybrid Coordinate Ocean Model (HYCOM) is used to simulate the sea surface temperature of the Tropical and North Pacific. Based on the different combinations of two air-Sea flux data sets (COADS and ECMWF) and two bulk parameter formulas (non-constant and constant), four numerical experiments are carried out. The following conclusions can be deduced from the numerical results. (1) The numerical results using non-constant bulk parameter formula are much better than those using constant one. In the Pacific area from 40°N to 20°S, the annual average SST obtained from the experiment using non-constant bulk parameter formula is 0.21 ℃ higher than that from the satellite-based SST climatology (the pathfinder data). However, the difference is 0.63 ℃ for the experiment when the using constant one. (2) HYCOM successfully simulates the monthly variation of climatological SST in tropical and north Pacific basins and monthly spatial variation of Western Pacific Warm Pool. Especially in the Pacific area from 40°N to 20°S, the difference of the seasonal averaged SST between pathfinder data and the result of experiment 2 (using COADS data set and non-constant bulk parameter formula) is only about 0.02 ℃. (3)The simulation results using different Air-Sea flux data are different and the difference is very large in some regions. In the northwest of the model region, the annual average SST obtained from experiment 2 (using COADS data set) is 1℃ higher than that obtained from experiment 4 (using ECMWF data set). Contrarily, the result of experiment 4 is 1 ℃ larger than that of experiment 2 in the southeast of the model region. The largest difference is about 4 ℃ occurred near the area of 58°N, 140°E and the Bohai sea.展开更多
Two mono iron complexes Fe(CO)2PR3(NN) (R = Cy (3), Ph (4), NN = o-phenylenediamine dianion ligand, N2H2Ph2-) derived from the ligand substitution of Fe(CO)3hPR3 by the NN ligand were isolated and structur...Two mono iron complexes Fe(CO)2PR3(NN) (R = Cy (3), Ph (4), NN = o-phenylenediamine dianion ligand, N2H2Ph2-) derived from the ligand substitution of Fe(CO)3hPR3 by the NN ligand were isolated and structurally characterized by single crystal X-ray diffraction. They have a similar first coordination sphere and oxidation state of the iron center as the [Fe]-hydrogenase active site, and can be a model of it IR demonstrated that the effect of the NN ligand on the coordinated CO stretch- ing frequencies was due to its excellent electron donating ability. The reversible protonation/deprotonation of the NN ligand was identified by infrared spectroscopy and density functional theory computation. The NN ligand is an effective proton acceptor as the internal base of the cysteine thiolate ligand in [Fe]-hydrogenase. The electrochemical properties of complexes 3, 4 were investigated by cyclic voltammograms. Complex 3 catalyzed the transfer hydrogenation of benzoquinone to hydroquinone effectively under mild conditions.展开更多
Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites...Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites with atomically dispersed oxygen(O)coordination on bacterial cellulose-converted graphitic carbon(Mn-O-C).Evidence of the atomically dispersed Mn-(O-C_(2))_(4)moieties embedding in the exposed basal plane of carbon surface is confirmed by X-ray absorption spectroscopy.As a result,the as-synthesized Mn-O-C catalyst exhibits superior NitRR activity with an NH_(3)yield rate(RNH_(3))of 1476.9±62.6μg h^(−1)cm^(−2)at−0.7 V(vs.reversible hydrogen electrode,RHE)and a faradaic efficiency(FE)of 89.0±3.8%at−0.5 V(vs.RHE)under ambient conditions.Further,when evaluated with a practical flow cell,Mn-O-C shows a high RNH_(3)of 3706.7±552.0μg h^(−1)cm^(−2)at a current density of 100 mA cm−2,2.5 times of that in the H cell.The in situ FT-IR and Raman spectroscopic studies combined with theoretical calculations indicate that the Mn-(O-C_(2))_(4)sites not only effectively inhibit the competitive hydrogen evolution reaction,but also greatly promote the adsorption and activation of nitrate(NO_(3)^(−)),thus boosting both the FE and selectivity of NH_(3)over Mn-(O-C_(2))_(4)sites.展开更多
The existing articulated arm coordinate measuring machines(AACMM) with one measurement model are easy to cause low measurement accuracy because the whole sampling space is much bigger than the result in the unstable...The existing articulated arm coordinate measuring machines(AACMM) with one measurement model are easy to cause low measurement accuracy because the whole sampling space is much bigger than the result in the unstable calibration parameters. To compensate for the deficiency of one measurement model, the multiple measurement models are built by the Denavit-Hartenberg's notation, the homemade standard rod components are used as a calibration tool and the Levenberg-Marquardt calibration algorithm is applied to solve the structural parameters in the measurement models. During the tests of multiple measurement models, the sample areas are selected in two situations. It is found that the measurement errors' sigma value(0.083 4 ram) dealt with one measurement model is nearly two times larger than that of the multiple measurement models(0.043 1 ram) in the same sample area. While in the different sample area, the measurement errors' sigma value(0.054 0 ram) dealt with the multiple measurement models is about 40% of one measurement model(0.137 3 mm). The preliminary results suggest that the measurement accuracy of AACMM dealt with multiple measurement models is superior to the accuracy of the existing machine with one measurement model. This paper proposes the multiple measurement models to improve the measurement accuracy of AACMM without increasing any hardware cost.展开更多
The mild-slope equation is familiar to coastal engineers as it can effectively describe wave propagation in nearshore regions. However, its computational method in Cartesian coordinates often renders the model inaccur...The mild-slope equation is familiar to coastal engineers as it can effectively describe wave propagation in nearshore regions. However, its computational method in Cartesian coordinates often renders the model inaccurate in areas with irregular shorelines, such as estuaries and harbors. Based on the hyperbolic mild-slope equation in Cartesian coordinates, the numerical model in orthogonal curvilinear coordinates is developed. The transformed model is discretized by the finite difference method and solved by the ADI method with space-staggered grids. The numerical predictions in curvilinear co- ordinates show good agreemenl with the data obtained in three typical physical expedments, which demonstrates that the present model can be used to simulate wave propagation, for normal incidence and oblique incidence, in domains with complicated topography and boundary conditions.展开更多
A new oceanic general circulation model in pressure coordinates is formulated. Since the bottom pressure changes with time, the vertical coordinate is actually a pressure-sigma coordinate. The numerical solution of th...A new oceanic general circulation model in pressure coordinates is formulated. Since the bottom pressure changes with time, the vertical coordinate is actually a pressure-sigma coordinate. The numerical solution of the model is based on an energy-conservation scheme of finite difference. The most important new feature of the model is that it is a truly compressible ocean model and it is free of the Boussinesq approximations. Thus, the new model is quite different from many existing models in the following ways: 1) the exact form of mass conservation, 2) the in-situ instantaneous pressure and the UNESCO equation of state to calculate density, 3) the in-situ density in the momentum. equations, 4) finite difference schemes that conserve the total energy. Initial tests showed that the model code runs smoothly, and it is quite stable. The quasi-steady circulation patterns generated by the new model compare well with existing models, but the time evolution of the new model seems different from some existing models. Thus, the non-Boussinesq models may provide more accurate information for climate study and satellite observations.展开更多
The computational cost required by the Ensemble Kalman Filter (EnKF) is much larger than that of some simpler assimilation schemes, such as Optimal Interpolation (OI) or three-dimension variational as- similation ...The computational cost required by the Ensemble Kalman Filter (EnKF) is much larger than that of some simpler assimilation schemes, such as Optimal Interpolation (OI) or three-dimension variational as- similation (3DVAR). Ensemble optimal interpolation (EnOI), a crudely simplified implementation of EnKF, is sometimes used as a substitute in some oceanic applications and requires much less computational time than EnKF. In this paper, to compromise between computational cost and dynamic covariance, we use the idea of "dressing" a small size dynamical ensemble with a larger number of static ensembles in order to form an approximate dynamic covariance. The term "dressing" means that a dynamical ensemble seed from model runs is perturbed by adding the anomalies of some static ensembles. This dressing EnKF (DrEnKF for short) scheme is tested in assimilation of real altimetry data in the Pacific using the HYbrid Coordinate Ocean Model (HYCOM) over a four-year period. Ten dynamical ensemble seeds are each dressed by 10 static ensemble members selected from a 100-member static ensemble. Results are compared to two EnKF assimilation runs that use 10 and 100 dynamical ensemble members. Both temperature and salinity fields from the DrEnKF and the EnKF are compared to observations from Argo floats and an OI SST dataset. The results show that the DrEnKF and the 100-member EnKF yield similar root mean square errors (RMSE) at every model level. Error covariance matrices from the DrEnKF and the 100-member EnKF are also compared and show good agreement.展开更多
Based on the analysis of the advantages and disadvantages of some vertical coordinates applied in the calculation of the Changjiang diluted water (CDW), a new hybrid vertical coordinate is designed, which uses σ co...Based on the analysis of the advantages and disadvantages of some vertical coordinates applied in the calculation of the Changjiang diluted water (CDW), a new hybrid vertical coordinate is designed, which uses σ coordinate for current and σ-z coordinate for salinity. To combine the current and salinity, the Eulerian-Lagrangian method is used for the salinity calculation, and the baroclinic pressure gradient (BPG) is calculated on the salinity sited layers. The new hybrid vertical coordinate is introduced to the widely used model of POM (Princeton Ocean Model) to make a new model of POM-σ-z. The BPG calculations of an ideal case show that POM-σ-z model brings smaller error than POM model does. The simulations of CDW also show that POM-σ-z model is better than POM model on simulating the salinity and its front.展开更多
As the market competition among enterprises grows intensively and the demand for high quality products increases rapidly, product quality inspection and control has become one of the most important issues of manufactu...As the market competition among enterprises grows intensively and the demand for high quality products increases rapidly, product quality inspection and control has become one of the most important issues of manufacturing, and improving the efficiency and accuracy of inspection is also one of problems which enterprises must solve. It is particularly important to establish rational inspection planning for parts before inspecting product quality correctly. The traditional inspection methods have been difficult to satisfy the requirements on the speed and accuracy of modern manufacturing, so CAD-based computer-aided inspection planning (CAIP) system with the coordinate measuring machines (CMM) came into being. In this paper, an algorithm for adaptive sampling and collision-free inspection path generation is proposed, aiming at the CAD model-based inspection planning for coordinate measuring machines (CMM). Firstly, using the method of step adaptive subdivision and iteration , the sampling points for the specified number with even distribution will be generated automatically. Then, it generates the initial path by planning the inspection sequence of measurement points according to the values of each point's weight sum of parameters, and detects collision by constructing section lines between the probe swept-volume surfaces and the part surfaces, with axis-aligned bounding box (AABB) filtering to improve the detection efficiency. For collided path segments, it implements collision avoidance firstly aiming at the possible outer-circle features, and then at other collisions, for which the obstacle-avoiding movements are planned with the heuristic rules, and combined with a designed expanded AABB to set the obstacle-avoiding points. The computer experimental results show that the presented algorithm can plan sampling points' locations with strong adaptability for different complexity of general surfaces, and generate efficient optimum path in a short time and avoid collision effectively.展开更多
For the simulation of the nonlinear wave propagation in coastal areas with complex boundaries, a numerical model is developed in curvilinear coordinates. In the model, the Boussinesq-type equations including the dissi...For the simulation of the nonlinear wave propagation in coastal areas with complex boundaries, a numerical model is developed in curvilinear coordinates. In the model, the Boussinesq-type equations including the dissipation terms are em- ployed as the governing equations. In the present model, the dependent variables of the transformed equations are the free surface elevation and the utility velocity variables, instead of the usual primitive velocity variables. The introduction of utility velocity variables which are the products of the contravariant components of the velocity vector and the Jacobi ma- trix can make the transformed equations relatively concise, the treatment of lateral boundary conditions easier and the de- velopment of the program simpler. The predictor-corrector method and five-point finite-difference scheme are employed to discretize the time derivatives and the spatial ones, respectively. The numerical model is tested for three cases. It is found that the numerical results are in good agreement with the analytical results and experimental data.展开更多
Cooperation among enterprises can bring overall and individual performance improvement,and a smooth coordination method is indispensable.However,due to the lack of customized coordination methods,cooperation in the do...Cooperation among enterprises can bring overall and individual performance improvement,and a smooth coordination method is indispensable.However,due to the lack of customized coordination methods,cooperation in the downstream oil supply chain cannot be carried out smoothly.This paper intends to propose a multi-party coordination method to promote cooperation between oil shippers and pipeline operator by optimizing oil transportation,oil substitution and pipeline pricing schemes.An integrated game-theoretic modeling and analysis approach is developed to characterize the operation behaviors of all stakeholders in the downstream oil supply chain.The proposed mixed integer nonlinear programming model constrains supply and demand capacity,transportation routes,oil substitution rules and pipeline freight levels.Logarithm transformation and price discretization are introduced for model linear approximation.Simulation experiments are carried out in the oil distribution system in South China.The results show that compared to the business-as-usual scheme,the new scheme saves transportation cost by 3.48%,increases pipeline turnover by 5.7%,and reduces energy consumption and emissions by 7.66%and 6.77%.It is proved that the proposed method improves the revenue of the whole system,achieves fair revenue distribution,and also improves the energy and environmental benefits of the oil supply chain.展开更多
River ice is a natural phenomenon in cold regions, influenced by meteorology, geomorphology, and hydraulic conditions. River ice processes involve complex interactions between hydrodynamic, mechanical, and thermal pro...River ice is a natural phenomenon in cold regions, influenced by meteorology, geomorphology, and hydraulic conditions. River ice processes involve complex interactions between hydrodynamic, mechanical, and thermal processes, and they are also influenced by weather and hydrologic conditions. Because natural rivers are serpentine, with bends, narrows, and straight reaches, the commonly-used one-dimensional river ice models and two-dimensional models based on the rectangular Cartesian coordinates are incapable of simulating the physical phenomena accurately. In order to accurately simulate the complicated river geometry and overcome the difficulties of numerical simulation resulting from both complex boundaries and differences between length and width scales, a two-dimensional river ice numerical model based on a boundary-fitted coordinate transformation method was developed. The presented model considers the influence of the frazil ice accumulation under ice cover and the shape of the leading edge of ice cover during the freezing process. The model is capable of determining the velocity field, the distribution of water temperature, the concentration distribution of frazil ice, the transport of floating ice, the progression, stability, and thawing of ice cover, and the transport, accumulation, and erosion of ice under ice cover. A MacCormack scheme was used to solve the equations numerically. The model was validated with field observations from the Hequ Reach of the Yellow River. Comparison of simulation results with field data indicates that the model is capable of simulating the river ice process with high accuracy.展开更多
Based on the primitive equation model with p- σ incorporated coordinate system originally developed by Qian et al., a one-way nested fine mesh limited area model is developed. This model is nested with ECMWF T42 data...Based on the primitive equation model with p- σ incorporated coordinate system originally developed by Qian et al., a one-way nested fine mesh limited area model is developed. This model is nested with ECMWF T42 data to simulate the extra-intensive rainfall event occurring in the Changjiang and Huaihe River valleys in summer of 1991. The results show that the model has certain capacity to fairly reproduce the regional distribution and the movement of the main rainfall belts. Therefore it can be used as a regional climate model to simulate and predict the short-range regional climate changes.展开更多
Variations in water exchange through the Kerama Gap (between Okinawa Island and Miyakojima Island) from 1979 to 2003 were estimated with the 0.08° Pacific HYbrid Coordinate Ocean Model (HYCOM). The model resu...Variations in water exchange through the Kerama Gap (between Okinawa Island and Miyakojima Island) from 1979 to 2003 were estimated with the 0.08° Pacific HYbrid Coordinate Ocean Model (HYCOM). The model results show that the mean transport through the Kerama Gap (KGT) from the Pacific Ocean to the East China Sea (ECS) was 2.1 Sv, which agrees well with the observed mean KGT (2.0 Sv) for 2009- 2010. Over the time period examined, the monthly KGT varied from -10.9 Sv to 15.8 Sv and had a standard deviation of +5.0 Sv. The water mainly enters the ECS via the subsurface layer (300-500 m) along the northeastern slope of the Kerama Gap and mainly flows out of the ECS into the southwest of the Kerama Gap. The seasonal and interannual variations of the KGT and the Kuroshio upstream transport were negatively correlated. The Kuroshio upstream transport was largest in summer and smallest in auamm while the KGT was smallest in summer (1.02 Sv) and largest in spring (2.94 Sv) and autumn (2.44 Sv). The seasonal and interarmual variations in the Kuroshio downstream (across the PN-line) transport differed significantly from the Kuroshio upstream transport but corresponded well with the KGT and the sum of the transport through the Kerama Gap and the Kuroshio upstream, which indicates that information about variation in the KGT is important for determining variation in the Kuroshio transport along the PN-line.展开更多
In unit steam-boiler generation, a coordinated control strategy is required to ensure a higher rate of load change without violating thermal constraints. The process is characterized by nonlinearity and uncertainty. W...In unit steam-boiler generation, a coordinated control strategy is required to ensure a higher rate of load change without violating thermal constraints. The process is characterized by nonlinearity and uncertainty. While neural networks can model highly complex nonlinear dynamical systems, they produce black box models. This has led to significant interest in neuro-fuzzy networks (NFNs) to represent a nonlinear dynamical process by a set of locally valid and simpler submodels. Two alternative methods of exploiting the NFNs within a generalised predictive control (GPC) framework for nonlinear model predictive control are described. Coordinated control of steam-boiler generation using the two nonlinear GPC methods show excellent tracking and disturbance rejection results and improved performance compared with conventional linear GPC.展开更多
Based on the general requirements of the coordinated development of"ecological livable"and"affluent life"in the rural revitalization strategy,the evaluation index system of desertification control ...Based on the general requirements of the coordinated development of"ecological livable"and"affluent life"in the rural revitalization strategy,the evaluation index system of desertification control was constructed,the interaction between desertification control and regional social economy and the internal space-time coordination mechanism were explored,and the quality of desertification control and its coordination degree with regional economic development were quantitatively analyzed.The decoupling mechanism of desertification governance society economy system were analyzed,and the high level for the government to promote desertification governance,constructing ecological economy coordinated development pattern to provide decision basis to Xizang desertification governance-social economic system interaction and coupling coordination development as the research object,introducing the coupling decoupling model to measure the coupling coordination model and system coordination and decoupling decoupling.Desertification control in Xizang shows a trend of gradual improvement,but the overall level is still not high and there is a lot of room for optimization.The coupling coordination degree of desertification control-social and economic system is in a steady fluctuation trend,rising from D value less than 0.55 in 2004 to 0.87 in 2018,in a state of coordinated development(good),and grey prediction analysis shows that D value is in a continuous rise.The coupling coordination degree of the six prefecture-level cities in Xizang and Ngari region is different in time and space,but the overall development trend is coordinated.The development index of desertification control and the socio-economic development index show the interaction of strong decoupling,strong negative decoupling and weak decoupling,and there are interaction effects of desertification control,economic development and social development at different scales.展开更多
In the study,it is proposed that a coordinate-parametric matrix model is performed to a square-conjoint pattern of cross woven(SCPCW)in the bamboo mat.The patterns of SCPCW are firstly detected according to the perspe...In the study,it is proposed that a coordinate-parametric matrix model is performed to a square-conjoint pattern of cross woven(SCPCW)in the bamboo mat.The patterns of SCPCW are firstly detected according to the perspective of configuration,which is divided into the basic-monomer shape and the basic combination shape.Secondly,the compositions of design patterns in SCPCW are analyzed to attain the trend of curve shape.Based on the coordinate-parametric matrix model,the specimens of SCPCW are subsequently accomplished to elaborate the woven logic of bamboo mats.The digital innovation of SCPCW,defined by a mathematical resolution,is implemented by the software of Grasshopper(GH),which plays a crucial role in capturing image information by the Image Sampler component.Successively,the weaving logic of coordinated matrix is referred to apply in the computing component of Grasshopper software.Finally,the computer simulation could demonstrate that the coordinate-parametric matrix model of SCPCWwould be realized to analyze the micro-weaving structure and overall weaving effect in the bamboo mat.展开更多
A three-dimensional isopycnic-coordinate ocean model for the study of internal tides is presented. In this model, the ocean interior is viewed as a stack of isopycnic layers, each characterized by a constant density. ...A three-dimensional isopycnic-coordinate ocean model for the study of internal tides is presented. In this model, the ocean interior is viewed as a stack of isopycnic layers, each characterized by a constant density. The isopycnic coordinate performs well at tracking the depth variance of the thermocline, and is suitable for simulation of internal tides. This model consists of external and internal modes, and barotropic and baroclinic motions are calculated in the two modes, respectively. The capability of simulating internal tides was verified by comparing model results with an analytical solution. The model was then applied to the simulation of internal tides in the South China Sea (SCS) with the forcing of M2 and K1 tidal constituents. The results show that internal tides in the SCS are mainly generated in the Luzon Strait. The generated M2 internal tides propagate away in three different directions (branches). The branch with the widest tidal beam propagates eastward into the Pacific Ocean, the most energetic branch propagates westward toward Dongsha Island, and the least energetic branch propagates southwestward into the basin of the SCS. The generated KI internal tides propagate in two different directions (branches). One branch propagates eastward into the Pacific Ocean, and the other branch propagates southwestward into the SCS basin. The steepening process of internal tides due to shoaling effects is described briefly. Meridionally integrated westward energy fluxes into the SCS are comparable to the meridionally integrated eastward energy fluxes into the Pacific Ocean.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.41104069 and 41274124)the National 973 Project(Nos.2014CB239006 and 2011CB202402)+1 种基金the Shandong Natural Science Foundation of China(No.ZR2011DQ016)Fundamental Research Funds for Central Universities(No.R1401005A)
文摘The mapping method is a forward-modeling method that transforms the irregular surface to horizontal by mapping the rectangular grid as curved; moreover, the wave field calculations move from the physical domain to the calculation domain. The mapping method deals with the irregular surface and the low-velocity layer underneath it using a fine grid. For the deeper high-velocity layers, the use of a fine grid causes local oversampling. In addition, when the irregular surface is transformed to horizontal, the flattened interface below the surface is transformed to curved, which produces inaccurate modeling results because of the presence of ladder-like burrs in the simulated seismic wave. Thus, we propose the mapping method based on the dual-variable finite-difference staggered grid. The proposed method uses different size grid spacings in different regions and locally variable time steps to match the size variability of grid spacings. Numerical examples suggest that the proposed method requires less memory storage capacity and improves the computational efficiency compared with forward modeling methods based on the conventional grid.
文摘A Hybrid Coordinate Ocean Model (HYCOM) is used to simulate the sea surface temperature of the Tropical and North Pacific. Based on the different combinations of two air-Sea flux data sets (COADS and ECMWF) and two bulk parameter formulas (non-constant and constant), four numerical experiments are carried out. The following conclusions can be deduced from the numerical results. (1) The numerical results using non-constant bulk parameter formula are much better than those using constant one. In the Pacific area from 40°N to 20°S, the annual average SST obtained from the experiment using non-constant bulk parameter formula is 0.21 ℃ higher than that from the satellite-based SST climatology (the pathfinder data). However, the difference is 0.63 ℃ for the experiment when the using constant one. (2) HYCOM successfully simulates the monthly variation of climatological SST in tropical and north Pacific basins and monthly spatial variation of Western Pacific Warm Pool. Especially in the Pacific area from 40°N to 20°S, the difference of the seasonal averaged SST between pathfinder data and the result of experiment 2 (using COADS data set and non-constant bulk parameter formula) is only about 0.02 ℃. (3)The simulation results using different Air-Sea flux data are different and the difference is very large in some regions. In the northwest of the model region, the annual average SST obtained from experiment 2 (using COADS data set) is 1℃ higher than that obtained from experiment 4 (using ECMWF data set). Contrarily, the result of experiment 4 is 1 ℃ larger than that of experiment 2 in the southeast of the model region. The largest difference is about 4 ℃ occurred near the area of 58°N, 140°E and the Bohai sea.
基金supported by the National Natural Science Foundation of China(21103121,21276187)Tianjin Municipal Natural Science Foundation(13JCQNJC05800)the Specialized Research Fund for the Doctoral Program of Higher Education(20121317110009)~~
文摘Two mono iron complexes Fe(CO)2PR3(NN) (R = Cy (3), Ph (4), NN = o-phenylenediamine dianion ligand, N2H2Ph2-) derived from the ligand substitution of Fe(CO)3hPR3 by the NN ligand were isolated and structurally characterized by single crystal X-ray diffraction. They have a similar first coordination sphere and oxidation state of the iron center as the [Fe]-hydrogenase active site, and can be a model of it IR demonstrated that the effect of the NN ligand on the coordinated CO stretch- ing frequencies was due to its excellent electron donating ability. The reversible protonation/deprotonation of the NN ligand was identified by infrared spectroscopy and density functional theory computation. The NN ligand is an effective proton acceptor as the internal base of the cysteine thiolate ligand in [Fe]-hydrogenase. The electrochemical properties of complexes 3, 4 were investigated by cyclic voltammograms. Complex 3 catalyzed the transfer hydrogenation of benzoquinone to hydroquinone effectively under mild conditions.
基金the financial support from the Natural Science Foundation of China(Grant No.52172106)Anhui Provincial Natural Science Foundation(Grant Nos.2108085QB60 and 2108085QB61)China Postdoctoral Science Foundation(Grant Nos.2020M682057 and 2023T160651).
文摘Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites with atomically dispersed oxygen(O)coordination on bacterial cellulose-converted graphitic carbon(Mn-O-C).Evidence of the atomically dispersed Mn-(O-C_(2))_(4)moieties embedding in the exposed basal plane of carbon surface is confirmed by X-ray absorption spectroscopy.As a result,the as-synthesized Mn-O-C catalyst exhibits superior NitRR activity with an NH_(3)yield rate(RNH_(3))of 1476.9±62.6μg h^(−1)cm^(−2)at−0.7 V(vs.reversible hydrogen electrode,RHE)and a faradaic efficiency(FE)of 89.0±3.8%at−0.5 V(vs.RHE)under ambient conditions.Further,when evaluated with a practical flow cell,Mn-O-C shows a high RNH_(3)of 3706.7±552.0μg h^(−1)cm^(−2)at a current density of 100 mA cm−2,2.5 times of that in the H cell.The in situ FT-IR and Raman spectroscopic studies combined with theoretical calculations indicate that the Mn-(O-C_(2))_(4)sites not only effectively inhibit the competitive hydrogen evolution reaction,but also greatly promote the adsorption and activation of nitrate(NO_(3)^(−)),thus boosting both the FE and selectivity of NH_(3)over Mn-(O-C_(2))_(4)sites.
基金Supported by National Natural Science Foundation of China(Grant No.51265017)Jiangxi Provincial Science and Technology Planning Project,China(Grant No.GJJ12468)Science and Technology Planning Project of Ji’an City,China(Grant No.20131828)
文摘The existing articulated arm coordinate measuring machines(AACMM) with one measurement model are easy to cause low measurement accuracy because the whole sampling space is much bigger than the result in the unstable calibration parameters. To compensate for the deficiency of one measurement model, the multiple measurement models are built by the Denavit-Hartenberg's notation, the homemade standard rod components are used as a calibration tool and the Levenberg-Marquardt calibration algorithm is applied to solve the structural parameters in the measurement models. During the tests of multiple measurement models, the sample areas are selected in two situations. It is found that the measurement errors' sigma value(0.083 4 ram) dealt with one measurement model is nearly two times larger than that of the multiple measurement models(0.043 1 ram) in the same sample area. While in the different sample area, the measurement errors' sigma value(0.054 0 ram) dealt with the multiple measurement models is about 40% of one measurement model(0.137 3 mm). The preliminary results suggest that the measurement accuracy of AACMM dealt with multiple measurement models is superior to the accuracy of the existing machine with one measurement model. This paper proposes the multiple measurement models to improve the measurement accuracy of AACMM without increasing any hardware cost.
基金supported by the National Basic Research Program of China ( Grant No.2006CB403302)the National Natural Science Foundation of China (Grant Nos .50839001 and 50709004)the Scientific Research Foundation of the Higher Education Institutions of Liaoning Province (Grant No.2006T018)
文摘The mild-slope equation is familiar to coastal engineers as it can effectively describe wave propagation in nearshore regions. However, its computational method in Cartesian coordinates often renders the model inaccurate in areas with irregular shorelines, such as estuaries and harbors. Based on the hyperbolic mild-slope equation in Cartesian coordinates, the numerical model in orthogonal curvilinear coordinates is developed. The transformed model is discretized by the finite difference method and solved by the ADI method with space-staggered grids. The numerical predictions in curvilinear co- ordinates show good agreemenl with the data obtained in three typical physical expedments, which demonstrates that the present model can be used to simulate wave propagation, for normal incidence and oblique incidence, in domains with complicated topography and boundary conditions.
文摘A new oceanic general circulation model in pressure coordinates is formulated. Since the bottom pressure changes with time, the vertical coordinate is actually a pressure-sigma coordinate. The numerical solution of the model is based on an energy-conservation scheme of finite difference. The most important new feature of the model is that it is a truly compressible ocean model and it is free of the Boussinesq approximations. Thus, the new model is quite different from many existing models in the following ways: 1) the exact form of mass conservation, 2) the in-situ instantaneous pressure and the UNESCO equation of state to calculate density, 3) the in-situ density in the momentum. equations, 4) finite difference schemes that conserve the total energy. Initial tests showed that the model code runs smoothly, and it is quite stable. The quasi-steady circulation patterns generated by the new model compare well with existing models, but the time evolution of the new model seems different from some existing models. Thus, the non-Boussinesq models may provide more accurate information for climate study and satellite observations.
基金supported by the Knowledge Innovation Program of Chinese Academy of Sciences (Grant No. KZCX1-YW-12-03)National Basic Research Program of China (2006CB403600)+3 种基金Project of Young Scientists Fund by National Natural Sciences Foundation of China (Grant No. 40606008)National Science and Technology Infrastructure Program(2006BAC03B04)supported by National Natural Sciences Foundation of China (Grant No.40531006)supported by a private donation from Trond Mohn c/o Frank Mohn AS, Bergenand the MERSEA project from the European Commission (Grant No. SIP3-CT-2003-502885)
文摘The computational cost required by the Ensemble Kalman Filter (EnKF) is much larger than that of some simpler assimilation schemes, such as Optimal Interpolation (OI) or three-dimension variational as- similation (3DVAR). Ensemble optimal interpolation (EnOI), a crudely simplified implementation of EnKF, is sometimes used as a substitute in some oceanic applications and requires much less computational time than EnKF. In this paper, to compromise between computational cost and dynamic covariance, we use the idea of "dressing" a small size dynamical ensemble with a larger number of static ensembles in order to form an approximate dynamic covariance. The term "dressing" means that a dynamical ensemble seed from model runs is perturbed by adding the anomalies of some static ensembles. This dressing EnKF (DrEnKF for short) scheme is tested in assimilation of real altimetry data in the Pacific using the HYbrid Coordinate Ocean Model (HYCOM) over a four-year period. Ten dynamical ensemble seeds are each dressed by 10 static ensemble members selected from a 100-member static ensemble. Results are compared to two EnKF assimilation runs that use 10 and 100 dynamical ensemble members. Both temperature and salinity fields from the DrEnKF and the EnKF are compared to observations from Argo floats and an OI SST dataset. The results show that the DrEnKF and the 100-member EnKF yield similar root mean square errors (RMSE) at every model level. Error covariance matrices from the DrEnKF and the 100-member EnKF are also compared and show good agreement.
文摘Based on the analysis of the advantages and disadvantages of some vertical coordinates applied in the calculation of the Changjiang diluted water (CDW), a new hybrid vertical coordinate is designed, which uses σ coordinate for current and σ-z coordinate for salinity. To combine the current and salinity, the Eulerian-Lagrangian method is used for the salinity calculation, and the baroclinic pressure gradient (BPG) is calculated on the salinity sited layers. The new hybrid vertical coordinate is introduced to the widely used model of POM (Princeton Ocean Model) to make a new model of POM-σ-z. The BPG calculations of an ideal case show that POM-σ-z model brings smaller error than POM model does. The simulations of CDW also show that POM-σ-z model is better than POM model on simulating the salinity and its front.
基金Tsupported by Innovation Fund of Ministry of Science andTechnology of China for Small Technology-Based Firms (Grant No.04C26223400148)
文摘As the market competition among enterprises grows intensively and the demand for high quality products increases rapidly, product quality inspection and control has become one of the most important issues of manufacturing, and improving the efficiency and accuracy of inspection is also one of problems which enterprises must solve. It is particularly important to establish rational inspection planning for parts before inspecting product quality correctly. The traditional inspection methods have been difficult to satisfy the requirements on the speed and accuracy of modern manufacturing, so CAD-based computer-aided inspection planning (CAIP) system with the coordinate measuring machines (CMM) came into being. In this paper, an algorithm for adaptive sampling and collision-free inspection path generation is proposed, aiming at the CAD model-based inspection planning for coordinate measuring machines (CMM). Firstly, using the method of step adaptive subdivision and iteration , the sampling points for the specified number with even distribution will be generated automatically. Then, it generates the initial path by planning the inspection sequence of measurement points according to the values of each point's weight sum of parameters, and detects collision by constructing section lines between the probe swept-volume surfaces and the part surfaces, with axis-aligned bounding box (AABB) filtering to improve the detection efficiency. For collided path segments, it implements collision avoidance firstly aiming at the possible outer-circle features, and then at other collisions, for which the obstacle-avoiding movements are planned with the heuristic rules, and combined with a designed expanded AABB to set the obstacle-avoiding points. The computer experimental results show that the presented algorithm can plan sampling points' locations with strong adaptability for different complexity of general surfaces, and generate efficient optimum path in a short time and avoid collision effectively.
基金supported by the National Natural Science Foundation of China (Grant Nos .51079082 and 40676053)State Key Laboratory of Ocean Engineering ( Grant Nos . GKZD010012, GP010818 and GKZD010024)
文摘For the simulation of the nonlinear wave propagation in coastal areas with complex boundaries, a numerical model is developed in curvilinear coordinates. In the model, the Boussinesq-type equations including the dissipation terms are em- ployed as the governing equations. In the present model, the dependent variables of the transformed equations are the free surface elevation and the utility velocity variables, instead of the usual primitive velocity variables. The introduction of utility velocity variables which are the products of the contravariant components of the velocity vector and the Jacobi ma- trix can make the transformed equations relatively concise, the treatment of lateral boundary conditions easier and the de- velopment of the program simpler. The predictor-corrector method and five-point finite-difference scheme are employed to discretize the time derivatives and the spatial ones, respectively. The numerical model is tested for three cases. It is found that the numerical results are in good agreement with the analytical results and experimental data.
基金partially supported by the Science Foundation of China University of Petroleum,Beijing(2462023XKBH013)the National Natural Science Foundation of China(52202405)。
文摘Cooperation among enterprises can bring overall and individual performance improvement,and a smooth coordination method is indispensable.However,due to the lack of customized coordination methods,cooperation in the downstream oil supply chain cannot be carried out smoothly.This paper intends to propose a multi-party coordination method to promote cooperation between oil shippers and pipeline operator by optimizing oil transportation,oil substitution and pipeline pricing schemes.An integrated game-theoretic modeling and analysis approach is developed to characterize the operation behaviors of all stakeholders in the downstream oil supply chain.The proposed mixed integer nonlinear programming model constrains supply and demand capacity,transportation routes,oil substitution rules and pipeline freight levels.Logarithm transformation and price discretization are introduced for model linear approximation.Simulation experiments are carried out in the oil distribution system in South China.The results show that compared to the business-as-usual scheme,the new scheme saves transportation cost by 3.48%,increases pipeline turnover by 5.7%,and reduces energy consumption and emissions by 7.66%and 6.77%.It is proved that the proposed method improves the revenue of the whole system,achieves fair revenue distribution,and also improves the energy and environmental benefits of the oil supply chain.
基金supported by the National Natural Science Foundation of China(Grant No.50579030)
文摘River ice is a natural phenomenon in cold regions, influenced by meteorology, geomorphology, and hydraulic conditions. River ice processes involve complex interactions between hydrodynamic, mechanical, and thermal processes, and they are also influenced by weather and hydrologic conditions. Because natural rivers are serpentine, with bends, narrows, and straight reaches, the commonly-used one-dimensional river ice models and two-dimensional models based on the rectangular Cartesian coordinates are incapable of simulating the physical phenomena accurately. In order to accurately simulate the complicated river geometry and overcome the difficulties of numerical simulation resulting from both complex boundaries and differences between length and width scales, a two-dimensional river ice numerical model based on a boundary-fitted coordinate transformation method was developed. The presented model considers the influence of the frazil ice accumulation under ice cover and the shape of the leading edge of ice cover during the freezing process. The model is capable of determining the velocity field, the distribution of water temperature, the concentration distribution of frazil ice, the transport of floating ice, the progression, stability, and thawing of ice cover, and the transport, accumulation, and erosion of ice under ice cover. A MacCormack scheme was used to solve the equations numerically. The model was validated with field observations from the Hequ Reach of the Yellow River. Comparison of simulation results with field data indicates that the model is capable of simulating the river ice process with high accuracy.
文摘Based on the primitive equation model with p- σ incorporated coordinate system originally developed by Qian et al., a one-way nested fine mesh limited area model is developed. This model is nested with ECMWF T42 data to simulate the extra-intensive rainfall event occurring in the Changjiang and Huaihe River valleys in summer of 1991. The results show that the model has certain capacity to fairly reproduce the regional distribution and the movement of the main rainfall belts. Therefore it can be used as a regional climate model to simulate and predict the short-range regional climate changes.
基金Supported by the National Natural Science Foundation of China(No.41306020)the National Ocean Subject(No.XDA11020601)+1 种基金the NSFC Shandong Joint Found for Marine Science Research Centers(No.U1406401)the NSFC Innovative Group Grant(No.41421005)
文摘Variations in water exchange through the Kerama Gap (between Okinawa Island and Miyakojima Island) from 1979 to 2003 were estimated with the 0.08° Pacific HYbrid Coordinate Ocean Model (HYCOM). The model results show that the mean transport through the Kerama Gap (KGT) from the Pacific Ocean to the East China Sea (ECS) was 2.1 Sv, which agrees well with the observed mean KGT (2.0 Sv) for 2009- 2010. Over the time period examined, the monthly KGT varied from -10.9 Sv to 15.8 Sv and had a standard deviation of +5.0 Sv. The water mainly enters the ECS via the subsurface layer (300-500 m) along the northeastern slope of the Kerama Gap and mainly flows out of the ECS into the southwest of the Kerama Gap. The seasonal and interannual variations of the KGT and the Kuroshio upstream transport were negatively correlated. The Kuroshio upstream transport was largest in summer and smallest in auamm while the KGT was smallest in summer (1.02 Sv) and largest in spring (2.94 Sv) and autumn (2.44 Sv). The seasonal and interarmual variations in the Kuroshio downstream (across the PN-line) transport differed significantly from the Kuroshio upstream transport but corresponded well with the KGT and the sum of the transport through the Kerama Gap and the Kuroshio upstream, which indicates that information about variation in the KGT is important for determining variation in the Kuroshio transport along the PN-line.
基金Supported by National Natural Science Foundation of P. R. China (69804003, 50576022)the Natural Science Foundation of Beijing (4062030)
文摘In unit steam-boiler generation, a coordinated control strategy is required to ensure a higher rate of load change without violating thermal constraints. The process is characterized by nonlinearity and uncertainty. While neural networks can model highly complex nonlinear dynamical systems, they produce black box models. This has led to significant interest in neuro-fuzzy networks (NFNs) to represent a nonlinear dynamical process by a set of locally valid and simpler submodels. Two alternative methods of exploiting the NFNs within a generalised predictive control (GPC) framework for nonlinear model predictive control are described. Coordinated control of steam-boiler generation using the two nonlinear GPC methods show excellent tracking and disturbance rejection results and improved performance compared with conventional linear GPC.
基金supported by the Beijing Social Science Foundation Project(Grant No.18YJB011)the Ministry of Education Humanities and Social Science Research Fund for Youth Project(Grant No.20YJA790059)+2 种基金the National Social Science Foundation of China(Grant No.20FGLB022)the General Project of National Social Science Foundation of China(Grant No.19BGL052)the Innovation and Entrepreneurship Project of Beijing Forestry University(Grant No.X202110022111).
文摘Based on the general requirements of the coordinated development of"ecological livable"and"affluent life"in the rural revitalization strategy,the evaluation index system of desertification control was constructed,the interaction between desertification control and regional social economy and the internal space-time coordination mechanism were explored,and the quality of desertification control and its coordination degree with regional economic development were quantitatively analyzed.The decoupling mechanism of desertification governance society economy system were analyzed,and the high level for the government to promote desertification governance,constructing ecological economy coordinated development pattern to provide decision basis to Xizang desertification governance-social economic system interaction and coupling coordination development as the research object,introducing the coupling decoupling model to measure the coupling coordination model and system coordination and decoupling decoupling.Desertification control in Xizang shows a trend of gradual improvement,but the overall level is still not high and there is a lot of room for optimization.The coupling coordination degree of desertification control-social and economic system is in a steady fluctuation trend,rising from D value less than 0.55 in 2004 to 0.87 in 2018,in a state of coordinated development(good),and grey prediction analysis shows that D value is in a continuous rise.The coupling coordination degree of the six prefecture-level cities in Xizang and Ngari region is different in time and space,but the overall development trend is coordinated.The development index of desertification control and the socio-economic development index show the interaction of strong decoupling,strong negative decoupling and weak decoupling,and there are interaction effects of desertification control,economic development and social development at different scales.
基金financial support from the Hunan Provincial Key Research and Development Program(2020WK2018)the Arts Crafts Industrial Design Center of Hunan Province(No.2022GYMSZ2)the Scientific Innovation Fund for Post-Graduates of Central South University of Forestry and Technology(No.2022CX02079).
文摘In the study,it is proposed that a coordinate-parametric matrix model is performed to a square-conjoint pattern of cross woven(SCPCW)in the bamboo mat.The patterns of SCPCW are firstly detected according to the perspective of configuration,which is divided into the basic-monomer shape and the basic combination shape.Secondly,the compositions of design patterns in SCPCW are analyzed to attain the trend of curve shape.Based on the coordinate-parametric matrix model,the specimens of SCPCW are subsequently accomplished to elaborate the woven logic of bamboo mats.The digital innovation of SCPCW,defined by a mathematical resolution,is implemented by the software of Grasshopper(GH),which plays a crucial role in capturing image information by the Image Sampler component.Successively,the weaving logic of coordinated matrix is referred to apply in the computing component of Grasshopper software.Finally,the computer simulation could demonstrate that the coordinate-parametric matrix model of SCPCWwould be realized to analyze the micro-weaving structure and overall weaving effect in the bamboo mat.
基金Supported by the National High Technology Research and Development Program of China(863 Program)(Nos.2007AA09Z118,2008AA09A402)the National Natural Science Foundation of China(No.41076006)+1 种基金the International Cooperate Fund of NNSFC(No.40810104046)the Program for New Century Excellent Talents in University(111 Project)(No.B07036)
文摘A three-dimensional isopycnic-coordinate ocean model for the study of internal tides is presented. In this model, the ocean interior is viewed as a stack of isopycnic layers, each characterized by a constant density. The isopycnic coordinate performs well at tracking the depth variance of the thermocline, and is suitable for simulation of internal tides. This model consists of external and internal modes, and barotropic and baroclinic motions are calculated in the two modes, respectively. The capability of simulating internal tides was verified by comparing model results with an analytical solution. The model was then applied to the simulation of internal tides in the South China Sea (SCS) with the forcing of M2 and K1 tidal constituents. The results show that internal tides in the SCS are mainly generated in the Luzon Strait. The generated M2 internal tides propagate away in three different directions (branches). The branch with the widest tidal beam propagates eastward into the Pacific Ocean, the most energetic branch propagates westward toward Dongsha Island, and the least energetic branch propagates southwestward into the basin of the SCS. The generated KI internal tides propagate in two different directions (branches). One branch propagates eastward into the Pacific Ocean, and the other branch propagates southwestward into the SCS basin. The steepening process of internal tides due to shoaling effects is described briefly. Meridionally integrated westward energy fluxes into the SCS are comparable to the meridionally integrated eastward energy fluxes into the Pacific Ocean.