Anaerobic process is regarded as a green and sustainable process due to low carbon emission and minimal energy consumption in wastewater treatment plants(WWTPs).However,some water quality metrics are not measurable in...Anaerobic process is regarded as a green and sustainable process due to low carbon emission and minimal energy consumption in wastewater treatment plants(WWTPs).However,some water quality metrics are not measurable in real time,thus influencing the judgment of the operators and may increase energy consumption and carbon emission.One of the solutions is using a soft-sensor prediction technique.This article introduces a water quality soft-sensor prediction method based on Bidirectional Gated Recurrent Unit(BiGRU)combined with Gaussian Progress Regression(GPR)optimized by Tree-structured Parzen Estimator(TPE).TPE automatically optimizes the hyperparameters of BiGRU,and BiGRU is trained to obtain the point prediction with GPR for the interval prediction.Then,a case study applying this prediction method for an actual anaerobic process(2500 m^(3)/d)is carried out.Results show that TPE effectively optimizes the hyperparameters of BiGRU.For point prediction of CODeff and biogas yield,R^(2)values of BiGRU,which are 0.973 and 0.939,respectively,are increased by 1.03%–7.61%and 1.28%–10.33%,compared with those of other models,and the valid prediction interval can be obtained.Besides,the proposed model is assessed as a reliable model for anaerobic process through the probability prediction and reliable evaluation.It is expected to provide high accuracy and reliable water quality prediction to offer basis for operators in WWTPs to control the reactor and minimize carbon emission and energy consumption.展开更多
A new anaerobic reactor, Jet-loop anaerobic fluidized bed (JLAFB), was designed for treating high-sulfate wastewater. The treatment characteristics, including the effect of influent COD/SO42 ratio and alkalinity and...A new anaerobic reactor, Jet-loop anaerobic fluidized bed (JLAFB), was designed for treating high-sulfate wastewater. The treatment characteristics, including the effect of influent COD/SO42 ratio and alkalinity and sulfide inhibition in reactors, were discussed for a JLAFB and a general anaerobic fiuidized bed (AFB) reactor used as sulfate-reducing phase and methane-producing phase, respectively, in two-phase anaerobic digestion process. The formation of granules in the two reactors was also examined. The results indicated that COD and sulfate removal had different demand of influent COD/SO4^2- ratios. When total COD removal was up to 85%, the ratio was only required up to 1.2, whereas, total sulfate removal up to 95% required it exceeding 3.0. The alkalinity in the two reactors increased linearly with the growth of influent alkalinity. Moreover, the change of influent alkalinity had no significant effect on pH and volatile fatty acids (VFA) in the two reactors. Influent alkalinity kept at 400-500 mg/L could meet the requirement of the treating process. The JLAFB reactor had great advantage in avoiding sulfide and free-H2S accumulation and toxicity inhibition on microorganisms. When sulfate loading rate was up to 8. 1 kg/(m^3.d), the sulfide and free-H2S concentrations in JLAFB reactor were 58.6 and 49.7 mg/L, respectively. Furthermore, the granules, with offwhite color, ellipse shape and diameters of 1.0-3.0 mm, could be developed in JLAFB reactor. In granules, different groups of bacteria were distributed in different layers, and some inorganic metal compounds such as Fe, Ca, Mg etc. were found.展开更多
1 Introduction Recently the demand for fossil fuel has grown significantly with the rapid development of the Chinese economy.Renewable energy was developed to replace traditional fossil fuels,which would decrease the
Periodic anaerobic baffled reactor (PABR) is a novel reactor based on the design concept of anaerobic baffled reactor (ABR). Residence time distribution (RTD) studies on both clean and working reactors at the sa...Periodic anaerobic baffled reactor (PABR) is a novel reactor based on the design concept of anaerobic baffled reactor (ABR). Residence time distribution (RTD) studies on both clean and working reactors at the same hydraulic residence time (HRT) of 2 d were carded out to investigate the dead spaces and mixing patterns in PABRs at different organic loading rates (OLRs) in various switching manners and frequencies. The results showed that the fraction of dead space in PABR was similar to that in ABR, which was low in comparison with other reactor designs. Dead space may be divided into two categories, hydraulic and biological. In RTD studies without biomass, the hydraulic dead space in the PABR run in an "every second" switching manner with T = 2 d was the lowest whereas that in the PABR run in a T = ∞ (ABR) switching manner was the highest. The same trend was obtained with the total dead space in RTD studies with biomass no matter what the OLR was. Biological dead space was the major contributor to dead space but affected decreasingly at higher OLR whichever switching manner the PABR run in. The flow patterns within the PABRs were intermediate between plug-flow and perfectly mixed under all the conditions tested,展开更多
In this study,a sequential process(heterotrophic up-flow column and completely mixed membrane bioreactors)was proposed combining advantages of the both processes.The system was operated for 249 days with simulated and...In this study,a sequential process(heterotrophic up-flow column and completely mixed membrane bioreactors)was proposed combining advantages of the both processes.The system was operated for 249 days with simulated and real groundwater for nitrate removal at concentrations varying from 25 to 145 mg·L^(-1) NO_(3)^(-)-N.The contribution of heterotrophic process to total nitrate removal in the system was controlled by dozing the ethanol considering the nitrate concentration.By this way,sulfur based autotrophic denitrification rate was decreased and the effluent sulfate concentrations were controlled.The alkalinity requirement in the autotrophic process was produced in the heterotrophic reactor,and the system was operated without alkalinity supplementation.Throughout the study,the chemical oxygen demand in the heterotrophic reactor effluent was(23.7±22)mg L^(-1) and it was further decreased to(7.5±7.2)mg·L^(-1) in the system effluent,corresponding to a 70%reduction.In the last period of the study,the real groundwater containing 145 mg·L^(-1) NO_(3)^(-)-N was completely removed.Membrane was operated without chemical washing in the first 114 days.Between days 115-249 weekly chemical washing was required.展开更多
In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been co...In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been conducted. The test results shows that under moderate temperature, with 5\^2 kgCOD/(m\+3·d) volumetric load of COD Cr in the UASB reactor and 24h of HRT, 85% removal rate of BOD 5 and 83% of COD \{Cr\} and 1\^34 m\+3/(m\+3·d) volumetric gas production rate can be obtained respectively. The aerobic bio degradability can be increased by 20%—30% after the petro chemical wastewater has been treated by anaerobic process. As Ns=0\^45 kgCOD/(kgMLSS·d), HRT=4h in the aeration tank, 94% removal rate of BOD 5, 93% of COD \{Cr\}, 98\^8% total removal rate of COD \{Cr\} and 99% removal rate of BOD 5 can be reached.展开更多
Stability, boundedness and persistence are three important aspects for an ecological model. In this paper, a further analysis of a class of anaerobic digestion ecological models is performed. Based on the Liupunov Met...Stability, boundedness and persistence are three important aspects for an ecological model. In this paper, a further analysis of a class of anaerobic digestion ecological models is performed. Based on the Liupunov Method, the local stability of all equilibria in the system is got. According to the vector fields described by the system, the proof of the boundedness of the solution on the anaerobic digestion processes is completed in three steps. The method proposed in the discussion on the boundedness can be generalized to the similar problems. Results in this paper give information on how to run the ecological system well by adjusting the system parameters.展开更多
The effect of free ammonia on volatile fatty acid (VFA) accumulation and process instability was studied using a lab-scale anaerobic digester fed by two typical bio-wastes: fruit and vegetable waste (FVW) and foo...The effect of free ammonia on volatile fatty acid (VFA) accumulation and process instability was studied using a lab-scale anaerobic digester fed by two typical bio-wastes: fruit and vegetable waste (FVW) and food waste (FW) at 35℃ with an organic loading rate (OLR) of 3.0 kg VS/(m3-day). The inhibitory effects of free ammonia on methanogenesis were observed due to the low C/N ratio of each substrate (15.6 and 17.2, respectively). A high concentration of free ammonia inhibited methanogenesis resulting in the accumulation of VFAs and a low methane yield. In the inhibited state, acetate accumulated more quickly than propionate and was the main type of accumulated VFA. The co-accumulation of ammonia and VFAs led to an "inhibited steady state" and the ammonia was the main inhibitory substance that triggered the process perturbation. By statistical significance test and VFA fluctuation ratio analysis, the free ammonia inhibition threshold was identified as 45 mg/L. Moreover, propionate, iso-butyrate and valerate were determined to be the three most sensitive VFA parameters that were subject to ammonia inhibition.展开更多
A bench-scale anaerobic/anoxic/aerobic process-biological aerated filter (A^2/O-BAF) combined system was carded out to treat wastewater with lower C/N and C/P ratios. The A^2/O process was operated in a short aerobi...A bench-scale anaerobic/anoxic/aerobic process-biological aerated filter (A^2/O-BAF) combined system was carded out to treat wastewater with lower C/N and C/P ratios. The A^2/O process was operated in a short aerobic sludge retention time (SRT) for organic pollutants and phosphorus removal, and denitrification. The subsequent BAF process was mainly used for nitrification. The BAF effluent was partially returned to anoxic zone of the A^2/O process to provide electron acceptors for denitrification and anoxic P uptake. This unique system formed an environment for reproducing the denitdfying phosphate-accumulating organisms (DPAOs). The ratio of DPAOs to phosphorus accumulating organisms (PAOs) could be maintained at 28% by optimizing the organic loads in the anaerobic zone and the nitrate loads into the anoxic zone in the A^2/O process. The aerobic phosphorus over-uptake and discharge of excess activated sludge was the main mechanism of phosphorus removal in the combined system. The aerobic SRT of the A^2/O process should meet the demands for the development of aerobic PAOs and the restraint on the nitrifiers growth, and the contact time in the aerobic zone of the A^2/O process should be longer than 30 min, which ensured efficient phosphorus removal in the combined system. The adequate BAF effluent return rates should be controlled with 1--4 mg/L nitrate nitrogen in the anoxic zone effluent of A^2/O process to achieve the optimal nitrogen and phosphorus removal efficiencies.展开更多
The analysis of seven aliphatic carboxylic acids(formic,acetic,propionic,iso-butyric,n-butyric,iso-valeric and n-valeric acid) in anaerobic digestion process waters for biogas production was examined by ion-exclusion ...The analysis of seven aliphatic carboxylic acids(formic,acetic,propionic,iso-butyric,n-butyric,iso-valeric and n-valeric acid) in anaerobic digestion process waters for biogas production was examined by ion-exclusion chromatography with dilute acidic eluents(benzoic acid,perfluorobutyric acid(PFBA) and sulfuric acid) and non-suppressed conductivity/ultraviolet(UV) detection.The columns used were a styrene/divinylbenzene-based strongly acidic cation-exchange resin column(TSKgel SCX) and a polymethacrylate-based weakly acidic cation-exchange resin column(TSKgel Super IC-A/C).Good separation was performed on the TSKgel SCX in shorter retention times.For the TSKgel Super IC-A/C,peak shape of the acids was sharp and symmetrical in spite of longer retention times.In addition,the mutual separation of the acids was good except for iso-and n-butyric acids.The better separation and good detection was achieved by using the two columns(TSKgel SCX and TSKgel Super IC-A/C connected in series),lower concentrations of PFBA and sulfuric acid as eluents,non-suppressed conductivity detection and UV detection at 210 nm.This analysis was applied to anaerobic digestion process waters.The chromatograms with conductivity detection were relatively simpler compared with those of UV detection.The use of two columns with different selectivities for the aliphatic carboxylic acids and the two detection modes was effective for the determination and identification of the analytes in anaerobic digestion process waters containing complex matrices.展开更多
N,N-Dimethyldithiocarbamate (DMDTC) is a typical precursor of N-nitrosodimethylamine (NDMA). Based on separate hydrolysis, sorption and biodegradation studies of DMDTC, a laboratory-scale anaerobic-anoxic-oxic (...N,N-Dimethyldithiocarbamate (DMDTC) is a typical precursor of N-nitrosodimethylamine (NDMA). Based on separate hydrolysis, sorption and biodegradation studies of DMDTC, a laboratory-scale anaerobic-anoxic-oxic (AAO) system was established to investigate the removal mechanism of DMDTC in this nutrient removal biological treatment system. DMDTC hydrolyzed easily in water solution under either acidic conditions or strong alkaline conditions, and dimethylamine (DMA) was the main hydrolysate. Under anaerobic, anoxic or oxic conditions, DMDTC was biodegraded and completely mineralized. Furthermore, DMA was the main intermediate in DMDTC biodegradation. In the AAO system, the optimal conditions for both nutrient and DMDTC removal were hydraulic retention time 8 hr, sludge retention time 20 day, mixed-liquor return ratio 3:1 and sludge return ratio 1:1. Under these conditions, the removal efficiency of DMDTC reached 99.5%; the removal efficiencies of chemical organic demand, ammonium nitrogen, total nitrogen and total phosphorus were 90%, 98%, 81% and 93%, respectively. Biodegradation is the dominant mechanism for DMDTC removal in the AAO system, which was elucidated as consisting of two steps: first, DMDTC is transformed to DMA in the anaerobic and anoxic units, and then DMA is mineralized to CO2 and NH3 in the anoxic and oxic units. The mineralization of DMDTC in the biological treatment system can effectively avoid the formation of NDMA during subsequent disinfection processes.展开更多
This study investigated the degradation and production of volatile fatty acids(VFAs)in the acidogenic phase reactor of a two-phase anaerobic system.20 mmol/L bromoethanesulfonic acid(BESA)was used to inhibit acido...This study investigated the degradation and production of volatile fatty acids(VFAs)in the acidogenic phase reactor of a two-phase anaerobic system.20 mmol/L bromoethanesulfonic acid(BESA)was used to inhibit acidogenic methanogens(which were present in the acidogenic phase reactor)from degrading VFAs.The impact of undissociated volatile fatty acids(un VFAs)on"net"VFAs production in the acidogenic phase reactor was then evaluated,with the exclusion of concurrent VFAs degradation."Net"VFAs production from glucose degradation was partially inhibited at high un VFAs concentrations,with 59%,37% and 60% reduction in production rates at 2190 mg chemical oxygen demand(COD)/L undissociated acetic acid(un HAc),2130 mg COD/L undissociated propionic acid(un HPr)and 2280 mg COD/L undissociated n-butyric acid(un HBu),respectively.The profile of VFAs produced further indicated that while an un VFA can primarily affect its own formation,there were also un VFAs that affected the formation of other VFAs.展开更多
Volatile fatty acids(VFAs), which are largely generated during the anaerobic acidification process, are considered to be reliable indicators of the stable process operation. However,the common methods for monitoring V...Volatile fatty acids(VFAs), which are largely generated during the anaerobic acidification process, are considered to be reliable indicators of the stable process operation. However,the common methods for monitoring VFAs are offline, and they are typically manual requiring time-consuming, costly and complex instruments. This study aims to develop a novel online analyzer for automatic measuring VFAs, which was based on the 5-p H point titration, embedded with a proportional-integral-derivative(PID) feedback control system. The results show that it can achieve accurate and rapid monitoring of VFAs ranging between 0-400 mg/L(<9 min/sample) but simultaneously faces the problems of overtitration and interference of complex characteristics of wastewater. In order to improve its accuracy and stability, the effects of three general coefficients(K_(I),K_(P), and K_(D)) of PID on the titration were investigated, and the optimal values of K_(I), K_(P), and K_(D)were found to be 1.5, 1.0, and-1.0~0.5,respectively. Besides, the initial titration speed was set at 0.06 m L/min, equal to the minimum speed of the peristaltic pump, and the dichotomy approach was integrated into the PID feedback controller. Owing to the above improvements, the relative mean deviation and standard deviation of measuring VFAs in both synthetic and real wastewaters were mostly lower than 5.0% and 5.0 mg/L, proving the online analyzer is rapid, accurate and reliable.展开更多
基金This research was supported by the National Natural Science Foundation of China(Nos.41977300 and 41907297)the Science and Technology Program of Guangzhou(China)(No.202002020055)the Fujian Provincial Natural Science Foundation(China)(No.2020I1001).
文摘Anaerobic process is regarded as a green and sustainable process due to low carbon emission and minimal energy consumption in wastewater treatment plants(WWTPs).However,some water quality metrics are not measurable in real time,thus influencing the judgment of the operators and may increase energy consumption and carbon emission.One of the solutions is using a soft-sensor prediction technique.This article introduces a water quality soft-sensor prediction method based on Bidirectional Gated Recurrent Unit(BiGRU)combined with Gaussian Progress Regression(GPR)optimized by Tree-structured Parzen Estimator(TPE).TPE automatically optimizes the hyperparameters of BiGRU,and BiGRU is trained to obtain the point prediction with GPR for the interval prediction.Then,a case study applying this prediction method for an actual anaerobic process(2500 m^(3)/d)is carried out.Results show that TPE effectively optimizes the hyperparameters of BiGRU.For point prediction of CODeff and biogas yield,R^(2)values of BiGRU,which are 0.973 and 0.939,respectively,are increased by 1.03%–7.61%and 1.28%–10.33%,compared with those of other models,and the valid prediction interval can be obtained.Besides,the proposed model is assessed as a reliable model for anaerobic process through the probability prediction and reliable evaluation.It is expected to provide high accuracy and reliable water quality prediction to offer basis for operators in WWTPs to control the reactor and minimize carbon emission and energy consumption.
基金Project supported by the National Natural Science Foundation of China(No. 50278036)the Natural Science Foundation of Guangdong Province (No. 04105951)
文摘A new anaerobic reactor, Jet-loop anaerobic fluidized bed (JLAFB), was designed for treating high-sulfate wastewater. The treatment characteristics, including the effect of influent COD/SO42 ratio and alkalinity and sulfide inhibition in reactors, were discussed for a JLAFB and a general anaerobic fiuidized bed (AFB) reactor used as sulfate-reducing phase and methane-producing phase, respectively, in two-phase anaerobic digestion process. The formation of granules in the two reactors was also examined. The results indicated that COD and sulfate removal had different demand of influent COD/SO4^2- ratios. When total COD removal was up to 85%, the ratio was only required up to 1.2, whereas, total sulfate removal up to 95% required it exceeding 3.0. The alkalinity in the two reactors increased linearly with the growth of influent alkalinity. Moreover, the change of influent alkalinity had no significant effect on pH and volatile fatty acids (VFA) in the two reactors. Influent alkalinity kept at 400-500 mg/L could meet the requirement of the treating process. The JLAFB reactor had great advantage in avoiding sulfide and free-H2S accumulation and toxicity inhibition on microorganisms. When sulfate loading rate was up to 8. 1 kg/(m^3.d), the sulfide and free-H2S concentrations in JLAFB reactor were 58.6 and 49.7 mg/L, respectively. Furthermore, the granules, with offwhite color, ellipse shape and diameters of 1.0-3.0 mm, could be developed in JLAFB reactor. In granules, different groups of bacteria were distributed in different layers, and some inorganic metal compounds such as Fe, Ca, Mg etc. were found.
基金National Natural Science Foundation of China (41572326) for the support of this study
文摘1 Introduction Recently the demand for fossil fuel has grown significantly with the rapid development of the Chinese economy.Renewable energy was developed to replace traditional fossil fuels,which would decrease the
基金Project supported by the Hi-Tech Research and Development Program (863) of China (No.2002AA601310).
文摘Periodic anaerobic baffled reactor (PABR) is a novel reactor based on the design concept of anaerobic baffled reactor (ABR). Residence time distribution (RTD) studies on both clean and working reactors at the same hydraulic residence time (HRT) of 2 d were carded out to investigate the dead spaces and mixing patterns in PABRs at different organic loading rates (OLRs) in various switching manners and frequencies. The results showed that the fraction of dead space in PABR was similar to that in ABR, which was low in comparison with other reactor designs. Dead space may be divided into two categories, hydraulic and biological. In RTD studies without biomass, the hydraulic dead space in the PABR run in an "every second" switching manner with T = 2 d was the lowest whereas that in the PABR run in a T = ∞ (ABR) switching manner was the highest. The same trend was obtained with the total dead space in RTD studies with biomass no matter what the OLR was. Biological dead space was the major contributor to dead space but affected decreasingly at higher OLR whichever switching manner the PABR run in. The flow patterns within the PABRs were intermediate between plug-flow and perfectly mixed under all the conditions tested,
基金supported by Harran University Scientific Research Projects Coordination Unit(HUBAP,project no 18018)。
文摘In this study,a sequential process(heterotrophic up-flow column and completely mixed membrane bioreactors)was proposed combining advantages of the both processes.The system was operated for 249 days with simulated and real groundwater for nitrate removal at concentrations varying from 25 to 145 mg·L^(-1) NO_(3)^(-)-N.The contribution of heterotrophic process to total nitrate removal in the system was controlled by dozing the ethanol considering the nitrate concentration.By this way,sulfur based autotrophic denitrification rate was decreased and the effluent sulfate concentrations were controlled.The alkalinity requirement in the autotrophic process was produced in the heterotrophic reactor,and the system was operated without alkalinity supplementation.Throughout the study,the chemical oxygen demand in the heterotrophic reactor effluent was(23.7±22)mg L^(-1) and it was further decreased to(7.5±7.2)mg·L^(-1) in the system effluent,corresponding to a 70%reduction.In the last period of the study,the real groundwater containing 145 mg·L^(-1) NO_(3)^(-)-N was completely removed.Membrane was operated without chemical washing in the first 114 days.Between days 115-249 weekly chemical washing was required.
文摘In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been conducted. The test results shows that under moderate temperature, with 5\^2 kgCOD/(m\+3·d) volumetric load of COD Cr in the UASB reactor and 24h of HRT, 85% removal rate of BOD 5 and 83% of COD \{Cr\} and 1\^34 m\+3/(m\+3·d) volumetric gas production rate can be obtained respectively. The aerobic bio degradability can be increased by 20%—30% after the petro chemical wastewater has been treated by anaerobic process. As Ns=0\^45 kgCOD/(kgMLSS·d), HRT=4h in the aeration tank, 94% removal rate of BOD 5, 93% of COD \{Cr\}, 98\^8% total removal rate of COD \{Cr\} and 99% removal rate of BOD 5 can be reached.
基金Supported by the National Natural Science Foundation of China (No.60372012) and NSF of Chongqing (No.0831)
文摘Stability, boundedness and persistence are three important aspects for an ecological model. In this paper, a further analysis of a class of anaerobic digestion ecological models is performed. Based on the Liupunov Method, the local stability of all equilibria in the system is got. According to the vector fields described by the system, the proof of the boundedness of the solution on the anaerobic digestion processes is completed in three steps. The method proposed in the discussion on the boundedness can be generalized to the similar problems. Results in this paper give information on how to run the ecological system well by adjusting the system parameters.
基金supported by the Ministry of Science and Technology of China(Nos.2008BADC4B18,2014BAC27B01)
文摘The effect of free ammonia on volatile fatty acid (VFA) accumulation and process instability was studied using a lab-scale anaerobic digester fed by two typical bio-wastes: fruit and vegetable waste (FVW) and food waste (FW) at 35℃ with an organic loading rate (OLR) of 3.0 kg VS/(m3-day). The inhibitory effects of free ammonia on methanogenesis were observed due to the low C/N ratio of each substrate (15.6 and 17.2, respectively). A high concentration of free ammonia inhibited methanogenesis resulting in the accumulation of VFAs and a low methane yield. In the inhibited state, acetate accumulated more quickly than propionate and was the main type of accumulated VFA. The co-accumulation of ammonia and VFAs led to an "inhibited steady state" and the ammonia was the main inhibitory substance that triggered the process perturbation. By statistical significance test and VFA fluctuation ratio analysis, the free ammonia inhibition threshold was identified as 45 mg/L. Moreover, propionate, iso-butyrate and valerate were determined to be the three most sensitive VFA parameters that were subject to ammonia inhibition.
文摘A bench-scale anaerobic/anoxic/aerobic process-biological aerated filter (A^2/O-BAF) combined system was carded out to treat wastewater with lower C/N and C/P ratios. The A^2/O process was operated in a short aerobic sludge retention time (SRT) for organic pollutants and phosphorus removal, and denitrification. The subsequent BAF process was mainly used for nitrification. The BAF effluent was partially returned to anoxic zone of the A^2/O process to provide electron acceptors for denitrification and anoxic P uptake. This unique system formed an environment for reproducing the denitdfying phosphate-accumulating organisms (DPAOs). The ratio of DPAOs to phosphorus accumulating organisms (PAOs) could be maintained at 28% by optimizing the organic loads in the anaerobic zone and the nitrate loads into the anoxic zone in the A^2/O process. The aerobic phosphorus over-uptake and discharge of excess activated sludge was the main mechanism of phosphorus removal in the combined system. The aerobic SRT of the A^2/O process should meet the demands for the development of aerobic PAOs and the restraint on the nitrifiers growth, and the contact time in the aerobic zone of the A^2/O process should be longer than 30 min, which ensured efficient phosphorus removal in the combined system. The adequate BAF effluent return rates should be controlled with 1--4 mg/L nitrate nitrogen in the anoxic zone effluent of A^2/O process to achieve the optimal nitrogen and phosphorus removal efficiencies.
文摘The analysis of seven aliphatic carboxylic acids(formic,acetic,propionic,iso-butyric,n-butyric,iso-valeric and n-valeric acid) in anaerobic digestion process waters for biogas production was examined by ion-exclusion chromatography with dilute acidic eluents(benzoic acid,perfluorobutyric acid(PFBA) and sulfuric acid) and non-suppressed conductivity/ultraviolet(UV) detection.The columns used were a styrene/divinylbenzene-based strongly acidic cation-exchange resin column(TSKgel SCX) and a polymethacrylate-based weakly acidic cation-exchange resin column(TSKgel Super IC-A/C).Good separation was performed on the TSKgel SCX in shorter retention times.For the TSKgel Super IC-A/C,peak shape of the acids was sharp and symmetrical in spite of longer retention times.In addition,the mutual separation of the acids was good except for iso-and n-butyric acids.The better separation and good detection was achieved by using the two columns(TSKgel SCX and TSKgel Super IC-A/C connected in series),lower concentrations of PFBA and sulfuric acid as eluents,non-suppressed conductivity detection and UV detection at 210 nm.This analysis was applied to anaerobic digestion process waters.The chromatograms with conductivity detection were relatively simpler compared with those of UV detection.The use of two columns with different selectivities for the aliphatic carboxylic acids and the two detection modes was effective for the determination and identification of the analytes in anaerobic digestion process waters containing complex matrices.
基金supported by the National Natural Science Foundation of China(No.50878165)the Program for New Century Excellent Talents in University(No.NCET-08-0403)+1 种基金the National Hi-Tech Research and Development Program(863)of China(No.2011AA060902)the Fundamental Research Funds for the Central Universities(No.2012KJ019)
文摘N,N-Dimethyldithiocarbamate (DMDTC) is a typical precursor of N-nitrosodimethylamine (NDMA). Based on separate hydrolysis, sorption and biodegradation studies of DMDTC, a laboratory-scale anaerobic-anoxic-oxic (AAO) system was established to investigate the removal mechanism of DMDTC in this nutrient removal biological treatment system. DMDTC hydrolyzed easily in water solution under either acidic conditions or strong alkaline conditions, and dimethylamine (DMA) was the main hydrolysate. Under anaerobic, anoxic or oxic conditions, DMDTC was biodegraded and completely mineralized. Furthermore, DMA was the main intermediate in DMDTC biodegradation. In the AAO system, the optimal conditions for both nutrient and DMDTC removal were hydraulic retention time 8 hr, sludge retention time 20 day, mixed-liquor return ratio 3:1 and sludge return ratio 1:1. Under these conditions, the removal efficiency of DMDTC reached 99.5%; the removal efficiencies of chemical organic demand, ammonium nitrogen, total nitrogen and total phosphorus were 90%, 98%, 81% and 93%, respectively. Biodegradation is the dominant mechanism for DMDTC removal in the AAO system, which was elucidated as consisting of two steps: first, DMDTC is transformed to DMA in the anaerobic and anoxic units, and then DMA is mineralized to CO2 and NH3 in the anoxic and oxic units. The mineralization of DMDTC in the biological treatment system can effectively avoid the formation of NDMA during subsequent disinfection processes.
基金supported and administered by the Singapore National Research Foundation(NRF-CRP5-2009-2)
文摘This study investigated the degradation and production of volatile fatty acids(VFAs)in the acidogenic phase reactor of a two-phase anaerobic system.20 mmol/L bromoethanesulfonic acid(BESA)was used to inhibit acidogenic methanogens(which were present in the acidogenic phase reactor)from degrading VFAs.The impact of undissociated volatile fatty acids(un VFAs)on"net"VFAs production in the acidogenic phase reactor was then evaluated,with the exclusion of concurrent VFAs degradation."Net"VFAs production from glucose degradation was partially inhibited at high un VFAs concentrations,with 59%,37% and 60% reduction in production rates at 2190 mg chemical oxygen demand(COD)/L undissociated acetic acid(un HAc),2130 mg COD/L undissociated propionic acid(un HPr)and 2280 mg COD/L undissociated n-butyric acid(un HBu),respectively.The profile of VFAs produced further indicated that while an un VFA can primarily affect its own formation,there were also un VFAs that affected the formation of other VFAs.
基金supported by the National Natural Science Foundation of China (No. 52100040)the National Key Research & Development Program of China (No. 2019YFC1904005)the Natural Science Foundation of Hubei Province (No. 2020CFB403)。
文摘Volatile fatty acids(VFAs), which are largely generated during the anaerobic acidification process, are considered to be reliable indicators of the stable process operation. However,the common methods for monitoring VFAs are offline, and they are typically manual requiring time-consuming, costly and complex instruments. This study aims to develop a novel online analyzer for automatic measuring VFAs, which was based on the 5-p H point titration, embedded with a proportional-integral-derivative(PID) feedback control system. The results show that it can achieve accurate and rapid monitoring of VFAs ranging between 0-400 mg/L(<9 min/sample) but simultaneously faces the problems of overtitration and interference of complex characteristics of wastewater. In order to improve its accuracy and stability, the effects of three general coefficients(K_(I),K_(P), and K_(D)) of PID on the titration were investigated, and the optimal values of K_(I), K_(P), and K_(D)were found to be 1.5, 1.0, and-1.0~0.5,respectively. Besides, the initial titration speed was set at 0.06 m L/min, equal to the minimum speed of the peristaltic pump, and the dichotomy approach was integrated into the PID feedback controller. Owing to the above improvements, the relative mean deviation and standard deviation of measuring VFAs in both synthetic and real wastewaters were mostly lower than 5.0% and 5.0 mg/L, proving the online analyzer is rapid, accurate and reliable.