Tricyanide building block K[Ru(ttpy)(CN)3] and [MnⅢ(salen)](ClO4) have been used to design and synthesize a heterobimetallic one-dimensional(1D) zigzag chain complex 1,[RuⅡ(ttpy)(CN)3 MnⅢ(salen)](ttpy = 4′-(p-toly...Tricyanide building block K[Ru(ttpy)(CN)3] and [MnⅢ(salen)](ClO4) have been used to design and synthesize a heterobimetallic one-dimensional(1D) zigzag chain complex 1,[RuⅡ(ttpy)(CN)3 MnⅢ(salen)](ttpy = 4′-(p-tolyl)-2,2′:6′,2″-terpyridine, salen = N,N?-ethylenebis-(salicylideneaminato)dianion). Single-crystal X-ray diffraction analysis shows complex 1 crystallizes in orthorhombic Pbca space group and the asymmetric unit of 1 contains one[-NC-RuⅡ(ttpy)(CN)(m-CN)-Mn Ⅲ-(salen)-] molecule. In the structure of 1, each [Ru Ⅱ(ttpy)(CN)3]-connects two [MnⅢ(salen)]+ with two cyanide groups in a cis-conformation, and in turn each[MnⅢ(salen)]+ unit links two [RuⅡ(ttpy)(CN)3]-building blocks in a trans-conformation, resulting in a 1D [-NC-RuⅡ-CN-MnⅢ-]n chain. Furthermore, the electronic absorption spectra and luminescence spectroscopy of complex 1 have also been studied.展开更多
The crystal of the title compound, [Co(en)3]4[Ru(CN)6]310H2O (en = ethylenediamine, C2H8N2), is formed from the octahedral cations of Co(en)33+ and anions of Ru(CN)64. The Co atom is coordinated to six nitrogen atoms ...The crystal of the title compound, [Co(en)3]4[Ru(CN)6]310H2O (en = ethylenediamine, C2H8N2), is formed from the octahedral cations of Co(en)33+ and anions of Ru(CN)64. The Co atom is coordinated to six nitrogen atoms of ethylenediamines in a L configuration and the Ru atom is also coordinated to six carbon atoms of cyanides. There is no bridging-cyanide between the metal ions in the structure. The crystal is of monoclinic, space group P21/c with a = 17.686(4), b = 14.496(4), c = 18.019(7) ? b = 116.07(2), V = 4150(2) 3, Z = 2, Mr = 1908.60, C42H116N42O10Co4Ru3, m(MoKa) = 1.391 mm1, Dc = 1.527 g/cm3, F(000) = 2084, R = 0.0520 and wR = 0.1070 for 5443 observed reflections (I > 2s(I)).展开更多
Lithium (Li)-CO_(2) battery is rising as an attractive energy-storage system with the competence of CO_(2) conversion/fixation. However, its practical development is seriously hindered by the high overpotential. Herei...Lithium (Li)-CO_(2) battery is rising as an attractive energy-storage system with the competence of CO_(2) conversion/fixation. However, its practical development is seriously hindered by the high overpotential. Herein, a rational design on a highly catalytic Li-CO_(2) battery electrode built by graphdiyne powder as a multi-functional laminar scaffold with anchored highly dispersed Ru nanoparticles is explored. The strong interaction between the abundant acetylenic bond sites of graphdiyne scaffold and Ru nanoparticles can effectively promote the electrochemical progress and reduce the voltage polarization. The unique channels architecture of the cathodic catalyst with enough space not only accelerates CO_(2) diffusion and electrons/Li+ transport, but also allows a large amount of accommodation for discharged product (Li2CO3) to assure an advanced capacity. The corresponding Li-CO_(2) battery displays an advanced discharged capacity of 15,030 mAh/g at 500 mA/g, great capacity retention of 8873 mAh/g at 2 A/g, high coulombic efficiency of 97.6% at 500 mA/g and superior life span for 120 cycles with voltage gap of 1.67 V under a restricted capacity of 1000 mAh/g at 500 mA/g. Ex/in-situ studies prove that synergy between Ru nanoparticles and acetylene bonds of GDY can boost the round-trip CO_(2)RR and CO_(2)ER kinetics.展开更多
基金Supported by the Science and Technology Research Project of Hubei Provincial Department of Education(China,No.Q20174302)the Scientific Research Foundation of Jingchu University of Technology(No.QN201602)National college students innovation and entrepreneurship training program(No.201811336003,China)
文摘Tricyanide building block K[Ru(ttpy)(CN)3] and [MnⅢ(salen)](ClO4) have been used to design and synthesize a heterobimetallic one-dimensional(1D) zigzag chain complex 1,[RuⅡ(ttpy)(CN)3 MnⅢ(salen)](ttpy = 4′-(p-tolyl)-2,2′:6′,2″-terpyridine, salen = N,N?-ethylenebis-(salicylideneaminato)dianion). Single-crystal X-ray diffraction analysis shows complex 1 crystallizes in orthorhombic Pbca space group and the asymmetric unit of 1 contains one[-NC-RuⅡ(ttpy)(CN)(m-CN)-Mn Ⅲ-(salen)-] molecule. In the structure of 1, each [Ru Ⅱ(ttpy)(CN)3]-connects two [MnⅢ(salen)]+ with two cyanide groups in a cis-conformation, and in turn each[MnⅢ(salen)]+ unit links two [RuⅡ(ttpy)(CN)3]-building blocks in a trans-conformation, resulting in a 1D [-NC-RuⅡ-CN-MnⅢ-]n chain. Furthermore, the electronic absorption spectra and luminescence spectroscopy of complex 1 have also been studied.
基金This subject was supported by the Natural Science Foundation of Shanxi and Hunan Provinces(99JJY2009)
文摘The crystal of the title compound, [Co(en)3]4[Ru(CN)6]310H2O (en = ethylenediamine, C2H8N2), is formed from the octahedral cations of Co(en)33+ and anions of Ru(CN)64. The Co atom is coordinated to six nitrogen atoms of ethylenediamines in a L configuration and the Ru atom is also coordinated to six carbon atoms of cyanides. There is no bridging-cyanide between the metal ions in the structure. The crystal is of monoclinic, space group P21/c with a = 17.686(4), b = 14.496(4), c = 18.019(7) ? b = 116.07(2), V = 4150(2) 3, Z = 2, Mr = 1908.60, C42H116N42O10Co4Ru3, m(MoKa) = 1.391 mm1, Dc = 1.527 g/cm3, F(000) = 2084, R = 0.0520 and wR = 0.1070 for 5443 observed reflections (I > 2s(I)).
基金the National Natural Science Foundation of China(Nos.21971132 and 52072197)Outstanding Youth Foundation of Shandong Province,China(No.ZR2019JQ14)+7 种基金Youth Innovation and Technology Foundation of Shandong Higher Education Institutions,China(No.2019KJC004)Major Scientific and Technological Innovation Project(No.2019JZZY020405)Major Basic Research Program of Natural Science Foundation of Shandong Province(No.ZR2020ZD09)Taishan Scholar Young Talent Program(No.tsqn201909114)the Key Laboratory of Resource Chemistry,Ministry of Education(No.KLRC_ME2101)Scientific and Technological Innovation Promotion Project for Small-medium Enterprises of Shandong Province(No.2022TSGC1257)Major Research Program of Jining City(No.2020ZDZP024)The 111 Project of China(No.D20017).
文摘Lithium (Li)-CO_(2) battery is rising as an attractive energy-storage system with the competence of CO_(2) conversion/fixation. However, its practical development is seriously hindered by the high overpotential. Herein, a rational design on a highly catalytic Li-CO_(2) battery electrode built by graphdiyne powder as a multi-functional laminar scaffold with anchored highly dispersed Ru nanoparticles is explored. The strong interaction between the abundant acetylenic bond sites of graphdiyne scaffold and Ru nanoparticles can effectively promote the electrochemical progress and reduce the voltage polarization. The unique channels architecture of the cathodic catalyst with enough space not only accelerates CO_(2) diffusion and electrons/Li+ transport, but also allows a large amount of accommodation for discharged product (Li2CO3) to assure an advanced capacity. The corresponding Li-CO_(2) battery displays an advanced discharged capacity of 15,030 mAh/g at 500 mA/g, great capacity retention of 8873 mAh/g at 2 A/g, high coulombic efficiency of 97.6% at 500 mA/g and superior life span for 120 cycles with voltage gap of 1.67 V under a restricted capacity of 1000 mAh/g at 500 mA/g. Ex/in-situ studies prove that synergy between Ru nanoparticles and acetylene bonds of GDY can boost the round-trip CO_(2)RR and CO_(2)ER kinetics.
