Here,we demonstrate a readily prepared anthrazoline photocatalyst,which can effectively promote C—O bond formation reactions with the aid of Ni(II)complex.This methodology enables the esterification(36 examples)and e...Here,we demonstrate a readily prepared anthrazoline photocatalyst,which can effectively promote C—O bond formation reactions with the aid of Ni(II)complex.This methodology enables the esterification(36 examples)and etherification(8 examples)with a broad range of scope,allowing aryl and alkyl halides coupled with diverse carboxylic acids/alcohols.Our metal-free photocatalysts have a potential broad application,may serve as an alternative to some iridium and ruthenium based photocatalysts,and are of potential importance to the pharmaceutical industry.展开更多
基金This work was supported by the National Natural Science Foundation of China(22202128)the Fundamental Research Funds for the Central University(GK202205016 and GK202201006)+1 种基金China Postdoctoral Science Foundation(2020M683417)the Natural Science Basic Research Plan in Shaanxi Province of China(2021JQ-302),and the Jiangsu Province Key Laboratory of Fine Petrochemical Engineering(KF2201).
文摘Here,we demonstrate a readily prepared anthrazoline photocatalyst,which can effectively promote C—O bond formation reactions with the aid of Ni(II)complex.This methodology enables the esterification(36 examples)and etherification(8 examples)with a broad range of scope,allowing aryl and alkyl halides coupled with diverse carboxylic acids/alcohols.Our metal-free photocatalysts have a potential broad application,may serve as an alternative to some iridium and ruthenium based photocatalysts,and are of potential importance to the pharmaceutical industry.
