By using auger electron spectroscopy (AES) and diffusion theory to analyze the surface segregation of copper in antibacterial ferritic stainless steel, establishing a diffusion model, and calculating the activation ...By using auger electron spectroscopy (AES) and diffusion theory to analyze the surface segregation of copper in antibacterial ferritic stainless steel, establishing a diffusion model, and calculating the activation energy of diffusion of the copper in ferrite, the affect of surface segregation on the antibacterial capabilities were researched. The results show that the concentration of the copper surface at 973 K and 1 073 K could be expressed asln X^sCu/X^bCu = k0 √Dt/d(-△Hv^Cu+△Hf^tron+ △Hs^Cu)/3RT , with the parameters relating to the concentration of the diffusion layer, the coefficient of diffusion, the length of diffusion, the latent heat of evaporation and the latent heat of fusion. The activation energy of diffusion of copper in ferrite is approximately 221. 688 kJ/mol. The antibacterial property of the steel is improved as the surface segregation of the copper is increased. At 1 073 K for 60 min, the concentration of the surface copper is over three times higher than the basic concentration. The antibacterial property of the stainless steel can reach approximately 99.9%.展开更多
Electric Discharge Machining (EDM) is one of the most efficiently employed non-traditional machining processes for cutting hard-to-cut materials, to geometrically complex shapes that are difficult to machine by conven...Electric Discharge Machining (EDM) is one of the most efficiently employed non-traditional machining processes for cutting hard-to-cut materials, to geometrically complex shapes that are difficult to machine by conventional machines. In the present work, an experimental investigation has been carried out to study the effect of pulsed current on material removal rate, electrode wear, surface roughness and diameteral overcut in corrosion resistant stainless steels viz., 316 L and 17-4 PH. The materials used for the work were machined with different electrode materials such as copper, copper-tungsten and graphite. It is observed that the output parameters such as material removal rate, electrode wear and surface roughness of EDM increase with increase in pulsed current. The results reveal that high material removal rate have been achieved with copper electrode whereas copper-tungsten yielded lower electrode wear, smooth surface finish and good dimensional accuracy.展开更多
Laser processing and laser surface texturing in multiple fields have become a popular topic of study in recent decades. Understanding the principles behind the laser irradiation mechanism is an essential step in choos...Laser processing and laser surface texturing in multiple fields have become a popular topic of study in recent decades. Understanding the principles behind the laser irradiation mechanism is an essential step in choosing the most effective process parameters. Through this study, the effects of power and pulse duration on the structure and surface pattern of stainless steel type 304 were examined, and optimized laser parameters were introduced for desired laser penetration and heat-affected areas on the surface. The analyzed sample was prepared by using variations of pulse durations and different pulsed energies. Looking at the trend of change of non-dimensional temperature along the surface, thickness, and center of the sample, the effects of pulse duration and intensity (corresponding to energy) were observed. Upon considering all the aspects of the irradiated spots, such as heat-affected area diameter, surface patterns, and penetration depth, the advantages and disadvantages of short and long pulse durations are mapped out clearly. Also, a new method to obtain the ablation threshold of stainless steel is introduced, and a thorough analytical solution is obtained.展开更多
文摘By using auger electron spectroscopy (AES) and diffusion theory to analyze the surface segregation of copper in antibacterial ferritic stainless steel, establishing a diffusion model, and calculating the activation energy of diffusion of the copper in ferrite, the affect of surface segregation on the antibacterial capabilities were researched. The results show that the concentration of the copper surface at 973 K and 1 073 K could be expressed asln X^sCu/X^bCu = k0 √Dt/d(-△Hv^Cu+△Hf^tron+ △Hs^Cu)/3RT , with the parameters relating to the concentration of the diffusion layer, the coefficient of diffusion, the length of diffusion, the latent heat of evaporation and the latent heat of fusion. The activation energy of diffusion of copper in ferrite is approximately 221. 688 kJ/mol. The antibacterial property of the steel is improved as the surface segregation of the copper is increased. At 1 073 K for 60 min, the concentration of the surface copper is over three times higher than the basic concentration. The antibacterial property of the stainless steel can reach approximately 99.9%.
文摘Electric Discharge Machining (EDM) is one of the most efficiently employed non-traditional machining processes for cutting hard-to-cut materials, to geometrically complex shapes that are difficult to machine by conventional machines. In the present work, an experimental investigation has been carried out to study the effect of pulsed current on material removal rate, electrode wear, surface roughness and diameteral overcut in corrosion resistant stainless steels viz., 316 L and 17-4 PH. The materials used for the work were machined with different electrode materials such as copper, copper-tungsten and graphite. It is observed that the output parameters such as material removal rate, electrode wear and surface roughness of EDM increase with increase in pulsed current. The results reveal that high material removal rate have been achieved with copper electrode whereas copper-tungsten yielded lower electrode wear, smooth surface finish and good dimensional accuracy.
文摘Laser processing and laser surface texturing in multiple fields have become a popular topic of study in recent decades. Understanding the principles behind the laser irradiation mechanism is an essential step in choosing the most effective process parameters. Through this study, the effects of power and pulse duration on the structure and surface pattern of stainless steel type 304 were examined, and optimized laser parameters were introduced for desired laser penetration and heat-affected areas on the surface. The analyzed sample was prepared by using variations of pulse durations and different pulsed energies. Looking at the trend of change of non-dimensional temperature along the surface, thickness, and center of the sample, the effects of pulse duration and intensity (corresponding to energy) were observed. Upon considering all the aspects of the irradiated spots, such as heat-affected area diameter, surface patterns, and penetration depth, the advantages and disadvantages of short and long pulse durations are mapped out clearly. Also, a new method to obtain the ablation threshold of stainless steel is introduced, and a thorough analytical solution is obtained.