The hydrophilicity, dyeing and antistatic ability of polypropylene microfibre (PPMF) were improved by plasma-induced vapor grafting with acrylic acid. The effects of plasma discharge time, power, liquid phase acrylic ...The hydrophilicity, dyeing and antistatic ability of polypropylene microfibre (PPMF) were improved by plasma-induced vapor grafting with acrylic acid. The effects of plasma discharge time, power, liquid phase acrylic acid temperature and environmental temperature on grafting yield were investigated. The existence of grafted polyacrylic acid (PAA) was verified by ESCA and ATR FT-IR. The morphology of grafted PAA was directly observed by SEM. The wicking test shows that the hydrophilicity of modified PPMF is greatly enhanced. The dyeability test of modified PPMF was carried out using Dispersion Yellow. It was found that the dye uptake ratio is linear to the weight percent of grafting. The antistatic ability was indicated by specific resistance. The specific resistance of modified PPMF was reduced to 10(6) similar to 10(7) Ohm . cm, thus the antistatic ability was considerably improved.展开更多
Lipase preparation from Aspergillus oryzae could act on ester bonds on the surface of poly (ethylene terephthalate) fibers and a possible hydrolytic product mono (2-hydroxyethyl) terephthalate was released. After ...Lipase preparation from Aspergillus oryzae could act on ester bonds on the surface of poly (ethylene terephthalate) fibers and a possible hydrolytic product mono (2-hydroxyethyl) terephthalate was released. After the iipase modification, there were more carboxyi groups on the treated poly (ethylene terephthalate) fabric surface that resulted in binding with more cationic dyes. Increased hydrophilicity and antistatic ability of poly (ethylene terephthalate) samples were found based on moisture regain, water contact angle and static half decay time.展开更多
文摘The hydrophilicity, dyeing and antistatic ability of polypropylene microfibre (PPMF) were improved by plasma-induced vapor grafting with acrylic acid. The effects of plasma discharge time, power, liquid phase acrylic acid temperature and environmental temperature on grafting yield were investigated. The existence of grafted polyacrylic acid (PAA) was verified by ESCA and ATR FT-IR. The morphology of grafted PAA was directly observed by SEM. The wicking test shows that the hydrophilicity of modified PPMF is greatly enhanced. The dyeability test of modified PPMF was carried out using Dispersion Yellow. It was found that the dye uptake ratio is linear to the weight percent of grafting. The antistatic ability was indicated by specific resistance. The specific resistance of modified PPMF was reduced to 10(6) similar to 10(7) Ohm . cm, thus the antistatic ability was considerably improved.
基金Program for Changjiang Scholars and Inno■tive Research Team in University (IRT 0526)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry
文摘Lipase preparation from Aspergillus oryzae could act on ester bonds on the surface of poly (ethylene terephthalate) fibers and a possible hydrolytic product mono (2-hydroxyethyl) terephthalate was released. After the iipase modification, there were more carboxyi groups on the treated poly (ethylene terephthalate) fabric surface that resulted in binding with more cationic dyes. Increased hydrophilicity and antistatic ability of poly (ethylene terephthalate) samples were found based on moisture regain, water contact angle and static half decay time.