In this paper, we use pre-column 2 times low-temperature cryo-trap enrichment--gas chromatography（GC） /nitrogen and phosphorus detector（NPD）to detect and analyze phosphine in Arctic pole area for the first time. T...In this paper, we use pre-column 2 times low-temperature cryo-trap enrichment--gas chromatography（GC） /nitrogen and phosphorus detector（NPD）to detect and analyze phosphine in Arctic pole area for the first time. The results show phosphine exists in all of the samples in Arctic pole biosphere and phosphine concentration in Arctic atmosphere is between 18.54- 132.18 ng/m^3, almost the same as that in Antarctic atmosphere; phosphine concentration in Dalian bay sea surface sediments is between 116. 8- 554.3 ng/kg, almost the same as that reported in Jiao-zhou bay. Our research of phosphine will shed new light on the mechanisms showing how the phosphorus supplement influences the biogeochemical cycle and global warming.展开更多
Phosphine, a ubiquitous trace gas in the atmosphere, acts as a carrier of gasous phosphorus in the biogeochemical cycle. The research of phosphine will show new light on the mechanisms of how the phos- phorus suppleme...Phosphine, a ubiquitous trace gas in the atmosphere, acts as a carrier of gasous phosphorus in the biogeochemical cycle. The research of phosphine will show new light on the mechanisms of how the phos- phorus supplement influence the biogeochemical cycle and global wanning. In this paper, we detect the phosphine in Arctic Pole area for the first time. The result shows that matrix-bound phosphine（MBP） ex- ists in all the samplings. Phosphine distributions varied with different environmental origins. Average phosphine concentrations in tundra soil, lake sediments, sea sediments, seabird-droppings and deer guanos were 14.17ng/kg dry, 35.44 kg dry, 67.20 kg dry, 32.9 ng/kg dry, and 25.52 ng/kg dry re- spectively. Correlation analysis shows that there is an obviously positive correlation between Porg and MBP. It could be concluded that anaerobic decomposition of Porg and the mechano-chemistry action of the rock probably are the possible reasons explaining the mechanism of MBP production in Arctic Pole area.展开更多
The area of Arctic sea ice has dramatically decreased, and the length of the open water season has increased;these patterns have been observed by satellite remote sensing since the 1970 s. In this paper, we calculate ...The area of Arctic sea ice has dramatically decreased, and the length of the open water season has increased;these patterns have been observed by satellite remote sensing since the 1970 s. In this paper, we calculate the net primary productivity(NPP, calculated by carbon) from 2003 to 2016 based on sea ice concentration products,chlorophyll a(Chl a) concentration, photosynthetically active radiation(PAR), sea surface temperature(SST), and sunshine duration data. We then analyse the spatiotemporal changes in the Chl a concentration and NPP and further investigate the relations among NPP, the open water area, and the length of the open water season. The results indicate that(1) the Chl a concentration increased by 0.025 mg/m^3 per year;(2) the NPP increased by 4.29 mg/(m^2·d) per year, reaching a maximum of 525.74 mg/(m^2·d) in 2016;and(3) the Arctic open water area increased by 57.23×10^3 km^2/a, with a growth rate of 1.53 d/a for the length of the open water season. The annual NPP was significantly positively related to the open water area, the length of the open water season and the SST.The daily NPP was also found to have a lag correlation with the open water area, with a lag time of two months.With global warming, NPP has maintained an increasing trend, with the most significant increase occurring in the Kara Sea. In summary, this study provides a macroscopic understanding of the distribution of phytoplankton in the Arctic, which is valuable information for the evaluation and management of marine ecological environments.展开更多
基金Supported by the National High Technology Research and Development Programme of China ( No. 2008AA09Z114)the Polar Science Research Foundation ( No. 20070214)the Opening Foundation ( No. PCRRF08016) of State Key Laboratory of Pollution Control and Resource Reuse Nanjing University and the National Ocean science Foundation (No. 2008614)
文摘In this paper, we use pre-column 2 times low-temperature cryo-trap enrichment--gas chromatography（GC） /nitrogen and phosphorus detector（NPD）to detect and analyze phosphine in Arctic pole area for the first time. The results show phosphine exists in all of the samples in Arctic pole biosphere and phosphine concentration in Arctic atmosphere is between 18.54- 132.18 ng/m^3, almost the same as that in Antarctic atmosphere; phosphine concentration in Dalian bay sea surface sediments is between 116. 8- 554.3 ng/kg, almost the same as that reported in Jiao-zhou bay. Our research of phosphine will shed new light on the mechanisms showing how the phosphorus supplement influences the biogeochemical cycle and global warming.
基金Supported by the National High Technology. Research and Development Program of China （No. 2008AA09Z114）；the Polar Science Research Founda- tion （No. 20070214）；the Opening Foundation of State Key Laboratory of Pollution Control and Resource Reuse of Nanjing University （No. PCRRF08016）；the National Ocean Science Foundation （No. 2008614）
文摘Phosphine, a ubiquitous trace gas in the atmosphere, acts as a carrier of gasous phosphorus in the biogeochemical cycle. The research of phosphine will show new light on the mechanisms of how the phos- phorus supplement influence the biogeochemical cycle and global wanning. In this paper, we detect the phosphine in Arctic Pole area for the first time. The result shows that matrix-bound phosphine（MBP） ex- ists in all the samplings. Phosphine distributions varied with different environmental origins. Average phosphine concentrations in tundra soil, lake sediments, sea sediments, seabird-droppings and deer guanos were 14.17ng/kg dry, 35.44 kg dry, 67.20 kg dry, 32.9 ng/kg dry, and 25.52 ng/kg dry re- spectively. Correlation analysis shows that there is an obviously positive correlation between Porg and MBP. It could be concluded that anaerobic decomposition of Porg and the mechano-chemistry action of the rock probably are the possible reasons explaining the mechanism of MBP production in Arctic Pole area.
基金The National Key Research and Development Program of China under contract No.2016YFA0600102the National Natural Science Foundation of China under contract No.41371391the Consulting Research Project of Chinese Academy of Engineering under contract No.2016-XZ-15
文摘The area of Arctic sea ice has dramatically decreased, and the length of the open water season has increased;these patterns have been observed by satellite remote sensing since the 1970 s. In this paper, we calculate the net primary productivity(NPP, calculated by carbon) from 2003 to 2016 based on sea ice concentration products,chlorophyll a(Chl a) concentration, photosynthetically active radiation(PAR), sea surface temperature(SST), and sunshine duration data. We then analyse the spatiotemporal changes in the Chl a concentration and NPP and further investigate the relations among NPP, the open water area, and the length of the open water season. The results indicate that(1) the Chl a concentration increased by 0.025 mg/m^3 per year;(2) the NPP increased by 4.29 mg/(m^2·d) per year, reaching a maximum of 525.74 mg/(m^2·d) in 2016;and(3) the Arctic open water area increased by 57.23×10^3 km^2/a, with a growth rate of 1.53 d/a for the length of the open water season. The annual NPP was significantly positively related to the open water area, the length of the open water season and the SST.The daily NPP was also found to have a lag correlation with the open water area, with a lag time of two months.With global warming, NPP has maintained an increasing trend, with the most significant increase occurring in the Kara Sea. In summary, this study provides a macroscopic understanding of the distribution of phytoplankton in the Arctic, which is valuable information for the evaluation and management of marine ecological environments.
