Calculation and Analysis of Valence Electron Structure of Mo_2C and V_4C_3 in Hot Working Die Steel

Taking the hot working die steel （HWDS） 4Cr3Mo2NbVNi as an example, the phase electron structures （PES） and the biphase interface electron structures （BIES） of Mo2C and V4 C3 , which are two kinds of important carbides precipitated during tempering in steel were calculated, on the basis of the empirical electron theory of solids and molecules and the improved TFD theory. The influence of Mo2 C and V4 C3 on the mechanical properties of HWDS has been analyzed at electron structure level, and the fundamental reason that the characteristic of the PES and the BIES of carbides decides the behavior of them has been revealed.

Research on time structure characteristic of gas concentration sequence in the working face

In the procedure of coal industry production, the losses of the persons and economy caused by the gas explosion accidents are most serious, therefore, prevention and control of the gas explosion accident of the coal mines is an important issue needed to be solved urgently in the safety production work of our coal mines. The characteristic of time structure variation index characteristic was analyzed about gas concentration sequence of three measure points in the NO. 1I 1024 working face. It was found that the value of time variation about three measure points was mostly 1〈δ≤1.5, and gas emission presented consistently strong-clustering state twice, and the value of time variation presented continuous variation state in the active stage of gas concentration. Complex characteristics of the value indicated gas emission was continuously variable in time or space and presented the complex nonlinear characteristics. So the characteristic about gas emission system was correctly depicted and analyzed to gas emission system according to the relation of its state variation and essential of nonlinear system. The result also provided reliable warranty for its continued nonlinear research on gas emission.

High-performance Si-Containing anode materials in lithium-ion batteries: A superstructure of Si@Co-NC composite works effectively

To mitigate the massive volume expansion of Si-based anode during the charge/discharge cycles,we synthesized a superstructure of Si@Co±NC composite via the carbonization of zeolite imidazolate frameworks incorporated with Si nanoparticles.The Si@Co±NC is comprised of Sinanoparticle core and N-doped/Co-incorporated carbon shell,and there is void space between the core and the shell.When using as anode material for LIBs,Si@Co±NC displayed a super performance with a charge/discharge capacity of 191.6/191.4 mA h g^(-1)and a coulombic efficiency of 100.1%at 1000 mA g^(-1)after 3000 cycles,and the capacity loss rate is 0.022%per cycle only.The excellent electrochemical property of Si@Co±NC is because its electronic conductivity is enhanced by doping the carbon shell with N atoms and by incorporating with Co particles,and the pathway of lithium ions transmission is shortened by the hollow structure and abundant mesopores in the carbon shell.Also,the volume expansion of Si nanoparticles is well accommodated in the void space and suppressed by the carbon host matrix.This work shows that,through designing a superstructure for the anode materials,we can synergistically reduce the work function and introduce the confinement effect,thus significantly enhancing the anode materials’electrochemical performance in LIBs.

Multifunctional Perovskite Photodetectors: From Molecular-Scale Crystal Structure Design to Micro/Nano-scale Morphology Manipulation

Multifunctional photodetectors boost the development of traditional optical communication technology and emerging artificial intelligence fields, such as robotics and autonomous driving. However, the current implementation of multifunctional detectors is based on the physical combination of optical lenses, gratings, and multiple photodetectors, the large size and its complex structure hinder the miniaturization, lightweight, and integration of devices. In contrast, perovskite materials have achieved remarkable progress in the field of multifunctional photodetectors due to their diverse crystal structures, simple morphology manipulation, and excellent optoelectronic properties. In this review, we first overview the crystal structures and morphology manipulation techniques of perovskite materials and then summarize the working mechanism and performance parameters of multifunctional photodetectors. Furthermore, the fabrication strategies of multifunctional perovskite photodetectors and their advancements are highlighted, including polarized light detection, spectral detection, angle-sensing detection, and selfpowered detection. Finally, the existing problems of multifunctional detectors and the perspectives of their future development are presented.

Seismic Response Analysis of Structure with Cooperation of Laminated Rubber Bearing and Wind-Resistant Support

The purpose is to study the seismic reduction effect of an isolated structure,with wind-resistant bearings( WRBs) setting on its isolation layer to withstand great wind load,and the working mechanism of the WRB. In this paper,two isolation models with /without WRBs,taking an actual engineering as the background,are established in the finite element software ETABS. The one with WRBs has horizontal damping coefficient less than 0. 40 while the other between 0. 40 and 0. 53. WRBs are simulated by Plastic 1element and the collaborative work between them and isolation layer is described by a mechanical model. Time history analysis is conducted on the models to compare their responses under earthquake excitations. Results show that the one with WRBs,but less lead-rubber bearings( LRBs),has better damping effect than the other,although they both can meet wind requirements. It is also shown that under normal conditions and small earthquakes,WRBs function well and the isolation layer will not yield; under moderate earthquakes,WRBs will yield and be destroyed to stop functioning but without affecting the damping effect of the upper structure.Additionally, the total yield shear force provided by LRBs is proposed to be close to the standard value of wind load.

Improving Concrete Containment Structures Associated with Fixed-Cone Valves

Fixed-Cone valves are often used to dissipate energy and regulate flow at the low level outlet works of dams. Fixed-Cone valves, also known as Howell-Bunger valves, create an expanding conical jet allowing the energy of the water to dissipate over a large area. However, in many applications constructing the large stilling basin necessary for these valves is either not possible or not feasible. In order to reduce the relative size of the stilling basin, hoods or concrete containment structures have been used in conjunction with Fixed-Cone valves. This paper discusses the use of baffles in concrete containment structures in order to dissipate energy in a considerably confined space. It was determined that using baffles, in place of a deflector ring and end sill (Used in traditional containment structures.), significantly improves the function of containment structures by reducing downstream flow velocities and improving flow patterns and stability. This information will be useful to engineers allowing them to minimize scour and erosion associated with concrete containment structures.

LOW-DIMENSIONAL STRUCTURES:SP ARSE CODING FOR NEURONAL ACTIVITY

Neuronal ensemble activity codes working memory.In this work,we developed a neuronal ensemble sparse coding method,which can effectively reduce the dimension of the neuronal activity and express neural coding.Multichannel spike trains were recorded in rat prefrontal cortex during a work memory task in Y-maze.As discretesignals,spikes were transferred into cont inuous signals by estinating entropy.Then the normalized continuous signals were decomposed via non-negative sparse met hod.The non-negative components were extracted to reconstruct a low-dimensional ensemble,while none of the feature components were missed.The results showed that,for well-trained rats,neuronal ensemble activities in the prefrontal cortex changed dynamically during the.working memory task.And the neuronal ensemble is more explicit via using non-negative sparse coding.Our results indicate that the neuronal ensemblesparse coding method can effectively reduce the dimnension of neuronal activity and it is a useful tool to express neural coding.

Effect of Growth Morphology on the Electronic Structure of Epitaxial Graphene on SiC

Ultraviolet photoemission spectroscopy is used to investigate the electronic structure of epitaxial graphene grown by the thermal decomposition of the carbon face of 4H SiC. We find that the growth of the film on the chemical mechanically polished and hydrogen etched surface enhances spectral features in the valence band structure compared to the film grown on an unpolished hydrogen etched substrate. This result is indicative of a more highly ordered surface structure compared to the morphologically rough material and shows that substrate preparation plays an important role in the quality of the film. The work function of the smooth surface film is found to be 0.4 eV higher than that for graphite and 0.1 eV less than for the rough surface growth.

Electron emission degradation of nano-structured sp^2-bonded amorphous carbon films

The initial field electron emission degradation behaviour of original nano-structured sp^2-bonded amorphous carbon films has been observed, which can be attributed to the increase of the work function of the film in the field emission process analysed using a Fowler-Nordheim plot. The possible reason for the change of work function is suggested to be the desorption of hydrogen from the original hydrogen termination film surface due to field emission current-induced local heating. For the explanation of the emission degradation behaviour of the nano-structured sp2-bonded amorphous carbon film, a cluster model with a series of graphite （0001） basal surfaces has been presented, and the theoretical calculations have been performed to investigate work functions of graphite （0001） surfaces with different hydrogen atom and ion chemisorption sites by using first principles method based on density functional theory-local density approximation.

Rapid excavation with a newly developed retaining system: Spiral assembly steel structure

The spiral assembly steel structure, a newly developed retaining wall for the rapid excavation of small-sized foundation pits in unsaturated soil, is presented. This new type of retaining structure is prefabricated in the factory and is assembled on site in the excavation of a pit. This retaining structure is composed of several prefabricated steel structural units, in which the adjacent steel structural units are joined with connectors. Each steel structural unit has one steel pipe in the radial direction and is welded to a single piece of steel plate. After full installation in situ, the retaining structure becomes a cylindrical steel structure. With the protection afforded by this new type of retaining structure, excavation work can be completed within 24 h to a depth up to 5 m. In order to verify the reliability and effectiveness of this new retaining structure, field construction tests were conducted in Beijing, China. The test construction was monitored. The monitoring program included measuring stress in the structure, lateral earth pressure, and lateral deformation of the surrounding soil. The monitoring data from the field test were compared with the theoretical results. The results show that the proposed new structure is reliable and effective.

Modeling Spatial Opportunity Structures and Youths’ Transitions from School to Training

This paper examines the significance of spatial externalities for youths’ school-to-training transitions in Germany. For this purpose, it is necessary to address the methodological question of how an individual’s spatial context has to be operationalized with respect to both its extent and the problem of spatial autocorrelation. Our analyses show that the “zone of influence” comprises of the whole of Germany, not only close-by districts, and that these effects differ between structurally weak and strong regions. Consequently, assuming that only close proximity affects individual outcomes may disregard relevant contextual influences, and for spatial models that require an a priori definition of the weights for spatial units, it may be erroneous to make a decision based on this assumption. Concerning spatial autocorrelation, we found that neglecting local spatial autocorrelation at the context level causes considerable bias to the estimates, especially for districts that are close to the home district.

Influence of Oxygen Addition on Structure and Properties of Titanium Produced by Electroslag Remelting

The current work is devoted to the investigation of oxygen impact on the structure and properties of titanium. For this purpose, oxygen was introduced into titanium during chamber electro-slag remelting by three different methods: alloying by oxygen-rich residues from the Kroll process to final values between 0.053 wt.-% and 0.40 wt.-%, by reaction with the gas phase to 0.27 wt.-% and by introduction of TiO2 nanoparticles to 0.73 wt.-%. The influence of oxygen on microstructure of titanium during crystallization, heat treatment and deformation is determined as well as the effect of oxygen on the hardness and the mechanical properties of the material in different structural states. Furthermore, control methods of the structure formation process by thermal effects are proposed. Results show that the chamber electroslag remelting allows obtaining a homogeneous structure of the ingot in the investigated range of oxygen content in titanium. The hardness does not vary by more than 10 percent in longitudinal or radial direction in any of the remelted ingots.

Virtual internal thermal work evaluation in the multifield variational statements for the analysis of multilayered structures

The principle of virtual displacements(PVDs)extended to elasto-thermo-electric problems includes virtual internal elastic,thermal and electric works.The governing equations have displacement vector,temperature and electric potential as primary variables of the problem,and the elasto-thermal,elasto-electric and pure elastic problems are obtained as particular cases by deleting the appropriate contributions in the general elasto-thermo-electric variational statement.The most sensitive issue is given by thermal coupling because the thermo-elastic and thermo-electric effects change depending on the type of load and analysis considered(mechanical load,temperature or electric potential imposed and free vibration analysis).This feature means that the form of the virtual internal thermal work in such variational statements changes depending on the analysis performed and the load applied.Results about multilayered plates and shells suggest the appropriate extension of the variational statement for each analysis,and they give an exhaustive explanation for several forms of the PVD proposed.

Experimental Investigation on Complex Structures Machining by Electrochemical Micromachining Technology

Electrochemical micromachining （EMM） technology for fabricating micro structures is presented in this article. By applying ultra short pulses, dissolution of a workpiece can be restricted to the region very close to the electrode. First, an EMM system for meeting the requirements of the EMM process is established. Second, sets of experiments is carried out to investigate the influence of some of the predominant electrochemical process parameters such as electrical parameters, feed rate, electrode geometry features and electrolyte composition on machining quality, especially the influences of pulse on time on shape precision and working end shape of electrode on machined surface quality. Finally, after the preliminary experiments, a complex microstructure with good shape precision and surface quality is successfully obtained.

Design and optimization of fluid lubricated bearings operated with extreme working performances——a comprehensive review

Fluid lubricated bearings have been widely adopted as support components for high-end equipment in metrology,semiconductor devices,aviation,strategic defense,ultraprecision manufacturing,medical treatment,and power generation.In all these applications,the equipment must deliver extreme working performances such as ultraprecise movement,ultrahigh rotation speed,ultraheavy bearing loads,ultrahigh environmental temperatures,strong radiation resistance,and high vacuum operation,which have challenged the design and optimization of reliable fluid lubricated bearings.Breakthrough of any related bottlenecks will promote the development course of high-end equipment.To promote the advancement of high-end equipment,this paper reviews the design and optimization of fluid lubricated bearings operated at typical extreme working performances,targeting the realization of extreme working performances,current challenges and solutions,underlying deficiencies,and promising developmental directions.This paper can guide the selection of suitable fluid lubricated bearings and optimize their structures to meet their required working performances.

Analysis of Spatial Data Structures for Proximity Detection

Construction is a dangerous business. According to statistics, in every of the past thirteen years more than 1000 workers died in the USA construction industry. In order to minimize the overall number of these incidents, the research presented in this paper investigates to monitor and analyze the trajectories of construction resources first in a simulated environment and later on the actual job site. Due to the complex nature of the construction environment, three dimensional (3D) positioning data of workers is hardly collected. Although technology is available that allows tracking construction assets in real-time, indoors and outdoors, in 3D, at the same time, the continuously changing spatial and temporal arrangement of job sites requires any successfully working data processing system to work in real-time. This research paper focuses is safety on spatial data structures that offer the capability of realigning itself and reporting the distance of the closest neighbor in real-time. This paper presents results to simulations that allow the processing of real-time location data for collision detection and proximity analysis. The presented data structures and perform-ance results to the developed algorithms demonstrate that real-time tracking and proximity detection of resources is feasible.

A High Capacity and Working Voltage Potassium-Based Dual Ion Batteries

Potassium-based dual ion batteries(KDIBs)have attracted significant attention owing to high working voltage,high safety,low processing cost,and environmental friendliness.Nevertheless,one great challenge for practical KDIBs is to develop suitable anode materials with high specific capacity.Herein,we report an architecture of hierarchically porous antimony nanoparticles/carbon nanofibers(HPSb CNFs)as flexible,free-standing anode for high-performance KDIBs.The HPSb CNFs with hierarchically porous structure,and high-content nitrogen doping,not only offer sufficient free space to tolerate the repetitive volume expansion of Sb nanoparticles during long-term cycling,but also greatly facilitate the transport of electrons and ions within electrode,ensuring high material utilization ratio.Thus,the KDIBs,constituted by HPSb CNFs-700(calcined at 700°C)anode and graphite cathode,exhibited a high reversible capacity of 440 m Ah g^(-1)with high discharge medium voltage of 4.5 V at a specific current of 200 m A g^(-1)(the highest capacity for all KDIBs normalized by the mass of the anode),and excellent cyclic life.Outstanding electrochemical reversibility of the KDIBs was further demonstrated by ex situ XRD,ex situ Raman spectrum,and HRTEM.These results suggest the as-designed HPSb CNFs-700 with highcapacity and long-term cycling stability is a promising anode material for high-performance KDIBs.

基于SolidWorks的高精度气体静压电主轴的结构设计研究

以高精度气体静压电主轴为研究对象,介绍了"T"字型、"工"字型及"中"字型等3种结构类型的应用特点;采用Solid Works软件对3种结构类型进行模态计算分析,并与Ansys软件的计算结果进行了对比;在模态分析中,研究了结构类型、轴向刚度大小等对转子特性的影响。结果表明:Solid Works的模态计算精度可以满足电主轴结构设计的理论分析需求;提高轴向刚度有助于提高各阶模态值,尤其是二、三阶模态值;在相同条件下,"中"字型电主轴结构具有较高的各阶模态值。