Salter's duck,an asymmetrical wave energy converter(WEC)device,showed high efficiency in extracting energy from 2D regular waves in the past;yet,challenges remain for fluctuating wave conditions.These can potentia...Salter's duck,an asymmetrical wave energy converter(WEC)device,showed high efficiency in extracting energy from 2D regular waves in the past;yet,challenges remain for fluctuating wave conditions.These can potentially be addressed by adopting a negative stiffness mechanism(NSM)in WEC devices to enhance system efficiency,even in highly nonlinear and steep 3D waves.A weakly nonlinear model was developed which incorporated a nonlinear restoring moment and NSM into the linear formulations and was applied to an asymmetric WEC using a time domain potential flow model.The model was initially validated by comparing it with published experimental and numerical computational fluid dynamics results.The current results were in good agreement with the published results.It was found that the energy extraction increased in the range of 6%to 17%during the evaluation of the effectiveness of the NSM in regular waves.Under irregular wave conditions,specifically at the design wave conditions for the selected test site,the energy extraction increased by 2.4%,with annual energy production increments of approximately 0.8MWh.The findings highlight the potential of NSM in enhancing the performance of asymmetric WEC devices,indicating more efficient energy extraction under various wave conditions.展开更多
Based on the perfect ohmic drop compensation by online electronic positive feedback, ultrafast cyclic voltammetry with asymmetrical potential scan is achieved for the first time, with the reduction of anthracene actin...Based on the perfect ohmic drop compensation by online electronic positive feedback, ultrafast cyclic voltammetry with asymmetrical potential scan is achieved for the first time, with the reduction of anthracene acting as the test system. Compared with the traditional cyclic voltammetry utilizing symmetrical triangular waveform as the excitation one, the new method allows a simpler approach to mechanistic analysis of ultrafast chemical reactions coupled with a charge transfer. And perhaps more important, it also provides a way to eliminate the interference of the adsorbed product in dynamic monitoring. 2007 Zhi Yong Guo. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.展开更多
The pulsatile electroosmotic flow (PEOF) of a Maxwell fluid in a parallel flat plate microchannel with asymmetric wall zeta potentials is theoretically analyzed. By combining the linear Maxwell viscoelastic model, t...The pulsatile electroosmotic flow (PEOF) of a Maxwell fluid in a parallel flat plate microchannel with asymmetric wall zeta potentials is theoretically analyzed. By combining the linear Maxwell viscoelastic model, the Cauchy equation, and the electric field solution obtained from the linearized PoissomBoltzmann equation, a hyperbolic par- tial differential equation is obtained to derive the flow field. The PEOF is controlled by the angular Reynolds number, the ratio of the zeta potentials of the microchannel walls, the electrokinetic parameter, and the elasticity number. The main results obtained from this analysis show strong oscillations in the velocity profiles when the values of the elas- ticity number and the angular Reynolds number increase due to the competition among the elastic, viscous, inertial, and electric forces in the flow.展开更多
We report some novel dynamical phenomena of dissipative solitons supported by introducing an asymmetric wedge-shaped potential(just as a sharp ‘razor') into the complex Ginzburg–Landau equation with the cubicqui...We report some novel dynamical phenomena of dissipative solitons supported by introducing an asymmetric wedge-shaped potential(just as a sharp ‘razor') into the complex Ginzburg–Landau equation with the cubicquintic nonlinearity. The potentials corresponding to a local refractive index modulation with breaking symmetry can be realized in an active optical medium with respective expanding antiwaveguiding structures. Using the razor potential acting on a central dissipative soliton, possible outcomes of asymmetric and single-side splitting of dissipative solitons are achieved with setting different strengths and steepness of the potentials. The results can potentially be used to design a multi-route splitter for light beams.展开更多
Based on a simple model, we theoretically show the transport behaviors of two harmonically coupled Brownian particles in an asymmetric saw-tooth potential with two slopes. The coupled particles are subject to stochast...Based on a simple model, we theoretically show the transport behaviors of two harmonically coupled Brownian particles in an asymmetric saw-tooth potential with two slopes. The coupled particles are subject to stochastic fluctuations. It is found that when the equilibrium distance of the coupled particles is between the two slopes of the potential, the transport direction of the coupled particles will be reversed with a certain harmonic coupling strength. This current reversal can be easily understood with the near rigid approximation, where the two coupled particles can be regarded as a single particle in an effective potential. Compared with the original saw-tooth potential, the asymmetry of the effective potential could be reversed when the equilibrium distance is between the two slopes of the original potential, which results in the current reversal.展开更多
In this study,the characteristics of azimuthally asymmetric equivalent potential temperature(θ_(e))distributions in the outer core of tropical cyclones(TCs)encountering weak and strong vertical wind shear are examine...In this study,the characteristics of azimuthally asymmetric equivalent potential temperature(θ_(e))distributions in the outer core of tropical cyclones(TCs)encountering weak and strong vertical wind shear are examined using a Lagrangian trajectory method.Evaporatively forced downdrafts in the outer rainbands can transport low-entropy air downward,resulting in the lowestθ_(e)in the downshear-left boundary layer.Quantitative estimations ofθ_(e)recovery indicate that air parcels,especially those originating from the downshear-left outer core,can gradually revive from a low entropy state through surface enthalpy fluxes as the parcels move cyclonically.As a result,the maximumθ_(e)is observed in the downshear-right quadrant of a highly sheared TC.The trajectory analyses also indicate that parcels that move upward in the outer rainbands and those that travel through the inner core due to shear make a dominant contribution to the midlevel enhancement ofθ_(e)in the downshear-left outer core.In particular,the former plays a leading role in suchθ_(e)enhancements,while the latter plays a secondary role.As a result,moist potential stability occurs in the middle-to-lower troposphere in the downshear-left outer core.展开更多
Because of its unique optoelectronic properties,people have studied the characteristics of polarons in various quantum well(QW)models.Among them,the asymmetrical semiexponential QW(ASEQW)is a new model for studying th...Because of its unique optoelectronic properties,people have studied the characteristics of polarons in various quantum well(QW)models.Among them,the asymmetrical semiexponential QW(ASEQW)is a new model for studying the structure of QWs in recent years.It is of great significance to study the influences of the impurity and anisotropic parabolic confinement potential(APCP)on the crystal’s properties,because some of the impurities,usually regarded as Coulomb’s impurity potential(CIP),will exist in the crystal more or less,and the APCP has flexible adjustment parameters.However,the energy characteristics of the ASEQW under the combined actions of impurities and APCP have not been studied,which is the motivation of this paper.Using the linear combination operation and Lee-Low-Pines unitary transformation methods,we investigate the vibrational frequency and the ground state energy of the strong coupling polaron in an ASEQW with the influences of the CIP at the origin of coordinates and APCP,and make a comparison between our results and previous literature’s.Our numerical results about the energy properties in the ASEQW influenced by the CIP and APCP may have important significances for experimental design and device preparation.展开更多
We consider a time independent one dimensional finite range and repulsive constant potential barrier between two impenetrable walls. For a nonrelativistic massive particle projected towards the potential with energies...We consider a time independent one dimensional finite range and repulsive constant potential barrier between two impenetrable walls. For a nonrelativistic massive particle projected towards the potential with energies less than the barrier and irrespective of the spatial positioning of the potential allowing for quantum tunneling, analytically we solve the corresponding Schrodinger equation. For a set of suitable parameters utilizing Mathematica we display the wave functions along with their associated probabilities for the entire region. We investigate the sensitivity of the probability distributions as a function of the potential range and display a gallery of our analysis. We extend our analysis for bound state particles confined within constant attractive potentials.展开更多
The partial potential energy surface was constructed by ab initio method [QCISD(T)/6- 311++G(2df,2pd)]for F+CH4→HF+CH3 reaction system. It not only explained the reaction mechanism brought forward by Diego Tr...The partial potential energy surface was constructed by ab initio method [QCISD(T)/6- 311++G(2df,2pd)]for F+CH4→HF+CH3 reaction system. It not only explained the reaction mechanism brought forward by Diego Troya by means of quasiclassical trajectory (QCT) but also successfully validated Kopin Liu's experimental phenomena about the existence of the reactive resonance. The lifetime of the scattering resonance state was about 0.07 ps. All these were in agreement with the experiments.展开更多
A simplified mechanical model of pillar-hang wall was established in asymmetric mining and instability of the system was discussed by means of potential energy principle and cusp catastrophe theory. The necessary-suff...A simplified mechanical model of pillar-hang wall was established in asymmetric mining and instability of the system was discussed by means of potential energy principle and cusp catastrophe theory. The necessary-sufficient condition and the jump value of displacement of pillar and the released energy expressions were derived, which established foundation for quantifying of the instability of system. The results show that instability of the system is related to load and its stiffness distribution. The critical load increases with the increasing relative stiffness, and the system is more stable. On the contrary, the instability of system is likely to occur, and the released energy is larger in instability process, and the harm is more tremendous accordingly. Furthermore, an example was calculated, and the estimated results are in good agreement with the practical experience, which provide basis for mining order and arranging stope.展开更多
: The effects of a magnetic field on the vibrational frequency, the ground state energy and the ground state binding energy of a weak-coupling polaron in asymmetrical Gaussian confinement potential quantum well (AGC...: The effects of a magnetic field on the vibrational frequency, the ground state energy and the ground state binding energy of a weak-coupling polaron in asymmetrical Gaussian confinement potential quantum well (AGCPQW) are investigated by using linear combination operator and unitary transformation methods. Our cal- culated results show that the vibrational frequency increases with increasing cyclotron frequency of the magnetic field; meanwhile, the absolute value of the ground state energy and the ground state binding energy decrease. The vibrational frequency, the absolute value of the ground state energy and the ground state binding energy are in- creasing functions of the barrier height of the AGCPQW. It is shown that the barrier height of the AGCPQW and the magnetic field are important factors that influence the properties of the magnetopolaron in AGCPQW.展开更多
Under the influence of an applied magnetic field(MF), the eigenenergies and the eigenfunctions of the ground and the first excited states(GFES) are obtained by using a variational method of the Pekar type(VMPT) in a s...Under the influence of an applied magnetic field(MF), the eigenenergies and the eigenfunctions of the ground and the first excited states(GFES) are obtained by using a variational method of the Pekar type(VMPT) in a strong electron-LO-phonon coupling asymmetrical Gaussian potential quantum well(AGPQW). This AGPQW system may be employed as a two-level qubit. The numerical results have indicated(i) that when the electron situates in the superposition state of the GFES, we obtain the time evolution and the coordinate change of the electron probability density in the AGPQW,(ii) that due to the presence of the asymmetrical potential in the growth direction of the AGPQW, the probability density shows double-peak configuration, whereas there is only one peak if the confinement is a two dimensional symmetric one in the xy plane of the AGPQW,(iii) that the oscillatory period is a decreasing function of the cyclotron frequency of the MF, the height of the AGPQW and the polaron radius,(iv) and that as the range of the confinement potential(RCP) decreases the oscillatory period will decrease firstly and then increase and it will take a minimum when R =-0.234 nm.展开更多
Based on the theory of potential vorticity(PV),the unstable development of the South Asia High(SAH)due to diabatic heating and its impacts on the Indian Summer Monsoon(ISM)onset are studied via a case diagnosis of 199...Based on the theory of potential vorticity(PV),the unstable development of the South Asia High(SAH)due to diabatic heating and its impacts on the Indian Summer Monsoon(ISM)onset are studied via a case diagnosis of 1998.The Indian Summer Monsoon onset in 1998 is related to the rapidly strengthening and northward moving of a tropical cyclone originally located in the south of Arabian Sea.It is demonstrated that the rapid enhancement of the cyclone is a consequence of a baroclinic development characterized by the phase-lock of high PV systems in the upper and lower troposphere.Both the intensification of the SAH and the development of the zonal asymmetric PV forcing are forced by the rapidly increasing latent heat released from the heavy rainfall in East Asia and South East Asia after the onsets of the Bay of Bengal(BOB)monsoon and the South China Sea(SCS)monsoon.High PV moves southwards along the intensified northerlies on the eastern side of the SAH and travels westwards on its south side,which can reach its northwest.Such a series of high PV eddies are transported to the west of the SAH continuously,which is the main source of PV anomalies in the upper troposphere over the Arabian Sea from late spring to early summer.A cyclonic curvature on the southwest of the SAH associated with increasing divergence,which forms a strong upper tropospheric pumping,is generated by the anomalous positive PV over the Arabian Sea on 355 K.The cyclone in the lower troposphere moves northwards from low latitudes of the Arabian Sea,and the upper-layer high PV extends downwards and southwards.Baroclinic development thus occurs and the tropical low-pressure system develops into an explosive vortex of the ISM,which leads to the onset of the ISM.In addition,evolution of subtropical anticyclone over the Arabian Peninsula is another important factor contributing to the onset of the ISM.Before the onset,the surface sensible heating on the Arabian Peninsula is very strong.Consequently the subtropical anticyclone which dominated the Arabian Sea in spring retreats westwards to the Arabian Peninsula and intensifies rapidly.The zonal asymmetric PV forcing develops gradually with high PV eddies moving southwards along northerlies on the eastern side of the anticyclone,and a high PV trough is formed in the middle troposphere over the Arabian Sea,which is favorable to the explosive barotropic development of the tropical cyclone into the vortex.Results from this study demonstrate that the ISM onset,which is different from the BOB and the SCS monsoon onset,is a special dynamical as well as thermodynamic process occurring under the condition of fully coupling of the upper,middle,and lower tropospheric circulations.展开更多
We have applied strong coupling unitary transformation method combined with Bose–Einstein statistical law to investigate magnetopolaron energy level temperature effects in halogen ion crystal quantum wells.The obtain...We have applied strong coupling unitary transformation method combined with Bose–Einstein statistical law to investigate magnetopolaron energy level temperature effects in halogen ion crystal quantum wells.The obtained results showed that under magnetic field effect,magnetopolaron quasiparticle was formed through the interaction of electrons and surrounding phonons.At the same time,magnetopolaron was influenced by phonon temperature statistical law and important energy level shifts down and binding energy increases.This revealed that lattice temperature and magnetic field could easily affect magnetopolaron and the above results could play key roles in exploring thermoelectric conversion and conductivity of crystal materials.展开更多
By a combination method of Lee-Low-Pines unitary transformation method and Pekar-type variational method,the ground state energy(GSE)of the bound polaron is studied in the asymmetrical Gaussian potential quantum well ...By a combination method of Lee-Low-Pines unitary transformation method and Pekar-type variational method,the ground state energy(GSE)of the bound polaron is studied in the asymmetrical Gaussian potential quantum well considering the temperature and electromagneticfield.The impacts of the temperature and asymmetrical Gaussian potential,electromagnetic field and phonon-electron coupling upon the GSE are obtained.The results show that the GSE of the bound polaron not only oscillates as the temperature changes regardless of the electromagneticfield and asymmetrical Gaussian potential and Coulomb impurity potential(CIP)and electron-phonon coupling but also has different rules with the electromagnetic field and asymmetrical Gaussian potential and CIP and electron-phonon coupling at different temperature zones.展开更多
We investigate the neutron and proton single particle (s.p.) potentials of asymmetric nuclear matter and their isospin dependence in various spin-isospin ST channels within the framework of the BruecknerHartree-Fock...We investigate the neutron and proton single particle (s.p.) potentials of asymmetric nuclear matter and their isospin dependence in various spin-isospin ST channels within the framework of the BruecknerHartree-Fock approach. It is shown that in symmetric nuclear matter, the s.p. potentials in both the isospinsinglet T = 0 channel and isospin-triplet T = 1 channel are essentially attractive, and the magnitudes in the two different channels are roughly the same. In neutron-rich nuclear matter, the isospin-splitting of the proton and neutron s.p. potentials turns out to be mainly determined by the isospin-singlet T = 0 channel contribution which becomes more attractive for the proton and more repulsive for the neutron at higher asymmetries.展开更多
With the circumstance of the electron strongly coupled to LO-phonon and using the variational method of Pekar type(VMPT),we study the eigenenergies and the eigenfunctions(EE) of the ground and the first excited st...With the circumstance of the electron strongly coupled to LO-phonon and using the variational method of Pekar type(VMPT),we study the eigenenergies and the eigenfunctions(EE) of the ground and the first excited states(GFES) in a RbCl crystal asymmetric Gaussian potential quantum well(AGPQW).It concludes:(i) Twoenergy-level of the AGPQW may be seen as a qubit.(ii) When the electron located in the superposition state of the two-energy-level system,the time evolution and the coordinate changes of the electron probability density oscillated periodically in the AGPQW with every certain period T0=22.475 fs.(iii) Due to the confinement that is a two dimensional x-y plane symmetric structure in the AGPQW and the asymmetrical Gaussian potential(AGP) in the AGPQW growth direction,the electron probability density presents only one peak configuration located in the coordinate of z 〉 0,whereas it is zero in the range of z 〈 0.(iv) The oscillatory period is a decreasing function of the AGPQW height and the polaron radius,(v) The oscillating period is a decreasing one in the confinement potential R 〈 0.24 nm,whereas it is an increasing one in the confinement potential R 〉 0.24 nm and it takes a minimum value in R = 0.24 nm.展开更多
基金financially supported by Basic Science Research Program through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(Grant No.2022R1I1A1A01069442)the 2024 Hongik University Research Fund。
文摘Salter's duck,an asymmetrical wave energy converter(WEC)device,showed high efficiency in extracting energy from 2D regular waves in the past;yet,challenges remain for fluctuating wave conditions.These can potentially be addressed by adopting a negative stiffness mechanism(NSM)in WEC devices to enhance system efficiency,even in highly nonlinear and steep 3D waves.A weakly nonlinear model was developed which incorporated a nonlinear restoring moment and NSM into the linear formulations and was applied to an asymmetric WEC using a time domain potential flow model.The model was initially validated by comparing it with published experimental and numerical computational fluid dynamics results.The current results were in good agreement with the published results.It was found that the energy extraction increased in the range of 6%to 17%during the evaluation of the effectiveness of the NSM in regular waves.Under irregular wave conditions,specifically at the design wave conditions for the selected test site,the energy extraction increased by 2.4%,with annual energy production increments of approximately 0.8MWh.The findings highlight the potential of NSM in enhancing the performance of asymmetric WEC devices,indicating more efficient energy extraction under various wave conditions.
基金We are grateful to the National Natural Science Foundation of China (No. 20173054);the Natural Science Foundation of Ningbo City (No. 2006A610044).
文摘Based on the perfect ohmic drop compensation by online electronic positive feedback, ultrafast cyclic voltammetry with asymmetrical potential scan is achieved for the first time, with the reduction of anthracene acting as the test system. Compared with the traditional cyclic voltammetry utilizing symmetrical triangular waveform as the excitation one, the new method allows a simpler approach to mechanistic analysis of ultrafast chemical reactions coupled with a charge transfer. And perhaps more important, it also provides a way to eliminate the interference of the adsorbed product in dynamic monitoring. 2007 Zhi Yong Guo. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
基金Project supported by the Fondo Sectorial de Investigación para la Educación from the Secretar a de Educación Pública-Consejo Nacional de Ciencia y Tecnología(No.CB-2013/220900)the Secretaría de Investigación y Posgrado from Instituto Politécnico Nacional of Mexico(No.20171181)
文摘The pulsatile electroosmotic flow (PEOF) of a Maxwell fluid in a parallel flat plate microchannel with asymmetric wall zeta potentials is theoretically analyzed. By combining the linear Maxwell viscoelastic model, the Cauchy equation, and the electric field solution obtained from the linearized PoissomBoltzmann equation, a hyperbolic par- tial differential equation is obtained to derive the flow field. The PEOF is controlled by the angular Reynolds number, the ratio of the zeta potentials of the microchannel walls, the electrokinetic parameter, and the elasticity number. The main results obtained from this analysis show strong oscillations in the velocity profiles when the values of the elas- ticity number and the angular Reynolds number increase due to the competition among the elastic, viscous, inertial, and electric forces in the flow.
基金Supported by the National Natural Science Foundation of China under Grant No 61665007the Natural Science Foundation of Jiangxi Province under Grant No 20161BAB202039
文摘We report some novel dynamical phenomena of dissipative solitons supported by introducing an asymmetric wedge-shaped potential(just as a sharp ‘razor') into the complex Ginzburg–Landau equation with the cubicquintic nonlinearity. The potentials corresponding to a local refractive index modulation with breaking symmetry can be realized in an active optical medium with respective expanding antiwaveguiding structures. Using the razor potential acting on a central dissipative soliton, possible outcomes of asymmetric and single-side splitting of dissipative solitons are achieved with setting different strengths and steepness of the potentials. The results can potentially be used to design a multi-route splitter for light beams.
基金Supported the National Natural Science Foundation of China under Grant Nos 11175230 and 11474299the Key Research Program of Chinese Academy of Sciences under Grant No KJZD-EW-M03
文摘Based on a simple model, we theoretically show the transport behaviors of two harmonically coupled Brownian particles in an asymmetric saw-tooth potential with two slopes. The coupled particles are subject to stochastic fluctuations. It is found that when the equilibrium distance of the coupled particles is between the two slopes of the potential, the transport direction of the coupled particles will be reversed with a certain harmonic coupling strength. This current reversal can be easily understood with the near rigid approximation, where the two coupled particles can be regarded as a single particle in an effective potential. Compared with the original saw-tooth potential, the asymmetry of the effective potential could be reversed when the equilibrium distance is between the two slopes of the original potential, which results in the current reversal.
基金jointly supported by the National Key Research and Development Program of China under Grant No. 2017YFC1501601the National Natural Science Foundation of China under Grant Nos. 42175005 and 41875054
文摘In this study,the characteristics of azimuthally asymmetric equivalent potential temperature(θ_(e))distributions in the outer core of tropical cyclones(TCs)encountering weak and strong vertical wind shear are examined using a Lagrangian trajectory method.Evaporatively forced downdrafts in the outer rainbands can transport low-entropy air downward,resulting in the lowestθ_(e)in the downshear-left boundary layer.Quantitative estimations ofθ_(e)recovery indicate that air parcels,especially those originating from the downshear-left outer core,can gradually revive from a low entropy state through surface enthalpy fluxes as the parcels move cyclonically.As a result,the maximumθ_(e)is observed in the downshear-right quadrant of a highly sheared TC.The trajectory analyses also indicate that parcels that move upward in the outer rainbands and those that travel through the inner core due to shear make a dominant contribution to the midlevel enhancement ofθ_(e)in the downshear-left outer core.In particular,the former plays a leading role in suchθ_(e)enhancements,while the latter plays a secondary role.As a result,moist potential stability occurs in the middle-to-lower troposphere in the downshear-left outer core.
基金This project was supported by the National Natural Science Foundation of China under Grant No.11464034the National Science Foundation of Inner Mongolia Autonomous Region under Grant Nos.2016MS0119 and 2016BS0107+1 种基金Research Program of Science and Technology at Universities of Inner Mongolia Autonomous Region under Grant No.NJZY16183the Scientific Research Fund of Inner Mongolia University for Nationalities under Grant Nos.NMDYB1756 and NMDYB18024.
文摘Because of its unique optoelectronic properties,people have studied the characteristics of polarons in various quantum well(QW)models.Among them,the asymmetrical semiexponential QW(ASEQW)is a new model for studying the structure of QWs in recent years.It is of great significance to study the influences of the impurity and anisotropic parabolic confinement potential(APCP)on the crystal’s properties,because some of the impurities,usually regarded as Coulomb’s impurity potential(CIP),will exist in the crystal more or less,and the APCP has flexible adjustment parameters.However,the energy characteristics of the ASEQW under the combined actions of impurities and APCP have not been studied,which is the motivation of this paper.Using the linear combination operation and Lee-Low-Pines unitary transformation methods,we investigate the vibrational frequency and the ground state energy of the strong coupling polaron in an ASEQW with the influences of the CIP at the origin of coordinates and APCP,and make a comparison between our results and previous literature’s.Our numerical results about the energy properties in the ASEQW influenced by the CIP and APCP may have important significances for experimental design and device preparation.
文摘We consider a time independent one dimensional finite range and repulsive constant potential barrier between two impenetrable walls. For a nonrelativistic massive particle projected towards the potential with energies less than the barrier and irrespective of the spatial positioning of the potential allowing for quantum tunneling, analytically we solve the corresponding Schrodinger equation. For a set of suitable parameters utilizing Mathematica we display the wave functions along with their associated probabilities for the entire region. We investigate the sensitivity of the probability distributions as a function of the potential range and display a gallery of our analysis. We extend our analysis for bound state particles confined within constant attractive potentials.
基金the support of the Grant from the National Natural Science Foundation of China No.20573064 Ph.D.Special Research Foundation of Chinese Education Department.
文摘The partial potential energy surface was constructed by ab initio method [QCISD(T)/6- 311++G(2df,2pd)]for F+CH4→HF+CH3 reaction system. It not only explained the reaction mechanism brought forward by Diego Troya by means of quasiclassical trajectory (QCT) but also successfully validated Kopin Liu's experimental phenomena about the existence of the reactive resonance. The lifetime of the scattering resonance state was about 0.07 ps. All these were in agreement with the experiments.
文摘A simplified mechanical model of pillar-hang wall was established in asymmetric mining and instability of the system was discussed by means of potential energy principle and cusp catastrophe theory. The necessary-sufficient condition and the jump value of displacement of pillar and the released energy expressions were derived, which established foundation for quantifying of the instability of system. The results show that instability of the system is related to load and its stiffness distribution. The critical load increases with the increasing relative stiffness, and the system is more stable. On the contrary, the instability of system is likely to occur, and the released energy is larger in instability process, and the harm is more tremendous accordingly. Furthermore, an example was calculated, and the estimated results are in good agreement with the practical experience, which provide basis for mining order and arranging stope.
基金Project supported by the National Natural Science Foundation of China(Nos.11464033,11464034)
文摘: The effects of a magnetic field on the vibrational frequency, the ground state energy and the ground state binding energy of a weak-coupling polaron in asymmetrical Gaussian confinement potential quantum well (AGCPQW) are investigated by using linear combination operator and unitary transformation methods. Our cal- culated results show that the vibrational frequency increases with increasing cyclotron frequency of the magnetic field; meanwhile, the absolute value of the ground state energy and the ground state binding energy decrease. The vibrational frequency, the absolute value of the ground state energy and the ground state binding energy are in- creasing functions of the barrier height of the AGCPQW. It is shown that the barrier height of the AGCPQW and the magnetic field are important factors that influence the properties of the magnetopolaron in AGCPQW.
基金Supported by the National Science Foundation of China under Grant No.11464034
文摘Under the influence of an applied magnetic field(MF), the eigenenergies and the eigenfunctions of the ground and the first excited states(GFES) are obtained by using a variational method of the Pekar type(VMPT) in a strong electron-LO-phonon coupling asymmetrical Gaussian potential quantum well(AGPQW). This AGPQW system may be employed as a two-level qubit. The numerical results have indicated(i) that when the electron situates in the superposition state of the GFES, we obtain the time evolution and the coordinate change of the electron probability density in the AGPQW,(ii) that due to the presence of the asymmetrical potential in the growth direction of the AGPQW, the probability density shows double-peak configuration, whereas there is only one peak if the confinement is a two dimensional symmetric one in the xy plane of the AGPQW,(iii) that the oscillatory period is a decreasing function of the cyclotron frequency of the MF, the height of the AGPQW and the polaron radius,(iv) and that as the range of the confinement potential(RCP) decreases the oscillatory period will decrease firstly and then increase and it will take a minimum when R =-0.234 nm.
基金supported jointly by the National Basic Research Program of China(Grant Nos.2010CB950403,2012CB417203)National Natural Science Foundation of China(Grant Nos.40875034,40925015 and 41275088)
文摘Based on the theory of potential vorticity(PV),the unstable development of the South Asia High(SAH)due to diabatic heating and its impacts on the Indian Summer Monsoon(ISM)onset are studied via a case diagnosis of 1998.The Indian Summer Monsoon onset in 1998 is related to the rapidly strengthening and northward moving of a tropical cyclone originally located in the south of Arabian Sea.It is demonstrated that the rapid enhancement of the cyclone is a consequence of a baroclinic development characterized by the phase-lock of high PV systems in the upper and lower troposphere.Both the intensification of the SAH and the development of the zonal asymmetric PV forcing are forced by the rapidly increasing latent heat released from the heavy rainfall in East Asia and South East Asia after the onsets of the Bay of Bengal(BOB)monsoon and the South China Sea(SCS)monsoon.High PV moves southwards along the intensified northerlies on the eastern side of the SAH and travels westwards on its south side,which can reach its northwest.Such a series of high PV eddies are transported to the west of the SAH continuously,which is the main source of PV anomalies in the upper troposphere over the Arabian Sea from late spring to early summer.A cyclonic curvature on the southwest of the SAH associated with increasing divergence,which forms a strong upper tropospheric pumping,is generated by the anomalous positive PV over the Arabian Sea on 355 K.The cyclone in the lower troposphere moves northwards from low latitudes of the Arabian Sea,and the upper-layer high PV extends downwards and southwards.Baroclinic development thus occurs and the tropical low-pressure system develops into an explosive vortex of the ISM,which leads to the onset of the ISM.In addition,evolution of subtropical anticyclone over the Arabian Peninsula is another important factor contributing to the onset of the ISM.Before the onset,the surface sensible heating on the Arabian Peninsula is very strong.Consequently the subtropical anticyclone which dominated the Arabian Sea in spring retreats westwards to the Arabian Peninsula and intensifies rapidly.The zonal asymmetric PV forcing develops gradually with high PV eddies moving southwards along northerlies on the eastern side of the anticyclone,and a high PV trough is formed in the middle troposphere over the Arabian Sea,which is favorable to the explosive barotropic development of the tropical cyclone into the vortex.Results from this study demonstrate that the ISM onset,which is different from the BOB and the SCS monsoon onset,is a special dynamical as well as thermodynamic process occurring under the condition of fully coupling of the upper,middle,and lower tropospheric circulations.
基金the National Natural Science Foundation of China(Grant Nos.12164032,11964026,and 12364010)the Natural Science Foundation of Inner Mongolia Autonomous Region,China(Grant Nos.2019MS01010,2022MS01014,and 2020BS01009)+1 种基金the Doctor Research Start-up Fund of Inner Mongolia Minzu University(Grant Nos.BS625 and BS439)the Basic Research Funds for Universities Directly under the Inner Mongolia Autonomous Region,China(Grant No.GXKY23Z029).
文摘We have applied strong coupling unitary transformation method combined with Bose–Einstein statistical law to investigate magnetopolaron energy level temperature effects in halogen ion crystal quantum wells.The obtained results showed that under magnetic field effect,magnetopolaron quasiparticle was formed through the interaction of electrons and surrounding phonons.At the same time,magnetopolaron was influenced by phonon temperature statistical law and important energy level shifts down and binding energy increases.This revealed that lattice temperature and magnetic field could easily affect magnetopolaron and the above results could play key roles in exploring thermoelectric conversion and conductivity of crystal materials.
基金supported by the National Natural Science Foundation of China under Grant No.11975011。
文摘By a combination method of Lee-Low-Pines unitary transformation method and Pekar-type variational method,the ground state energy(GSE)of the bound polaron is studied in the asymmetrical Gaussian potential quantum well considering the temperature and electromagneticfield.The impacts of the temperature and asymmetrical Gaussian potential,electromagnetic field and phonon-electron coupling upon the GSE are obtained.The results show that the GSE of the bound polaron not only oscillates as the temperature changes regardless of the electromagneticfield and asymmetrical Gaussian potential and Coulomb impurity potential(CIP)and electron-phonon coupling but also has different rules with the electromagnetic field and asymmetrical Gaussian potential and CIP and electron-phonon coupling at different temperature zones.
基金Supported by National Natural Science Foundation of China (11175219, 10875151, 10740420550)Major State Basic Research Developing Program of China (2007CB815004)+2 种基金Knowledge Innovation Project of Chinese Academy of Sciences (KJCX2-EW-N01)Chinese Academy of Sciences Visiting Professorship for Senior International Scientists (2009J2-26)CAS/SAFEA International Partnership Program for Creative Research Teams (CXTD-J2005-1)
文摘We investigate the neutron and proton single particle (s.p.) potentials of asymmetric nuclear matter and their isospin dependence in various spin-isospin ST channels within the framework of the BruecknerHartree-Fock approach. It is shown that in symmetric nuclear matter, the s.p. potentials in both the isospinsinglet T = 0 channel and isospin-triplet T = 1 channel are essentially attractive, and the magnitudes in the two different channels are roughly the same. In neutron-rich nuclear matter, the isospin-splitting of the proton and neutron s.p. potentials turns out to be mainly determined by the isospin-singlet T = 0 channel contribution which becomes more attractive for the proton and more repulsive for the neutron at higher asymmetries.
基金Project supported by the National Natural Science Foundation of China(No.11464033)the Mongolia University for Nationalities Fund(No.NMDYB1445)
文摘With the circumstance of the electron strongly coupled to LO-phonon and using the variational method of Pekar type(VMPT),we study the eigenenergies and the eigenfunctions(EE) of the ground and the first excited states(GFES) in a RbCl crystal asymmetric Gaussian potential quantum well(AGPQW).It concludes:(i) Twoenergy-level of the AGPQW may be seen as a qubit.(ii) When the electron located in the superposition state of the two-energy-level system,the time evolution and the coordinate changes of the electron probability density oscillated periodically in the AGPQW with every certain period T0=22.475 fs.(iii) Due to the confinement that is a two dimensional x-y plane symmetric structure in the AGPQW and the asymmetrical Gaussian potential(AGP) in the AGPQW growth direction,the electron probability density presents only one peak configuration located in the coordinate of z 〉 0,whereas it is zero in the range of z 〈 0.(iv) The oscillatory period is a decreasing function of the AGPQW height and the polaron radius,(v) The oscillating period is a decreasing one in the confinement potential R 〈 0.24 nm,whereas it is an increasing one in the confinement potential R 〉 0.24 nm and it takes a minimum value in R = 0.24 nm.