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Asymmetric Drying and Wetting Trends in Eastern and Western China 被引量:1
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作者 Wen WU Fei JI +1 位作者 Shujuan HU Yongli HE 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第2期221-232,共12页
As an important factor that directly affects agricultural production, the social economy, and policy implementation,observed changes in dry/wet conditions have become a matter of widespread concern. However, previous ... As an important factor that directly affects agricultural production, the social economy, and policy implementation,observed changes in dry/wet conditions have become a matter of widespread concern. However, previous research has mainly focused on the long-term linear changes of dry/wet conditions, while the detection and evolution of the non-linear trends related to dry/wet changes have received less attention. The non-linear trends of the annual aridity index, obtained by the Ensemble Empirical Mode Decomposition(EEMD) method, reveal that changes in dry/wet conditions in China are asymmetric and can be characterized by contrasting features in both time and space in China. Spatially, most areas in western China have experienced transitions from drying to wetting, while opposite changes have occurred in most areas of eastern China. Temporally, the transitions occurred earlier in western China compared to eastern China. Research into the asymmetric spatial characteristics of dry/wet conditions compensates for the inadequacies of previous studies, which focused solely on temporal evolution;at the same time, it remedies the inadequacies of traditional research on linear trends over centennial timescales. Analyzing the non-linear trend also provides for a more comprehensive understanding of the drying/wetting changes in China. 展开更多
关键词 aridity index EEMD dry/wet conditions asymmetric evolution
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Effects of asymmetric coupling and boundary on the dynamic behaviors of a random nearest neighbor coupled system
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作者 徐玲 姜磊 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期309-322,共14页
This study investigates the dynamical behaviors of nearest neighbor asymmetric coupled systems in a confined space.First, the study derivative analytical stability and synchronization conditions for the asymmetrically... This study investigates the dynamical behaviors of nearest neighbor asymmetric coupled systems in a confined space.First, the study derivative analytical stability and synchronization conditions for the asymmetrically coupled system in an unconfined space, which are then validated through numerical simulations. Simulation results show that asymmetric coupling has a significant impact on synchronization conditions. Moreover, it is observed that irrespective of whether the system is confined, an increase in coupling asymmetry leads to a hastened synchronization pace. Additionally, the study examines the effects of boundaries on the system's collective behaviors via numerical experiments. The presence of boundaries ensures the system's stability and synchronization, and reducing these boundaries can expedite the synchronization process and amplify its effects. Finally, the study reveals that the system's output amplitude exhibits stochastic resonance as the confined boundary size increases. 展开更多
关键词 asymmetric coupled confined space SYNCHRONIZATION stochastic resonance stability
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Enhanced and asymmetric signatures of hybridization at climatic margins: Evidence from closely related dioecious fig species
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作者 Jian-Feng Huang Clive T.Darwell Yan-Qiong Peng 《Plant Diversity》 SCIE CAS CSCD 2024年第2期181-193,共13页
Hybridization plays a significant role in biological evolution. However, it is not clear whether ecological contingency differentially influences likelihood of hybridization, particularly at ecological margins where p... Hybridization plays a significant role in biological evolution. However, it is not clear whether ecological contingency differentially influences likelihood of hybridization, particularly at ecological margins where parental species may exhibit reduced fitnesses. Moreover, it is unknown whether future ecosystem change will increase the prevalence of hybridization. Ficus heterostyla and F. squamosa are closely related species co-distributed from southern Thailand to southwest China where hybridization, yielding viable seeds, has been documented. As a robust test of ecological factors driving hybridization, we investigated spatial hybridization signatures based on nuclear microsatellites from extensive population sampling across a widespread contact range. Both species showed high population differentiation and strong patterns of isolation by distance. Admixture estimates exposed asymmetric interspecific gene flow.Signatures of hybridization increase significantly towards higher latitude zones, peaking at the northern climatic margins. Geographic variation in reproductive phenology combined with ecologically challenging marginal habitats may promote this phenomenon. Our work is a first systematic evaluation of such patterns in a comprehensive, latitudinally-based clinal context, and indicates that tendency to hybridize appears strongly influenced by environmental conditions. Moreover, that future climate change scenarios will likely alter and possibly augment cases of hybridization at ecosystem scales. 展开更多
关键词 HYBRIDIZATION Heterospecific visitation FIG Pollinator wasp Asymmetric gene flow
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Night warming increases wheat yield by improving pre-anthesis plant growth and post-anthesis grain starch biosynthesis
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作者 Yonghui Fan Boya Qin +8 位作者 Jinhao Yang Liangliang Ma Guoji Cui Wei He Yu Tang Wenjing Zhang Shangyu Ma Chuanxi Ma Zhenglai Huang 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第2期536-550,共15页
Global climate change is characterized by asymmetric warming,i.e.,greater temperature increases in winter,spring,and nighttime than in summer,autumn,and daytime.Field experiments were conducted using four wheat cultiv... Global climate change is characterized by asymmetric warming,i.e.,greater temperature increases in winter,spring,and nighttime than in summer,autumn,and daytime.Field experiments were conducted using four wheat cultivars,namely‘Yangmai 18’(YM18),‘Sumai 188’(SM188),‘Yannong 19’(YN19),and‘Annong 0711’(AN0711),in the two growing seasons of 2019-2020 and 2020-2021,with passive night warming during different periods in the early growth stage.The treatments were night warming during the tillering-jointing(NW_(T-J)),jointing-booting(NWJ-B),and booting-anthesis(NWB-A)stages,with ambient temperature(NN)as the control.The effects of night warming during different stages on wheat yield formation were investigated by determining the characteristics of dry matter accumulation and translocation,as well as sucrose and starch accumulation in wheat grains.The wheat yields of all four cultivars were significantly higher in NW_(T-J)than in NN in the 2-year experiment.The yield increases of semi-winter cultivars YN19 and AN0711 were greater than those of spring cultivars YM18 and SM188.Treatment NW_(T-J)increased wheat yield mainly by increasing the 1,000-grain weight and the number of fertile spikelets,and it increased dry matter accumulation in various organs of wheat at the anthesis and maturity stages by increasing the growth rate at the vegetative growth stage.The flag leaf and spike showed the largest increases in dry matter accumulation.NW_(T-J)also increased the grain sucrose and starch contents in the early and middle grain-filling stages,promoting yield formation.Overall,night warming between the tillering and jointing stages increased the pre-anthesis growth rate,and thus,wheat dry matter production,which contributed to an increase in wheat yield. 展开更多
关键词 wheat asymmetric warming dry matter accumulation and translocation STARCH yield
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Decentralized Optimal Control and Stabilization of Interconnected Systems With Asymmetric Information
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作者 Na Wang Xiao Liang +1 位作者 Hongdan Li Xiao Lu 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第3期698-707,共10页
The paper addresses the decentralized optimal control and stabilization problems for interconnected systems subject to asymmetric information.Compared with previous work,a closed-loop optimal solution to the control p... The paper addresses the decentralized optimal control and stabilization problems for interconnected systems subject to asymmetric information.Compared with previous work,a closed-loop optimal solution to the control problem and sufficient and necessary conditions for the stabilization problem of the interconnected systems are given for the first time.The main challenge lies in three aspects:Firstly,the asymmetric information results in coupling between control and estimation and failure of the separation principle.Secondly,two extra unknown variables are generated by asymmetric information(different information filtration)when solving forward-backward stochastic difference equations.Thirdly,the existence of additive noise makes the study of mean-square boundedness an obstacle.The adopted technique is proving and assuming the linear form of controllers and establishing the equivalence between the two systems with and without additive noise.A dual-motor parallel drive system is presented to demonstrate the validity of the proposed algorithm. 展开更多
关键词 Asymmetric information decentralized control forwardbackward stochastic difference equations interconnected system stalibization
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Acoustic Bilayer Gradient Metasurfaces for Perfect and Asymmetric Beam Splitting
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作者 权家琪 孙宝印 +2 位作者 伏洋洋 高雷 徐亚东 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第1期39-50,共12页
We experimentally and theoretically present a paradigm for the accurate bilayer design of gradient metasurfaces for wave beam manipulation,producing an extremely asymmetric splitting effect by simply tailoring the int... We experimentally and theoretically present a paradigm for the accurate bilayer design of gradient metasurfaces for wave beam manipulation,producing an extremely asymmetric splitting effect by simply tailoring the interlayer size.This concept arises from anomalous diffraction in phase gradient metasurfaces and the precise combination of the phase gradient in bilayer metasurfaces.Ensured by different diffraction routes in momentum space for incident beams from opposite directions,extremely asymmetric acoustic beam splitting can be generated in a robust way,as demonstrated in experiments through a designed bilayer system.Our work provides a novel approach and feasible platform for designing tunable devices to control wave propagation. 展开更多
关键词 SURFACES SPLITTING ASYMMETRIC
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Activation Redistribution Based Hybrid Asymmetric Quantization Method of Neural Networks
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作者 Lu Wei Zhong Ma Chaojie Yang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第1期981-1000,共20页
The demand for adopting neural networks in resource-constrained embedded devices is continuously increasing.Quantization is one of the most promising solutions to reduce computational cost and memory storage on embedd... The demand for adopting neural networks in resource-constrained embedded devices is continuously increasing.Quantization is one of the most promising solutions to reduce computational cost and memory storage on embedded devices.In order to reduce the complexity and overhead of deploying neural networks on Integeronly hardware,most current quantization methods use a symmetric quantization mapping strategy to quantize a floating-point neural network into an integer network.However,although symmetric quantization has the advantage of easier implementation,it is sub-optimal for cases where the range could be skewed and not symmetric.This often comes at the cost of lower accuracy.This paper proposed an activation redistribution-based hybrid asymmetric quantizationmethod for neural networks.The proposedmethod takes data distribution into consideration and can resolve the contradiction between the quantization accuracy and the ease of implementation,balance the trade-off between clipping range and quantization resolution,and thus improve the accuracy of the quantized neural network.The experimental results indicate that the accuracy of the proposed method is 2.02%and 5.52%higher than the traditional symmetric quantization method for classification and detection tasks,respectively.The proposed method paves the way for computationally intensive neural network models to be deployed on devices with limited computing resources.Codes will be available on https://github.com/ycjcy/Hybrid-Asymmetric-Quantization. 展开更多
关键词 QUANTIZATION neural network hybrid asymmetric ACCURACY
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Dynamics of information diffusion and disease transmission in time-varying multiplex networks with asymmetric activity levels
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作者 谢笑笑 霍良安 +1 位作者 董雅芳 程英英 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期690-699,共10页
While the interaction between information and disease in static networks has been extensively investigated,many studies have ignored the characteristics of network evolution.In this study,we construct a new two-layer ... While the interaction between information and disease in static networks has been extensively investigated,many studies have ignored the characteristics of network evolution.In this study,we construct a new two-layer coupling model to explore the interactions between information and disease.The upper layer describes the diffusion of disease-related information,and the lower layer represents the disease transmission.We then use power-law distributions to examine the influence of asymmetric activity levels on dynamic propagation,revealing a mapping relationship characterizing the interconnected propagation of information and diseases among partial nodes within the network.Subsequently,we derive the disease outbreak threshold by using the microscopic Markov-chain approach(MMCA).Finally,we perform extensive Monte Carlo(MC)numerical simulations to verify the accuracy of our theoretical results.Our findings indicate that the activity levels of individuals in the disease transmission layer have a more significant influence on disease transmission compared with the individual activity levels in the information diffusion layer.Moreover,reducing the damping factor can delay disease outbreaks and suppress disease transmission,while improving individual quarantine measures can contribute positively to disease control.This study provides valuable insights into policymakers for developing outbreak prevention and control strategies. 展开更多
关键词 information diffusion disease transmission asymmetric activity levels quarantine strength
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Dynamics and vibration reduction performance of asymmetric tristable nonlinear energy sink
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作者 Hongyan CHEN Youcheng ZENG +2 位作者 Hu DING Siukai LAI Liqun CHEN 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第3期389-406,共18页
With its complex nonlinear dynamic behavior,the tristable system has shown excellent performance in areas such as energy harvesting and vibration suppression,and has attracted a lot of attention.In this paper,an asymm... With its complex nonlinear dynamic behavior,the tristable system has shown excellent performance in areas such as energy harvesting and vibration suppression,and has attracted a lot of attention.In this paper,an asymmetric tristable design is proposed to improve the vibration suppression efficiency of nonlinear energy sinks(NESs)for the first time.The proposed asymmetric tristable NES(ATNES)is composed of a pair of oblique springs and a vertical spring.Then,the three stable states,symmetric and asymmetric,can be achieved by the adjustment of the distance and stiffness asymmetry of the oblique springs.The governing equations of a linear oscillator(LO)coupled with the ATNES are derived.The approximate analytical solution to the coupled system is obtained by the harmonic balance method(HBM)and verified numerically.The vibration suppression efficiency of three types of ATNES is compared.The results show that the asymmetric design can improve the efficiency of vibration reduction through comparing the chaotic motion of the NES oscillator between asymmetric steady states.In addition,compared with the symmetrical tristable NES(TNES),the ATNES can effectively control smaller structural vibrations.In other words,the ATNES can effectively solve the threshold problem of TNES failure to weak excitation.Therefore,this paper reveals the vibration reduction mechanism of the ATNES,and provides a pathway to expand the effective excitation amplitude range of the NES. 展开更多
关键词 ASYMMETRIC nonlinear energy sink(NES) tristable vibration control po-tential barrier
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Coexistence behavior of asymmetric attractors in hyperbolic-type memristive Hopfield neural network and its application in image encryption
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作者 李晓霞 何倩倩 +2 位作者 余天意 才壮 徐桂芝 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期302-315,共14页
The neuron model has been widely employed in neural-morphic computing systems and chaotic circuits.This study aims to develop a novel circuit simulation of a three-neuron Hopfield neural network(HNN)with coupled hyper... The neuron model has been widely employed in neural-morphic computing systems and chaotic circuits.This study aims to develop a novel circuit simulation of a three-neuron Hopfield neural network(HNN)with coupled hyperbolic memristors through the modification of a single coupling connection weight.The bistable mode of the hyperbolic memristive HNN(mHNN),characterized by the coexistence of asymmetric chaos and periodic attractors,is effectively demonstrated through the utilization of conventional nonlinear analysis techniques.These techniques include bifurcation diagrams,two-parameter maximum Lyapunov exponent plots,local attractor basins,and phase trajectory diagrams.Moreover,an encryption technique for color images is devised by leveraging the mHNN model and asymmetric structural attractors.This method demonstrates significant benefits in correlation,information entropy,and resistance to differential attacks,providing strong evidence for its effectiveness in encryption.Additionally,an improved modular circuit design method is employed to create the analog equivalent circuit of the memristive HNN.The correctness of the circuit design is confirmed through Multisim simulations,which align with numerical simulations conducted in Matlab. 展开更多
关键词 hyperbolic-type memristor Hopfield neural network(HNN) asymmetric attractors image encryption
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Asymmetric Electrolytes Design for Aqueous Multivalent Metal Ion Batteries
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作者 Xiaochen Yang Xinyu Wang +2 位作者 Yue Xiang Longtao Ma Wei Huang 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期227-253,共27页
With the rapid development of portable electronics and electric road vehicles,high-energy-density batteries have been becoming front-burner issues.Traditionally,homogeneous electrolyte cannot simultaneously meet diame... With the rapid development of portable electronics and electric road vehicles,high-energy-density batteries have been becoming front-burner issues.Traditionally,homogeneous electrolyte cannot simultaneously meet diametrically opposed demands of high-potential cathode and low-potential anode,which are essential for high-voltage batteries.Meanwhile,homogeneous electrolyte is difficult to achieve bi-or multi-functions to meet different requirements of electrodes.In comparison,the asymmetric electrolyte with bi-or multi-layer disparate components can satisfy distinct requirements by playing different roles of each electrolyte layer and meanwhile compensates weakness of individual electrolyte.Consequently,the asymmetric electrolyte can not only suppress by-product sedimentation and continuous electrolyte decomposition at the anode while preserving active substances at the cathode for high-voltage batteries with long cyclic lifespan.In this review,we comprehensively divide asymmetric electrolytes into three categories:decoupled liquid-state electrolytes,bi-phase solid/liquid electrolytes and decoupled asymmetric solid-state electrolytes.The design principles,reaction mechanism and mutual compatibility are also studied,respectively.Finally,we provide a comprehensive vision for the simplification of structure to reduce costs and increase device energy density,and the optimization of solvation structure at anolyte/catholyte interface to realize fast ion transport kinetics. 展开更多
关键词 Asymmetric electrolyte Aqueous multivalent metal ion batteries Electrochemical stability windows Electrolyte interface
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Alkyl chain modulation of asymmetric hexacyclic fused acceptor synergistically with wide bandgap third component for high efficiency ternary organic solar cells
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作者 Shufang Li Huilan Guan +4 位作者 Can Zhu Chaoyuan Sun Qingya Wei Jun Yuan Yingping Zou 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第7期1713-1719,共7页
Herein,two asymmetric hexacyclic fused small molecule acceptors(SMAs),namely BP4F-HU and BP4F-UU,were synthesized.The elongated outside chains in the BP4F-UU molecule played a crucial role in optimizing the morphology... Herein,two asymmetric hexacyclic fused small molecule acceptors(SMAs),namely BP4F-HU and BP4F-UU,were synthesized.The elongated outside chains in the BP4F-UU molecule played a crucial role in optimizing the morphology of blend film,thereby improving charge mobility and reducing energy loss within the corresponding film.Notably,the PM6:BP4F-UU device exhibited a higher open-circuit voltage(V_(oc))of 0.878 V compared to the PM6:BP4F-HU device with a V_(oc)of 0.863 V.Further,a new wide bandgap SMA named BTP-TA was designed and synthesized as the third component to the PM6:BP4F-UU host binary devices,which showed an ideal complementary absorption spectrum in PM6:BP4F-UU system.In addition,BTP-TA can achieve efficient intermolecular energy transfer to BP4F-UU by fluorescence resonance energy transfer(FRET)pathway,due to the good overlap between the photoluminescence(PL)spectrum of BTP-TA and the absorption region of BP4F-UU.Consequently,ternary devices with 15wt%BTP-TA exhibits broader photon utilization,optimal blend morphology,and reduced charge recombination compared to the corresponding binary devices.Consequently,PM6:BP4F-UU:BTP-TA ternary device achieved an optimal power conversion efficiency(PCE)of 17.83%with simultaneously increased V_(oc)of 0.905 V,short-circuit current density(J_(sc))of 26.14 mA/cm^(2),and fill factor(FF)of 75.38%. 展开更多
关键词 asymmetric hexacyclic acceptor outside chain wide bandgap acceptor ternary organic solar cells
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Mechanism of Thermally Radiative Prandtl Nanofluids and Double-Diffusive Convection in Tapered Channel on Peristaltic Flow with Viscous Dissipation and Induced Magnetic Field
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作者 Yasir Khan Safia Akram +3 位作者 Maria Athar Khalid Saeed Alia Razia A.Alameer 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第2期1501-1520,共20页
The application of mathematical modeling to biological fluids is of utmost importance, as it has diverse applicationsin medicine. The peristaltic mechanism plays a crucial role in understanding numerous biological flo... The application of mathematical modeling to biological fluids is of utmost importance, as it has diverse applicationsin medicine. The peristaltic mechanism plays a crucial role in understanding numerous biological flows. In thispaper, we present a theoretical investigation of the double diffusion convection in the peristaltic transport of aPrandtl nanofluid through an asymmetric tapered channel under the combined action of thermal radiation andan induced magnetic field. The equations for the current flow scenario are developed, incorporating relevantassumptions, and considering the effect of viscous dissipation. The impact of thermal radiation and doublediffusion on public health is of particular interest. For instance, infrared radiation techniques have been used totreat various skin-related diseases and can also be employed as a measure of thermotherapy for some bones toenhance blood circulation, with radiation increasing blood flow by approximately 80%. To solve the governingequations, we employ a numerical method with the aid of symbolic software such as Mathematica and MATLAB.The velocity, magnetic force function, pressure rise, temperature, solute (species) concentration, and nanoparticlevolume fraction profiles are analytically derived and graphically displayed. The results outcomes are compared withthe findings of limiting situations for verification. 展开更多
关键词 Double diffusion convection thermal radiation induced magnetic field peristaltic flow tapered asymmetric channel viscous dissipation Prandtl nanofluid
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Stacking-dependent exchange bias in two-dimensional ferromagnetic/antiferromagnetic bilayers
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作者 李慧平 潘帅唯 +2 位作者 王喆 向斌 朱文光 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期708-714,共7页
A clear microscopic understanding of exchange bias is crucial for its application in magnetic recording, and further progress in this area is desired. Based on the results of our first-principles calculations and Mont... A clear microscopic understanding of exchange bias is crucial for its application in magnetic recording, and further progress in this area is desired. Based on the results of our first-principles calculations and Monte Carlo simulations,we present a theoretical proposal for a stacking-dependent exchange bias in two-dimensional compensated van der Waals ferromagnetic/antiferromagnetic bilayer heterostructures. The exchange bias effect emerges in stacking registries that accommodate inhomogeneous interlayer magnetic interactions between the ferromagnetic layer and different spin sublattices of the antiferromagnetic layer. Moreover, the on/off switching and polarity reversal of the exchange bias can be achieved by interlayer sliding, and the strength can be modulated using an external electric field. Our findings push the limits of exchange bias systems to extreme bilayer thickness in two-dimensional van der Waals heterostructures, potentially stimulating new experimental investigations and applications. 展开更多
关键词 exchange bias two-dimensional ferromagnetic/antiferromagnetic bilayers asymmetric magnetic interaction
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Asymmetric orbital hybridization in Zn-doped antiperovskite Cu_(1-x)Zn_(x)NMn_(3)enables highly efficient electrocatalytic hydrogen production
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作者 Yuxiang Yan Yuxin Cao +9 位作者 Zhichao Wang Ka Wang Hengdong Ren Shaoqi Zhang Yi Wang Jian Chen Yong Zhou Lizhe Liu Jun Dai Xinglong Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期304-312,I0008,共10页
Rational design of efficient and robust earth-abundant alkaline hydrogen evolution reaction(HER)catalysts is a key factor for developing energy conversion technologies.Currently,antiperovskite nitride CuNMn_(3)has gar... Rational design of efficient and robust earth-abundant alkaline hydrogen evolution reaction(HER)catalysts is a key factor for developing energy conversion technologies.Currently,antiperovskite nitride CuNMn_(3)has garnered significant interest due to its remarkable properties such as negative/zero thermal expansion and magnetocaloric effects.However,when utilized as hydrogen evolution catalysts,it encounters large challenge resulting from excessively strong/weak interactions with adsorbed H on Mn/Cu active sites,which leads to low HER activity.In this study,we introduce an asymmetric orbital hybridization strategy in Zn-doped Cu_(1-x)Zn_(x)NMn_(3)by leveraging the localization of Zn electronic states to reconfigure the electronic structures of Cu and Mn,thereby reducing the energy barrier for water dissociation and optimizing Cu and Mn active sites for hydrogen adsorption and H_(2)production.Electrochemical evaluations reveal that Cu_(0.85)Zn_(0.15)NMn_(3)with x=0.15 demonstrates exceptional electrocatalytic activity in alkaline electrolytes.A low overpotential of 52 mV at 10 mA cm^(-2)and outstanding stability over a 150-h test period are achieved,surpassing commercial Pt/C.This research offers a novel strategy for enhancing HER performance by modulating asymmetric hybridization of electron orbitals between multiple metal atoms within a material structure. 展开更多
关键词 Cu_(1-x)ZnxNMn_(3) Asymmetric orbital hybridization Hydrogen adsorption Hydrogen production
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Operationally Simple Enantioselective Silane Reduction of Ketones by the [Ir(OMe)(cod)]2/Azolium Catalytic System
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作者 Satoshi Sakaguchi Chika Nagao +1 位作者 Ryo Ichihara Shogo Matsuo 《International Journal of Organic Chemistry》 2024年第1期1-19,共19页
An operationally simple protocol was designed for the enantioselective silane reduction (ESR) of ketones using air- and moisture-stable [Ir(OMe)(cod)]<sub>2</sub> (cod = 1,5-cyclooctadiene) (3) as a metal ... An operationally simple protocol was designed for the enantioselective silane reduction (ESR) of ketones using air- and moisture-stable [Ir(OMe)(cod)]<sub>2</sub> (cod = 1,5-cyclooctadiene) (3) as a metal catalyst precursor. This reaction was driven by chiral hydroxyamide-functionalized azolium salt 2. The catalytic ESR reaction could be performed under benchtop conditions at room temperature. Treatment of 2 with 3 in THF yielded the monodentate IrCl(NHC)(cod) (NHC = N-heterocyclic carbene) complex 4 in 93% yield, herein the anionic methoxy ligand of 3 serves as an internal base that deprotonates the azolium ring of 2. The well-defined Ir complex 4 catalyzed the ESR reaction of propiophenone (6) with (EtO)<sub>2</sub>MeSiH using the pre-mixing reaction procedure. Based on this success, the catalytic ESR reaction was designed and implemented using an in situ-generated NHC/Ir catalyst derived from 2 and 3. Thus, a wide variety of aryl ketones could be reduced to the corresponding optically active alcohols in moderate to excellent stereoselectivities at room temperature without temperature control. Since the high catalytic activity of 3 was observed, we next evaluated several other transition metal catalyst precursors for the catalytic ESR reaction under the influence of 2. This evaluation revealed that Ir(acac)(cod) (acac = acetylacetonate) (28) and [IrCl(cod)]<sub>2</sub> (5) can be successfully used as metal catalyst precursors in the ESR reaction. 展开更多
关键词 Asymmetric Catalysis Enantioselective Reduction Hydrosilylation Reaction N-Heterocyclic Carbene IRIDIUM
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Constraints on Asymmetric Dark Matter in Quintessence Model
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作者 Sujuan Qiu Hoernisa Iminniyaz 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2024年第2期599-608,共10页
The modified cosmology like quintessence model with kination phase predicted the Hubble expansion rate of the universe before Big Bang Nucleosynthesis is different from the standard cosmological scenario. The modified... The modified cosmology like quintessence model with kination phase predicted the Hubble expansion rate of the universe before Big Bang Nucleosynthesis is different from the standard cosmological scenario. The modified expansion rate leaves its imprint on the relic density of asymmetric dark matter. In this work, we review the calculation of relic density of asymmetric WIMP dark matter in the standard cosmological scenario and quintessence model with kination phase. Then we use the Planck data to find constraints on the annihilation cross section and the mass of the asymmetric dark matter in those models. 展开更多
关键词 Asymmetric Dark Matter Standard Model Quintessence Model
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水稻TAC1基因的STARP标记开发及164份杂交稻TAC1基因型分析
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作者 杨绍华 桂毅杰 +4 位作者 陈睿 周淑芬 陈在杰 刘华清 王锋 《福建农业科技》 CAS 2023年第4期7-11,共5页
分蘖角度是水稻重要的株型性状,合适分蘖角是实现水稻高产的关键因素。针对控制水稻分蘖角度的主效基因TAC1的功能位点,设计了基于STARP(Semi-thermal asymmetric reverse PCR)技术的特异性分子标记S-TAC1,并对56份已测序常规水稻品种及... 分蘖角度是水稻重要的株型性状,合适分蘖角是实现水稻高产的关键因素。针对控制水稻分蘖角度的主效基因TAC1的功能位点,设计了基于STARP(Semi-thermal asymmetric reverse PCR)技术的特异性分子标记S-TAC1,并对56份已测序常规水稻品种及164份杂交水稻进行了基因型鉴定。S-TAC1准确地鉴定了56个已测序常规品种的基因型,紧凑纯合基因型tac1/tac136份,松散纯合型TAC1/TAC120份,表明S-TAC1分型结果准确可靠。在164份杂交水稻中,杂合基因型TAC1/tac162份,松散纯合型TAC1/TAC1102份。本研究开发的功能标记为通过分子标记辅助选择培育理想株型的水稻品种提供了技术支撑。 展开更多
关键词 水稻 TAC1基因 分子标记 STARP(Semi-thermal asymmetric reverse PCR)技术
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All-optical controlled-NOT logic gate achieving directional asymmetric transmission based on metasurface doublet 被引量:4
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作者 Yijia Huang Tianxiao Xiao +9 位作者 Shuai Chen Zhengwei Xie Jie Zheng Jianqi Zhu Yarong Su Weidong Chen Ke Liu Mingjun Tang Peter Müller-Buschbaum Ling Li 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2023年第7期41-49,共9页
Optical logic gates play important roles in all-optical logic circuits,which lie at the heart of the next-generation optical computing technology.However,the intrinsic contradiction between compactness and robustness ... Optical logic gates play important roles in all-optical logic circuits,which lie at the heart of the next-generation optical computing technology.However,the intrinsic contradiction between compactness and robustness hinders the development in this field.Here,we propose a simple design principle that can possess multiple-input-output states according to the incident circular polarization and direction based on the metasurface doublet,which enables controlled-NOT logic gates in infrared region.Therefore,the directional asymmetric electromagnetic transmission can be achieved.As a proof of concept,a spin-dependent Janus metasurface is designed and experimentally verified that four distinct images corresponding to four input states can be captured in the far-field.In addition,since the design method is derived from geometric optics,it can be easily applied to other spectra.We believe that the proposed metasurface doublet may empower many potential applications in chiral imaging,chiroptical spectroscopy and optical computing. 展开更多
关键词 metasurface polarization control asymmetric transmission logic gate
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Imidazole linker‐induced covalent triazine framework-ZIF hybrids for confined hollow carbon super‐heterostructures toward a long‐life supercapacitor 被引量:2
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作者 Madagonda MVadiyar Ji‐Young Kim +1 位作者 Jee‐Hwan Bae Kyung‐Wan Nam 《Carbon Energy》 SCIE EI CAS CSCD 2023年第10期25-39,共15页
Carbon super-heterostructures with high nitrogen contents from the covalent hybrid precursors of covalent triazine frameworks(CTFs)and zeolitic imidazolic frameworks(ZIFs)are scarcely explored because of CTF's ord... Carbon super-heterostructures with high nitrogen contents from the covalent hybrid precursors of covalent triazine frameworks(CTFs)and zeolitic imidazolic frameworks(ZIFs)are scarcely explored because of CTF's ordered structure and toxic superacid that dissolves or destabilizes the metal nodes.To solve this problem,herein,we report a straightforward two-step pathway for the covalent hybridization of disordered CTF(d–CTF)–ZIF composites via preincorporation of an imidazole(IM)linker into ordered CTFs,followed by the imidazole-site-specific covalent growth of ZIFs.Direct carbonization of these synthesized d–CTF−IM−ZIF hybrids results in unique hollow carbon super-heterostructures with ultrahigh nitrogen content(>18.6%),high specific surface area(1663m^(2)g^(−1)),and beneficial trace metal(Co/Zn NPs)contents for promoting the redox pseudocapacitance.As proof of concept,the obtained carbon super-heterostructure(Co–Zn–NC_(SNH)–800)is used as a positive electrode in an asymmetric supercapacitor,demonstrating a remarkable energy density of 61Wh kg^(−1)and extraordinary cyclic stability of 97%retention after 30,000 cycles at the cell level.Our presynthetic modifications of CTF and their covalent hybridization with ZIF crystals pave the way toward new design strategies for synthesizing functional porous carbon materials for promising energy applications. 展开更多
关键词 asymmetric supercapacitor defective covalent triazine frameworks hollow carbon superheterostructures linker defect
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