This paper investigates the breaking point between fast-and slow-light in a degenerate two-level atomic system,where fast-light can be converted to slow-light arbitrarily on a single transition line by adjusting the s...This paper investigates the breaking point between fast-and slow-light in a degenerate two-level atomic system,where fast-light can be converted to slow-light arbitrarily on a single transition line by adjusting the strength of the pumping field.An equivalent incoherent pumping rate is introduced in this simplified theoretical model which exploits the dependence of this feature.The experimental observation is presented as evidence of the breaking point where the injected power is about 0.08 mW.展开更多
In this paper, we have proposed the numerical calculations to study the quantum entanglement (QE) of moving two-level atom interacting with a coherent and the thermal field influenced by intrinsic decoherence (ID), Ke...In this paper, we have proposed the numerical calculations to study the quantum entanglement (QE) of moving two-level atom interacting with a coherent and the thermal field influenced by intrinsic decoherence (ID), Kerr medium (non-linear) and the Stark effect. The wave function of the complete system interacting with a coherent and the thermal field is calculated numerically affected by ID, Kerr (non-linear) and Stark effects. It has been seen that the Stark, Kerr, ID and the thermal environment have a significant effect during the time evolution of the quantum system. Quantum Fisher information (QFI) and QE decrease as the value of the ID parameter is increased in the thermal field without the atomic movement. It is seen that QFI and von Neumann entropy (VNE) show an opposite and periodic response in the presence of atomic motion. The non-linear Kerr medium has a more prominent and significant effect on the QE as the value of the Kerr parameter is decreased. At smaller values of the non-linear Kerr parameter, the VNE increases, however, QFI decreases, so QFI and VNE have a monotonic connection with one another. As the value of the Kerr parameter is increased, the effect of non-linear Kerr doesn’t stay critical on both QFI and QE. However, a periodic response of QE is seen because of the atomic movement which becomes modest under natural impacts. Moreover, it has been seen that QFI and QE rot soon at the smaller values of the Stark parameter. However, as the value of the Stark parameter is increased, the QFI and QE show periodic response even when the atomic movement is absent.展开更多
Localization of the three-level Λ-type atomic system interacting with two orthogonal standing-wave fields is proposed. Two equal and tunable peaks in the 2D plane are obtained by the detunings corresponding to the tw...Localization of the three-level Λ-type atomic system interacting with two orthogonal standing-wave fields is proposed. Two equal and tunable peaks in the 2D plane are obtained by the detunings corresponding to the two orthogonal standing-wave fields when the decreasing intensities of spontaneously generated coherence (SGC) arise in the three-level Λ-type atomic system, while one circular ring with shrinking radii in the 2D plane is obtained by the adjusted phases and wave vectors of the standing-wave fields when the increasing intensities of SGC occur in the three-level Λ-type atomic system. 2D atom localization with the single ring with shrinking radii realized by the multiple parametric manipulations demonstrated the flexibility for our scheme.展开更多
Rydberg atoms have been widely investigated due to their large size,long radiative lifetime,huge polarizability and strong dipole-dipole interactions.The position information of Rydberg atoms provides more possibiliti...Rydberg atoms have been widely investigated due to their large size,long radiative lifetime,huge polarizability and strong dipole-dipole interactions.The position information of Rydberg atoms provides more possibilities for quantum optics research,which can be obtained under the localization method.We study the behavior of three-dimensional(3D)Rydberg atom localization in a four-level configuration with the measurement of the spatial optical absorption.The atomic localization precision depends strongly on the detuning and Rabi frequency of the involved laser fields.A 100%probability of finding the Rydberg atom at a specific 3D position is achieved with precision of~0.031λ.This work demonstrates the possibility for achieving the 3D atom localization of the Rydberg atom in the experiment.展开更多
We study the dynamics of the entropic uncertainty for three types of three-level atomic systems coupled to an environment modeled by random matrices. The results show that the entropic uncertainty in the Ξ-type atomi...We study the dynamics of the entropic uncertainty for three types of three-level atomic systems coupled to an environment modeled by random matrices. The results show that the entropic uncertainty in the Ξ-type atomic system is lower than that in the V-type atomic system which is exactly the same as that in the Λ-type atomic system. In addition, the effect of relative coupling strength on entropic uncertainty is opposite in Markov region and non-Markov region, and the influence of a common environment and independent environments in Markov region and non-Markov region is also opposite. One can reduce the entropic uncertainty by decreasing relative coupling strength or placing the system in two separate environments in the Markov case. In the non-Markov case, the entropic uncertainty can be reduced by increasing the relative coupling strength or by placing the system in a common environment.展开更多
We have investigated numerically the dynamics of quantum Fisher information (QFI) and quantum entanglement (QE) for N-level atomic system interacting with a coherent field in the presence of Kerr (linear and non-linea...We have investigated numerically the dynamics of quantum Fisher information (QFI) and quantum entanglement (QE) for N-level atomic system interacting with a coherent field in the presence of Kerr (linear and non-linear medium) and Stark effects. It is observed that the Stark and Kerr effects play a prominent role during the time evolution of the quantum system. The evolving quantum Fisher information (QFI) is noted as time grows under the non-linear Kerr medium contrary to the QE for higher dimensional systems. The effect of non-linear Kerr medium is greater on the QE as we increase the value of Kerr parameter. However, QFI and QE maintain their periodic nature under atomic motion. On the other hand, linear Kerr medium has no prominent effects on the dynamics of N-level atomic system. Furthermore, it has been observed that QFI and QE decay soon under the influence of Stark effect. In short, the N-level atomic system is found prone to the change of the Kerr medium and Stark effect for higher dimensional systems.展开更多
A novel method to control the group velocity of light propagation in a two-level atomic system without additional optical field is proposed. Numerical result and experimental data shows that by changing the magnetic f...A novel method to control the group velocity of light propagation in a two-level atomic system without additional optical field is proposed. Numerical result and experimental data shows that by changing the magnetic field intensity and vapor temperature, the group velocity of probe light can be controlled in an appropriate region.展开更多
The mechanical angular momentum and magnetic moment of the electron and proton spin have been calculated semiclassically with the aid of the uncertainty principle for energy and time. The spin effects of both kinds of...The mechanical angular momentum and magnetic moment of the electron and proton spin have been calculated semiclassically with the aid of the uncertainty principle for energy and time. The spin effects of both kinds of the elementary particles can be expressed in terms of similar formulae. The quantization of the spin motion has been done on the basis of the old quantum theory. It gives a quantum number n = 1/2 as the index of the spin state acceptable for both the electron and proton particle. In effect of the spin existence the electron motion in the hydrogen atom can be represented as a drift motion accomplished in a combined electric and magnetic field. More than 18,000 spin oscillations accompany one drift circulation performed along the lowest orbit of the Bohr atom. The semiclassical theory developed in the paper has been applied to calculate the doublet separation of the experimentally well-examined D line entering the spectrum of the sodium atom. This separation is found to be much similar to that obtained according to the relativistic old quantum theory.展开更多
Transition metal dichalcogenides(TMDs)are a promising class of layered materials in the post-graphene era,with extensive research attention due to their diverse alternative elements and fascinating semiconductor behav...Transition metal dichalcogenides(TMDs)are a promising class of layered materials in the post-graphene era,with extensive research attention due to their diverse alternative elements and fascinating semiconductor behavior.Binary MX2 layers with different metal and/or chalcogen elements have similar structural parameters but varied optoelectronic properties,providing opportunities for atomically substitutional engineering via partial alteration of metal or/and chalcogenide atoms to produce ternary or quaternary TMDs.The resulting multinary TMD layers still maintain structural integrity and homogeneity while achieving tunable(opto)electronic properties across a full range of composition with arbitrary ratios of introduced metal or chalcogen to original counterparts(0–100%).Atomic substitution in TMD layers offers new adjustable degrees of freedom for tailoring crystal phase,band alignment/structure,carrier density,and surface reactive activity,enabling novel and promising applications.This review comprehensively elaborates on atomically substitutional engineering in TMD layers,including theoretical foundations,synthetic strategies,tailored properties,and superior applications.The emerging type of ternary TMDs,Janus TMDs,is presented specifically to highlight their typical compounds,fabrication methods,and potential applications.Finally,opportunities and challenges for further development of multinary TMDs are envisioned to expedite the evolution of this pivotal field.展开更多
The early stage evolution of local atomic structures in a multicomponent metallic glass during its crystallization process has been investigated via molecular dynamics simulation.It is found that the initial thermal s...The early stage evolution of local atomic structures in a multicomponent metallic glass during its crystallization process has been investigated via molecular dynamics simulation.It is found that the initial thermal stability and earliest stage evolution of the local atomic clusters show no strong correlation with their initial short-range orders,and this leads to an observation of a novel symmetry convergence phenomenon,which can be understood as an atomic structure manifestation of the ergodicity.Furthermore,in our system we have quantitatively proved that the crucial factor for the thermal stability against crystallization exhibited by the metallic glass is not the total amount of icosahedral clusters,but the degree of global connectivity among them.展开更多
Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,in...Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,increasing the binding of the*COOH to the active site will generally increase the*CO desorption energy.Breaking this relationship may be expected to dramatically improve the intrinsic activity of CO_(2)RR,but remains an unsolved challenge.Herein,we addressed this conundrum by constructing a unique atomic dispersed hetero-pair consisting of Mo-Fe di-atoms anchored on N-doped carbon carrier.This system shows an unprecedented CO_(2)RR intrinsic activity with TOF of 3336 h−1,high selectivity toward CO production,Faradaic efficiency of 95.96%at−0.60 V and excellent stability.Theoretical calculations show that the Mo-Fe diatomic sites increased the*COOH intermediate adsorption energy by bridging adsorption of*COOH intermediates.At the same time,d-d orbital coupling in the Mo-Fe di-atom results in electron delocalization and facilitates desorption of*CO intermediates.Thus,the undesirable correlation between these steps is broken.This work provides a promising approach,specifically the use of di-atoms,for breaking unfavorable relationships based on understanding of the catalytic mechanisms at the atomic scale.展开更多
It is assumed that reconfigurable intelligent surface(RIS)is a key technology to enable the potential of mmWave communications.The passivity of the RIS makes channel estimation difficult because the channel can only b...It is assumed that reconfigurable intelligent surface(RIS)is a key technology to enable the potential of mmWave communications.The passivity of the RIS makes channel estimation difficult because the channel can only be measured at the transceiver and not at the RIS.In this paper,we propose a novel separate channel estimator via exploiting the cascaded sparsity in the continuously valued angular domain of the cascaded channel for the RIS-enabled millimeter-wave/Tera-Hz systems,i.e.,the two-stage estimation method where the cascaded channel is separated into the base station(BS)-RIS and the RIS-user(UE)ones.Specifically,we first reveal the cascaded sparsity,i.e.,the sparsity exists in the hybrid angular domains of BS-RIS and the RIS-UEs separated channels,to construct the specific sparsity structure for RIS enabled multi-user systems.Then,we formulate the channel estimation problem using atomic norm minimization(ANM)to enhance the proposed sparsity structure in the continuous angular domains,where a low-complexity channel estimator via Alternating Direction Method of Multipliers(ADMM)is proposed.Simulation findings demonstrate that the proposed channel estimator outperforms the current state-of-the-arts in terms of performance.展开更多
Lithium–oxygen battery with ultrahigh theoretical energy density is considered a highly competitive next-generation energy storage device,but its practical application is severely hindered by issues such as difficult...Lithium–oxygen battery with ultrahigh theoretical energy density is considered a highly competitive next-generation energy storage device,but its practical application is severely hindered by issues such as difficult decomposition of discharge products at present.Here,we have developed N-doped carbon anchored atomically dispersed Ru sites cathode catalyst with open hollow structure(h-RuNC)for Lithium–oxygen battery.On one hand,the abundance of atomically dispersed Ru sites can effectively catalyze the formation and decomposition of discharge products,thereby greatly enhancing the redox kinetics.On the other hand,the open hollow structure not only enhances the mass activity of atomically dispersed Ru sites but also improves the diffusion efficiency of catalytic molecules.Therefore,the excellent activity from atomically dispersed Ru sites and the enhanced diffusion from open hollow structure respectively improve the redox kinetics and cycling stability,ultimately achieving a high-performance lithium–oxygen battery.展开更多
Developing cost-effective,robust and stable non-precious metal catalysts for oxygen reduction reaction(ORR) is of paramount importance for electrochemical energy conversion devices such as fuel cells and metal-air bat...Developing cost-effective,robust and stable non-precious metal catalysts for oxygen reduction reaction(ORR) is of paramount importance for electrochemical energy conversion devices such as fuel cells and metal-air batteries.Although Fe-N-C single atom catalysts(SACs) have been hailed as the most promising candidate due to the optimal binding strength of ORR intermediates on the Fe-N_(4) sites,they suffer from serious mass transport limitations as microporous templates/substrates,i.e.,zeolitic imidazolate frameworks(ZIFs),are usually employed to host the active sites.Motivated by this challenge,we herein develop a hydrogen-bonded organic framework(HOF)-assisted pyrolysis strategy to construct hierarchical micro/mesoporous carbon nanoplates for the deposition of atomically dispersed Fe-N_(4) sites.Such a design is accomplished by employing HOF nanoplates assembled from 2-aminoterephthalic acid(NH_(2)-BDC) and p-phenylenediamine(PDA) as both soft templates and C,N precursors.Benefitting from the structural merits inherited from HOF templates,the optimized catalyst(denoted as Fe-N-C SAC-950) displays outstanding ORR activity with a high half-wave potential of 0.895 V(vs.reversible hydrogen electrode(RHE)) and a small overpotential of 356 mV at 10 mA cm^(-2) for the oxygen evolution reaction(OER).More excitingly,its application potential is further verified by delivering superb rechargeability and cycling stability with a nearly unfading charge-discharge gap of 0.72 V after 160 h.Molecular dynamics(MD) simulations reveal that micro/mesoporous structure is conducive to the rapid mass transfer of O_(2),thus enhancing the ORR performance.In situ Raman results further indicate that the conversion of O_(2) to~*O_(2)-the rate-determining step(RDS) for Fe-N-C SAC-950.This work will provide a versatile strategy to construct single atom catalysts with desirable catalytic properties.展开更多
Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utiliz...Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utilization and exceptional catalytic functionality.Furthermore,accurately controlling atomic physical properties including spin,charge,orbital,and lattice degrees of atomically dispersed catalysts can realize the optimized chemical properties including maximum atom utilization efficiency,homogenous active centers,and satisfactory catalytic performance,but remains elusive.Here,through physical and chemical insight,we review and systematically summarize the strategies to optimize atomically dispersed ORR catalysts including adjusting the atomic coordination environment,adjacent electronic orbital and site density,and the choice of dual-atom sites.Then the emphasis is on the fundamental understanding of the correlation between the physical property and the catalytic behavior for atomically dispersed catalysts.Finally,an overview of the existing challenges and prospects to illustrate the current obstacles and potential opportunities for the advancement of atomically dispersed catalysts in the realm of electrocatalytic reactions is offered.展开更多
Urea oxidation reaction(UOR) has been selected as substitution for oxygen evolution reaction ascribing to its low thermodynamic voltage as well as utilization of nickel as electrocatalyst.Herein,we report the formatio...Urea oxidation reaction(UOR) has been selected as substitution for oxygen evolution reaction ascribing to its low thermodynamic voltage as well as utilization of nickel as electrocatalyst.Herein,we report the formation of nickel single atoms(Ni-SAs) as exceptional bifunctional electrocatalyst toward UOR and hydrogen evolution reaction(HER) in urea-assisted water splitting.In UOR catalysis,Ni-SAs perform a superior catalytic performance than Ni-NP/NC and Pt/C ascribing to the formation of HOO-Ni-N_(4) structure evidenced by in-situ Raman spectroscopy,corresponding to a boosted mass activity by 175-fold at 1.4 V vs.RHE than Ni-NP/NC.Furthermore,Ni-SAs requires only 450 mV overpotential to obtain HER current density of 500 mA cm^(-2).136 mA cm^(-2) is achieved in urea-assisted water splitting at1.7 V for Ni-SAs,boosted by 5.7 times than Pt/C-IrO_(2) driven water splitting.展开更多
The atomic-vapor cell is a vital component for Rydberg atomic microwave sensors,and impacts on overall capability of Rydberg sensors.However,the conventional analysis approach on effect of vapor-cell length contains t...The atomic-vapor cell is a vital component for Rydberg atomic microwave sensors,and impacts on overall capability of Rydberg sensors.However,the conventional analysis approach on effect of vapor-cell length contains two implicit assumptions,that is,the same atomic population density and buffer gas pressure,which make it unable to accurately capture actual response about effect of Rydberg-atom-based sensor performance on different Rydberg atom populations.Here,utilizing a stepped cesium atomic-vapor cell with five different dimensions at the same atomic population density and buffer gas pressure,the height and full width at half maximum of electromagnetically induced transparency(EIT)signal,and the sensitivity of the atomic superheterodyne sensor are comprehensively investigated under conditions of the same Rabi frequencies(saturated laser power).It is identified that EIT signal height is proportional to the cell length,full width at half maximum and sensitivity grow with the increment of cell length to a certain extent.Employing the coherent integration signal theory and atomic linear expansion coefficient method,theoretical analysis of the EIT height and sensitivity are further investigated.The results could shed new light on understanding and design of ultrahigh-sensitivity Rydberg atomic microwave sensors and find promising applications in quantum measurement,communication,and imaging.展开更多
We investigate the electromagnetic properties of a four-level dense atomic gas medium with Doppler effect.It is shown that the relative permittivity and relative permeability of the medium can be negative simultaneous...We investigate the electromagnetic properties of a four-level dense atomic gas medium with Doppler effect.It is shown that the relative permittivity and relative permeability of the medium can be negative simultaneously with low absorption in the same detuning interval on account of electromagnetically induced transparency.Furthermore,with the suitable parameters,the nonreciprocal negative refraction can be obtained due to the Doppler effect,and the nonreciprocity frequency band can be regulated by adjusting the temperature,the intensity of the control field and the atomic density in this hot atomic medium.展开更多
An experimental investigation of two-color polarization spectroscopy(TCPS) is presented based on the cesium 6 S1/2– 6P3/2– 8S1/2(852.3 nm + 794.6 nm) ladder-type system in a room-temperature vapor cell. The dependen...An experimental investigation of two-color polarization spectroscopy(TCPS) is presented based on the cesium 6 S1/2– 6P3/2– 8S1/2(852.3 nm + 794.6 nm) ladder-type system in a room-temperature vapor cell. The dependency of line shapes of TCPS on the power of a 852.3 nm pump and a 794.6 nm probe laser is measured in detail, and we confirm that the linewidth of TCPS in a counter-propagating configuration between the pump and probe laser beams is obviously narrower than that of a co-propagating configuration, due to the atomic coherence effect. It is helpful for laser stabilization of the excited state transition using TCPS without frequency modulation.展开更多
Applying the atomic sparse decomposition in the distribution network with harmonics and small current grounding to decompose the transient zero sequence current that appears after the single phase to ground fault occu...Applying the atomic sparse decomposition in the distribution network with harmonics and small current grounding to decompose the transient zero sequence current that appears after the single phase to ground fault occurred. Based on dictionary of Gabor atoms and matching pursuit algorithm, the method extracts the atomic components iteratively from the feature signals and translated them to damped sinusoidal components. Then we can obtain the parametrical and analytical representation of atomic components. The termination condition of decomposing iteration is determined by the threshold of the initial residual energy with the purpose of extract the features more effectively. Accordingly, the proposed method can extract the starting and ending moment of disturbances precisely as well as their magnitudes, frequencies and other features. The numerical examples demonstrate its effectiveness.展开更多
基金Project supported by the Key Program of the National Natural Science Foundation of China (Grant No.60837004)the Key Project of Jiangxi Electric Power Company (Grant Nos.200950801 and 200950802)
文摘This paper investigates the breaking point between fast-and slow-light in a degenerate two-level atomic system,where fast-light can be converted to slow-light arbitrarily on a single transition line by adjusting the strength of the pumping field.An equivalent incoherent pumping rate is introduced in this simplified theoretical model which exploits the dependence of this feature.The experimental observation is presented as evidence of the breaking point where the injected power is about 0.08 mW.
文摘In this paper, we have proposed the numerical calculations to study the quantum entanglement (QE) of moving two-level atom interacting with a coherent and the thermal field influenced by intrinsic decoherence (ID), Kerr medium (non-linear) and the Stark effect. The wave function of the complete system interacting with a coherent and the thermal field is calculated numerically affected by ID, Kerr (non-linear) and Stark effects. It has been seen that the Stark, Kerr, ID and the thermal environment have a significant effect during the time evolution of the quantum system. Quantum Fisher information (QFI) and QE decrease as the value of the ID parameter is increased in the thermal field without the atomic movement. It is seen that QFI and von Neumann entropy (VNE) show an opposite and periodic response in the presence of atomic motion. The non-linear Kerr medium has a more prominent and significant effect on the QE as the value of the Kerr parameter is decreased. At smaller values of the non-linear Kerr parameter, the VNE increases, however, QFI decreases, so QFI and VNE have a monotonic connection with one another. As the value of the Kerr parameter is increased, the effect of non-linear Kerr doesn’t stay critical on both QFI and QE. However, a periodic response of QE is seen because of the atomic movement which becomes modest under natural impacts. Moreover, it has been seen that QFI and QE rot soon at the smaller values of the Stark parameter. However, as the value of the Stark parameter is increased, the QFI and QE show periodic response even when the atomic movement is absent.
文摘Localization of the three-level Λ-type atomic system interacting with two orthogonal standing-wave fields is proposed. Two equal and tunable peaks in the 2D plane are obtained by the detunings corresponding to the two orthogonal standing-wave fields when the decreasing intensities of spontaneously generated coherence (SGC) arise in the three-level Λ-type atomic system, while one circular ring with shrinking radii in the 2D plane is obtained by the adjusted phases and wave vectors of the standing-wave fields when the increasing intensities of SGC occur in the three-level Λ-type atomic system. 2D atom localization with the single ring with shrinking radii realized by the multiple parametric manipulations demonstrated the flexibility for our scheme.
基金the National R&D Program of China(Grant No.2017YFA0304203)the National Natural Science Foundation of China(Grant Nos.61875112,61705122,62075121,and 91736209)+1 种基金the Program for Sanjin Scholars of Shanxi Province,the Key Research and Development Program of Shanxi Province for International Cooperation(Grant No.201803D421034)Shanxi Scholarship Council of China(Grant Nos.2020-073),and 1331KSC.
文摘Rydberg atoms have been widely investigated due to their large size,long radiative lifetime,huge polarizability and strong dipole-dipole interactions.The position information of Rydberg atoms provides more possibilities for quantum optics research,which can be obtained under the localization method.We study the behavior of three-dimensional(3D)Rydberg atom localization in a four-level configuration with the measurement of the spatial optical absorption.The atomic localization precision depends strongly on the detuning and Rabi frequency of the involved laser fields.A 100%probability of finding the Rydberg atom at a specific 3D position is achieved with precision of~0.031λ.This work demonstrates the possibility for achieving the 3D atom localization of the Rydberg atom in the experiment.
基金Project supported by the National Natural Science Foundation of China(Grant No.11374096).
文摘We study the dynamics of the entropic uncertainty for three types of three-level atomic systems coupled to an environment modeled by random matrices. The results show that the entropic uncertainty in the Ξ-type atomic system is lower than that in the V-type atomic system which is exactly the same as that in the Λ-type atomic system. In addition, the effect of relative coupling strength on entropic uncertainty is opposite in Markov region and non-Markov region, and the influence of a common environment and independent environments in Markov region and non-Markov region is also opposite. One can reduce the entropic uncertainty by decreasing relative coupling strength or placing the system in two separate environments in the Markov case. In the non-Markov case, the entropic uncertainty can be reduced by increasing the relative coupling strength or by placing the system in a common environment.
文摘We have investigated numerically the dynamics of quantum Fisher information (QFI) and quantum entanglement (QE) for N-level atomic system interacting with a coherent field in the presence of Kerr (linear and non-linear medium) and Stark effects. It is observed that the Stark and Kerr effects play a prominent role during the time evolution of the quantum system. The evolving quantum Fisher information (QFI) is noted as time grows under the non-linear Kerr medium contrary to the QE for higher dimensional systems. The effect of non-linear Kerr medium is greater on the QE as we increase the value of Kerr parameter. However, QFI and QE maintain their periodic nature under atomic motion. On the other hand, linear Kerr medium has no prominent effects on the dynamics of N-level atomic system. Furthermore, it has been observed that QFI and QE decay soon under the influence of Stark effect. In short, the N-level atomic system is found prone to the change of the Kerr medium and Stark effect for higher dimensional systems.
文摘A novel method to control the group velocity of light propagation in a two-level atomic system without additional optical field is proposed. Numerical result and experimental data shows that by changing the magnetic field intensity and vapor temperature, the group velocity of probe light can be controlled in an appropriate region.
文摘The mechanical angular momentum and magnetic moment of the electron and proton spin have been calculated semiclassically with the aid of the uncertainty principle for energy and time. The spin effects of both kinds of the elementary particles can be expressed in terms of similar formulae. The quantization of the spin motion has been done on the basis of the old quantum theory. It gives a quantum number n = 1/2 as the index of the spin state acceptable for both the electron and proton particle. In effect of the spin existence the electron motion in the hydrogen atom can be represented as a drift motion accomplished in a combined electric and magnetic field. More than 18,000 spin oscillations accompany one drift circulation performed along the lowest orbit of the Bohr atom. The semiclassical theory developed in the paper has been applied to calculate the doublet separation of the experimentally well-examined D line entering the spectrum of the sodium atom. This separation is found to be much similar to that obtained according to the relativistic old quantum theory.
基金This work was supported by National Key R&D Program of China(2021YFF1200200)Peiyang Talents Project of Tianjin University.
文摘Transition metal dichalcogenides(TMDs)are a promising class of layered materials in the post-graphene era,with extensive research attention due to their diverse alternative elements and fascinating semiconductor behavior.Binary MX2 layers with different metal and/or chalcogen elements have similar structural parameters but varied optoelectronic properties,providing opportunities for atomically substitutional engineering via partial alteration of metal or/and chalcogenide atoms to produce ternary or quaternary TMDs.The resulting multinary TMD layers still maintain structural integrity and homogeneity while achieving tunable(opto)electronic properties across a full range of composition with arbitrary ratios of introduced metal or chalcogen to original counterparts(0–100%).Atomic substitution in TMD layers offers new adjustable degrees of freedom for tailoring crystal phase,band alignment/structure,carrier density,and surface reactive activity,enabling novel and promising applications.This review comprehensively elaborates on atomically substitutional engineering in TMD layers,including theoretical foundations,synthetic strategies,tailored properties,and superior applications.The emerging type of ternary TMDs,Janus TMDs,is presented specifically to highlight their typical compounds,fabrication methods,and potential applications.Finally,opportunities and challenges for further development of multinary TMDs are envisioned to expedite the evolution of this pivotal field.
基金supported by the National Natural Science Foundation of China (Grant Nos. 52031016 and 11804027)the China Scholarship Council for financial support during part of this work
文摘The early stage evolution of local atomic structures in a multicomponent metallic glass during its crystallization process has been investigated via molecular dynamics simulation.It is found that the initial thermal stability and earliest stage evolution of the local atomic clusters show no strong correlation with their initial short-range orders,and this leads to an observation of a novel symmetry convergence phenomenon,which can be understood as an atomic structure manifestation of the ergodicity.Furthermore,in our system we have quantitatively proved that the crucial factor for the thermal stability against crystallization exhibited by the metallic glass is not the total amount of icosahedral clusters,but the degree of global connectivity among them.
基金the National Natural Science Foundation of China(22279044,12034002,and 22202080)the Project for Self-Innovation Capability Construction of Jilin Province Development and Reform Commission(2021C026)+1 种基金Jilin Province Science and Technology Development Program(20210301009GX)the Fundamental Research Funds for the Central Universities.
文摘Electrochemical carbon dioxide reduction reaction(CO_(2)RR)involves a variety of intermediates with highly correlated reaction and ad-desorption energies,hindering optimization of the catalytic activity.For example,increasing the binding of the*COOH to the active site will generally increase the*CO desorption energy.Breaking this relationship may be expected to dramatically improve the intrinsic activity of CO_(2)RR,but remains an unsolved challenge.Herein,we addressed this conundrum by constructing a unique atomic dispersed hetero-pair consisting of Mo-Fe di-atoms anchored on N-doped carbon carrier.This system shows an unprecedented CO_(2)RR intrinsic activity with TOF of 3336 h−1,high selectivity toward CO production,Faradaic efficiency of 95.96%at−0.60 V and excellent stability.Theoretical calculations show that the Mo-Fe diatomic sites increased the*COOH intermediate adsorption energy by bridging adsorption of*COOH intermediates.At the same time,d-d orbital coupling in the Mo-Fe di-atom results in electron delocalization and facilitates desorption of*CO intermediates.Thus,the undesirable correlation between these steps is broken.This work provides a promising approach,specifically the use of di-atoms,for breaking unfavorable relationships based on understanding of the catalytic mechanisms at the atomic scale.
文摘It is assumed that reconfigurable intelligent surface(RIS)is a key technology to enable the potential of mmWave communications.The passivity of the RIS makes channel estimation difficult because the channel can only be measured at the transceiver and not at the RIS.In this paper,we propose a novel separate channel estimator via exploiting the cascaded sparsity in the continuously valued angular domain of the cascaded channel for the RIS-enabled millimeter-wave/Tera-Hz systems,i.e.,the two-stage estimation method where the cascaded channel is separated into the base station(BS)-RIS and the RIS-user(UE)ones.Specifically,we first reveal the cascaded sparsity,i.e.,the sparsity exists in the hybrid angular domains of BS-RIS and the RIS-UEs separated channels,to construct the specific sparsity structure for RIS enabled multi-user systems.Then,we formulate the channel estimation problem using atomic norm minimization(ANM)to enhance the proposed sparsity structure in the continuous angular domains,where a low-complexity channel estimator via Alternating Direction Method of Multipliers(ADMM)is proposed.Simulation findings demonstrate that the proposed channel estimator outperforms the current state-of-the-arts in terms of performance.
基金This work was supported by National Key R&D Program of China(2021YFF0500503)National Natural Science Foundation of China(21925202,U22B2071)International Joint Mission on Climate Change and Carbon Neutrality.
文摘Lithium–oxygen battery with ultrahigh theoretical energy density is considered a highly competitive next-generation energy storage device,but its practical application is severely hindered by issues such as difficult decomposition of discharge products at present.Here,we have developed N-doped carbon anchored atomically dispersed Ru sites cathode catalyst with open hollow structure(h-RuNC)for Lithium–oxygen battery.On one hand,the abundance of atomically dispersed Ru sites can effectively catalyze the formation and decomposition of discharge products,thereby greatly enhancing the redox kinetics.On the other hand,the open hollow structure not only enhances the mass activity of atomically dispersed Ru sites but also improves the diffusion efficiency of catalytic molecules.Therefore,the excellent activity from atomically dispersed Ru sites and the enhanced diffusion from open hollow structure respectively improve the redox kinetics and cycling stability,ultimately achieving a high-performance lithium–oxygen battery.
基金financially supported by the National Key R&D Program of China(2022YFB4004100)the National Natural Science Foundation of China(22272161)+6 种基金the Jilin Province Science and Technology Development Program(20230101367JC)financially supported by the National Natural Science Foundation of China(22073094)the Science and Technology Development Program of Jilin Province(20210402059GH)the Science and Technology Plan Projects of Yunnan Province(202101BC070001–007)the Major Science and Technology Projects for Independent Innovation of China FAW Group Co.,Ltd(20220301018GX)the essential support of the Network and Computing Center,CIAC,CASthe Computing Center of Jilin Province。
文摘Developing cost-effective,robust and stable non-precious metal catalysts for oxygen reduction reaction(ORR) is of paramount importance for electrochemical energy conversion devices such as fuel cells and metal-air batteries.Although Fe-N-C single atom catalysts(SACs) have been hailed as the most promising candidate due to the optimal binding strength of ORR intermediates on the Fe-N_(4) sites,they suffer from serious mass transport limitations as microporous templates/substrates,i.e.,zeolitic imidazolate frameworks(ZIFs),are usually employed to host the active sites.Motivated by this challenge,we herein develop a hydrogen-bonded organic framework(HOF)-assisted pyrolysis strategy to construct hierarchical micro/mesoporous carbon nanoplates for the deposition of atomically dispersed Fe-N_(4) sites.Such a design is accomplished by employing HOF nanoplates assembled from 2-aminoterephthalic acid(NH_(2)-BDC) and p-phenylenediamine(PDA) as both soft templates and C,N precursors.Benefitting from the structural merits inherited from HOF templates,the optimized catalyst(denoted as Fe-N-C SAC-950) displays outstanding ORR activity with a high half-wave potential of 0.895 V(vs.reversible hydrogen electrode(RHE)) and a small overpotential of 356 mV at 10 mA cm^(-2) for the oxygen evolution reaction(OER).More excitingly,its application potential is further verified by delivering superb rechargeability and cycling stability with a nearly unfading charge-discharge gap of 0.72 V after 160 h.Molecular dynamics(MD) simulations reveal that micro/mesoporous structure is conducive to the rapid mass transfer of O_(2),thus enhancing the ORR performance.In situ Raman results further indicate that the conversion of O_(2) to~*O_(2)-the rate-determining step(RDS) for Fe-N-C SAC-950.This work will provide a versatile strategy to construct single atom catalysts with desirable catalytic properties.
基金supported by the National Natural Science Foundation of China(22234005,21974070)the Natural Science Foundation of Jiangsu Province(BK20222015)。
文摘Atomically dispersed catalysts exhibit significant influence on facilitating the sluggish oxygen reduction reaction(ORR)kinetics with high atom economy,owing to remarkable attributes including nearly 100%atomic utilization and exceptional catalytic functionality.Furthermore,accurately controlling atomic physical properties including spin,charge,orbital,and lattice degrees of atomically dispersed catalysts can realize the optimized chemical properties including maximum atom utilization efficiency,homogenous active centers,and satisfactory catalytic performance,but remains elusive.Here,through physical and chemical insight,we review and systematically summarize the strategies to optimize atomically dispersed ORR catalysts including adjusting the atomic coordination environment,adjacent electronic orbital and site density,and the choice of dual-atom sites.Then the emphasis is on the fundamental understanding of the correlation between the physical property and the catalytic behavior for atomically dispersed catalysts.Finally,an overview of the existing challenges and prospects to illustrate the current obstacles and potential opportunities for the advancement of atomically dispersed catalysts in the realm of electrocatalytic reactions is offered.
基金supported by the National Natural Science Foundation of China(No.22209126)。
文摘Urea oxidation reaction(UOR) has been selected as substitution for oxygen evolution reaction ascribing to its low thermodynamic voltage as well as utilization of nickel as electrocatalyst.Herein,we report the formation of nickel single atoms(Ni-SAs) as exceptional bifunctional electrocatalyst toward UOR and hydrogen evolution reaction(HER) in urea-assisted water splitting.In UOR catalysis,Ni-SAs perform a superior catalytic performance than Ni-NP/NC and Pt/C ascribing to the formation of HOO-Ni-N_(4) structure evidenced by in-situ Raman spectroscopy,corresponding to a boosted mass activity by 175-fold at 1.4 V vs.RHE than Ni-NP/NC.Furthermore,Ni-SAs requires only 450 mV overpotential to obtain HER current density of 500 mA cm^(-2).136 mA cm^(-2) is achieved in urea-assisted water splitting at1.7 V for Ni-SAs,boosted by 5.7 times than Pt/C-IrO_(2) driven water splitting.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 61901495 and 12104509)
文摘The atomic-vapor cell is a vital component for Rydberg atomic microwave sensors,and impacts on overall capability of Rydberg sensors.However,the conventional analysis approach on effect of vapor-cell length contains two implicit assumptions,that is,the same atomic population density and buffer gas pressure,which make it unable to accurately capture actual response about effect of Rydberg-atom-based sensor performance on different Rydberg atom populations.Here,utilizing a stepped cesium atomic-vapor cell with five different dimensions at the same atomic population density and buffer gas pressure,the height and full width at half maximum of electromagnetically induced transparency(EIT)signal,and the sensitivity of the atomic superheterodyne sensor are comprehensively investigated under conditions of the same Rabi frequencies(saturated laser power).It is identified that EIT signal height is proportional to the cell length,full width at half maximum and sensitivity grow with the increment of cell length to a certain extent.Employing the coherent integration signal theory and atomic linear expansion coefficient method,theoretical analysis of the EIT height and sensitivity are further investigated.The results could shed new light on understanding and design of ultrahigh-sensitivity Rydberg atomic microwave sensors and find promising applications in quantum measurement,communication,and imaging.
基金Project supported by the National Natural Science Foundation of China(Grant No.61671279)financial support from Xi’an Key Laboratory of Optical Information Manipulation and Augmentation(OMA)。
文摘We investigate the electromagnetic properties of a four-level dense atomic gas medium with Doppler effect.It is shown that the relative permittivity and relative permeability of the medium can be negative simultaneously with low absorption in the same detuning interval on account of electromagnetically induced transparency.Furthermore,with the suitable parameters,the nonreciprocal negative refraction can be obtained due to the Doppler effect,and the nonreciprocity frequency band can be regulated by adjusting the temperature,the intensity of the control field and the atomic density in this hot atomic medium.
基金financially supported by the National Natural Science Foundation of China(Nos.11774210,11104172,and 61575112)the National Key Research and Development Program of China(No.2017YFA0304502)
文摘An experimental investigation of two-color polarization spectroscopy(TCPS) is presented based on the cesium 6 S1/2– 6P3/2– 8S1/2(852.3 nm + 794.6 nm) ladder-type system in a room-temperature vapor cell. The dependency of line shapes of TCPS on the power of a 852.3 nm pump and a 794.6 nm probe laser is measured in detail, and we confirm that the linewidth of TCPS in a counter-propagating configuration between the pump and probe laser beams is obviously narrower than that of a co-propagating configuration, due to the atomic coherence effect. It is helpful for laser stabilization of the excited state transition using TCPS without frequency modulation.
文摘Applying the atomic sparse decomposition in the distribution network with harmonics and small current grounding to decompose the transient zero sequence current that appears after the single phase to ground fault occurred. Based on dictionary of Gabor atoms and matching pursuit algorithm, the method extracts the atomic components iteratively from the feature signals and translated them to damped sinusoidal components. Then we can obtain the parametrical and analytical representation of atomic components. The termination condition of decomposing iteration is determined by the threshold of the initial residual energy with the purpose of extract the features more effectively. Accordingly, the proposed method can extract the starting and ending moment of disturbances precisely as well as their magnitudes, frequencies and other features. The numerical examples demonstrate its effectiveness.