Applications of Atomic and Molecular Theory to Calculations in Space Science and Engineering

A systematic elaboration is given on atomic and molecular theory problems encountered in dealing with space science and engineering. Three sections are presented in the paper on calculations for gas thermodynamic and transfer properties, characteristics of the optical radiation from the reentry' bodies, and the interaction between surfaces of man-made satellites and incident particles. Researches on them are much related to the fundamental problems regarding the atomic and molecular theory.

Preparation of Arbitrary Four-Qubit W State with Atomic Ensembles via Rydberg Blockade

The generation of various entangled states is an essential task in quantum information processing. Recently, a scheme （PRA 79, 022304） has been suggested for generating Greenberger-Horne-Zeilinger state and cluster state with atomic ensembles based on the Rydberg blockade. Using similar resources as the earlier scheme, here we propose an experimentally feasible scheme of preparing arbitrary four-qubit W class of maximally and non- maximally entangled states with atomic ensembles in a single step. Moreover, we carefully analyze the realistic noises and predict that four-qubit W states can be produced with high fidelity （F - 0.994） via our scheme.

Corrections to atomic ground state energy due to interaction between atomic electric quadrupole and optical field

We study the ground state energy of an atom interacting with an oscillating optical field with electric dipole and quadrupole coupling.Under the rotating wave approximation,we derive the effective atomic Hamiltonians of the dipole/quadrupole coupling term within the perturbation theory up to the second order.Based on the effective Hamiltonians,we analyze the atomic ground-state energy corrections of these two processes in detail.As an application,we find that for alkali-like atoms,the energy correction from the quadrupole coupling is negligible small in comparison with that from the dipole coupling,which justifies the so-called dipole approximation used in literatures.Some special cases where the quadrupole interaction may have considerable energy corrections are also discussed.Our results would be beneficial for the study of atom–light interaction beyond dipole approximation.

Studies of Atomic Structure and Physical Properties of Metal Clusters in MgO by HREM and Nano-probe Methods

Nanometer-sized metal clusters were prepared inside single crystalline MgO films by vacuum co-deposition of metals and MgO. The atomic structure was studied by high-resolution electron microscopy (HREM) and nm-area electron diffraction. The size of the clusters is ranging from 1 nm to 3 nm without those larger than 5 nm, and most of them have definite epitaxial orientations with the MgO matrix films. The character of the composite films is very much useful for the studies of various kinds of physical properties with anisotroPy. The physical properties such as electric transport, magnetic, optical absorption, sintering and catalytic ones were thus measured on the same samples analyzed by HREM by using high sensitivity apparatus with interest of clarifying the retationship between the atomic structure and physical properties

Spatial Splitting and Intensity Suppression of Four-Wave Mixing in V-Type Three-Level Atomic System

We illustrate our experimental observation of coexisting the controllable spatial splitting and intensity suppression of four-wave mixing （FWM） beam in a V-type three-level atomic system. The peak number and separation distance of the FWM beam are controlled by the intensities and frequencies of the laser beams, as well as atomic density.

Collapse and Revival of an Atomic Beam Interacting with a Coherent State Light Field

We report on the phenomena of the periodic spontaneous collapse and revival in the dynamics of an atomic beam interacting with a single-mode and coherent-state light field. Conventional collapse and revival by Eberly et al. [Phys. Rev. Lett. 44（1980）1323 ] are presented in the case of the evolution with time of the population inversion. Here, we study the evolution with coupling strength of population inversion. We define the collapse and revival coupling strengths as characteristic parameters to describe the above collapse and revival. Furthermore, we present the analytic formulas for the population inversion, the collapse and revival coupling strengths.

Enhancement of Continuous Variable Entanglement in Four-Wave Mixing due to Atomic Memory Effects

We explore the effects of atomic memory on quantum correlations of two-mode light fields from four-wave mixing. A three-level atomic system in A configuration is considered, in which the atomic relaxation times are comparable to or longer than the cavity relaxation times and thus there exists the atomic memory. The quantum correlation spectrum in the output is calculated without the adiabatic elimination of atomic variables. It is shown that the continuous variable entanglement is enhanced over a wide range of the normalized detuning in the intermediate and bad cavity cases compared with the good cavity case. In some situations more significant enhancement occurs at sidebands.

Generation of a Super Strong Attosecond Pulse from an Atomic Superposition State Irradiated by a Shape-Optimized Short Pulse

Using a linearly polarized, phase-stabilized 3-fs driving pulse of 800 nm central wavelength shape-optimized on its＇ascending edge by its an amplitude-reduced pulse irradiating on a superposition state of the helium atom, we demonstrate theoretically the generation of a super strong isolated 176-attosecond pulse in the spectral region of 93-124 eV. The unusually high intensity of this attosecond pulse is marked by the Rabi-like oscillations emerging in the time-dependent populations of the ground state and the continuum during the occurrence of the electron recombination, which is for the first time observed in this work.

Ionization and Charge Transfer of Atomic Hydrogen by Highly Charged Ions

Cross sections for charge transfer and ionization of atomic hydrogen by highly charged ions A^q＋ （q =6 9） are evaluated using a simple and classical method based on the previous works by Bohr and Lindhard [K. Dan. Vidensk. Selsk. Mat. Fys. Medd 28 （1954） No 7], Brandt [Nucl. Instrum. Methods Phys. Res. 214 （1983） 93] and Ben-Itzhak et al. [J. Phys. B： At. Mol. Opt. Phys. 26 （1993） 1711]. It is proved that the present calculations are feasible to some extent in comparison with available experimental data and quantum calculations.

A Time-Dependent Wavepacket Method for Photodissociation Dynamics of Triatomic Molecule

We report a time-dependent quantum wavepacket theory employed to interpret the photoabsorption spectrum of the N20 molecule in terms of the nuclear motion on the upper 21A＇ and 11A＂ potential energy surfaces. The N2-O bond breaks upon excitation leading to dissociation. The total angular momentum is treated correctly taking into account the vector property of the electric field of the exciting radiation.

A Simple Remark Leading to a Basic Precision Estimate for Non-Relativistic (NR) Real Values of Quantum Mechanics Operators

Starting with a very basic statement that any physical constants cannot be written with an infinite precision, it is shown how to introduce this uncertainty into the Hamiltonian of non-relativistic atomic (NR) physics and how to estimate errors on quantum operators (energy, frequency, momenta) when an uncertainty is assigned to . The Schrödinger equation is written and the kinetic energy term is transformed into a Laplacian: . This transformation leads (as known since 1926) to the wave equation, whose solutions are wave functions. The relativity correction to the kinetic energy term is introduced and its effect is discussed. (h constant has an uncertainty value taken from CODATA.)

A Cosmological Model for the Early Universe: The Formation of Fundamental Particles

A cosmological model for the very early universe is proposed which may modify the present point of view of physicists and astrophysicists, concerning the very early universe at a miniscule fraction of a second, approximately 10-60 seconds after the Big Bang. The model proposes the presence of a primordial s-particle that, following the Big Bang, was violently ejected in all spatial directions together with extremely high-frequency radiation that dominates this era. The proposed s-particles underwent two geometrical phase transitions in space-time that led to the formation of the known fundamental particles (i.e., dark matter, quarks, electrons, neutrinos, etc.). Furthermore, in the model, the four fundamental forces may be accommodated within one structural framework. It shows that the electronic charge is not a fundamental quantity (intrinsic property of the particle), but rather that it can be derived from the tangential velocity of the s-particle. Moreover, it appears that the masses of the fundamental particles are proportional to the curvature of the path of the s-particle.

Dressed Four-Wave Mixing Spectroscopy Modified by Polarization Interference and Atom-Wall Collision in Micrometric Thin Cells

Dressed four-wave mixing （DFWM） spectroscopy is investigated theoretically in some micrometric thin cells. It is found that DFWM spectra can be modified by polarization interference of atoms and transient effects induced by atom-wall collision. This modification can lead to width-narrowing of DFWM lines and facilitates to implement experiment of high resolution DFWM spectroscopy in a confined atomic system.

Progress of the 87Rb Fountain Clock

A fountain atomic clock based on cold 87Rb atoms has been in operation in our laboratory for several months. We therefore report the design of the rubidium fountain clock including its physical package, optical system and daily operation. Ramsey fringes have been attained with the signal to noise ratio of about 100.

Theoretical Investigation of Femtosecond-Resolved Photoelectron Spectra of the Li2 Molecule

The time-dependent quantum wave packet method is used to investigate the dynamics for the Li2 molecule, and the time-resolved photoelectron spectra （TRPES） of the Li2 molecule are calculated. At the short delay time, the particular phenomenon of TRPES with four peaks is qualitatively interpreted in a dressed state picture by analyzing wave packet motion on light-induced potential （LIP）. The significant difference in the electronic structure of E1∑g^＋ between the inner and outer turning points has an impact on the TRPES. The control for the first excited state A1∑u^＋ of the initial wave packet is discussed.

Analysis of Nanometer Structure for Chromium Atoms in Gauss Standing Laser Wave

The equation of motion of two-level chromium atoms in Gauss standing laser wave is discussed and the distribution of chromium atoms is given under different transverse velocity conditions. The results show that the focusing position of atoms will be affected by the transverse velocity of atoms. Based on the four-order Runge- Kutta method, the locus of chromium atoms in Gauss standing laser wave is simulated. The three-dimensional characteristics of nanometer structures are stimulated under perfect and emanative conditions.

Coherent Population Trapping-Ramsey Interference in Cold Atoms

We demonstrate an experimental observation of coherent population trapping-Ramsey interference in cold 87Rb atoms by employing the time-domain separated oscillatory fields＇ method. The interference fringe with line width of 80 Hz is obtained. We propose a novel method to measure the cold atom number. The measurement is insensitive to the pump beam intensity, the single photon detuning and even the initial state population. We use this method to normalize the interference signal and to improve the signal-to-noise ratio significantly.

Destructive and Constructive Interference of High-Order Harmonic Generation in Mixture of He and Ne Gases

Using the single-atom induced dipole moment under strong field approximation as a source, we suggest a model to simulate the macroscopic high-order harmonic generation （HHG） from the mixed gases （He and Ne） interacting with intense infrared laser by solving the three-dimensional Maxwell＇s equation of the harmonic field. Regular destructive interference （DI） and constructive interference （CI） are observed in the macroscopic HHG spectra when the gas jet is put at a good phase-matching position. A semiclassical model of short and long electron trajectories is applied to interpret the DI and CI of HHG qualitatively.

Scheme for Generating a χ-Type Four-Atom Entangled State in Cavity QED

We propose a scheme for generating a χ-type four-atom entangled state in cavity QED. In the present scheme, the atoms interact simultaneously with a highly detuned cavity mode with the assistance of a strong classical field. The scheme is insensitive to the cavity decay and the thermal field, which is of importance from the experimental point of view.

Using Gamma-Radiation for Drug Releasing from MWNT Vehicle

A drug delivery system via multi-walled carbon nanotube （MWNT） vehicle was synthesized in aqueous solution. MWNTs were first noncovalently functionalized with chitosan oligomers （CS） with a molecule weight of 4000-6000, making MWNTs water-soluble, and then a cancer ancillary drug tea polyphenols （TP） was conjugated mainly via the hydrogen bond between CS and TP molecules, making MWNTs efficient vehicle for drug delivering. The release of drug molecules can be realized by pH variation and γ-radiation, leading to new methods for controlling drug release from carbon nanotubes carrier. Due to the high penetrability of γ-rays, γ-radiation shows up new opportunities in controlled drug release, possibly facilitating the future cancer treatment in vivo.