A super heavy element Uub (z = 112) has been studied theoretically in conjunction with rela-tivistic effects and the effects of electron correlations.The atomic structure and the oscillator strengths of low-lying leve...A super heavy element Uub (z = 112) has been studied theoretically in conjunction with rela-tivistic effects and the effects of electron correlations.The atomic structure and the oscillator strengths of low-lying levels have been calculated,and the ground states have also been determined for the singly and doubly charged ions. The influence of relativity and correlation effects to the atomic properties of such a super heavy element has been investigated in detail. The results have been compared with the properties of an element Hg. Two energy levels at wave numbers 64470 and 94392 are suggested to be of good candidates for experimental observations.展开更多
We have deduced analytical solutions of an energy level diagram of the doubly driven/dressed atom for a two-level atom exposed to a strong near-resonant bichromatic laser field in a special case, i.e., the bichromatic...We have deduced analytical solutions of an energy level diagram of the doubly driven/dressed atom for a two-level atom exposed to a strong near-resonant bichromatic laser field in a special case, i.e., the bichromatic field with frequencies ω1 and ω2, and Rabi frequencies ？1 and ？2, in which the first coupling field of ？1 acts on the bare atomic levels, and then the resulting singly dressed states are driven by the second coupling field of ？2, thus resulting in the doubly dressed atom.We have measured the probe absorption spectra of a doubly driven two-level atom. The system consists of 52S1/2, F= 2 and 5~2P_（3/2）, F＇= 3 states of ^（87）Rb atoms in a magneto-optical trap（MOT） as well as the cooling/trapping beams and an additional coupling field. As for the spectroscopic properties of the doubly driven two-level atom, theoretical analytical solutions are in general agreement with the experimental spectrum as a whole.展开更多
Using the multi-configuration Dirac-Fock self-consistent field method and the relativistic configuration interaction method with quantum-electrodynamics corrections performed by the GRASP code, we calculate the fine-s...Using the multi-configuration Dirac-Fock self-consistent field method and the relativistic configuration interaction method with quantum-electrodynamics corrections performed by the GRASP code, we calculate the fine-structure energy levels of the ground-state configuration （1s^22s^22p^3） of the nitrogen isoelectronic sequence, according to the L-S coupling scheme with atomic number Z up to 22. Based on the calculated results, we elucidate the mechanism of the orderings of fine-structure energy levels of 2^ D3/2,5/2 and 2^P1/2,3/2 respectively, i.e. for 2^D3/2,5/2 orderings, the competition between the spin-orbit interactions and the Breit interactions; for 2^P1/2,3/2 orderings, the electron correlations, especially the electron correlations owing to the 2p^5 configuration interactions.展开更多
Non-monotonic, asymmetrical electric field dependence of photoluminescence （PL） intensity is observed in a mono- layer sample of tris-（8-hydroxyquinoline） aluminum （A1Q） doped N,N＇-bis（3-methylphenyl）-N,N＇-...Non-monotonic, asymmetrical electric field dependence of photoluminescence （PL） intensity is observed in a mono- layer sample of tris-（8-hydroxyquinoline） aluminum （A1Q） doped N,N＇-bis（3-methylphenyl）-N,N＇-bis（phenyl）-benzidine （TPD）. A possible model is proposed： the charge separation from the dissociated photoexcited excitons causes energy band bending in the organic films and improves the hole injection from the electrode, which brings about the extra fluorescence. This mechanism is further verified by a series of experiments using a series of samples, variously featuring symmetrical electrodes, block layers, and hosts with lower hole mobilities.展开更多
CsMnCl32H2O是典型的准一维反铁磁体.最近V V Eremenko测定了CsMnCl3·2H2O·Cu2+的吸收光谱,利用晶 体场理论,结合晶体结构,分别计算晶体中Mn2+在Oh下和Cu2+在D2h下的能级,研究结果表明:CsMnCl3·2H2O:Cu2+在 28000,3000,3...CsMnCl32H2O是典型的准一维反铁磁体.最近V V Eremenko测定了CsMnCl3·2H2O·Cu2+的吸收光谱,利用晶 体场理论,结合晶体结构,分别计算晶体中Mn2+在Oh下和Cu2+在D2h下的能级,研究结果表明:CsMnCl3·2H2O:Cu2+在 28000,3000,32000吸收峰是来自Cu2+的d-d跃迁.展开更多
基金Supported by the National Natural Science Foundation of China (Grant Nos. 10376026 and 10434100)the Foundation of Theoretical Nuclear Physics of National Laboratory of Heavy Ion Accelerator of Lanzhouthe China/Ireland Science and Technology Collaboration Research Fund (No. CI-2004-07)
文摘A super heavy element Uub (z = 112) has been studied theoretically in conjunction with rela-tivistic effects and the effects of electron correlations.The atomic structure and the oscillator strengths of low-lying levels have been calculated,and the ground states have also been determined for the singly and doubly charged ions. The influence of relativity and correlation effects to the atomic properties of such a super heavy element has been investigated in detail. The results have been compared with the properties of an element Hg. Two energy levels at wave numbers 64470 and 94392 are suggested to be of good candidates for experimental observations.
基金Project supported by Beijing Natural Science Foundation,China(Grant No.1164016)the National Natural Science Foundation of China(Grant Nos.11604334,61227807,and 61575108)the Tsinghua Initiative Scientific Research Program,China(Grant No.2013THZ02-3)
文摘We have deduced analytical solutions of an energy level diagram of the doubly driven/dressed atom for a two-level atom exposed to a strong near-resonant bichromatic laser field in a special case, i.e., the bichromatic field with frequencies ω1 and ω2, and Rabi frequencies ？1 and ？2, in which the first coupling field of ？1 acts on the bare atomic levels, and then the resulting singly dressed states are driven by the second coupling field of ？2, thus resulting in the doubly dressed atom.We have measured the probe absorption spectra of a doubly driven two-level atom. The system consists of 52S1/2, F= 2 and 5~2P_（3/2）, F＇= 3 states of ^（87）Rb atoms in a magneto-optical trap（MOT） as well as the cooling/trapping beams and an additional coupling field. As for the spectroscopic properties of the doubly driven two-level atom, theoretical analytical solutions are in general agreement with the experimental spectrum as a whole.
基金Supported by the Key Project of the Ministry of Education of China under Grant No 306020, the National Natural Science Foundation of China, the National High-Tech ICF Committee in China and the Yin-He Super-computer Center, Institute of Applied Physics and Mathematics, Beijing, China, and the National Basic Research Programme of China under Grant No 2006CB921408.
文摘Using the multi-configuration Dirac-Fock self-consistent field method and the relativistic configuration interaction method with quantum-electrodynamics corrections performed by the GRASP code, we calculate the fine-structure energy levels of the ground-state configuration （1s^22s^22p^3） of the nitrogen isoelectronic sequence, according to the L-S coupling scheme with atomic number Z up to 22. Based on the calculated results, we elucidate the mechanism of the orderings of fine-structure energy levels of 2^ D3/2,5/2 and 2^P1/2,3/2 respectively, i.e. for 2^D3/2,5/2 orderings, the competition between the spin-orbit interactions and the Breit interactions; for 2^P1/2,3/2 orderings, the electron correlations, especially the electron correlations owing to the 2p^5 configuration interactions.
基金Project supported by the National Natural Science Foundation of China(Grant No.11134002)the National Science and Technology Major Project of the Ministry of Science and Technology of China(Grant No.2012CB921401)
文摘Non-monotonic, asymmetrical electric field dependence of photoluminescence （PL） intensity is observed in a mono- layer sample of tris-（8-hydroxyquinoline） aluminum （A1Q） doped N,N＇-bis（3-methylphenyl）-N,N＇-bis（phenyl）-benzidine （TPD）. A possible model is proposed： the charge separation from the dissociated photoexcited excitons causes energy band bending in the organic films and improves the hole injection from the electrode, which brings about the extra fluorescence. This mechanism is further verified by a series of experiments using a series of samples, variously featuring symmetrical electrodes, block layers, and hosts with lower hole mobilities.
文摘CsMnCl32H2O是典型的准一维反铁磁体.最近V V Eremenko测定了CsMnCl3·2H2O·Cu2+的吸收光谱,利用晶 体场理论,结合晶体结构,分别计算晶体中Mn2+在Oh下和Cu2+在D2h下的能级,研究结果表明:CsMnCl3·2H2O:Cu2+在 28000,3000,32000吸收峰是来自Cu2+的d-d跃迁.
