Inter-layer interference for multi-layered tight gas reservoir in the absence and presence of movable water

Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer interference for tight gas reservoirs are really limited,especially for those reservoirs in the presence of water.In this work,five types of possible inter-layer interferences,including both absence and presence of water,are identified for commingled production of tight gas reservoirs.Subsequently,a series of reservoir-scale and pore-scale numerical simulations are conducted to quantify the degree of influence of each type of interference.Consistent field evidence from the Yan'an tight gas reservoir(Ordos Basin,China)is found to support the simulation results.Additionally,suggestions are proposed to mitigate the potential inter-layer interferences.The results indicate that,in the absence of water,commingled production is favorable in two situations:when there is a difference in physical properties and when there is a difference in the pressure system of each layer.For reservoirs with a multi-pressure system,the backflow phenomenon,which significantly influences the production performance,only occurs under extreme conditions(such as very low production rates or well shut-in periods).When water is introduced into the multi-layer system,inter-layer interference becomes nearly inevitable.Perforating both the gas-rich layer and water-rich layer for commingled production is not desirable,as it can trigger water invasion from the water-rich layer into the gas-rich layer.The gas-rich layer might also be interfered with by water from the neighboring unperforated water-rich layer,where the water might break the barrier(eg weak joint surface,cement in fractures)between the two layers and migrate into the gas-rich layer.Additionally,the gas-rich layer could possibly be interfered with by water that accumulates at the bottom of the wellbore due to gravitational differentiation during shut-in operations.

Preparation of single atom catalysts for high sensitive gas sensing

Single atom catalysts(SACs)have garnered significant attention in the field of catalysis over the past decade due to their exceptional atom utilization efficiency and distinct physical and chemical properties.For the semiconductor-based electrical gas sensor,the core is the catalysis process of target gas molecules on the sensitive materials.In this context,the SACs offer great potential for highly sensitive and selective gas sensing,however,only some of the bubbles come to the surface.To facilitate practical applications,we present a comprehensive review of the preparation strategies for SACs,with a focus on overcoming the challenges of aggregation and low loading.Extensive research efforts have been devoted to investigating the gas sensing mechanism,exploring sensitive materials,optimizing device structures,and refining signal post-processing techniques.Finally,the challenges and future perspectives on the SACs based gas sensing are presented.

Highly Sensitive Ammonia Gas Sensors at Room Temperature Based on the Catalytic Mechanism of N,C Coordinated Ni Single-Atom Active Center

Significant challenges are posed by the limitations of gas sensing mechanisms for trace-level detection of ammonia(NH3).In this study,we propose to exploit single-atom catalytic activation and targeted adsorption properties to achieve highly sensitive and selective NH3 gas detection.Specifically,Ni singleatom active sites based on N,C coordination(Ni-N-C)were interfacially confined on the surface of two-dimensional(2D)MXene nanosheets(Ni-N-C/Ti_(3)C_(2)Tx),and a fully flexible gas sensor(MNPE-Ni-N-C/Ti_(3)C_(2)Tx)was integrated.The sensor demonstrates a remarkable response value to 5 ppm NH3(27.3%),excellent selectivity for NH3,and a low theoretical detection limit of 12.1 ppb.Simulation analysis by density functional calculation reveals that the Ni single-atom center with N,C coordination exhibits specific targeted adsorption properties for NH3.Additionally,its catalytic activation effect effectively reduces the Gibbs free energy of the sensing elemental reaction,while its electronic structure promotes the spill-over effect of reactive oxygen species at the gas-solid interface.The sensor has a dual-channel sensing mechanism of both chemical and electronic sensitization,which facilitates efficient electron transfer to the 2D MXene conductive network,resulting in the formation of the NH3 gas molecule sensing signal.Furthermore,the passivation of MXene edge defects by a conjugated hydrogen bond network enhances the long-term stability of MXene-based electrodes under high humidity conditions.This work achieves highly sensitive room-temperature NH3 gas detection based on the catalytic mechanism of Ni single-atom active center with N,C coordination,which provides a novel gas sensing mechanism for room-temperature trace gas detection research.

Optimal preparation of Bose and Fermi atomic gas mixtures of ^(87)Rb and ^(40)K in a crossed optical dipole trap

We report on the optimal production of the Bose and Fermi mixtures with ^(87) Rb and ^(40)K in a crossed optical dipole trap(ODT).We measure the atomic number and lifetime of the mixtures in combination of the spin state |F=9/2,m_(F)=9/2> of^(40)K and |1,1>of ^(87) Rb in the ODT,which is larger and longer compared with the combination of the spin state |9/2,9/2> of^(40)K and 12,2) of ^(87)Rb in the ODT.We observe the atomic numbers of ^(87)Rb and ^(40)K shown in each stage of the sympathetic cooling process while gradually reducing the depth of the optical trap.By optimizing the relative loading time of atomic mixtures in the MOT,we obtain the large atomic number of ^(40)K(~6 ×10^(6)) or the mixtures of atoms with an equal number(~1.6 × 10^(6)) at the end of evaporative cooling in the ODT.We experimentally investigate the evaporative cooling in an enlarged volume of the ODT via adding a third laser beam to the crossed ODT and found that more atoms(8 × 10^(6)) and higher degeneracy(T/T_(F)=0.25) of Fermi gases are obtained.The ultracold atomic gas mixtures pave the way to explore phenomena such as few-body collisions and the Bose-Fermi Hubbard model,as well as for creating ground-state molecules of ^(87)Rb^(40)K.

Atomically dispersed Ni electrocatalyst for superior urea-assisted water splitting

Urea oxidation reaction(UOR) has been selected as substitution for oxygen evolution reaction ascribing to its low thermodynamic voltage as well as utilization of nickel as electrocatalyst.Herein,we report the formation of nickel single atoms(Ni-SAs) as exceptional bifunctional electrocatalyst toward UOR and hydrogen evolution reaction(HER) in urea-assisted water splitting.In UOR catalysis,Ni-SAs perform a superior catalytic performance than Ni-NP/NC and Pt/C ascribing to the formation of HOO-Ni-N_(4) structure evidenced by in-situ Raman spectroscopy,corresponding to a boosted mass activity by 175-fold at 1.4 V vs.RHE than Ni-NP/NC.Furthermore,Ni-SAs requires only 450 mV overpotential to obtain HER current density of 500 mA cm^(-2).136 mA cm^(-2) is achieved in urea-assisted water splitting at1.7 V for Ni-SAs,boosted by 5.7 times than Pt/C-IrO_(2) driven water splitting.

Gas-Water Production of a Continental Tight-Sandstone Gas Reservoir under Different Fracturing Conditions

A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the interlayer stress difference,the fracturing discharge rate and the fracturing fluid viscosity.The results show that these factors affect the gas and water production by influencing the fracture size.The interlayer stress difference can effectively control the fracture height.The greater the stress difference,the smaller the dimensionless reconstruction volume of the reservoir,while the flowback rate and gas production are lower.A large displacement fracturing construction increases the fracture-forming efficiency and expands the fracture size.The larger the displacement of fracturing construction,the larger the dimensionless reconstruction volume of the reservoir,and the higher the fracture-forming efficiency of fracturing fluid,the flowback rate,and the gas production.Low viscosity fracturing fluid is suitable for long fractures,while high viscosity fracturing fluid is suitable for wide fractures.With an increase in the fracturing fluid viscosity,the dimensionless reconstruction volume and flowback rate of the reservoir display a non-monotonic behavior,however,their changes are relatively small.

Rate transient analysis methods for water-producing gas wells in tight reservoirs with mobile water

Tight gas reservoirs with mobile water exhibit multi-phase flow and high stress sensitivity.Accurately analyzing the reservoir and well parameters using conventional single-phase rate transient analysis methods proves challenging.This study introduces novel rate transient analysis methods incorporating evaluation processes based on the conventional flowing material balance method and the Blasingame type-curve method to examine fractured gas wells producing water.By positing a gas-water two-phase equivalent homogenous phase that considers characteristics of mobile water,gas,and high stress sensitivity,the conventional single-phase rate transient analysis methods can be applied by integrating the phase's characteristics and defining the phase's normalized parameters and material balance pseudotime.The rate transient analysis methods based on the equivalent homogenous phase can be used to quantitatively assess the parameters of wells and gas reservoirs,such as original gas-in-place,fracture half-length,reservoir permeability,and well drainage radius.This facilitates the analysis of production dynamics of fractured wells and well-controlled areas,subsequently aiding in locating residual gas and guiding the configuration of well patterns.The specific evaluation processes are detailed.Additionally,a numerical simulation mechanism model was constructed to verify the reliability of the developed methods.The methods introduced have been successfully implemented in field water-producing gas wells within tight gas reservoirs containing mobile water.

Application of pre-alloyed powders for diamond tools by ultrahigh pressure water atomization

Copper, iron and cobalt based pre-alloyed powders for diamond tools were prepared by ultrahigh pressure water atomization（UPWA） process. Pre-alloyed powders prepared by different processes including UPWA, conventional water atomization （CWA） and elemental metal mechanical mixing （EMMM） were sintered to segments and then compared in mechanical properties, holding force between matrix and diamond, fracture morphology of blank and sintering diamond section containing matrix. The results showed that the pre-alloyed powder prepared by UPWA exhibits the best mechanical properties including the relative density, the hardness and the bending strength of matrix sinteredsegment. Sintered segments fractography of UPWA pre-alloyed powder indicatesmechanical mosaic strength and chemical bonding force between the pre-alloyed powder and the diamond, leading to the great increase in the holding force between matrix and diamond. The mechanical performance andthe service life of diamond tools were greatly improved by UPWA pre-alloyed powders.

Criterion of gas and solid dual-phase flow atomization crash in molten metal

A self-invented atomization process, in which molten metal is atomized into powder by a high-velocity gas stream carrying solid particles as the atomization medium, was introduced. The characteristics of powders prepared by common gas atomization and dual-phase flow atomization under similar conditions were compared. The experimental results show that the dual-phase flow-atomized powders have average particle sizes that are one-half that of the common gas-atomized particles;additionally, they possess a finer microstructure and higher cooling rate under the same atomization gas pressure and the same gas flow. The Weber number in the crash criteria of liquid atomization is adopted to measure the crash ability of the atomization media. The Weber number of the dual-phase flow atomization medium is the sum of that of the gas and the solid particles. Furthermore, the critical equation of the crash model in dual-phase flow atomization is established, and the main regularities associated with this process were analyzed.

For more and purer hydrogen-the progress and challenges in water gas shift reaction

The water gas shift(WGS) reaction is a standard reaction that is widely used in industrial hydrogen production and removal of carbon monoxide. The improved catalytic performance of WGS reaction also contributes to ammonia synthesis and other reactions. Advanced catalysts have been developed for both high and low-temperature reactions and are widely used in industry. In recent years, supported metal nanoparticle catalysts have been researched due to their high metal utilization. Low-temperature catalysts have shown promising results, including high selectivity, high shift rates, and higher activity potential. Additionally, significant progress has been made in removing trace CO through the redox reaction in electrolytic cell. This paper reviews the development of WGS reaction catalysts, including the reaction mechanism, catalyst design, and innovative research methods. The catalyst plays a crucial role in the WGS reaction, and this paper provides an instant of catalyst design under different conditions. The progress of catalysts is closely related to the development of advanced characterization techniques.Furthermore, modifying the catalyst surface to enhance activity and significantly increase reaction kinetics is a current research direction. This review goals to stimulate a better understanding of catalyst design, performance optimization, and driving mechanisms, leading to further progress in this field.

Atomic layer deposition to heterostructures for application in gas sensors

Atomic layer deposition(ALD) is a versatile technique to deposit metals and metal oxide sensing materials at the atomic scale to achieve improved sensor functions. This article reviews metals and metal oxide semiconductor(MOS) heterostructures for gas sensing applications in which at least one of the preparation steps is carried out by ALD. In particular, three types of MOS-based heterostructures synthesized by ALD are discussed, including ALD of metal catalysts on MOS, ALD of metal oxides on MOS and MOS core–shell(C–S) heterostructures.The gas sensing performances of these heterostructures are carefully analyzed and discussed.Finally, the further developments required and the challenges faced by ALD for the synthesis of MOS gas sensing materials are discussed.

Shale gas transport in nanopores with mobile water films and water bridge

Gas flow properties in nanopores are significantly determined by the flow patterns. Slug flow pattern is a potential water–gas two phase flow pattern, in which gas molecules flow in form of gas slugs and water molecules separate gas slugs. Considering water slippage, a portion of water molecules accumulates at the wall with lower mobility, while the remaining water molecules take the shape of a water bridge. Adopting foam apparent viscosity model to represent slug rheological behavior, how water bridge disturbs on gas flow capacity is estimated. The results are compared with the water–gas two phase flow model that assumes annular flow pattern as well as the single gas flow model without the consideration of water. The comparison illustrates that gas molecular movement is significantly hindered by flow space reduction and loss of gas slippage. The impact from water phase of slug flow pattern is more significant than that of annular flow pattern on gas flow capacity. It is discovered that larger nanopores improve gas flow capacity while maintaining bulk water layer thickness and increasing water bridge thickness tend to reduce gas transport ability. A better understanding of the structure and transport of water and gas molecules is conducive to figure out the specific gas–water flow behavior and predict shale gas production.

Permeability evolution and gas flow in wet coal under non-equilibrium state:Considering both water swelling and process-based gas swelling

Accurate knowledge of gas flow within the reservoir and related controlling factors will be important for enhancing the production of coal bed methane.At present,most studies focused on the permeability evolution of dry coal under gas adsorption equilibrium,gas flow and gas diffusion within wet coal under the generally non-equilibrium state are often ignored in the process of gas recovery.In this study,an improved apparent permeability model is proposed which accommodates the water and gas adsorption,stress dependence,water film thickness and gas flow regimes.In the process of modeling,the water adsorption is only affected by water content while the gas adsorption is time and water content dependent;based on poroelastic mechanics,the effective fracture aperture and effective pore radius are derived;and then the variation in water film thickness for different pore types under the effect of water content,stress and adsorption swelling are modeled;the flow regimes are considered based on Beskok’s model.Further,after validation with experimental data,the proposed model was applied to numerical simulations to investigate the evolution of permeability-related factors under the effect of different water contents.The gas flow in wet coal under the non-equilibrium state is explicitly revealed.

Self-sealing of fractures in indurated claystones measured by water and gas flow

Self-sealing of fractures in the indurated Callovo-Oxfordian(COX)and Opalinus(OPA)claystones,which are considered as host rocks for disposal of radioactive waste,was investigated on artificially fractured samples.The samples were extracted from four lithological facies relatively rich in clay mineral,carbonate and quartz,respectively.The self-sealing of fractures was measured by fracture closure,water permeability variation,gas penetration,and recovery of gas-induced pathways.Most of the fractured samples exhibited a dramatic reduction inwater permeability to low levels that is close to that of intact rock,depending on their mineralogical composition,fracture intensity,confining stress,and load duration.The self-sealing capacity of the clay-rich samples is higher than that of the carbonate-rich and sandy ones.Significant effects of sample size and fracture intensity were identified.The sealed fractures become gas-tight for certain in-jection pressures.However,the measured gas breakthrough pressures are still lower than the confining stresses.The gas-induced pathways can recover when contacting water.These important findings imply that fractures in such indurated claystones can effectively recover to hinder water transport but allow gas release under relatively low pressures without compromising the rock integrity.

Characterization of spherical AlSi10Mg powder produced by double-nozzle gas atomization using different parameters

A self-developed double-nozzle gas atomization technique was used to produce AlSi10Mg powder.Effects of delivery tube diameter,gas pressure,and melt superheat on powder characteristics were investigated.The concepts of bluntness and outgrowth were introduced to analyze powder sphericity and satellite index quantitatively.The results showed that the median diameters of all atomized powders ranged from 25 to 33μm.The highest yield rate(72.13%)of fine powder(<50μm)was obtained at a superheat of 350 K.The powder size decreased with increasing melt superheat but increased with increasing delivery tube diameter.Powders with bluntness values between 96%and 98%accounted for over 60%.The outgrowth values demonstrated that 70%-85%of all powders did not contain satellite particles,with few powders adhered two or three particles.Not only Al and Si phases were present but also a metastable Al9Si phase was detected.

Design and evaluation of a Laval-type supersonic atomizer for low-pressure gas atomization of molten metals

A Laval-type supersonic gas atomizer was designed for low-pressure gas atomization of molten metals. The principal design ob-jectives were to produce small-particle uniform powders at lower operating pressures by improving the gas inlet and outlet structures and op-timizing structural parameters. A computational fluid flow model was developed to study the flow field characteristics of the designed atom-izer. Simulation results show that the maximum gas velocity in the atomization zone can reach 440 m＆#183;s-1;this value is independent of the atomization gas pressure P0 when P0〉0.7 MPa. When P0=1.1 MPa, the aspiration pressure at the tip of the delivery tube reaches a mini-mum, indicating that the atomizer can attain the best atomization efficiency at a relatively low atomization pressure. In addition, atomization experiments with pure tin at P0=1.0 MPa and with 7055Al alloy at P0=0.8 and 0.4 MPa were conducted to evaluate the atomization capa-bility of the designed atomizer. Nearly spherical powders were obtained with the mass median diameters of 28.6, 43.4, and 63.5μm, respec-tively. Compared with commonly used atomizers, the designed Laval-type atomizer has a better low-pressure gas atomization capability.

Numerical investigation on flow process of liquid metals in melt delivery nozzle during gas atomization process for fine metal powder production

Based on volume of fluid(VoF)interface capturing method and shear-stress transport(SST)k-ω turbulence model,numerical simulation was performed to reveal the flow mechanism of metal melts in melt delivery nozzle(MDN)during gas atomization(GA)process.The experimental validation indicated that the numerical models could give a reasonable prediction on the melt flow process in the MDN.With the decrease of the MDN inner-diameter,the melt flow resistance increased for both molten aluminum and iron,especially achieving an order of 10^(2) kPa in the case of the MDN inner-diameter≤1 mm.Based on the conventional GA process,the positive pressure was imposed on the viscous aluminum alloy melt to overcome its flow resistance in the MDN,thus producing powders under different MDN inner-diameters.When the MDN inner-diameter was reduced from 4 to 2 mm,the yield of fine powder(<150μm)soared from 54.7%to 94.2%.The surface quality of powders has also been improved when using a smaller inner-diameter MDN.

Effect of Mg/Al atom ratio of support on catalytic performance of Co-Mo/MgO-Al_2O_3 catalyst for water gas shift reaction

Co-Mo-based catalysts supported on mixed oxide supports MgO-Al2O3 with different Mg/Al atom ratios for water gas shift reaction were studied by means of TPR, Raman, XPS and ESR. It was found that the octahedral Mo species in oxidized Co-Mo/MgO（x）-Al2O3 catalyst and the contents of Mo^5＋, Mo^4＋, S^2- and S^2-2 species in the functioning catalysts increased with increasing the Mg/Al atom ratio of the support under the studied experimental conditions. This is favorable for the formation of the active Co-Mo-S phase of the catalysts. Catalytic performance testing results showed that the catalysts Co-Mo/MgO-Al2O3 with the Mg/Al atom ratio of the support in the range of 0.475-0.525 exhibited optimal catalytic activity for the reaction.

Microstructure evolution of Al_(0.6)CoCrFeNi high entropy alloy powder prepared by high pressure gas atomization

The influence of cooling rate on the microstructure of Al0.6CoCrFeNi high entropy alloy（HEA） powders was investigated. The spherical HEA powders（D50≈78.65 μm） were prepared by high pressure gas atomization. The different cooling rates were achieved by adjusting the powder diameter. Based on the solidification model, the relationship between the cooling rate and the powder diameter was developed. The FCC phase gradually disappears as particle size decreases. Further analysis reveals that the phase structure gradually changes from FCC＋BCC dual-phase to a single BCC phase with the increase of the cooling rate. The microstructure evolves from planar crystal to equiaxed grain with the cooling rate increasing from 3.19×10^4 to 1.11×10^6 K/s.

Process modeling gas atomization of close-coupled ring-hole nozzle for 316L stainless steel powder production

The paper aims at modeling and simulating the atomization process of the close-coupled ring-hole nozzle in vacuum induction gas atomization(VIGA)for metallic powder production.First of all,the primary atomization of the ring-hole nozzle is simulated by the volume of fluid(VOF)coupled large eddy simulation(LES)model.To simulate the secondary atomization process,we use the method of selecting the droplet sub-model and the VOF model.The results show that the ring-hole nozzle forms a gas recirculation zone at the bottom of the delivery tube,which is the main reason for the formation of an annular liquid film during the primary atomization.In addition,the primary atomization process of the ring-hole nozzle consists of three stages:the formation of the serrated liquid film tip,the appearance and shedding of the ligaments,and the fragmentation of ligaments.At the same time,the primary atomization mainly forms spherical droplets and long droplets,but only the long droplets can be reserved and proceed to the secondary atomization.Moreover,increasing the number of ring holes from 18 to 30,the mass median diameter(MMD,d_(50))of the primary atomized droplets decreases first and then increases,which is mainly due to the change of the thickness of the melt film.Moreover,the secondary atomization of the ring-hole nozzles is mainly in bag breakup mode and multimode breakup model,and bag breakup will result in the formation of hollow powder,which can be avoided by increasing the gas velocity.