Silica supported gold nanoparticles were synthesized and promoted by lanthanum oxide as dopant. The influences of LaOand silica textural structure on the gold dispersion, formation of active species, crystalline compo...Silica supported gold nanoparticles were synthesized and promoted by lanthanum oxide as dopant. The influences of LaOand silica textural structure on the gold dispersion, formation of active species, crystalline composition and the reacting role of dopants were studied in detail. The characterization results suggested that the dispersion of gold nanoparticles depended on the textural structure of silica without lanthanum oxide doping where small mesopores are more preferable to disperse gold nanoparticles. The addition of lanthanum oxide largely increased the dispersion of gold nanoparticles and oxygen active sites independent of the textural structure of silica support. The interaction between lanthanum oxide and silica enhanced by the synergy facilitated the release of oxygen vacancies and transition of active oxygen species. In addition, the chemical properties were greatly changed after lanthanum oxide addition which was only inconspicuously impacted by the initial textural structure of silica supports, shedding light on the further design of economic gold catalyst based on simple synthesis method.展开更多
基金supported by the National Key Research and Development Program of China(No.2021YFA1500703 to Ganglong Cui)Distinguished Professorship of Chang Jiang Scholars of Ministry of Education of China(Ganglong Cui)+1 种基金the Fundamental Research Funds for the Central Universitiesthe National Natural Science Foundation of China(No.22233001 to Ganglong Cui,No.22003043 to Xiang-Yang Liu)。
基金supported by the foundation of programme from Education Department of Sichuan (15ZA0303)New Century Excellent Talent Project of China (NCET-05-0783)
文摘Silica supported gold nanoparticles were synthesized and promoted by lanthanum oxide as dopant. The influences of LaOand silica textural structure on the gold dispersion, formation of active species, crystalline composition and the reacting role of dopants were studied in detail. The characterization results suggested that the dispersion of gold nanoparticles depended on the textural structure of silica without lanthanum oxide doping where small mesopores are more preferable to disperse gold nanoparticles. The addition of lanthanum oxide largely increased the dispersion of gold nanoparticles and oxygen active sites independent of the textural structure of silica support. The interaction between lanthanum oxide and silica enhanced by the synergy facilitated the release of oxygen vacancies and transition of active oxygen species. In addition, the chemical properties were greatly changed after lanthanum oxide addition which was only inconspicuously impacted by the initial textural structure of silica supports, shedding light on the further design of economic gold catalyst based on simple synthesis method.
