The interfacial microstructure evolution of 12Cr1MoV/TP347H dissimilar steel welded joints with a nickel-based filler metal during aging was studied in detail to elucidate the mechanism of premature failures of this k...The interfacial microstructure evolution of 12Cr1MoV/TP347H dissimilar steel welded joints with a nickel-based filler metal during aging was studied in detail to elucidate the mechanism of premature failures of this kind of joints.The results showed that not only a band of granular Cr_(23)C_(6)carbides were formed along the fusion boundary in the ferritic steel during aging,but also a large number of granular or plate-like Cr_(23)C_(6)carbides,which have a cube-cube orientation relationship with the matrix,were also precipitated on the weld metal side of the fu-sion boundary,making this zone be etched more easily than the other zone and become a dark etched band.Stacking faults were found in some Cr_(23)C_(6)carbides.In the as-welded state,deformation twins were observed in the weld metal with a fully austenitic structure.The peak micro-hardness was shifted from the ferritic steel side to the weld metal side of the fusion boundary after aging and the peak value increased signific-antly.Based on the experimental results,a mechanism of premature failures of the joints was proposed.展开更多
In the harsh service environment of high temperature and intense neutron irradiation in water-cooled nuclear reactors,the austenitic stainless steel weld overlay cladding on the inner surface of the reactor pressure v...In the harsh service environment of high temperature and intense neutron irradiation in water-cooled nuclear reactors,the austenitic stainless steel weld overlay cladding on the inner surface of the reactor pressure vessel suffers from thermal aging and irradiation damage simultaneously,which can induce microstructural evolution and hardening of the material.Since it is quite difficult to achieve this simul-taneous process out of the pile,two kinds of combined experiments,i.e.,post-irradiation thermal aging and post-aging irradiation were performed on 308 L stainless steel weld metals in this work.The interactive effect of thermal aging and proton irradiation on microstructural evolution and hardening ofδ-ferrite in 308 L weld metal was investigated by combining atom probe tomography,transmission elec-tron microscopy and nanoindentation tests.The results revealed that thermal aging could eliminate the dislocation loops induced by irradiation and affect the phase transition process by accelerating spinodal decomposition and G-phase precipitation,thus enhancing hardening of irradiatedδ-ferrite.For the effect of irradiation on the microstructure and hardening of thermally agedδ-ferrite,however,intensive collision cascades can intensify G-phase precipitation and dislocation loop formation but decrease spinodal decomposition,leading to a limited effect on hardening of thermally agedδ-ferrite.Furthermore,the interaction of thermal aging and irradiation can promote G-phase precipitation.Meanwhile,the interaction can causeδ-ferrite hardening,which is mainly influenced by spinodal decomposition,followed by G-phase and dislocation loops,where spinodal decomposition and G-phase cause hardening by inducing strain fields.展开更多
The effect of heat input on fume and their compositions during gas metal arc welding (GMAW) of AISI 316 stainless steel plates are investigated. Fume generation rate (FGR) and fume percentage were determined by AN...The effect of heat input on fume and their compositions during gas metal arc welding (GMAW) of AISI 316 stainless steel plates are investigated. Fume generation rate (FGR) and fume percentage were determined by ANSI/AWS F1.2 methods. Particle characterization was performed with SEM-XEDS and XRF analysis to reveal the particle morphology and chemical composition of the fume particles. The SEM analysis reveals the morphology of particles having three distinct shapes namely spherical, irregular, and agglomerated. Spherical particles were the most abundant type of individual particle. All the fume particle size falls in the range of less than 100 nm. Mechanical properties (strength, hardness and toughness) and microstructural analysis of the weld deposits were evaluated. It is found that heat input of 1.15 kJ/mm is beneficial to weld stainless steel by GMAW process due to lower level of welding fume emissions and superior mechanical properties of the joints.展开更多
In order to improve the weldability of duplex stainless steels,obtaining more secondary austenite in the weld metal is an effective way.Therefore,optimizing the secondary austenite by changing its morphology,volume fr...In order to improve the weldability of duplex stainless steels,obtaining more secondary austenite in the weld metal is an effective way.Therefore,optimizing the secondary austenite by changing its morphology,volume fraction and stability may be expected to enhance the ductility of the weld.The secondary austenite morphologies in the fusion zone of the laser continuously heat treated welds of 2205 duplex stainless steel were investigated.The secondary austenite morphologies were found to be influenced by different laser power level.The secondary austenite with penniform,freely grown and dendritic shape appeared in the course of 4,6 and 8 kW continuous heat treatment,respectively.It was found that there were three kinds of morphologies of secondary austenite in the fusion zone treated by different power,i.e.,widmannst¨atten austenite,grain boundary austenite and intragranular austenite.The results demonstrated that the mechanism of the secondary austenite formation was a displacement mechanism during the initial austenite lath formation and a diffusion mechanism during cooling.The nitrides provided the nitrogen for the transformation and at the same time acted as nucleation sites for the secondary austenite.展开更多
文摘The interfacial microstructure evolution of 12Cr1MoV/TP347H dissimilar steel welded joints with a nickel-based filler metal during aging was studied in detail to elucidate the mechanism of premature failures of this kind of joints.The results showed that not only a band of granular Cr_(23)C_(6)carbides were formed along the fusion boundary in the ferritic steel during aging,but also a large number of granular or plate-like Cr_(23)C_(6)carbides,which have a cube-cube orientation relationship with the matrix,were also precipitated on the weld metal side of the fu-sion boundary,making this zone be etched more easily than the other zone and become a dark etched band.Stacking faults were found in some Cr_(23)C_(6)carbides.In the as-welded state,deformation twins were observed in the weld metal with a fully austenitic structure.The peak micro-hardness was shifted from the ferritic steel side to the weld metal side of the fusion boundary after aging and the peak value increased signific-antly.Based on the experimental results,a mechanism of premature failures of the joints was proposed.
基金supported by the National Natural Science Foundation of China(No.52071018).
文摘In the harsh service environment of high temperature and intense neutron irradiation in water-cooled nuclear reactors,the austenitic stainless steel weld overlay cladding on the inner surface of the reactor pressure vessel suffers from thermal aging and irradiation damage simultaneously,which can induce microstructural evolution and hardening of the material.Since it is quite difficult to achieve this simul-taneous process out of the pile,two kinds of combined experiments,i.e.,post-irradiation thermal aging and post-aging irradiation were performed on 308 L stainless steel weld metals in this work.The interactive effect of thermal aging and proton irradiation on microstructural evolution and hardening ofδ-ferrite in 308 L weld metal was investigated by combining atom probe tomography,transmission elec-tron microscopy and nanoindentation tests.The results revealed that thermal aging could eliminate the dislocation loops induced by irradiation and affect the phase transition process by accelerating spinodal decomposition and G-phase precipitation,thus enhancing hardening of irradiatedδ-ferrite.For the effect of irradiation on the microstructure and hardening of thermally agedδ-ferrite,however,intensive collision cascades can intensify G-phase precipitation and dislocation loop formation but decrease spinodal decomposition,leading to a limited effect on hardening of thermally agedδ-ferrite.Furthermore,the interaction of thermal aging and irradiation can promote G-phase precipitation.Meanwhile,the interaction can causeδ-ferrite hardening,which is mainly influenced by spinodal decomposition,followed by G-phase and dislocation loops,where spinodal decomposition and G-phase cause hardening by inducing strain fields.
文摘The effect of heat input on fume and their compositions during gas metal arc welding (GMAW) of AISI 316 stainless steel plates are investigated. Fume generation rate (FGR) and fume percentage were determined by ANSI/AWS F1.2 methods. Particle characterization was performed with SEM-XEDS and XRF analysis to reveal the particle morphology and chemical composition of the fume particles. The SEM analysis reveals the morphology of particles having three distinct shapes namely spherical, irregular, and agglomerated. Spherical particles were the most abundant type of individual particle. All the fume particle size falls in the range of less than 100 nm. Mechanical properties (strength, hardness and toughness) and microstructural analysis of the weld deposits were evaluated. It is found that heat input of 1.15 kJ/mm is beneficial to weld stainless steel by GMAW process due to lower level of welding fume emissions and superior mechanical properties of the joints.
基金support from the National Basic Research Program of China(973 Program,No. 2010CB630800)the Shanghai Municipal Science and Technology Commission Foundation of China (Grant No. 0852nm02500)
文摘In order to improve the weldability of duplex stainless steels,obtaining more secondary austenite in the weld metal is an effective way.Therefore,optimizing the secondary austenite by changing its morphology,volume fraction and stability may be expected to enhance the ductility of the weld.The secondary austenite morphologies in the fusion zone of the laser continuously heat treated welds of 2205 duplex stainless steel were investigated.The secondary austenite morphologies were found to be influenced by different laser power level.The secondary austenite with penniform,freely grown and dendritic shape appeared in the course of 4,6 and 8 kW continuous heat treatment,respectively.It was found that there were three kinds of morphologies of secondary austenite in the fusion zone treated by different power,i.e.,widmannst¨atten austenite,grain boundary austenite and intragranular austenite.The results demonstrated that the mechanism of the secondary austenite formation was a displacement mechanism during the initial austenite lath formation and a diffusion mechanism during cooling.The nitrides provided the nitrogen for the transformation and at the same time acted as nucleation sites for the secondary austenite.