Anti-Corrosion and Reconstruction of Surface Crystal Plane for Zn Anodes by an Advanced Metal Passivation Technique

For the aqueous Zn-ion battery,dendrite formation,corrosion,and interfacial parasitic reactions are major issues,which greatly inhibits their practical application.How to develop a method of Zn construction or treatment to solve these issues for Zn anodes are still great challenges.Herein,a simple and cheap metal passivation technique is proposed for Zn anodes from a corrosion science perspective.Similar to the metal anticorrosion engineering,the formed interfacial protective layer in a chemical way can sufficiently solve the corrosion issues.Furthermore,the proposed passivity approach can reconstruct Zn surface-preferred crystal planes,exposing more(002)planes and improving surface hydrophilicity,which inhibits the formation of Zn dendrites and hydrogen evolution effectively.As expected,the passivated Zn achieves outstanding cycling life(1914 h)with low voltage polarization(<40 mV).Even at 6 mA cm^(−2) and 3 mA h cm^(−2),it can achieve stable Zn deposition over 460 h.The treated Zn anode coupled with MnO_(2) cathode shows prominently reinforced full batteries service life,making it a potential Zn anode candidate for excellent performance aqueous Zn-ion batteries.The proposed passivation approach provides a guideline for other metal electrodes preparation in various batteries and establishes the connections between corrosion science and batteries.

Digital CEOs in Digital Enterprises:Automating,Augmenting,and Parallel in Metaverse/CPSS/TAOs

BIG models or foundation models are rapidly emerging as a key force in advancing intelligent societies[1]–[3]Their significance stems not only from their exceptional ability to process complex data and simulate advanced cognitive functions,but also from their potential to drive innovation across various industries.

基于智慧职教平台的混合式教学模式课程设计与教学实践研究——以Auto CAD绘图课程为例

传统Auto CAD绘图课程的教学模式是老师不断输出知识和操作演示,学生被动接受和模仿学习,学生未能真正将知识进行内化,也没有思考后的输出和应用。该方式教学内容与企业需求脱轨,学生只能完成课堂布置的练习及课后作业,缺乏学习探索的主动性。据此,将现代信息化教学手段与普通线下教学方式进行糅合,并在此基础上进行课程内容重构、教学过程设计和多元化评价体系等,以求达到更好的教学效果,培养出企业需要、社会满意的学生。

Auto CAD二次开发在幕墙设计中的应用

随着建筑幕墙行业的快速发展,幕墙设计工作也越来越复杂.幕墙设计不仅在招投标阶段发挥重要作用,更在工程施工过程中给予大量的技术支持,导致幕墙设计人员肩上的担子越来越重.本文通过研究Auto CAD二次开发来解决复杂幕墙设计问题,减少重复机械操作,提高幕墙设计人员的工作效率.

基于Auto CAD的通风管道系统的优化

当前通风管道系统的尺寸优化主要由人工完成,效率较低,针对该问题,分析了通风管道系统的结构特性,选用了B树作为基本数据结构,根据通风管道中线图及其连通特性建立管路构建方法。依据通风管道中风速、风量与截面积的关系,计算出各个管道的理论截面积,确定了管道截面尺寸优化策略。最后使用上述方法针对某通风管道进行了优化设计。

基于AUTO Civil 3D的水利工程勘察设计

本文通过无人机技术和数字高程模型,采集水库工程的地形和地貌数据;将原始工程资料、采集的地貌数据以及地形数据,输入至AUTO Civil 3D软件中,生成水库工程地形曲面模型和地质三维实体模型,完成模型颜色渲染,进行水库工程勘察设计。这种基于AUTO Civil 3D的水利工程勘察方法测试结果表明,该方法能够有效完成水利工程地质模型的生成,呈现地质信息的实体结果;模型的构建精度较高,可有效完成航道疏浚时河底清淤勘察设计。

Injuries Associated with Auto-Tricycle Crashes in an African City: Incidence and Pattern

Purpose: The aim of this study was to determine the incidence and pattern of injuries resulting from auto-tricycle crashes among patients in a tertiary referral centre in Ghana. Methods: Data were retrospectively extracted from hospital records of patients who got involved in auto-tricycle crashes and presented to the Accident and Emergency Centre of the Komfo Anokye Teaching Hospital (KATH), over a one-year period using a structured questionnaire. The gathered data were then entered into an electronic database and then analysed with SPSS version 20.0. Results: The incidence of injury following auto-tricycle crashes over the one-year period was 5.9% (95% CI: 4.9% - 7.0%) with a case fatality rate (FR) of 3.8% (95% CI: 1.3% - 8.7%). All the mortalities resulted from head and neck injuries and none of the patients involved wore a crash helmet. Only 5% of those studied wore crash helmets and were all drivers. Closed fractures accounted for 58% of the injuries, followed by open fractures, 28%. The most commonly fractured bones were the tibia/fibula, followed by the femur and then radius/ulna. The most common mechanism of injury was auto-tricycle toppling over (29%). Passengers were the most injured (48%), followed by drivers (37%) and pedestrians (15%). Most (72%) injuries among participants involved a single body part. On the injury severity scale, most (61%) of patients had minor trauma and 38% had major trauma. Conclusion: Auto-tricycle crashes account for 5.9% of injuries at the study site with a case fatality rate of 3.8%. Passengers had a higher injury rate (48%) than drivers (37%). Fractures of the tibia/fibula were most commonly associated with auto-tricycle crashes. Injuries to the head and neck were responsible for the deaths in the study participants and non-use of a crash helmet was associated with mortalities.

基于Auto bank的某水库大坝渗流安全评价

以富水水库为例,依托达西定律和渗流理论基础,并结合Auto bank有限元软件分析了水库在正常高水位、设计洪水位、校核洪水位下坝体及坝基的渗流状况,计算结果表明水库日渗漏量远小于允许日渗漏量,水库渗漏量满足规范要求。大坝各工况最大渗透坡降均小于规范允许值,渗透变形满足规范要求。左坝肩存绕渗现象,建议加强监测。

Auto CAD在陶瓷产品设计三视图中的应用研究

Auto CAD制图的应用为陶瓷产品设计提供了有力帮助,能显著提升陶瓷产品的观赏性、艺术性,同时使陶瓷产品保持其应有的实用性。对此,本文针对Auto CAD在陶瓷产品设计三视图中的应用价值展开探讨,对于Auto CAD的应用原理进行研究,而后对Auto CAD在陶瓷产品设计三视图中的具体应用进行分析,对于如何推动这一制图软件的深度应用提出一些建议,希望能为相关从业者在Auto CAD的应用方面提供一些借鉴。

Preparation technology and anti-corrosion performances of black ceramic coatings formed by micro-arc oxidation on aluminum alloys

In order to prepare ornamental and anti-corrosive coating on aluminum alloys, preparation technology of black micro-arc ceramic coatings on Al alloys in silicate based electrolyte was studied. The influence of content of Na2WO4 and combination additive in solution on the performance of black ceramic coatings was studied; the anticorrosion performances of black ceramic coatings were evaluated through whole-immersion test and electrochemical method in 3.5% NaCl solution at different pH value; SEM and XRD were used to analyze the surface morphology and phase constitutes of the black ceramic coatings. Experimental results indicated that, without combination additives, with the increasing of Na2WO4 content in the electrolyte, ceramic coating became darker and thicker, but the color was not black; after adding combination additive, the coating turned to be black; the black ceramic coating was multi-hole form in surface. There was a small quantity of tungsten existing in the black ceramic coating beside α-Al2O3 phase and β-Al2O3 phase. And aluminum alloy with black ceramic coating exhibited excellent anti-corrosion property in acid, basic and neutral 3.5% NaCl solution.

Atomic-Scale Layer-by-Layer Deposition of Fe SiAl@ZnO@Al_(2)O_(3) Hybrid with Threshold Anti-Corrosion and Ultra-High Microwave Absorption Properties in Low-Frequency Bands

Developing highly efficient magnetic microwave absorb-ers(MAs)is crucial,and yet challenging for anti-corrosion properties in extremely humid and salt-induced foggy environments.Herein,a dual-oxide shell of ZnO/Al_(2)O_(3) as a robust barrier to FeSiAl core is introduced to mitigate corrosion resistance.The FeSiAl@ZnO@Al_(2)O_(3) layer by layer hybrid structure is realized with atomic-scale precision through the atomic layer deposition technique.Owing to the unique hybrid structure,the FeSiAl@ZnO@Al_(2)O_(3) exhibits record-high micro-wave absorbing performance in low-frequency bands covering L and S bands with a minimum reflection loss(RLmin)of-50.6 dB at 3.4 GHz.Compared with pure FeSiAl(RLmin of-13.5 dB,a bandwidth of 0.5 GHz),the RLmin value and effective bandwidth of this designed novel absorber increased up to~3.7 and~3 times,respectively.Fur-thermore,the inert ceramic dual-shells have improved 9.0 times the anti-corrosion property of FeSiAl core by multistage barriers towards corrosive medium and obstruction of the electric circuit.This is attributed to the large charge transfer resistance,increased impedance modulus|Z|0.01 Hz,and frequency time constant of FeSiAl@ZnO@Al_(2)O_(3).The research demonstrates a promising platform toward the design of next-generation MAs with improved anti-corrosion properties.

一种基于AutoLISP的地形图斜坡类要素处理程序的设计与实现

在大比例尺地形图编辑中存在大量的依比例斜坡类符号要素,包括依比例斜坡、干堤、加固岸、路堤、路堑等,该类符号是一种复合性符号,由坡顶线和坡面两部分组成,坡顶线由坡顶母线和长短齿符号组成,其中长齿长度和坡面宽度一致且垂直于坡顶母线,该符号表示复杂,编辑工作较为费时费力。利用AutoLISP语言开发斜坡类符号要素处理程序,实现符号长齿自动延伸,可大大提高该类符号编辑工作效率,提升制图表达效果。

A Comparative Study on Several Anti-Corrosion Materials for Power FGD System

In the study organic-inorganic hybrid composite, epoxy modified silicone coating and vinyl ester flake mastic were comparatively used as several anti-corrosion materials that provided protection for flue gas desulfu-rization (FGD). The relationship between curing conversion rate of hybrid polymer and temperature was investigated by differential scanning calorimeter (DSC). The adhesion strength, coefficient of thermal expansion and flame retardant properties of three anti-corrosion materials were measured and analyzed. A corrosion test in 8% H2SO4 and 5% HCl at temperature cycle of 40°C~ 160°C was applied to study corrosion resistance of several anti-corrosion materials. Gravimetric measurement and morphological observation of three materials before and after corrosion test were comparatively analyzed in the paper. The small weight change and good morphological structure of hybrid composite during corrosion test demonstrate that hybrid composite has better anti-corrosion properties than epoxy modified silicone coating and vinyl ester flake mastic.

Influence of graphene on the anti-corrosion performance of epoxy-based coatings

In this work, graphene-modified epoxy-based anti-corrosion coatings were prepared and the influence of graphene on the anti-corrosion performance of the epoxy-based coatings was investigated with water contact angle test ,chemical solution immersion test, and electrochemical test. The water contact angle and chemical solution resistance of the epoxy-based coatings were improved with an increase in graphene content from 0 to 0.4%. These results prove that addition of graphene can significantly improve the hydrophobicity and impermeability of epoxy- based coatings. However, when the graphene content was increased to 0.5%, the performance of the epoxy-based coatings decreased because of graphene aggregation. Tafel polarization results show that graphene addition can significantly reduce the corrosion current density and corrosion potential of epoxy-based coatings, which enhance their anti-corrosion performance.

Investigation of anti-corrosion property of hybrid coatings fabricated by combining PEC with MAO on pure magnesium

Novel hybrid coatings on pure magnesium were prepared by combining plasma electrolytic carburizing(PEC)with micro-arc oxidation(MAO)to further enhance the anti-corrosion property in this paper.Scanning electron microscopy(SEM)was used to observe the microstructure of the coatings,meanwhile,energy dispersive spectrometry(EDS)and X-ray diffraction(XRD)were separately used to investigate the elemental as well as phase compositions of the coatings.The anti-corrosion property of the coatings was evaluated by potentiodynamic polarization curves as well as electrochemical impedance spectroscopy(EIS).The results show that PEC process is closely related with the effects of adsorption as well as diffusion of the activated carbon atoms,and it can provide a favorable pretreatment surface with predesigned chemical composition to obtain a new kind of phase,namely Si C with superior corrosion resistance and chemical stability,in the following PEC+MAO hybrid coatings.Meanwhile,PEC preprocessing also can afford an excellent micro-structure to increase the coating thickness as well as to improve the compactness of the PEC+MAO hybrid coatings.During the fabrication process of the PEC+MAO hybrid coatings,an overlapping phenomenon in regard to coating thickness can be observed instead of heaping up layer by layer.Compared with both single PEC surface modification layers as well as single MAO coatings,the PEC+MAO hybrid coatings exhibit more superior anti-corrosion property.Especially,the EIS data reveal that the PEC+MAO hybrid coatings can act as an effective protection system to provide relatively excellent long-range anti-corrosion protection.Note also that employing same MAO technique for both single MAO treatment as well as PEC+MAO combining procedure is the key to this research.

An electrochemical method for evaluating the resistance to cathodic disbondment of anti-corrosion coatings on buried pipelines

Methods for evaluating the resistance to cathodic disbondment （RCD） of anti-corrosion coatings on buried pipelines were reviewed. It is obvious that these traditional cathodic disbondment tests （CDT） have some disadvantages and the evaluated results are only simple figures and always rely on the subjective experience of the operator. A new electrochemical method for evaluating the RCD of coatings, that is, the potentiostatic evaluation method （PEM）, was developed and studied. During potentiostatic anodic polarization testing, the changes of stable polarization current of specimens before and after cathodic disbonding （CD） were measured, and the degree of cathodic disbondment of the coating was quantitatively evaluated, among which the equivalent cathodic disbonded distance AD was suggested as a parameter for evaluating the RCD. A series of testing parameters of the PEM were determined in these experiments.

The Effect of Cerium Dioxide (CeO_2) in an Anti-corrosion and Self-lubricating Coating

The effect of cerium dioxide(CeO_2)as an additive on the structure and properties of a melting type coating has been studied by means of microhardness measurement,scanning electron microscopy and thermal analysis. The results show that cerium dioxide can modify the microstructure and tribological properties of the coating. Model LIC-23 composite coating which contains CeO_2 performs well as a self-lubricating coating in hydrochloric acid solution.

An Abrasion Resistant TPU/SH-SiO_(2) Superhydrophobic Coating for Anti-Icing and Anti-Corrosion Applications

As a passive anti-icing strategy,properly designed superhydrophobic coatings can demonstrate outstanding performances.However,common preparation strategies for superhydrophobic coatings often lead to environmental pollution,high energy-consumption,high-cost and other undesirable issues.Besides,the durability of superhydrophobic coating also plagues its commercial application.In this paper,we introduced a facile and environment-friendly technique for fabricating abrasion-resistant superhydrophobic surfaces using thermoplastic polyurethane(TPU)and modified SiO_(2)particles(SH-SiO_(2)).Both materials are non-toxicity,low-cost,and commercial available.Our methodology has the following advantages:use of minimal amounts of formulation,take the most streamlined technical route,and no waste material.These advantages make it attractive for industrial applications,and its usage sustainability can be promised.In this study,the mechanical stability of the superhydrophobic surface was evaluated by linear wear test.It is found that the excellent wear resistance of the superhydrophobic coating benefits from the characteristics of raw materials,the preparation strategy,and the special structure.In anti-icing properties test,the TPU/SH-SiO_(2)coating exhibits the repellency to the cold droplets and the ability to extend the freezing time.The electrochemical corrosion measurement shows that the asprepared superhydrophobic surface has excellent corrosion resistance that can provide effective protection for the bare Q235 substrates.These results indicate that the TPU/SH-SiO_(2)coating possesses good abrasion resistance and has great potential in anti-corrosion and anti-icing applications.

A novel anti-corrosion coating for magnesium alloy

A novel enviromental protective water based metallic coating were prepared on the surface of AZ91D magnesium alloy. The properties and structure of the coating were investigated by adhension test, hardness test, heat resisting test, neutral salt spray test and scanning electron microscopy (SEM). The results show that the coating has a stepped structure which can achieve good adhesion of first-grade, heat resistance temperature of 400℃, hardness of HV_ 0.50/30210 and anti-corrosion time of 250h in salt spray test. Meanwhile, the film forming and corrosion mechanism of the coating were also put forward based on the results of the Fourier transform infrared spectroscopy (FTIR) test and electrochemical impedance spectroscopy (EIS) test.

Auto CAD图解法在缓和曲线计算中的应用

本文以缓和曲线直角坐标计算公式及切线角计算公式为基础,先用Excel分段计算出缓和曲线坐标,用较短长度直线连接成一条多段线来拟合缓和曲线;然后利用Auto CAD中自定义坐标系、旋转和平移等命令,实现在直线段和圆曲线之间插入缓和曲线的图解坐标计算方法。