The semi-continuous seeded emulsion eopolymerization of vinyl acetate and butyl acrylate was carried out with hydroxyethyl cellulose as a colloid stabilizer. The morphology of the latex particle and the relationship b...The semi-continuous seeded emulsion eopolymerization of vinyl acetate and butyl acrylate was carried out with hydroxyethyl cellulose as a colloid stabilizer. The morphology of the latex particle and the relationship between the reaction time and the average particle diameter and/or the conversion ratio during the polymerization were invstiguted. The experimental results shaw that the morphology of the latex particle possesses the stable sterie construction. In the seeded polymerizution, the average particle diameter of latex decreased while the conversion ratio increased. At the second term of the emulsion copolymerization (the growth stage of particle size), the latex particle average diameter increased with copolymerization continuously, but the instantaneous conversation ratio was not large, so it was very necessaO to properly prolong the time during the holding temperature stage.展开更多
La2O3 is a combustion improver suitable for burning pulverized coal in blast furnace. La2O3 forms the active species La3+(CO-)3 that weakens the bridge adhesion of carbon structural units and alters the lattice str...La2O3 is a combustion improver suitable for burning pulverized coal in blast furnace. La2O3 forms the active species La3+(CO-)3 that weakens the bridge adhesion of carbon structural units and alters the lattice structures, thus reducing the activation energy of the pulverized coal and accelerating the burning process. Research shows that La2O3 can form the active species La3+(CO-)3, which weakens the bridge adhesion of carbon structural units and alters the lattice structures of the fixed carbon, hence decreasing the activation energy of the pulverized coal and accelerating the burning process.展开更多
文摘The semi-continuous seeded emulsion eopolymerization of vinyl acetate and butyl acrylate was carried out with hydroxyethyl cellulose as a colloid stabilizer. The morphology of the latex particle and the relationship between the reaction time and the average particle diameter and/or the conversion ratio during the polymerization were invstiguted. The experimental results shaw that the morphology of the latex particle possesses the stable sterie construction. In the seeded polymerizution, the average particle diameter of latex decreased while the conversion ratio increased. At the second term of the emulsion copolymerization (the growth stage of particle size), the latex particle average diameter increased with copolymerization continuously, but the instantaneous conversation ratio was not large, so it was very necessaO to properly prolong the time during the holding temperature stage.
基金the National Key Laboratory in University of Science and Technology Beijing of China (KFI3-02) and the Natural Science Foundation of Hebei province (E2013209339).
文摘La2O3 is a combustion improver suitable for burning pulverized coal in blast furnace. La2O3 forms the active species La3+(CO-)3 that weakens the bridge adhesion of carbon structural units and alters the lattice structures, thus reducing the activation energy of the pulverized coal and accelerating the burning process. Research shows that La2O3 can form the active species La3+(CO-)3, which weakens the bridge adhesion of carbon structural units and alters the lattice structures of the fixed carbon, hence decreasing the activation energy of the pulverized coal and accelerating the burning process.