We have systematically studied the structures, electronic properties, and lattice dynamics of B–P compounds at high pressures. BP and B_6 P are found to be thermodynamically stable below 100 GPa, and other stoichiome...We have systematically studied the structures, electronic properties, and lattice dynamics of B–P compounds at high pressures. BP and B_6 P are found to be thermodynamically stable below 100 GPa, and other stoichiometries are decomposable under pressure. The predicted structures of F-43 m BP and R-3 m B_6 P are in good agreement with the experimental results by comparing the powder diffraction file(PDF) standard cards with our simulated x-ray diffractions. The bonding properties of BP and B_6 P have also been analyzed by electronic localization functions, charge density difference, and Bader charge analysis. Our results show that BP and B_6 P decompose into B and P under high pressure, which is proven to be dominated by the volumes of them. Furthermore, the infrared and Raman spectra of F-43 m and R-3 m are investigated at selected pressures and will provide useful information for future experimental studies about B–P compounds.展开更多
分析宁镇及宜溧地区中晚全新世典型剖面的地层划分与特征,采用R-Q型因子分析方法估算气候变化值,揭示5 700 a B.P.前后发生在本区的干燥降温异常气候突变事件。气候曲线与沉积相序列的对比分析表明,宝华山浅棕黄色砂土夹角砾层洪-坡积...分析宁镇及宜溧地区中晚全新世典型剖面的地层划分与特征,采用R-Q型因子分析方法估算气候变化值,揭示5 700 a B.P.前后发生在本区的干燥降温异常气候突变事件。气候曲线与沉积相序列的对比分析表明,宝华山浅棕黄色砂土夹角砾层洪-坡积相是该突变事件背景下的产物,且该突变事件还具有全球变化区域响应的征候,林峰桥同期淤泥质层中Fe3+/Fe2+比和粘土百分含量异常值进一步印证了这一论断。展开更多
采用程序升温汽化(programmed temperature vaporization,PTV)大体积进样与气相色谱-质谱选择离子扫描模式(GC/MS-SIM)联用,检测了卷烟主流烟气中苯并[a]芘(benzo[a]pyrene B[a]P),优化了PTV-GC/MS-SIM检测卷烟烟气B[a]P的参数。样品经...采用程序升温汽化(programmed temperature vaporization,PTV)大体积进样与气相色谱-质谱选择离子扫描模式(GC/MS-SIM)联用,检测了卷烟主流烟气中苯并[a]芘(benzo[a]pyrene B[a]P),优化了PTV-GC/MS-SIM检测卷烟烟气B[a]P的参数。样品经反相C18固相萃取柱(solid-phase extraction,SPE)纯化后的洗脱液不再需要浓缩,直接应用PTV技术进样,提高了洗脱液的利用率,缩短了分析时间,提高了GC/MS-SIM检测卷烟烟气B[a]P的灵敏度。展开更多
重庆中坝遗址地层Rb、Sr、Hg及TOC研究表明:Rb、Sr和Rb/Sr值较好地反映了约4250 a B.P.以来气候变化过程,主要干冷期可与敦德冰川δ18O曲线谷值、湖光岩沉积物磁化率和Ti曲线峰值、以及大气14C浓度峰值和太阳活动水平较长期变化的低谷对...重庆中坝遗址地层Rb、Sr、Hg及TOC研究表明:Rb、Sr和Rb/Sr值较好地反映了约4250 a B.P.以来气候变化过程,主要干冷期可与敦德冰川δ18O曲线谷值、湖光岩沉积物磁化率和Ti曲线峰值、以及大气14C浓度峰值和太阳活动水平较长期变化的低谷对比,反映出地层中Rb、Sr不易受人类活动干扰的特性。结合考古遗存对比还发现,Hg、P、Ca、Mg和TOC记录了该遗址约4250 a B.P.以来人类活动的三个不同演变阶段。进一步研究认为,盐业遗址的衰落可能与洪水事件。展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51632002,51572108,11634004,11174102,and 11774119)the Program for Changjiang Scholars and Innovative Research Team in University,China(Grant No.IRT 15R23)+3 种基金the National Found for Fostering Talents of Basic Science,China(Grant No.J1103202)the National Key Research and Development Program of China(Grant No.2016YFB0201204)the Development Program of Science and Technology of Jilin Province,China(Grant No.20150312002ZG)the 111 Project,China(Grant No.B12011)
文摘We have systematically studied the structures, electronic properties, and lattice dynamics of B–P compounds at high pressures. BP and B_6 P are found to be thermodynamically stable below 100 GPa, and other stoichiometries are decomposable under pressure. The predicted structures of F-43 m BP and R-3 m B_6 P are in good agreement with the experimental results by comparing the powder diffraction file(PDF) standard cards with our simulated x-ray diffractions. The bonding properties of BP and B_6 P have also been analyzed by electronic localization functions, charge density difference, and Bader charge analysis. Our results show that BP and B_6 P decompose into B and P under high pressure, which is proven to be dominated by the volumes of them. Furthermore, the infrared and Raman spectra of F-43 m and R-3 m are investigated at selected pressures and will provide useful information for future experimental studies about B–P compounds.
基金the National Natural Science Foundation of China(Nos.52174372,51974224)the Natural Science Foundation of Shaanxi Province,China(No.2020JM-047)the Fundamental Research Funds for Central Universities,China(No.xtr0118008)for their support。
文摘分析宁镇及宜溧地区中晚全新世典型剖面的地层划分与特征,采用R-Q型因子分析方法估算气候变化值,揭示5 700 a B.P.前后发生在本区的干燥降温异常气候突变事件。气候曲线与沉积相序列的对比分析表明,宝华山浅棕黄色砂土夹角砾层洪-坡积相是该突变事件背景下的产物,且该突变事件还具有全球变化区域响应的征候,林峰桥同期淤泥质层中Fe3+/Fe2+比和粘土百分含量异常值进一步印证了这一论断。
文摘采用程序升温汽化(programmed temperature vaporization,PTV)大体积进样与气相色谱-质谱选择离子扫描模式(GC/MS-SIM)联用,检测了卷烟主流烟气中苯并[a]芘(benzo[a]pyrene B[a]P),优化了PTV-GC/MS-SIM检测卷烟烟气B[a]P的参数。样品经反相C18固相萃取柱(solid-phase extraction,SPE)纯化后的洗脱液不再需要浓缩,直接应用PTV技术进样,提高了洗脱液的利用率,缩短了分析时间,提高了GC/MS-SIM检测卷烟烟气B[a]P的灵敏度。
文摘重庆中坝遗址地层Rb、Sr、Hg及TOC研究表明:Rb、Sr和Rb/Sr值较好地反映了约4250 a B.P.以来气候变化过程,主要干冷期可与敦德冰川δ18O曲线谷值、湖光岩沉积物磁化率和Ti曲线峰值、以及大气14C浓度峰值和太阳活动水平较长期变化的低谷对比,反映出地层中Rb、Sr不易受人类活动干扰的特性。结合考古遗存对比还发现,Hg、P、Ca、Mg和TOC记录了该遗址约4250 a B.P.以来人类活动的三个不同演变阶段。进一步研究认为,盐业遗址的衰落可能与洪水事件。
