The addition of platinum over the B2O3/TiO2-ZrO2 remarkably enhanced its catalytic stability in the vapor phase Beckmann rearrangement of cyclohexanone oxime under the carder gas of H2. The content of coke deposited ...The addition of platinum over the B2O3/TiO2-ZrO2 remarkably enhanced its catalytic stability in the vapor phase Beckmann rearrangement of cyclohexanone oxime under the carder gas of H2. The content of coke deposited on catalyst surface was decreased from 1.92% over the B2O3/TiO2-ZrO2 to 1.14% over the platinum promoted B2O3/TiO2-ZrO2 after reaction of six hours. This result indicates that the platinum added on the B2O3/TiO2-ZrO2 catalyst plays an important role in reducing the coke formation on the catalyst surface.展开更多
The effect of ZnO-B2O3（ZB） glass addition on the sintering behavior, microstructures and microwave dielectric properties of BaO-Nd2O3-TiO2-Bi2O3 （BNTB） system was investigated with the aid of X-ray diffraction, sc...The effect of ZnO-B2O3（ZB） glass addition on the sintering behavior, microstructures and microwave dielectric properties of BaO-Nd2O3-TiO2-Bi2O3 （BNTB） system was investigated with the aid of X-ray diffraction, scanning electron microscopy and capacitance meter. It is found that the ZB glass addition, acting as a sintering aid, can effectively lower the sintering temperature of BNTB system to 850 ℃. The dielectric constant of BNTB-ZB ceramics increases with the increase of soaking time and the value of dielectric loss decreased with increasing soak time. The optical dielectric properties at 1 GHz of ε=74, tan δ=4×10^-4, and TCC=25 ppm/℃ were obtained for the BNTB system doped with 25 wt% ZB glass sintered at 850 ℃ for 2 h, representing that the BNTB-ZB ceramics could be promising for multilayer low temperature co-fired ceramics applications.展开更多
TiB2-Al2O3 composite powders were produced by self-propagating high-temperature synthesis（SHS） method with reductive process from B2O3-TiO2-AI system. X-ray diffraction（XRD） and scanning electron microscopy（SEM...TiB2-Al2O3 composite powders were produced by self-propagating high-temperature synthesis（SHS） method with reductive process from B2O3-TiO2-AI system. X-ray diffraction（XRD） and scanning electron microscopy（SEM） analyses show the presence of TiB2 and Al2O3 only in the composite powders produced by SHS. The powders are uniform and free-agglomerate. Transmission electron microscopy （TEM） and high resolution electron microscopy （HREM） observation of microstructure of the composite powders indicate that the interfaces of the TiB2-Al2O3 bond well, without any interfacial reaction products. It is proposed that the good interfacial bonding of the composite powders can be resulted from the TiB2 particles crystallizing and growing on the Al2O3 particles surface with surface defects acting as nucleation centers.展开更多
SHS method with reductive process was used to synthesize TiB2 ceramic powder from B2O3-TiO2-Mg system. X-ray diffraction, SEM and Image analysis were used to analyse microstructure of TiB2 powder and compare with micr...SHS method with reductive process was used to synthesize TiB2 ceramic powder from B2O3-TiO2-Mg system. X-ray diffraction, SEM and Image analysis were used to analyse microstructure of TiB2 powder and compare with microstructure of TiB, fabricated by SHS elements syn-thesis from Ti+B system. The results show that TiB? powder fabricated by SHS reductive synthesis is finer (about 1. 5?m) ,uni former and free-agglomerate.展开更多
文摘The addition of platinum over the B2O3/TiO2-ZrO2 remarkably enhanced its catalytic stability in the vapor phase Beckmann rearrangement of cyclohexanone oxime under the carder gas of H2. The content of coke deposited on catalyst surface was decreased from 1.92% over the B2O3/TiO2-ZrO2 to 1.14% over the platinum promoted B2O3/TiO2-ZrO2 after reaction of six hours. This result indicates that the platinum added on the B2O3/TiO2-ZrO2 catalyst plays an important role in reducing the coke formation on the catalyst surface.
基金Funded by the Tianjin Natural Science Foundation of China (No.06YFJMJC01000)
文摘The effect of ZnO-B2O3（ZB） glass addition on the sintering behavior, microstructures and microwave dielectric properties of BaO-Nd2O3-TiO2-Bi2O3 （BNTB） system was investigated with the aid of X-ray diffraction, scanning electron microscopy and capacitance meter. It is found that the ZB glass addition, acting as a sintering aid, can effectively lower the sintering temperature of BNTB system to 850 ℃. The dielectric constant of BNTB-ZB ceramics increases with the increase of soaking time and the value of dielectric loss decreased with increasing soak time. The optical dielectric properties at 1 GHz of ε=74, tan δ=4×10^-4, and TCC=25 ppm/℃ were obtained for the BNTB system doped with 25 wt% ZB glass sintered at 850 ℃ for 2 h, representing that the BNTB-ZB ceramics could be promising for multilayer low temperature co-fired ceramics applications.
文摘TiB2-Al2O3 composite powders were produced by self-propagating high-temperature synthesis（SHS） method with reductive process from B2O3-TiO2-AI system. X-ray diffraction（XRD） and scanning electron microscopy（SEM） analyses show the presence of TiB2 and Al2O3 only in the composite powders produced by SHS. The powders are uniform and free-agglomerate. Transmission electron microscopy （TEM） and high resolution electron microscopy （HREM） observation of microstructure of the composite powders indicate that the interfaces of the TiB2-Al2O3 bond well, without any interfacial reaction products. It is proposed that the good interfacial bonding of the composite powders can be resulted from the TiB2 particles crystallizing and growing on the Al2O3 particles surface with surface defects acting as nucleation centers.
文摘SHS method with reductive process was used to synthesize TiB2 ceramic powder from B2O3-TiO2-Mg system. X-ray diffraction, SEM and Image analysis were used to analyse microstructure of TiB2 powder and compare with microstructure of TiB, fabricated by SHS elements syn-thesis from Ti+B system. The results show that TiB? powder fabricated by SHS reductive synthesis is finer (about 1. 5?m) ,uni former and free-agglomerate.
