Two new organic couductot-semiconductor with Cu-containing binuclear polyhalide complex anion (BEDT-TTF)3Cu2Brx(A)and(TTM-TTF) (Cu2Bry) (B) are prepared and the crystal sttucture of B is determined. The conductivity o...Two new organic couductot-semiconductor with Cu-containing binuclear polyhalide complex anion (BEDT-TTF)3Cu2Brx(A)and(TTM-TTF) (Cu2Bry) (B) are prepared and the crystal sttucture of B is determined. The conductivity of the crystal A and B at room temperature along the crystal growth direction is about 10 and 7.10(-4)S. cm(-1), respectively.展开更多
Ⅰ. INTRODUCTIONThirty organic superconductors have been synthesized since the first organic superconductor （TMTSF）<sub>2</sub>PF<sub>6</sub> was synthesized in 1980. According to their donor...Ⅰ. INTRODUCTIONThirty organic superconductors have been synthesized since the first organic superconductor （TMTSF）<sub>2</sub>PF<sub>6</sub> was synthesized in 1980. According to their donors, they can be classified into four families, TMTSF, BEDT-TTF, DMET and Ni（dmit）<sub>2</sub>. The BEDT-TTF is the largest one in which there are many kinds of compounds with T<sub>c</sub>展开更多
文摘Two new organic couductot-semiconductor with Cu-containing binuclear polyhalide complex anion (BEDT-TTF)3Cu2Brx(A)and(TTM-TTF) (Cu2Bry) (B) are prepared and the crystal sttucture of B is determined. The conductivity of the crystal A and B at room temperature along the crystal growth direction is about 10 and 7.10(-4)S. cm(-1), respectively.
文摘Ⅰ. INTRODUCTIONThirty organic superconductors have been synthesized since the first organic superconductor （TMTSF）<sub>2</sub>PF<sub>6</sub> was synthesized in 1980. According to their donors, they can be classified into four families, TMTSF, BEDT-TTF, DMET and Ni（dmit）<sub>2</sub>. The BEDT-TTF is the largest one in which there are many kinds of compounds with T<sub>c</sub>
