Mechanical properties and deformation behavior of Zr-based bulk metallic glass composites reinforced with tungsten fibers or tungsten powders

The tungsten fibers or powders reinforced Zr_(52)Cu_(32)Ni_(6)Al_(10),(Zr_(52)Cu_(32)Ni_(6)Al_(10))_(98)Nb_(2),and(Zr_(52)Cu_(32)Ni_(6)Al_(10))_(98)Be_(2)bulk metallic glass composites(BMGCs)were fabricated using the infiltration casting method.In this study,the wettability between the amorphous alloy melts and tungsten substrates was investigated using the sessile drop method,revealing excellent wettability at 1,010℃.Consequently,an infiltration temperature of 1,010°C was chosen for composite material fabrication.Structural characterization and mechanical property test of both composites were conducted through scanning electron microscopy(SEM),and X-ray diffraction(XRD),and universal mechanical testing.Both tungsten fiber or tungsten powder reinforced Zr_(52)Cu_(32)Ni_(6)Al_(10)and(Zr_(52)Cu_(32)Ni_(6)Al_(10))_(98)Be_(2)composites exhibit the formation of W-Zr phase.In contrast,the tungsten fiber or tungsten powder reinforced(Zr_(52)Cu_(32)Ni_(6)Al_(10))_(98)Nb_(2)composites does not show the formation of W-Zr phase.X-ray diffraction patterns confirm the presence of W reinforcement phases in both composites.The successful fabrication of both composites is evidenced by their remarkable mechanical properties under room temperature compression.The yield strength of all the three tungsten fiber-reinforced composite sample exceeds 2,400 MPa,with the plastic strain exceeding 3.9%,while the yield strength of all the three tungsten powder-reinforced composite sample surpasses 2,700 MPa,with the plastic strain exceeding 30%.Fracture analysis reveals longitudinal splitting in the tungsten fiber-reinforced composites,contrasting with brittle fracture in the tungsten powder-reinforced composites.The denser the shear bands on the amorphous matrix of the two types of composite materials,the better their mechanical properties.

Effect of Cu content on microstructure and mechanical properties of in-situ β phases reinforced Ti/Zr-based bulk metallic glass matrix composite by selective laser melting(SLM)

In this study,non-toxic in-situβphases of reinforced Ti/Zr-based bulk metallic glass matrix composites(BMGCs)of(Ti_(0.65)Zr_(0.35))100-xCux(x=5,10,15 at.%)are fabricated via selective laser melting.The effect of Cu content on phase formation,microstructure,and mechanical properties is investigated.The average volume fraction and width of theβphase decreases with increasing Cu content,while a more amorphous phase and the(Ti,Zr)_(2)Cu phase forms.In the center zone of the molten pool,theβphase grows in the direction of the temperature gradient,and the amorphous phase distributes among theβphases.This occurs using:sphere morphology(for x=5),a more continuous elongated sphere and network morphology(for x=10),and network morphology(for x=15),respectively.In the edge zone of the molten pool,due to the smaller cooling rate and the existence of a partially molten zone,theβphase becomes coarser,and an amorphous phase forms for more continuous networks.Furthermore,the hardness improves significantly with increasing Cu content.No crack is found for x=5.Although the average volume fraction of theβphase for x=5 is about 90%,the compression yield strength is 1386±64 MPa,reaching to an average level of conventionally fabricated counterparts,due to finer microstructure,and twinning and martensitic transformation of theβphase.