BNi-2/WC composite wear-resisting coating was prepared on carbon steel by the method of induction brazing.The microstructure and phase composition of the composite coating were analyzed,and the bonding strength and we...BNi-2/WC composite wear-resisting coating was prepared on carbon steel by the method of induction brazing.The microstructure and phase composition of the composite coating were analyzed,and the bonding strength and wear-resisting performance of the coating were tested.During the process of induction brazing,the tungsten carbide partially dissolves and reacts with the filler metal alloy to form NiW compound phase,which realizes the metallurgical combination of tungsten carbide and filler metal alloy.The matrix of the filler metal alloy consists of Ni solid solution and Ni_(3)B/Ni_(3)Si eutectic phase,and the metallurgical diffusion reaction occurs between the filler metal alloy and the steel matrix.The mechanical analysis results show that the self-strength of the composite coating reaches 140 MPa and the bonding strength of the filler metal alloy to the steel matrix reaches 360 MPa.The dry sand rubber wheel wear testing machine showed that the coating weight loss was only 0.2824 g,which was only 1/5 of the weight loss of 65 Mn matrix under the same conditions.展开更多
采用钎焊对7A52铝合金和直径∅10 mm表面镀镍的氧化铝陶瓷球进行封装,研究了加热温度和保温时间对显微组织特征、特征点成分和抗剪强度的影响。结果表明,采用硅镁焊料的7A52铝合金和Al 2 O 3(Ni)陶瓷封接的最佳工艺参数:加热温度为590℃...采用钎焊对7A52铝合金和直径∅10 mm表面镀镍的氧化铝陶瓷球进行封装,研究了加热温度和保温时间对显微组织特征、特征点成分和抗剪强度的影响。结果表明,采用硅镁焊料的7A52铝合金和Al 2 O 3(Ni)陶瓷封接的最佳工艺参数:加热温度为590℃,压力2 MPa,保温时间1 h,反应层厚度在10~27μm,接头达到的最大抗剪强度为24.8 MPa,接头界面结构为Al 2 O 3陶瓷/Al-Ni金属间化合物/Al-Si共晶/7A52铝合金。展开更多
Development of the technological process for brazing of heat-resistant copper alloy strengthened with Al2O3 oxide particles is an important task of fabrication of high-temperature application structures. As mechanical...Development of the technological process for brazing of heat-resistant copper alloy strengthened with Al2O3 oxide particles is an important task of fabrication of high-temperature application structures. As mechanical properties of the brazed joints directly depend on the structural factor and morphological peculiarities of the brazed seams, the latter are of technological interest in terms of making of permanent joints. This study gives results of X-ray spectral microanalysis of the brazed joints on dispersion-strengthened copper alloy （ Gridcop Al-25 ） produced by using the Ti-Cu system adhesion-active brazing filler alloy, different heat sources and temperature-time parameters of the brazing process. Shown are differences in formation of structure of the seams made by vacuum brazing using radiation and high-frequency heating. Vacuum brazing with radiation heating provides the homogeneous seams with crystallisation of the phases based on the CuTi and CuTi2 compounds in the form of discrete faceted particles 2 - 9μm in size against the background of the copper matrix. Based on investigation of structural peculiarities of the brazed seams, the temperature-time conditions of vacuum brazing with radiation heating were selected for manufacture of specimens for mechanical tests. Analysis of the results of strength tests of the butt brazed specimens proved the expediency of preliminary heat treatment of the base material, providing strength of the joints at a level of about 92% of that of the base material.展开更多
Al2O3 and Ti-6Al-4V alloy were brazed with Ag-Cu-Ti ＋B fillers in different brazing conditions. Effects of brazing temperature, holding time and additive Ti content on joints microstructure and shear strength were in...Al2O3 and Ti-6Al-4V alloy were brazed with Ag-Cu-Ti ＋B fillers in different brazing conditions. Effects of brazing temperature, holding time and additive Ti content on joints microstructure and shear strength were investigated by scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction, transmission electron microscopy and shear testing. Results indicate that TiCu and Ti（Cu,Al） decrease, but Ti2Cu and -Ti2（Cu,Al） increase in brazing seam with increasing brazing temperature, holding time and additive Ti content. Area consisting of Ti3（Cu,Al）30 and TiO near Al2O3 becomes gradually discontinuous from continuity when brazing temperature rises or holding time extends. As Ti additive content increases, TiO is absent near Al2O3, area consisting of only Ti3（Cu,Al）30 thickens. TiB whiskers are in situ synthesized by Ti and B atoms during brazing process. The brazing temperature, holding time and additive Ti content on joints microstructure influence the joints shear strength directly. The shear strength of joints, obtained at 850 ℃ holding for 10 min, reaches the maximum of 78 MPa. According to the experimental results, phase diagram and thermodynamics calculation, the interface evolution mechanism of the Al2O3/Ti-6Al-4V alloy joint was analyzed.展开更多
Effect of post-welding heat treatment on the microstructure and properties of BNi-2 brazing coating was analyzed. The phase transformation in the heat treatment process was analyzed by high temperature metallographic ...Effect of post-welding heat treatment on the microstructure and properties of BNi-2 brazing coating was analyzed. The phase transformation in the heat treatment process was analyzed by high temperature metallographic microscope, scanning electron microscope and X-ray diffraction, and the microhardness after the post heat treatment was tested by microhardness tester. The results show that the microstructure of brazing BNi-2 brazing coating is mainly CrB phase, Ni solid solution phase and eutectic phase of Ni_(3)B and Ni_(3)Si. After brazing,the overall hardness value is higher, generally higher than 510 HV, and the microhardness in some areas is higher than 700 HV. After quenching, the solid solution phase of Ni increased, and the eutectic phase of Ni and Ni_(3)Si decreased, leading to the softening of the brazing coating, the area whose microhardness in the range of 342 HV–454 HV increased. After tempering the brazed coating samples, the eutectic phases of Ni and Ni_(3)Si grew and the hardness recovered, but the overall hardness distribution was still lower than the brazing one. The results of the brazing post-heat treatment test show that the post-welding heat treatment will bring adverse effects on the hardness distribution of the coating, which may affect the wear resistance of the coating.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.U2004186).
文摘BNi-2/WC composite wear-resisting coating was prepared on carbon steel by the method of induction brazing.The microstructure and phase composition of the composite coating were analyzed,and the bonding strength and wear-resisting performance of the coating were tested.During the process of induction brazing,the tungsten carbide partially dissolves and reacts with the filler metal alloy to form NiW compound phase,which realizes the metallurgical combination of tungsten carbide and filler metal alloy.The matrix of the filler metal alloy consists of Ni solid solution and Ni_(3)B/Ni_(3)Si eutectic phase,and the metallurgical diffusion reaction occurs between the filler metal alloy and the steel matrix.The mechanical analysis results show that the self-strength of the composite coating reaches 140 MPa and the bonding strength of the filler metal alloy to the steel matrix reaches 360 MPa.The dry sand rubber wheel wear testing machine showed that the coating weight loss was only 0.2824 g,which was only 1/5 of the weight loss of 65 Mn matrix under the same conditions.
文摘Development of the technological process for brazing of heat-resistant copper alloy strengthened with Al2O3 oxide particles is an important task of fabrication of high-temperature application structures. As mechanical properties of the brazed joints directly depend on the structural factor and morphological peculiarities of the brazed seams, the latter are of technological interest in terms of making of permanent joints. This study gives results of X-ray spectral microanalysis of the brazed joints on dispersion-strengthened copper alloy （ Gridcop Al-25 ） produced by using the Ti-Cu system adhesion-active brazing filler alloy, different heat sources and temperature-time parameters of the brazing process. Shown are differences in formation of structure of the seams made by vacuum brazing using radiation and high-frequency heating. Vacuum brazing with radiation heating provides the homogeneous seams with crystallisation of the phases based on the CuTi and CuTi2 compounds in the form of discrete faceted particles 2 - 9μm in size against the background of the copper matrix. Based on investigation of structural peculiarities of the brazed seams, the temperature-time conditions of vacuum brazing with radiation heating were selected for manufacture of specimens for mechanical tests. Analysis of the results of strength tests of the butt brazed specimens proved the expediency of preliminary heat treatment of the base material, providing strength of the joints at a level of about 92% of that of the base material.
基金the National Natural Science Foundation of China (Grant Nos.51275135,51105107 and 51021002)the Natural Science Foundation of Heilongjiang Province,China (Grant No.QC2011C044)the Specialized Research Fund for the Doctoral Program of Higher Education,China (Grant No.20112302130005)
文摘Al2O3 and Ti-6Al-4V alloy were brazed with Ag-Cu-Ti ＋B fillers in different brazing conditions. Effects of brazing temperature, holding time and additive Ti content on joints microstructure and shear strength were investigated by scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction, transmission electron microscopy and shear testing. Results indicate that TiCu and Ti（Cu,Al） decrease, but Ti2Cu and -Ti2（Cu,Al） increase in brazing seam with increasing brazing temperature, holding time and additive Ti content. Area consisting of Ti3（Cu,Al）30 and TiO near Al2O3 becomes gradually discontinuous from continuity when brazing temperature rises or holding time extends. As Ti additive content increases, TiO is absent near Al2O3, area consisting of only Ti3（Cu,Al）30 thickens. TiB whiskers are in situ synthesized by Ti and B atoms during brazing process. The brazing temperature, holding time and additive Ti content on joints microstructure influence the joints shear strength directly. The shear strength of joints, obtained at 850 ℃ holding for 10 min, reaches the maximum of 78 MPa. According to the experimental results, phase diagram and thermodynamics calculation, the interface evolution mechanism of the Al2O3/Ti-6Al-4V alloy joint was analyzed.
基金Zhongyuan Leading Talents of Science and Technology Innovation(ZYQR20180030)Zhengzhou major Science and Technology Innovation Project(2019CXZX0065)Major Science and Technology Projects of Henan Province(191110210100)。
文摘Effect of post-welding heat treatment on the microstructure and properties of BNi-2 brazing coating was analyzed. The phase transformation in the heat treatment process was analyzed by high temperature metallographic microscope, scanning electron microscope and X-ray diffraction, and the microhardness after the post heat treatment was tested by microhardness tester. The results show that the microstructure of brazing BNi-2 brazing coating is mainly CrB phase, Ni solid solution phase and eutectic phase of Ni_(3)B and Ni_(3)Si. After brazing,the overall hardness value is higher, generally higher than 510 HV, and the microhardness in some areas is higher than 700 HV. After quenching, the solid solution phase of Ni increased, and the eutectic phase of Ni and Ni_(3)Si decreased, leading to the softening of the brazing coating, the area whose microhardness in the range of 342 HV–454 HV increased. After tempering the brazed coating samples, the eutectic phases of Ni and Ni_(3)Si grew and the hardness recovered, but the overall hardness distribution was still lower than the brazing one. The results of the brazing post-heat treatment test show that the post-welding heat treatment will bring adverse effects on the hardness distribution of the coating, which may affect the wear resistance of the coating.
