High-resolution atomic-beam laser spectroscopy has been performed to study Stark effect of Ba atom. Stark spectra have been observed at various electric fields for Ba highly excited states. The scalar polarizability o...High-resolution atomic-beam laser spectroscopy has been performed to study Stark effect of Ba atom. Stark spectra have been observed at various electric fields for Ba highly excited states. The scalar polarizability of the transition from 6s5d3D2 to 5d6p3F3 at 728.0 nm and the tensor polarizability of the 3F3 level have been determined for the first time, to be αs = -89.8 (12) kHz/(kV/cm)2 and αt = -133.7 (20) kHz/(kV/cm)2, respectively.展开更多
One of the basic ingredients in conventional preparation of cuprates-based superconducting materials such as the Nd-Ba-Cu-O superconducting system, especially the Nd1Ba2Cu3O7-δ phase is Barium Carbonate (BaCO3). It h...One of the basic ingredients in conventional preparation of cuprates-based superconducting materials such as the Nd-Ba-Cu-O superconducting system, especially the Nd1Ba2Cu3O7-δ phase is Barium Carbonate (BaCO3). It has the potential to produce the carbon dioxide (CO2) air pollutant. Therefore it is necessary to look for other materials as the source of Ba atom which does not produce CO2 gas. In this research has been successfully made the Nd1Ba2Cu3O7-δ phase with the Barium Hydroxide Octahydrate (Ba(OH)2·8H2O) as a source of Ba atom. The results of the characterization XRD has been shown the main peaks of the Nd1Ba2Cu3O7-δ phase. Refinement of the XRD data by using Rietica software, obtained the value of GofF (Goodness of Fit) = 1.7023 and lattice parameter a ≈ b < c/3 with a value of c/3 = 3.9275 A.展开更多
High sensitive immunoassay platforms have gained intense attention due to their vital roles in early-stage disease diagnosis and therapeutic information feedback. Although random covalent-binding of antibody has been ...High sensitive immunoassay platforms have gained intense attention due to their vital roles in early-stage disease diagnosis and therapeutic information feedback. Although random covalent-binding of antibody has been widely adopted in immunoassays due to its simplicity and effectiveness, it readily loses its activity and fails to exhibit high antigen-binding capacity. In this work, copolymer of zwitterionic sulfobetaine methacrylate（SBMA） and glycidyl methacrylate（GMA） brushes were immobilized onto inert polypropylene（PP） via surface-initiated atom transfer radical polymerization（ATRP） based on biomimetic dopamine pretreatment. Subsequently, boronic acid（BA） groups were covalently bonded via active GMA units, followed by the introduction of oriented immobilization of antibody. Owing to the oriented immobilization of antibody facilitated by BA groups in polymer brush, the bioactivity of antibody is well preserved, which endows the surface with significantly enhanced antigen-binding capacity. Moreover, the existence of SBMA segments in polymer brushes renders the surface high resistance to nonspecific protein adsorption, significantly alleviating the signal interference of antigen recognition. This strategy could find potential applications in developing high sensitive immunoassay platforms based on the different substrates.展开更多
文摘High-resolution atomic-beam laser spectroscopy has been performed to study Stark effect of Ba atom. Stark spectra have been observed at various electric fields for Ba highly excited states. The scalar polarizability of the transition from 6s5d3D2 to 5d6p3F3 at 728.0 nm and the tensor polarizability of the 3F3 level have been determined for the first time, to be αs = -89.8 (12) kHz/(kV/cm)2 and αt = -133.7 (20) kHz/(kV/cm)2, respectively.
文摘One of the basic ingredients in conventional preparation of cuprates-based superconducting materials such as the Nd-Ba-Cu-O superconducting system, especially the Nd1Ba2Cu3O7-δ phase is Barium Carbonate (BaCO3). It has the potential to produce the carbon dioxide (CO2) air pollutant. Therefore it is necessary to look for other materials as the source of Ba atom which does not produce CO2 gas. In this research has been successfully made the Nd1Ba2Cu3O7-δ phase with the Barium Hydroxide Octahydrate (Ba(OH)2·8H2O) as a source of Ba atom. The results of the characterization XRD has been shown the main peaks of the Nd1Ba2Cu3O7-δ phase. Refinement of the XRD data by using Rietica software, obtained the value of GofF (Goodness of Fit) = 1.7023 and lattice parameter a ≈ b < c/3 with a value of c/3 = 3.9275 A.
基金financially supported by the Research Program Funds of Jilin University(Nos.419080500665 and 451170301076)
文摘High sensitive immunoassay platforms have gained intense attention due to their vital roles in early-stage disease diagnosis and therapeutic information feedback. Although random covalent-binding of antibody has been widely adopted in immunoassays due to its simplicity and effectiveness, it readily loses its activity and fails to exhibit high antigen-binding capacity. In this work, copolymer of zwitterionic sulfobetaine methacrylate（SBMA） and glycidyl methacrylate（GMA） brushes were immobilized onto inert polypropylene（PP） via surface-initiated atom transfer radical polymerization（ATRP） based on biomimetic dopamine pretreatment. Subsequently, boronic acid（BA） groups were covalently bonded via active GMA units, followed by the introduction of oriented immobilization of antibody. Owing to the oriented immobilization of antibody facilitated by BA groups in polymer brush, the bioactivity of antibody is well preserved, which endows the surface with significantly enhanced antigen-binding capacity. Moreover, the existence of SBMA segments in polymer brushes renders the surface high resistance to nonspecific protein adsorption, significantly alleviating the signal interference of antigen recognition. This strategy could find potential applications in developing high sensitive immunoassay platforms based on the different substrates.
