Erlangshan Pluton from Urad Zhongqi, central Inner Mongolia, is located in the middle segment of the northern margin of the North China Plate. The rocks consist mainly of diorites with gneissic structure. Petrochemica...Erlangshan Pluton from Urad Zhongqi, central Inner Mongolia, is located in the middle segment of the northern margin of the North China Plate. The rocks consist mainly of diorites with gneissic structure. Petrochemical characteristics reveal that the diorites belong to metaluminous, high- potassium calc-alkaline series, with chemical signatures of I-type granites. They are characterized by low SiOz contents (56.63%-58.53%) and A/CNK (0.90-0.96), high Al2O3 contents (17.30%-17.96%) and Na20/K20 ratios (1.20-1.70), enrichment in large ion lithophile elements (LILE, e.g., Ba=556-915 ppm, Sr=463-595 ppm), and relative depletion in high field strength elements (HFSE, e.g., Nb, Ta, Ti) in primitive mantle-normalized spidergram, and right-declined rare earth element patterns with slightly negative Eu anomalies (8Eu=0.72-0.90). They have Sr/Y ratios (20-25) evidently less than Kebu Pluton (49-75) to its east. Sensitive high resolution ion micro-probe U-Pb zircon dating of the diorites has yielded an intrusive age of 270±8 Ma. This leads us to conclude that Erlangshan diorites were formed by mixing between the middle or lower crustal-derived magma and minor mantle-derived mafic magma, followed by fractional crystallization, which was trigged by crustal extension and fault activity in post-collisional setting.展开更多
The Nagercoil block is the southernmost crustal segment of the Southern Granulite Terrane(SGT)in India and is mainly composed of charnockitic rocks and felsic gneisses(charnockite suite).In this study,we present petro...The Nagercoil block is the southernmost crustal segment of the Southern Granulite Terrane(SGT)in India and is mainly composed of charnockitic rocks and felsic gneisses(charnockite suite).In this study,we present petrologic,geochemical,zircon U-Pb,REE,and Hf isotopic studies on the charnockites and leucogneiss from the Nagercoil block.Based on field investigations and petrologic studies,the charnockites can be divided into garnet-bearing and garnet-absent anhydrous granulite facies rocks with orthopyroxene.The charnockites and leucogneiss show transition from adakites to non-adakitic magmatic rocks,with enrichment in LREEs(light rare earth elements)and LILEs(large ion lithophile elements),and depletion in HREEs(heavy rare earth elements)and HFSEs(high field strength elements).Some of the charnockites and the leucogneiss show typical HSA(high silica adakite)characters,(high SiO_(2),Al_(2)O_(3),Ba-Sr,La/Yb,and Sr/Y).The HSA is considered to have formed from the interaction of slab derived melts and peridotitic mantle wedge.The high Ba-Sr features were possibly inherited from subducted oceanic crust melting under high thermal gradient during Precambrian.The magmas were underplated and subjected to fractional crystallization.Zircon grains from the charnockite and leucogneiss show zoned magmatic cores surrounded by structureless metamorphic rims.Magmatic zircon grains from the charnockites show ages ranging from 1983±8.8 Ma to 2046±14 Ma,and the metamorphic domains show an age range of 502±14 Ma to 547±8.7 Ma.Zircon from the leucogneiss yielded magmatic and metamorphic ages of 1860±20 Ma and 575.6±8.8 Ma.Both charnockites and leucogneiss show two prominent age peaks at 1987 Ma and 568 Ma.The REE data of the zircon grains show LREE depletion and HREE enrichment,with the metamorphic grains showing more depletion in HREE.Zircon Hf isotopic data of the magmatic cores of zircon grains from the charnockite yieldedε_(Hf)(t)values from-1.17 to 0.46 with T_(DM)and T_(DM)~C and age peaks at 2392 Ma and 2638 Ma,suggesting Neoarchean to Paleoproterozoic juvenile sources.We suggest that the high Ba-Sr adakitic charnockite suite from the Nagercoil block formed in a Paleoproterozoic magmatic arc setting during the assembly of the Columbia supercontinent,and underwent high-grade metamorphism associated with the amalgamation of the Gondwana supercontinent during the late Neoproterozoic-Cambrian.Our study provides new insights into the vestiges of Columbia fragments within the Gondwana assembly with two distinct cycles of crustal evolution.展开更多
Voluminous granitoids are widely distributed in the Langshan region,northeast of the Alxa block,and record the evolutionary processes of the southern Central Asian Orogenic Belt.The Dabashan pluton was emplaced into t...Voluminous granitoids are widely distributed in the Langshan region,northeast of the Alxa block,and record the evolutionary processes of the southern Central Asian Orogenic Belt.The Dabashan pluton was emplaced into the Paleoproterozoic Diebusige complex.Early Carboniferous zircon LA-ICP MS U-Pb ages were from 327 Ma to 346 Ma.The Dabashan pluton can be classified as monzogranite and syenogranite,and exhibits high K2 O contents and K2 O/Na2 O ratios,which reveal a high-K calc-alkaline nature.The samples display strongly fractionated REE patterns,and are enriched in large ion lithophile elements(LILE)relative to high field strength elements(HFSE).The Dabashan plutons display unusually high Ba(823–2817 ppm)and Sr(166–520 ppm)contents and K/Rb ratios(315–627),but low Rb/Ba ratios(0.02–0.14),and exhibit fertile zircon Hf isotopic compositions[εHf(t)=-14 to-20],which are comparable to those of typical high Ba–Sr granitoids.Based on the geochemical compositions of the samples,we suggest that subducted sediments and ancient crustal materials both played important roles in their generation.Basaltic melts were derived from partial melting of subcontinental lithophile mantle metasomatized by subducted sediment-related melts with residual garnet in the source,which caused partial melting of ancient lower crust.Magmas derived from underplating ascended and emplaced in the middle–upper crust at different depths.The resultant magmas experienced some degree of fractional crystallization during their ascent.Given these geochemical characteristics,together with regional tectonic,magmatic,and structure analysis data,an active continental margin environment is proposed for the generation of these rocks.展开更多
The present study is a systematic effort to investigate the structure-sensitive magnetic parameters of Ce^(3+) substituted Ba-Sr hexaferrite nanocrystals chemically formulated as Ba_(0.5)Sr_(0.5)Ce_(x)Fe_(12-x)O_(19) ...The present study is a systematic effort to investigate the structure-sensitive magnetic parameters of Ce^(3+) substituted Ba-Sr hexaferrite nanocrystals chemically formulated as Ba_(0.5)Sr_(0.5)Ce_(x)Fe_(12-x)O_(19) where x=0.0-0.2 with Δx=0.05.The hexaferrite powders were prepared using the sol-gel self-ignition route and structurally characterized by means of powder X-ray diffraction and Fourier transform infrared spectroscopy.The creation of the M-type hexaferrite phase within the synthesized samples was revealed from the Rietveld refinement of the X-ray diffractograms.The occurrence of a secondary phase of CeO_(2) was revealed within the hexaferrites for the substitution,x> 0.The refined X-ray diffraction data were utilized to compute the lattice parameters,X-ray density,and lattice parameter ratio.The crystal structure plotted from the refined XRD data reveals the occupancy of the ions at different lattice sites.The XPS data of the hexaferrite were analyzed to confirm the oxidation states of the constituent elements.The nanocrystalline nature of the hexaferrites was revealed from the crystallite sizes calculated using Scherer's formula.The analysis of FTIR spectra confirms that only a fraction of Ce^(3+)accommodated in the lattice and the remaining Ce content reside in the form of the CeO_(2) phase.The morphology of the hexaferrites was analyzed from the FESEM profiles of the ferrite samples.The magnetic behavior study was performed by analyzing the Curie temperature,hysteresis loops,and hyperfine interactions by means of susceptibility,V.S.M,and Mossbauer spectroscopy,respectively.The hexaferrites with increasing coercivity,decreasing saturation magnetization,and decreasing Curie temperature are reported in the study.The substituted Ce^(3+)ions inhibit the grain growth and create lattice imperfections giving rise to hexaferrites with tuned magnetic parameters suitable for different applications.展开更多
The origin of the Mesozoic high Ba-Sr(HBS)granitic magmatism in the Jiaodong Peninsula remains controversial in petrogenesis models and geodynamic settings.Here,we report zircon UPb age,trace element and oxygen isotop...The origin of the Mesozoic high Ba-Sr(HBS)granitic magmatism in the Jiaodong Peninsula remains controversial in petrogenesis models and geodynamic settings.Here,we report zircon UPb age,trace element and oxygen isotope compositions,and whole-rock major-trace element and Sr-Nd isotope compositions of the HBS Yashan granodiorite.The zircon U-Pb age of~118 Ma denotes that the Yashan granodiorite belongs to the Weideshan-stage magmatic activity,which is consistent with the age of Mo mineralization in the Yashan intrusion.The low Sr/Y(48.8-115)and high(La/Yb)_(N)(23.8-50.4)ratios of the Yashan granodiorite are analogous to adakitic features derived from the lower-crust.This is also supported by the whole-rock initial^(87)Sr/^(86)Sr ratios(0.7096-0.7103)and zircon δ^(18) O values(6.79‰-8.03‰).Contemporaneous mantle-derived mafic microgranular enclaves indicate the involvement of the metasomatized lithospheric mantle.The high magma oxygen fugacity of the Yashan intrusion as indicated by high zircon Ce^(4+)/Ce^(3+) values suggests the involvement of plate subduction.The obviously lower Dy/Yb,La/Yb and Sr/Y ratios of magmatic rocks in the Weideshan-stage than those in the early-stage imply lithospheric thinning of the eastern North China Craton.We propose that the Yashan HBS granodiorite was formed by crust-mantle interactions during slab rollback.展开更多
基金supported by the NationalNatural Science Foundation of China(No.40672146)
文摘Erlangshan Pluton from Urad Zhongqi, central Inner Mongolia, is located in the middle segment of the northern margin of the North China Plate. The rocks consist mainly of diorites with gneissic structure. Petrochemical characteristics reveal that the diorites belong to metaluminous, high- potassium calc-alkaline series, with chemical signatures of I-type granites. They are characterized by low SiOz contents (56.63%-58.53%) and A/CNK (0.90-0.96), high Al2O3 contents (17.30%-17.96%) and Na20/K20 ratios (1.20-1.70), enrichment in large ion lithophile elements (LILE, e.g., Ba=556-915 ppm, Sr=463-595 ppm), and relative depletion in high field strength elements (HFSE, e.g., Nb, Ta, Ti) in primitive mantle-normalized spidergram, and right-declined rare earth element patterns with slightly negative Eu anomalies (8Eu=0.72-0.90). They have Sr/Y ratios (20-25) evidently less than Kebu Pluton (49-75) to its east. Sensitive high resolution ion micro-probe U-Pb zircon dating of the diorites has yielded an intrusive age of 270±8 Ma. This leads us to conclude that Erlangshan diorites were formed by mixing between the middle or lower crustal-derived magma and minor mantle-derived mafic magma, followed by fractional crystallization, which was trigged by crustal extension and fault activity in post-collisional setting.
基金funded by Foreign Expert grants to M.Santosh from the China University of Geosciences Beijing,Chinapartially supported by NRF 2017R1A6A1A07015374 and NRF 2019R1A2C1002211supervised by the Ministry of Science and ICT,Korea to Sanghoon Kwonfunded the Fundamental Research Fund of Central Universities(Grant 2652019210)through CUGB,China。
文摘The Nagercoil block is the southernmost crustal segment of the Southern Granulite Terrane(SGT)in India and is mainly composed of charnockitic rocks and felsic gneisses(charnockite suite).In this study,we present petrologic,geochemical,zircon U-Pb,REE,and Hf isotopic studies on the charnockites and leucogneiss from the Nagercoil block.Based on field investigations and petrologic studies,the charnockites can be divided into garnet-bearing and garnet-absent anhydrous granulite facies rocks with orthopyroxene.The charnockites and leucogneiss show transition from adakites to non-adakitic magmatic rocks,with enrichment in LREEs(light rare earth elements)and LILEs(large ion lithophile elements),and depletion in HREEs(heavy rare earth elements)and HFSEs(high field strength elements).Some of the charnockites and the leucogneiss show typical HSA(high silica adakite)characters,(high SiO_(2),Al_(2)O_(3),Ba-Sr,La/Yb,and Sr/Y).The HSA is considered to have formed from the interaction of slab derived melts and peridotitic mantle wedge.The high Ba-Sr features were possibly inherited from subducted oceanic crust melting under high thermal gradient during Precambrian.The magmas were underplated and subjected to fractional crystallization.Zircon grains from the charnockite and leucogneiss show zoned magmatic cores surrounded by structureless metamorphic rims.Magmatic zircon grains from the charnockites show ages ranging from 1983±8.8 Ma to 2046±14 Ma,and the metamorphic domains show an age range of 502±14 Ma to 547±8.7 Ma.Zircon from the leucogneiss yielded magmatic and metamorphic ages of 1860±20 Ma and 575.6±8.8 Ma.Both charnockites and leucogneiss show two prominent age peaks at 1987 Ma and 568 Ma.The REE data of the zircon grains show LREE depletion and HREE enrichment,with the metamorphic grains showing more depletion in HREE.Zircon Hf isotopic data of the magmatic cores of zircon grains from the charnockite yieldedε_(Hf)(t)values from-1.17 to 0.46 with T_(DM)and T_(DM)~C and age peaks at 2392 Ma and 2638 Ma,suggesting Neoarchean to Paleoproterozoic juvenile sources.We suggest that the high Ba-Sr adakitic charnockite suite from the Nagercoil block formed in a Paleoproterozoic magmatic arc setting during the assembly of the Columbia supercontinent,and underwent high-grade metamorphism associated with the amalgamation of the Gondwana supercontinent during the late Neoproterozoic-Cambrian.Our study provides new insights into the vestiges of Columbia fragments within the Gondwana assembly with two distinct cycles of crustal evolution.
基金supported by the National Key Research and Development Program of China from the Ministry of ScienceandTechnologyofChina(No.2017YFC0601301)the National Natural Science Foundation of China(41502214,41230207 and 41572190)+5 种基金the Outlay Research Fund of Institute of Geology,Chinese Academy of Geological Sciences(J1706)the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(XDB18020203)the CPSF-CAS Joint Foundation for Excellent Postdoctoral Fellows(Grant no.2015LH0049)the China Postdoctoral Foundation funded project(2016M590990)the Key Research Program of Frontier Sciences,CAS(QYZDJSSW-SYS012)China Geological Survey(12120115069601)
文摘Voluminous granitoids are widely distributed in the Langshan region,northeast of the Alxa block,and record the evolutionary processes of the southern Central Asian Orogenic Belt.The Dabashan pluton was emplaced into the Paleoproterozoic Diebusige complex.Early Carboniferous zircon LA-ICP MS U-Pb ages were from 327 Ma to 346 Ma.The Dabashan pluton can be classified as monzogranite and syenogranite,and exhibits high K2 O contents and K2 O/Na2 O ratios,which reveal a high-K calc-alkaline nature.The samples display strongly fractionated REE patterns,and are enriched in large ion lithophile elements(LILE)relative to high field strength elements(HFSE).The Dabashan plutons display unusually high Ba(823–2817 ppm)and Sr(166–520 ppm)contents and K/Rb ratios(315–627),but low Rb/Ba ratios(0.02–0.14),and exhibit fertile zircon Hf isotopic compositions[εHf(t)=-14 to-20],which are comparable to those of typical high Ba–Sr granitoids.Based on the geochemical compositions of the samples,we suggest that subducted sediments and ancient crustal materials both played important roles in their generation.Basaltic melts were derived from partial melting of subcontinental lithophile mantle metasomatized by subducted sediment-related melts with residual garnet in the source,which caused partial melting of ancient lower crust.Magmas derived from underplating ascended and emplaced in the middle–upper crust at different depths.The resultant magmas experienced some degree of fractional crystallization during their ascent.Given these geochemical characteristics,together with regional tectonic,magmatic,and structure analysis data,an active continental margin environment is proposed for the generation of these rocks.
文摘The present study is a systematic effort to investigate the structure-sensitive magnetic parameters of Ce^(3+) substituted Ba-Sr hexaferrite nanocrystals chemically formulated as Ba_(0.5)Sr_(0.5)Ce_(x)Fe_(12-x)O_(19) where x=0.0-0.2 with Δx=0.05.The hexaferrite powders were prepared using the sol-gel self-ignition route and structurally characterized by means of powder X-ray diffraction and Fourier transform infrared spectroscopy.The creation of the M-type hexaferrite phase within the synthesized samples was revealed from the Rietveld refinement of the X-ray diffractograms.The occurrence of a secondary phase of CeO_(2) was revealed within the hexaferrites for the substitution,x> 0.The refined X-ray diffraction data were utilized to compute the lattice parameters,X-ray density,and lattice parameter ratio.The crystal structure plotted from the refined XRD data reveals the occupancy of the ions at different lattice sites.The XPS data of the hexaferrite were analyzed to confirm the oxidation states of the constituent elements.The nanocrystalline nature of the hexaferrites was revealed from the crystallite sizes calculated using Scherer's formula.The analysis of FTIR spectra confirms that only a fraction of Ce^(3+)accommodated in the lattice and the remaining Ce content reside in the form of the CeO_(2) phase.The morphology of the hexaferrites was analyzed from the FESEM profiles of the ferrite samples.The magnetic behavior study was performed by analyzing the Curie temperature,hysteresis loops,and hyperfine interactions by means of susceptibility,V.S.M,and Mossbauer spectroscopy,respectively.The hexaferrites with increasing coercivity,decreasing saturation magnetization,and decreasing Curie temperature are reported in the study.The substituted Ce^(3+)ions inhibit the grain growth and create lattice imperfections giving rise to hexaferrites with tuned magnetic parameters suitable for different applications.
基金supported by the National Key R&D Program of China(No.2016YFC0600408)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB42020203)。
文摘The origin of the Mesozoic high Ba-Sr(HBS)granitic magmatism in the Jiaodong Peninsula remains controversial in petrogenesis models and geodynamic settings.Here,we report zircon UPb age,trace element and oxygen isotope compositions,and whole-rock major-trace element and Sr-Nd isotope compositions of the HBS Yashan granodiorite.The zircon U-Pb age of~118 Ma denotes that the Yashan granodiorite belongs to the Weideshan-stage magmatic activity,which is consistent with the age of Mo mineralization in the Yashan intrusion.The low Sr/Y(48.8-115)and high(La/Yb)_(N)(23.8-50.4)ratios of the Yashan granodiorite are analogous to adakitic features derived from the lower-crust.This is also supported by the whole-rock initial^(87)Sr/^(86)Sr ratios(0.7096-0.7103)and zircon δ^(18) O values(6.79‰-8.03‰).Contemporaneous mantle-derived mafic microgranular enclaves indicate the involvement of the metasomatized lithospheric mantle.The high magma oxygen fugacity of the Yashan intrusion as indicated by high zircon Ce^(4+)/Ce^(3+) values suggests the involvement of plate subduction.The obviously lower Dy/Yb,La/Yb and Sr/Y ratios of magmatic rocks in the Weideshan-stage than those in the early-stage imply lithospheric thinning of the eastern North China Craton.We propose that the Yashan HBS granodiorite was formed by crust-mantle interactions during slab rollback.
