We report a newly found strong disturbing effect orAl addition to the intensity ratios of blue and green emissions from single host full-colour phosphor of Ba3MgSi2-xAlxO8：0.02Eu^2＋, 0.1Mn^2＋ for near-UV excited wh...We report a newly found strong disturbing effect orAl addition to the intensity ratios of blue and green emissions from single host full-colour phosphor of Ba3MgSi2-xAlxO8：0.02Eu^2＋, 0.1Mn^2＋ for near-UV excited white light. The phase-pure silicate phosphor in the size of around 4μm is prepared by salt-assisted spray pyrolysis route, having three-colour emissions at the wavelength peak values of 437nm, 500 nm and 608 nm simultaneously under the excitation of 375 nm. The amount variation orAl ion added to the phosphor host results in a drastic change of the intensity ratio between green and blue emissions, while the intensity of red light keeps unchanged. As a consequence, the combination of three colours lies in the white light region and can be tuned by precisely controlled addition oral content. The Raman spectroscopy verifies the modifying effect oral ion to the tetrahedral network in silicate hosts. We assume that by addition of Al ion, the amount of those two kinds of Eu^2＋ substituting for those two kinds of Ba^2＋ lattice sites with distinct energy levels of blue and green featured emissions can be adjusted to contribute to diversification of the ratios of blue and green emissions.展开更多
Fluorescence enhancement of red and blue concurrently emitting Ba3MgSi2O8:Eu2+,Mn2+ phosphors for plant cultivation has been investigated by Dy3+ addition.The Ba3MgSi2O8:Eu2+,Mn2+,Dy3+(BMS-EMD) phosphors have two-colo...Fluorescence enhancement of red and blue concurrently emitting Ba3MgSi2O8:Eu2+,Mn2+ phosphors for plant cultivation has been investigated by Dy3+ addition.The Ba3MgSi2O8:Eu2+,Mn2+,Dy3+(BMS-EMD) phosphors have two-color emissions at the wavelength peak values of 437 nm and 620 nm at the excitation of 350 nm.The two emission bands are coincident with the absorption spectrum for photosynthesis of plants.An obvious enhancement effect has been observed upon addition of Dy3+ with amount of 0.03 mol%,in which the intensities of both blue and red bands reach a maximum.The origin of red and blue emission bands is analysed.The photochromic parameters of the samples at the nearly UV excitation are tested.This fluoresence enhancement is of great significance for special solid state lighting equipment used in plant cultivation.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 50364002, and the Tianjin Natural Science Foundation （06YFJMJC02300）.
文摘We report a newly found strong disturbing effect orAl addition to the intensity ratios of blue and green emissions from single host full-colour phosphor of Ba3MgSi2-xAlxO8：0.02Eu^2＋, 0.1Mn^2＋ for near-UV excited white light. The phase-pure silicate phosphor in the size of around 4μm is prepared by salt-assisted spray pyrolysis route, having three-colour emissions at the wavelength peak values of 437nm, 500 nm and 608 nm simultaneously under the excitation of 375 nm. The amount variation orAl ion added to the phosphor host results in a drastic change of the intensity ratio between green and blue emissions, while the intensity of red light keeps unchanged. As a consequence, the combination of three colours lies in the white light region and can be tuned by precisely controlled addition oral content. The Raman spectroscopy verifies the modifying effect oral ion to the tetrahedral network in silicate hosts. We assume that by addition of Al ion, the amount of those two kinds of Eu^2＋ substituting for those two kinds of Ba^2＋ lattice sites with distinct energy levels of blue and green featured emissions can be adjusted to contribute to diversification of the ratios of blue and green emissions.
基金supported by National Natural Science Foundation of China (Grant No 50872091)the Natural Science Foundation of Tianjin,China(06YFJMJC02300,06TXTJJC14602)
文摘Fluorescence enhancement of red and blue concurrently emitting Ba3MgSi2O8:Eu2+,Mn2+ phosphors for plant cultivation has been investigated by Dy3+ addition.The Ba3MgSi2O8:Eu2+,Mn2+,Dy3+(BMS-EMD) phosphors have two-color emissions at the wavelength peak values of 437 nm and 620 nm at the excitation of 350 nm.The two emission bands are coincident with the absorption spectrum for photosynthesis of plants.An obvious enhancement effect has been observed upon addition of Dy3+ with amount of 0.03 mol%,in which the intensities of both blue and red bands reach a maximum.The origin of red and blue emission bands is analysed.The photochromic parameters of the samples at the nearly UV excitation are tested.This fluoresence enhancement is of great significance for special solid state lighting equipment used in plant cultivation.
