Highly-dispersed BaLuFs:yb3+/Er3+ nanocrystals were prepared by a facile potassium sodium tartrate- assisted hydrothermal method. The average particle size was approximately 20-25 nm. The formation mechanism is dis...Highly-dispersed BaLuFs:yb3+/Er3+ nanocrystals were prepared by a facile potassium sodium tartrate- assisted hydrothermal method. The average particle size was approximately 20-25 nm. The formation mechanism is discussed. Potassium sodium tartrate led to form a complex with an approximately three- dimensional network structure, which insured largely concurrent nucleation. As a result, we acquired uniform nanoparticles. The hydrothermal temperature, holding time, and pH value were important fac- tors affecting the formation of the BaLuF5 :yb3+/Er3+ nanocrystals. We investigated their influence on the formation and realized the optimal reaction parameters. Remarkably, potassium sodium tartrate also con- tributed to the biocompatibility and potential biomedical applications of BaLuFs :Yb3+/Er3+ nanocrystals by decomposing into small organic groups attached to the nanoparticles.展开更多
为提高聚合物光波导放大器的增益性能,利用高温法合成了Ba Lu F5∶Yb3+,Er3+纳米晶,并分别对纳米晶的形貌、晶体结构和近红外发射特性进行了表征。测试结果表明,纳米晶平均粒径为13 nm,并在1 530 nm处具有较强的发射,荧光半高宽为50 nm...为提高聚合物光波导放大器的增益性能,利用高温法合成了Ba Lu F5∶Yb3+,Er3+纳米晶,并分别对纳米晶的形貌、晶体结构和近红外发射特性进行了表征。测试结果表明,纳米晶平均粒径为13 nm,并在1 530 nm处具有较强的发射,荧光半高宽为50 nm。将合成的纳米晶掺杂入SU-8聚合物作为光波导放大器的芯层材料,使用光刻显影等工艺,在表面长有二氧化硅的硅衬底上制备出了聚合物光波导放大器。当980 nm波长泵浦光功率为280 m W、信号光波长为1 530 nm且功率为0.1 m W时,在长度为1.1 cm的光波导放大器中,获得了3.95 d B的相对增益。展开更多
文摘Highly-dispersed BaLuFs:yb3+/Er3+ nanocrystals were prepared by a facile potassium sodium tartrate- assisted hydrothermal method. The average particle size was approximately 20-25 nm. The formation mechanism is discussed. Potassium sodium tartrate led to form a complex with an approximately three- dimensional network structure, which insured largely concurrent nucleation. As a result, we acquired uniform nanoparticles. The hydrothermal temperature, holding time, and pH value were important fac- tors affecting the formation of the BaLuF5 :yb3+/Er3+ nanocrystals. We investigated their influence on the formation and realized the optimal reaction parameters. Remarkably, potassium sodium tartrate also con- tributed to the biocompatibility and potential biomedical applications of BaLuFs :Yb3+/Er3+ nanocrystals by decomposing into small organic groups attached to the nanoparticles.
文摘为提高聚合物光波导放大器的增益性能,利用高温法合成了Ba Lu F5∶Yb3+,Er3+纳米晶,并分别对纳米晶的形貌、晶体结构和近红外发射特性进行了表征。测试结果表明,纳米晶平均粒径为13 nm,并在1 530 nm处具有较强的发射,荧光半高宽为50 nm。将合成的纳米晶掺杂入SU-8聚合物作为光波导放大器的芯层材料,使用光刻显影等工艺,在表面长有二氧化硅的硅衬底上制备出了聚合物光波导放大器。当980 nm波长泵浦光功率为280 m W、信号光波长为1 530 nm且功率为0.1 m W时,在长度为1.1 cm的光波导放大器中,获得了3.95 d B的相对增益。