Background Absorption of Lutecium and Ytterbium Matrices in Graphite Furnace Atomic Absorption Spectrometry

The background absorption of Lu and Yb matrices was studied. The experimental results show that there is a significantly wavelength-dependent. The effects of ashing temperature, heating mode, atomization temperature, recording time and matrix modifiers affecting the non-specific absorption of Lu and Yb matrices were discussed.

A Study of the Background Absorption of Slurry Algae in the Graphite Furnace Atomic Absorption Spectrometry

In general, biological organisms have the ability to absorb a specific element selectively. Holcombe and his co-workers reported that copper, nickel and cobalt could be separated from riverine and sea-water samples and cadmium from river water samples by unicellular green algae and were determined by slurry GFAAS. Dar-

Comparison between Spectrophotometry and Gas Phase Molecular Absorption Spectrometry for Determination of Nitrite Nitrogen in Flue Gas

Spectrophotometry and gas phase molecular absorption spectrometry for determination of nitrite nitrogen in flue gas were compared.KOH absorption solution was used to absorb nitrite nitrogen in flue gas,and the concentration of nitrite nitrogen in the absorption solution was determined by spectrophotometry and gas phase molecular absorption spectrometry to obtain the concentration of nitrite nitrogen in flue gas.The experiments show that both methods are accurate and reliable.

A Study of the Background Absorption of Chitosan in the Graphite Furnace Atomic Absorption Spectrometry

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An Innovative Method for the Determination of Sulfur-containing Compounds by Vapor Molecular Absorption Spectrometry

Since the most sensitive resonance lines of nonmetallic elements are situated in vacuum ultraviolet region （below 190 nm）, they can not be directly determined with a common AAS instrument covering the spectral range from 190 to 700 nm. The molecular absorption spectrometry is often used for the determination of nonmetallic elements. Syty et al. used vapor molecular absorption spectrometry（VMAS） to determine the sulfur dioxide and sulfide, in which a hydrogen hollow cathode lamp was used as a continuum source to determine SO;at 210 nm and a deuterium arc

A method for absorption compensation based on adaptive molecular decomposition

In this paper,we present a new method for seismic stratigraphic absorption compensation based on the adaptive molecular decomposition.Using this method,we can remove most of the effects resulting from wavelets truncation and interference which usually exist in the common time-frequency absorption compensation method.Based on the assumption that the amplitude spectrum of the source wavelet is smooth,we first construct a set of adaptive Gabor frames based on the time-variant properties of the seismic signal to transform the signal into the time-frequency domain and then extract the slowly varying component（the wavelet＇s time-varying amplitude spectrum） in each window in the timefrequency domain.Then we invert the absorption compensation filter parameters with an objective function defined using the correlation coefficients in each window to get the corresponding compensation filters.Finally,we use these filters to compensate the timefrequency spectrum in each window and then transform the time-frequency spectrum to the time domain to obtain the absorption-compensated signal.By using adaptive molecular decomposition,this method can adapt to isolated and overlapped seismic signals from the complex layers in the inhomogeneous viscoelastic medium.The viability of the method is verified by synthetic and real data sets.

Background Absorption of TmCl_3 and Tm(NO_3)_3 Matrices in Graphite Furnace Atomic Absorption Spectrometry

The effects of background absorption of TmCl 3 and Tm(NO 3) 3 matrices in graphite furnace atomic absorption spectrometry(GFAAS) were inverstigated. The experiments demonstrated that the background absorption of Tm matrices is obviously wavelength dependent. The background absorption of TmCl 3 is larger than that of Tm(NO 3) 3, especially in short wavelength region. The background absorption of TmCl 3 is decreased significantly as the ashing temperature increases and that of Tm matrices is eliminated completely at about 1900 ℃. The time distribution of background signal is related to the atomization temperature and the heating mode of atomization HNO 3 can be used to reduce the background absorption of TmCl 3 matrix.

Investigation of Projectile Impact Behaviors of Graphene Aerogel Using Molecular Dynamics Simulations

Graphene aerogel(GA),as a novel solid material,has shown great potential in engineering applications due to its unique mechanical properties.In this study,the mechanical performance of GA under high-velocity projectile impacts is thoroughly investigated using full-atomic molecular dynamics(MD)simulations.The study results show that the porous structure and density are key factors determining the mechanical response of GA under impact loading.Specifically,the impact-induced penetration of the projectile leads to the collapse of the pore structure,causing stretching and subsequent rupture of covalent bonds in graphene sheets.Moreover,the effects of temperature on the mechanical performance of GA have been proven to be minimal,thereby highlighting the mechanical stability of GA over a wide range of temperatures.Finally,the energy absorption density(EAD)and energy absorption efficiency(EAE)metrics are adopted to assess the energy absorption capacity of GA during projectile penetration.The research findings of this work demonstrate the significant potential of GA for energy absorption applications.

Structure of Liquid Aluminum and Hydrogen Absorption

The hydrogen content in aluminum melts at different temperature was detected. The structure in aluminum melts was investigated by molecular dynamics simulation. The first peak position of pair correlation function, atomic coordination number and viscosity of aluminum melts were calculated and they changed abnormally in the same temperature range. The mechanism of hydrogen absorption has been discussed. From molecular dynamics calculations, the interdependence between melt structural properties and hydrogen absorption were obtained.

Oxidative Molecular Layer Deposition Tailoring Eco-Mimetic Nanoarchitecture to Manipulate Electromagnetic Attenuation and Self-Powered Energy Conversion

Advanced electromagnetic devices,as the pillars of the intelligent age,are setting off a grand transformation,redefining the structure of society to present pluralism and diversity.However,the bombardment of electromagnetic radiation on society is also increasingly serious along with the growing popularity of"Big Data".Herein,drawing wisdom and inspiration from nature,an eco-mimetic nanoarchitecture is constructed for the first time,highly integrating the advantages of multiple components and structures to exhibit excellent electromagnetic response.Its electromagnetic properties and internal energy conversion can be flexibly regulated by tailoring microstructure with oxidative molecular layer deposition(oMLD),providing a new cognition to frequency-selective microwave absorption.The optimal reflection loss reaches≈−58 dB,and the absorption frequency can be shifted from high frequency to low frequency by increasing the number of oMLD cycles.Meanwhile,a novel electromagnetic absorption surface is designed to enable ultra-wideband absorption,covering almost the entire K and Ka bands.More importantly,an ingenious self-powered device is constructed using the eco-mimetic nanoarchitecture,which can convert electromagnetic radiation into electric energy for recycling.This work offers a new insight into electromagnetic protection and waste energy recycling,presenting a broad application prospect in radar stealth,information communication,aerospace engineering,etc.

Absorption spectra and isotope shifts of the(2, 0),(3, 1), and(8, 5) bands of the A^2Π_u-X^2Σ_g^+ system of ^(15)N_2^+ in near infrared

The high-resolution absorption spectra of the （2,0）,（3,1）,and （8,5） bands of the A^2Π^u-X^2∑g^＋ system of ^15N2^＋ have been recorded by using velocity modulation spectroscopy technique in the near infrared region.The rotational constants of the X^2∑g^＋ and A^2Πu states of ^15N2^＋ were derived from the spectroscopic data.The isotope shifts of these bands of the A^2Πu-X^2∑g^＋ system of ^14N2^＋ and ^15N2^＋ were also analyzed and discussed.

Statistical method for predicting protein absorption peaks in terahertz region

Terahertz vibrational spectroscopy has recently been demonstrated as a novel noninvasive technique for the characterization of biological molecules. But the interpretation of the experimentally measured terahertz absorption bands requires robust computational method. In this paper, we present a statistical method for predicting the absorption peak positions of a macromolecule in the terahertz region. The essence of this method is to calculate the absorption spectra of a biological molecule based on multiple short scale molecular dynamics trajectories instead of using a long time scale trajectory. The method was employed to calculate the absorption peak positions of the protein, thioredoxin from Escherichia coli (E.coli), in the range of 10-25 cm -1 to verify the reliability of this statistical method. The predicted absorption peak positions of thioredoxin show good correlation with measured results demonstrating that the proposed method is effective in terahertz absorption spectra modeling. Such approach can be applied to predict characteristic spectral features of biomolecules in the terahertz region.

Rat small intestine absorption and membrane digestion in the process of aging

Recently, in our experiments, we used the short-circuit current technique to study the kinetic constants for nutrient transporters in rat gastric-intestinal tract and the thickness of the intestinal unstirred layer near the mucosa surface. It was shown that, during the process of aging, the number of nutrient monomer transporters in the small intestine increases twofold, whereas the affinity of transporters to the correspondent nutrients remains unchanged. The situation for peptides may be opposite. The layer thickness in the vicinity of the mucosa surface, measured through glucose, decreased during the process of aging. It was suggested that, in old rats, the role of the digestive volume is more important, which results in an increase of the number of nutrient monomer transporters.

产学研合作、知识吸收能力与企业创新绩效——高管学术背景与政府创新补贴的调节作用

在梳理产学研合作与企业创新绩效关系研究的基础上,结合交易成本理论、资源基础理论以及高层梯队理论,以2010-2021年中国A股上市公司为研究样本,探讨产学研合作对企业创新绩效的促进作用及机制,并将高管学术背景和政府创新补贴作为调节变量纳入研究框架。实证分析发现:产学研合作对企业创新绩效发挥显著促进作用;当企业具有学术背景的高管比例较高时,这一效应更加显著;高水平政府创新补贴同样能够增强这一效应。中介效应检验发现,企业参与产学研合作对其知识吸收能力具有显著促进作用,同时,企业可以通过提升知识吸收能力,增强自身对环境变化感知的敏锐性与自主创新能力,进而提高创新绩效。

肠道中钙和铁相互作用对其吸收影响的研究进展

钙和铁是人体健康必需的金属元素,在骨骼形成、氧气运输等多种代谢过程中发挥重要作用。然而,钙和铁缺乏却是常见的营养问题,可能会分别导致骨质疏松和贫血。而且其相互作用可能会干扰彼此的吸收和生物利用度,因此,了解钙和铁在肠道中的吸收机制及其相互作用对制定有效的预防或治疗营养性疾病的策略至关重要。已有大量研究表明,短期补充钙会抑制铁的吸收,而长期补充钙对总体铁稳态没有影响。这可能是由于钙摄入对铁吸收的影响是一种短暂和适应性反应,具体的分子机制可能是钙对铁相关转运蛋白的调节,但还需要更多的研究阐明这一过程。此外,关于铁如何影响钙吸收的研究较少,有研究表明高剂量的铁可能对钙的吸收和保留有负面作用,但铁对钙吸收的具体影响和机制尚不清楚。本文综述了钙和铁在肠道中的吸收机理、摄入钙和铁直至吸收过程中钙和铁所发生的相互作用,并详细阐述了钙和铁吸收过程中相互影响的内在机制,这对改善钙和铁的摄入和吸收,以及预防由营养缺乏导致的公共健康问题具有一定的指导意义。

Polarization-driven multifunctional organohydrogels with strain sensitivity toward electromagnetic wave absorption

Rapid advancements in flexible electronics and military applications necessitate high-performance electromagnetic wave(EMW)absorbers.While huge breakthroughs in achieving high-attenuation microwave absorption,conventional EMW absorbing materials have single function and ambiguous absorption mechanisms.Herein,numerous gel-type absorbers are fabricated by introducing“regulators”into poly(acrylamide-co-acrylic acid)(P(AM-co-AA))networks through radical polymerization in a glycerol-water mixed solvent.The dielectric constant and EMW absorption performance of the gels are precisely predicted by adjusting monomer concentration,the ratio of glycerol/water,and the content of the regulators.Notably,A_(6)G_(20)T_(20)-2 exhibits promising absorption performance with a minimum reflection loss(RL_(min))of-33.8 dB at 12.4 GHz.The effective absorption bandwidth(EAB)covers the entire X-band(8.2-12.4 GHz)at a thickness of 2.7 mm.A_(6)G_(20)T_(20)-2 also has sensitive deformation responses and excellent tensile strength,adhesiveness,self-healing and anti-freezing properties.Overall,this work not only provides insight into the polarization loss mechanism of the gels as the result of high correlation between EMW absorbing properties and molecular polarization,but also offers an important reference for developing functional protective materials because of the rich functionalities and efficient protective capabilities of the gels.

离子液体吸收式制冷工质对气液相平衡研究及其分子动力学模拟

为了克服传统吸收式制冷工质对的种种缺陷,离子液体型制冷工质对被视作理想替代品,得到了广泛的开发与应用。采用静态实验和分子动力学模拟两种方法,对[EMIM]BF_(4)/CH_(3)OH离子液体二元体系的气液相平衡性质展开研究。研究结果显示,[EMIM]BF_(4)/CH_(3)OH离子液体二元溶液具有良好的气液相平衡性质,实验测得饱和蒸气压比其他醇类离子液体二元溶液低约21%;模拟结果与实验值有相同的数量级和变化趋势,相对误差普遍小于8%。研究结果为离子液体制冷工质对的筛选和进一步的理论循环系统研究提供了物性数据基础,另一方面也为离子液体基础物性研究提供了一种模拟预测的新方法。

Ballistic Penetration Damage of Hybrid Thermoplastic Composites Reinforced with Kevlar and UHMWPE Fabrics

Polymer matrix types of fiber hybrid composites are key factors to improve ballistic impact damage tolerances.Here we report ballistic penetration damages of Kevlar/ultra-high molecular weight polyethylene(UHMWPE)hybrid composites with thermoplastic polyurethane(PU)matrix.The hybrid composites were penetrated by fragment-simulating projectiles(FSPs)using an air gun impact system.The effects of stacking sequences on the ballistic performance of hybrid composites were analyzed.Two types of specific energy absorption(the energy absorption per unit area density and the energy absorption per unit thickness)were investigated.It was found that the main damage modes of PU hybrid composites were fiber breakage,matrix damage,fiber pullout and interlayer delamination.The instantaneous deformation could not be used as a reference index for evaluating the ballistic performance of the target plate.The energy absorption process of the PU hybrid composites showed a nonlinear pattern.The hybrid structure affected the specific energy absorption of the materials.

GPMAS测定土壤中亚硝酸盐氮的干扰探讨

文章探讨了气相分子吸收光谱法测定土壤中亚硝酸盐氮时,硫化物、甲醛、VOCs、乙草胺、丙烯酰胺、尿素等土壤中存在的物质对分析可能产生的干扰及干扰去除方法。实验结果表明,硫化物、VOCs对亚硝酸盐氮的测定结果产生正干扰。土壤提取液中加入乙酸锌+乙酸钠混合溶液并将溶液调为弱碱性(p H 10~11),可消除硫化物干扰;土壤提取液加热煮沸3~5 min,可消除VOCs的干扰。甲醛、乙草胺、丙烯酰胺、尿素基本无干扰。

土壤中无机氮检测方法研究进展

土壤中无机氮含量的检测是了解土壤氮迁移、精准把控氮肥施用量、有效防治土壤氮素过量的首要前提。本文对现行国内外土壤中无机氮的标准分析方法的原理、特性及优缺点进行了归纳和总结。结果发现,现行标准中使用的方法基本为分光光度法和凯式法。现行手工分析法操作步骤多、耗时长,难以满足批量土壤样品快速分析测试的要求。自动仪器分析法反应复杂、易受干扰,直接影响测定结果的准确性。此外,在基于同种原理的前提下,现行标准在前处理方法及检测条件等方面存在众多不统一,导致所得数据不具有可比性。通过综合比较后提出,气相分子吸收光谱法在方法性能、检测效率及仪器成本等方面具有明显优势,必将成为今后各级标准制修订的首选方法。