The main purpose of the present research is to study geological issues of urban areas in Bagh-e Malek in Khuzestan province of Iran and improving the municipal environment. The present research is an applied study in ...The main purpose of the present research is to study geological issues of urban areas in Bagh-e Malek in Khuzestan province of Iran and improving the municipal environment. The present research is an applied study in sake of nature and a descriptive-analytical survey in sake of method. Library and field method has been used in data collection. In field study, 325 citizens in Bagh-e Malek in 2015 were selected as sample group via sampling method well suited to sample size using questionnaire of citizens’ participation. Software SPSS and Excel are used to analyze data. Friedman test has been used to determine rank of each of selected indices for testing hypotheses and finding research. Results from Friedman test indicate that satisfaction with pedestrian passages has the highest mean with rank (9.90) and awareness from municipality’s rights has the lowest mean with rank (2.95).展开更多
The granitoids-diroretic complex and associated volcanic suits of Malek Siah Kuh (eastern Iran) were examined by RS, XRD, XRF, AAS and ICP-MS methods. The Multispectral data were used for differentiating of lithologic...The granitoids-diroretic complex and associated volcanic suits of Malek Siah Kuh (eastern Iran) were examined by RS, XRD, XRF, AAS and ICP-MS methods. The Multispectral data were used for differentiating of lithological units, main alterations, structural trends, and hydrothermally altered minerals. Based on the results of remote sensing, field studies and petrographic data, the complex classified into three main groups: 1) mafic unit (gabbro-basalt), 2) intermediate rocks (diorite-andesite suite) and 3) felsic unit (granitoide rocks). The complex is characterized by high Al2O3 and Sr contents as well as high Sr/Y and La/Yb ratios, while low in Y and Yb contents. The geochemical characteristics of these rocks indicate that they are similar to adakite like rocks. The complex is high calc-alkaline to shoshonitic nature. The results indicated derivation from similar silicate melt source followed by differentiation and assimilation of crustal rocks. Based on set of petrological and geochemical relations, 3 distinct stages of mineralization process can be recognized. 1) It is differentiation during magma evolution as well as metal enrichment and subsolidus leaching by hot fluids. 2) It occurred by ascending of the gas-rich magma and release of S and As. 3) It was accompanied by hydrothermal activities leading to the generation of sulfidation and associated polymetallic (Cu, Au, Fe) mineralization.展开更多
In this study,to better understand the reaction mechanism between inorganic salts and nitrocellulose,CaCO_(3) and Li_(2)CO_(3) were evaluated with respect to their effects on the thermal degradation of NC in nitrogen ...In this study,to better understand the reaction mechanism between inorganic salts and nitrocellulose,CaCO_(3) and Li_(2)CO_(3) were evaluated with respect to their effects on the thermal degradation of NC in nitrogen atmosphere using TG/DSC at three different heating rates(2,5,10 K/min).The numerical relationship between activation energy(E)and conversion rate was obtained by FWO and KAS method,and it was discovered that CaCO_(3) could improve the thermal stability of NC.Activation energy values were calculated by Kissinger method,and it was found that NC that contain Li2CO3had the highest activation energy while NC containing CaCO3had the lowest E value.By combining the thermal analysis data with Malek method,the most probable mechanism model of thermal degradation is obtained as Sesták-Berggren model,which expression is f(α)=α^(m)(1-α)^(n).As a result of this study,there are certain guiding principles that can be applied to the pyrolysis reaction model and to the actual production process of nitrocellulose.展开更多
目的研究海因环氧树脂的固化行为,为绿色环保水性涂层和表面粘接剂的开发与研制提供一定的基础数据和理论指导。方法合成了一种新型海因环氧树脂,以六氢苯酐(HHPA)为固化剂,制备了海因环氧/HHPA树脂体系。采用差示扫描量热法研究其在不...目的研究海因环氧树脂的固化行为,为绿色环保水性涂层和表面粘接剂的开发与研制提供一定的基础数据和理论指导。方法合成了一种新型海因环氧树脂,以六氢苯酐(HHPA)为固化剂,制备了海因环氧/HHPA树脂体系。采用差示扫描量热法研究其在不同升温速率下的固化行为,通过Melak等效转换公式及双参数(m,n)自催化模型,分别确定海因环氧/HHPA树脂体系的固化反应机理函数和相关动力学参数,得到固化反应动力学方程。结果所制备的新型海因环氧值为0.65当量,无机氯含量为0.000 673当量,有机氯含量为0.0274当量。通过Ozawa-Flynn-Wall法和Friedman-Reich-Levi法确定了海因环氧树脂/HHPA体系的表观活化能分别为82.2、83.7 k J/mol,通过malek方程计算得到树脂体系的反应级数n=1.531,m=0.68,指前因子A=1.75×10^(10)。所建立的固化动力学方程为βdα/dT=1.75×10^(10)α^(0.68)(1-α)^(1.531)expa(-Eα/RT)。结论海因环氧树脂/HHPA固化反应按照自催化反应机理进行,并建立了海因环氧树脂的固化反应动力学模型。所确立的固化反应动力学模型计算得到的曲线与实验得到的DSC曲线吻合较好,在该研究范围内能较好地描述海因环氧树脂/HHPA体系的固化反应过程。展开更多
文摘The main purpose of the present research is to study geological issues of urban areas in Bagh-e Malek in Khuzestan province of Iran and improving the municipal environment. The present research is an applied study in sake of nature and a descriptive-analytical survey in sake of method. Library and field method has been used in data collection. In field study, 325 citizens in Bagh-e Malek in 2015 were selected as sample group via sampling method well suited to sample size using questionnaire of citizens’ participation. Software SPSS and Excel are used to analyze data. Friedman test has been used to determine rank of each of selected indices for testing hypotheses and finding research. Results from Friedman test indicate that satisfaction with pedestrian passages has the highest mean with rank (9.90) and awareness from municipality’s rights has the lowest mean with rank (2.95).
文摘The granitoids-diroretic complex and associated volcanic suits of Malek Siah Kuh (eastern Iran) were examined by RS, XRD, XRF, AAS and ICP-MS methods. The Multispectral data were used for differentiating of lithological units, main alterations, structural trends, and hydrothermally altered minerals. Based on the results of remote sensing, field studies and petrographic data, the complex classified into three main groups: 1) mafic unit (gabbro-basalt), 2) intermediate rocks (diorite-andesite suite) and 3) felsic unit (granitoide rocks). The complex is characterized by high Al2O3 and Sr contents as well as high Sr/Y and La/Yb ratios, while low in Y and Yb contents. The geochemical characteristics of these rocks indicate that they are similar to adakite like rocks. The complex is high calc-alkaline to shoshonitic nature. The results indicated derivation from similar silicate melt source followed by differentiation and assimilation of crustal rocks. Based on set of petrological and geochemical relations, 3 distinct stages of mineralization process can be recognized. 1) It is differentiation during magma evolution as well as metal enrichment and subsolidus leaching by hot fluids. 2) It occurred by ascending of the gas-rich magma and release of S and As. 3) It was accompanied by hydrothermal activities leading to the generation of sulfidation and associated polymetallic (Cu, Au, Fe) mineralization.
基金the National Natural Science Foundation of China(NSFC,Grants No.52176114 and 52111530091)Jiangsu Funding Program for Excellent Postdoctoral Talent。
文摘In this study,to better understand the reaction mechanism between inorganic salts and nitrocellulose,CaCO_(3) and Li_(2)CO_(3) were evaluated with respect to their effects on the thermal degradation of NC in nitrogen atmosphere using TG/DSC at three different heating rates(2,5,10 K/min).The numerical relationship between activation energy(E)and conversion rate was obtained by FWO and KAS method,and it was discovered that CaCO_(3) could improve the thermal stability of NC.Activation energy values were calculated by Kissinger method,and it was found that NC that contain Li2CO3had the highest activation energy while NC containing CaCO3had the lowest E value.By combining the thermal analysis data with Malek method,the most probable mechanism model of thermal degradation is obtained as Sesták-Berggren model,which expression is f(α)=α^(m)(1-α)^(n).As a result of this study,there are certain guiding principles that can be applied to the pyrolysis reaction model and to the actual production process of nitrocellulose.
文摘目的研究海因环氧树脂的固化行为,为绿色环保水性涂层和表面粘接剂的开发与研制提供一定的基础数据和理论指导。方法合成了一种新型海因环氧树脂,以六氢苯酐(HHPA)为固化剂,制备了海因环氧/HHPA树脂体系。采用差示扫描量热法研究其在不同升温速率下的固化行为,通过Melak等效转换公式及双参数(m,n)自催化模型,分别确定海因环氧/HHPA树脂体系的固化反应机理函数和相关动力学参数,得到固化反应动力学方程。结果所制备的新型海因环氧值为0.65当量,无机氯含量为0.000 673当量,有机氯含量为0.0274当量。通过Ozawa-Flynn-Wall法和Friedman-Reich-Levi法确定了海因环氧树脂/HHPA体系的表观活化能分别为82.2、83.7 k J/mol,通过malek方程计算得到树脂体系的反应级数n=1.531,m=0.68,指前因子A=1.75×10^(10)。所建立的固化动力学方程为βdα/dT=1.75×10^(10)α^(0.68)(1-α)^(1.531)expa(-Eα/RT)。结论海因环氧树脂/HHPA固化反应按照自催化反应机理进行,并建立了海因环氧树脂的固化反应动力学模型。所确立的固化反应动力学模型计算得到的曲线与实验得到的DSC曲线吻合较好,在该研究范围内能较好地描述海因环氧树脂/HHPA体系的固化反应过程。
