Based on ECMWF monthly mean data from January 1980 to December 1989,characterishcs of the three-dimensional structure of the mean water vapor transport over Monsoon Asia are described,and the more forportant features ...Based on ECMWF monthly mean data from January 1980 to December 1989,characterishcs of the three-dimensional structure of the mean water vapor transport over Monsoon Asia are described,and the more forportant features of the different regional water vapor transport in the indian Monsoon region and the East AsianMonsoon region are analyzed.It is found that there is a moist tongue extending from the equator POleWard to the Asian Monsoon region.The three-dimensional distributions of the mean water vapor transport fields over the entire globe renect clearly the asymmetry of the Asian Monsoon system,and the existence of a counterrHadley monsoon circulation.The moisture conver-gened(divergence) area in Asia coincides with the connuellt(diffiuent) zone of the monsoon cjrculahon.Furthermore,the moist featllres of the tWo sub-regions of the Asian Monsoon area are different both in their magnitudes and in their seasonal variations.展开更多
The purpose of this study was to examine Econometric analysis of transport sector on economic growth in Rwanda for the period of 1999 up to 2018</span><span style="font-family:Verdana;">.</spa...The purpose of this study was to examine Econometric analysis of transport sector on economic growth in Rwanda for the period of 1999 up to 2018</span><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> It’s an empirical study which used econometric techniques such as unit root test, Engle granger test/cointegration test, linear regression model and the error correction model to analyze the contribution of transport sector on economic growth based on Gross Capital formation in terms of transport infrastructures, trade balance as import and export can be affected by transport system, and contribution of transport services to economic growth. This study found that, there was a strong statistically significant relationship between GDP and transport sector as measured by transport services for both short run and long run as it is shown by R-squared of 0.997316 and 0.782009 of the long run regression model and error correction model respectively. ECM showed a quick recovery of 81.3% every year after a shock happen. This study concluded that there is a short run and long run relationship between Transport service and economic growth. This study recommends that policy implication that can be deducted from this study to </span><span style="font-family:Verdana;">facilitate transport sector through expansion of road networks and maintenance of existing road networks coupled with revitalization of alternative mode of transportation such as air transport, rail system and waterways will significantly improve the growth of the展开更多
Conjugated polymers with well-balanced ambipolar charge transport is essential for organic circuits at low cost and large area with simplified fabrication techniques.Aiming at this point,herein,a novel asymmetric thio...Conjugated polymers with well-balanced ambipolar charge transport is essential for organic circuits at low cost and large area with simplified fabrication techniques.Aiming at this point,herein,a novel asymmetric thiophene/pyridine-flanked diketopyrrolopyrrole-based copolymer(PPyTDPP-2FBT)is designed and synthesized.Due to the effect of incorporating F atoms on molecular energy alignment and conjugation conformation,the PPyTDPP-2FBT copolymer exhibits typical V-shaped ambipolar field-effect transfer characteristics with well-balanced hole and electron mobilities of 0.64 and 0.46 cm^(2)V^(−1)s^(−1),respectively.Furthermore,organic digital and analog circuits such as inverters and frequency doublers are successfully constructed based on solution-processed films of the PPyTDPP-2FBT copolymers which show a typical circuit operating mode with a high gain of 133 due to the well-balanced electrical properties.In addition,PPyTDPP-2FBT-based devices also demonstrate good stability and batch repeatability,suggesting their great potential applications in organic integrated electronic circuits.展开更多
Since polymer-based light-emitting diodes(PLEDs)arewellsuited building blocks for large-area and low-cost flexible display equipment,state-of-the-art thermally activated delayed fluorescence(TADF)PLEDs are in high dem...Since polymer-based light-emitting diodes(PLEDs)arewellsuited building blocks for large-area and low-cost flexible display equipment,state-of-the-art thermally activated delayed fluorescence(TADF)PLEDs are in high demand.To respond to this demand,light-emitting TADF units have initially been modified with electron-transporting units to balance the carrier transport of regiorandom TADF polymers,and simultaneously,an intramolecular sensitizing strategy has also been employed by covalently incorporating TADF sensitizers with light-emitting TADF units and hosts in conjugated polymers to accelerate the spin-flip of triplet excitons.Superior photophysical properties have been achieved by a rational regulation of the proportions of each component,achieving a photoluminescence quantumyield of 90%,an extremely high rate of reverse intersystem crossing of 3×106 s−1,and a relatively low nonradiative decay rate of around 105 s−1.As a result,the solutionprocessed PLEDs can attain an external quantum efficiency(EQE)value of 25.4%with emission peaks of around 550 nm,representing record-high performance for PLEDs.The efficiency roll-off can also be significantly suppressed,maintaining an EQE value of 24.2%at 1000 cd/m2 with ideal efficiency roll-off of lower than 5%.Encouragingly,this work provides a valid strategy to tackle the imperative need for PLEDs with high EQE and low efficiency roll-off.展开更多
In this paper, co-doping method is used to improve the current efficiency of solution-processed organic light-emitting diodes(OLEDs). By changing the ratio of two thermally activated delayed fluorescent(TADF) emitters...In this paper, co-doping method is used to improve the current efficiency of solution-processed organic light-emitting diodes(OLEDs). By changing the ratio of two thermally activated delayed fluorescent(TADF) emitters, we studied the performance of device and its mechanism. A solution processed OLED with a structure of indium tin oxide(ITO, 150 nm)/PEDOT:PSS(30 nm)/CBP:4 Cz IPN-x%:4 Cz PN-y%(30 nm)/TPBi(40 nm)/Li F(1 nm)/Al(100 nm) was fabricated. The current efficiencies of 26.6 cd/A and 26.4 cd/A were achieved by the devices with dopant ratio of 6% 4 Cz IPN:2% 4 Cz PN and 2% 4 Cz IPN:6% 4 Cz PN in emitting material layer(EML), respectively. By investigating the tendency of current density change in devices with different doping ratio, we suggested that the enhancement of the current efficiency should be due to the charge transport balance improvement induced by assist dopant in EML.展开更多
文摘Based on ECMWF monthly mean data from January 1980 to December 1989,characterishcs of the three-dimensional structure of the mean water vapor transport over Monsoon Asia are described,and the more forportant features of the different regional water vapor transport in the indian Monsoon region and the East AsianMonsoon region are analyzed.It is found that there is a moist tongue extending from the equator POleWard to the Asian Monsoon region.The three-dimensional distributions of the mean water vapor transport fields over the entire globe renect clearly the asymmetry of the Asian Monsoon system,and the existence of a counterrHadley monsoon circulation.The moisture conver-gened(divergence) area in Asia coincides with the connuellt(diffiuent) zone of the monsoon cjrculahon.Furthermore,the moist featllres of the tWo sub-regions of the Asian Monsoon area are different both in their magnitudes and in their seasonal variations.
文摘The purpose of this study was to examine Econometric analysis of transport sector on economic growth in Rwanda for the period of 1999 up to 2018</span><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> It’s an empirical study which used econometric techniques such as unit root test, Engle granger test/cointegration test, linear regression model and the error correction model to analyze the contribution of transport sector on economic growth based on Gross Capital formation in terms of transport infrastructures, trade balance as import and export can be affected by transport system, and contribution of transport services to economic growth. This study found that, there was a strong statistically significant relationship between GDP and transport sector as measured by transport services for both short run and long run as it is shown by R-squared of 0.997316 and 0.782009 of the long run regression model and error correction model respectively. ECM showed a quick recovery of 81.3% every year after a shock happen. This study concluded that there is a short run and long run relationship between Transport service and economic growth. This study recommends that policy implication that can be deducted from this study to </span><span style="font-family:Verdana;">facilitate transport sector through expansion of road networks and maintenance of existing road networks coupled with revitalization of alternative mode of transportation such as air transport, rail system and waterways will significantly improve the growth of the
基金This work is financially supported by the Ministry of Science and Technology of China(2018YFA0703200,2017YFA0204503)the National Natural Science Foundation of China(91833306,61890943,51725304,22021002)Beijing National Laboratory for Molecular Sciences(BNLMS-CXXM-202012),the Youth Innovation Promotion Association of the Chinese Academy of Sciences,and the National Program for Support of Top-notch Young Professionals.
文摘Conjugated polymers with well-balanced ambipolar charge transport is essential for organic circuits at low cost and large area with simplified fabrication techniques.Aiming at this point,herein,a novel asymmetric thiophene/pyridine-flanked diketopyrrolopyrrole-based copolymer(PPyTDPP-2FBT)is designed and synthesized.Due to the effect of incorporating F atoms on molecular energy alignment and conjugation conformation,the PPyTDPP-2FBT copolymer exhibits typical V-shaped ambipolar field-effect transfer characteristics with well-balanced hole and electron mobilities of 0.64 and 0.46 cm^(2)V^(−1)s^(−1),respectively.Furthermore,organic digital and analog circuits such as inverters and frequency doublers are successfully constructed based on solution-processed films of the PPyTDPP-2FBT copolymers which show a typical circuit operating mode with a high gain of 133 due to the well-balanced electrical properties.In addition,PPyTDPP-2FBT-based devices also demonstrate good stability and batch repeatability,suggesting their great potential applications in organic integrated electronic circuits.
基金the National Natural Science Foundation of China(nos.51922021 and 52103220)the Shandong Provincial Natural Science Foundation(no.ZR2019ZD50).
文摘Since polymer-based light-emitting diodes(PLEDs)arewellsuited building blocks for large-area and low-cost flexible display equipment,state-of-the-art thermally activated delayed fluorescence(TADF)PLEDs are in high demand.To respond to this demand,light-emitting TADF units have initially been modified with electron-transporting units to balance the carrier transport of regiorandom TADF polymers,and simultaneously,an intramolecular sensitizing strategy has also been employed by covalently incorporating TADF sensitizers with light-emitting TADF units and hosts in conjugated polymers to accelerate the spin-flip of triplet excitons.Superior photophysical properties have been achieved by a rational regulation of the proportions of each component,achieving a photoluminescence quantumyield of 90%,an extremely high rate of reverse intersystem crossing of 3×106 s−1,and a relatively low nonradiative decay rate of around 105 s−1.As a result,the solutionprocessed PLEDs can attain an external quantum efficiency(EQE)value of 25.4%with emission peaks of around 550 nm,representing record-high performance for PLEDs.The efficiency roll-off can also be significantly suppressed,maintaining an EQE value of 24.2%at 1000 cd/m2 with ideal efficiency roll-off of lower than 5%.Encouragingly,this work provides a valid strategy to tackle the imperative need for PLEDs with high EQE and low efficiency roll-off.
基金supported by the National High Technology Research and Development Program of China (No.2012AA011901)the National Program on Key Basic Research Project of China (No.2012CB723406)+2 种基金the National Natural Science Foundation of China (No.51573036)the Fundamental Research Funds for the Central Universities of China (No.JD2016JGPY0007)the Industry-University-Research Cooperation Project of Aviation Industry Corporation of China (No.CXY2013HFGD20)。
文摘In this paper, co-doping method is used to improve the current efficiency of solution-processed organic light-emitting diodes(OLEDs). By changing the ratio of two thermally activated delayed fluorescent(TADF) emitters, we studied the performance of device and its mechanism. A solution processed OLED with a structure of indium tin oxide(ITO, 150 nm)/PEDOT:PSS(30 nm)/CBP:4 Cz IPN-x%:4 Cz PN-y%(30 nm)/TPBi(40 nm)/Li F(1 nm)/Al(100 nm) was fabricated. The current efficiencies of 26.6 cd/A and 26.4 cd/A were achieved by the devices with dopant ratio of 6% 4 Cz IPN:2% 4 Cz PN and 2% 4 Cz IPN:6% 4 Cz PN in emitting material layer(EML), respectively. By investigating the tendency of current density change in devices with different doping ratio, we suggested that the enhancement of the current efficiency should be due to the charge transport balance improvement induced by assist dopant in EML.