Hemicellulose has a wide range of applications,including that as an emulsifier for the food industry and raw material for the synthesis of bioethanol/biochemicals and biodegradable films.Hemicellulose is usually prese...Hemicellulose has a wide range of applications,including that as an emulsifier for the food industry and raw material for the synthesis of bioethanol/biochemicals and biodegradable films.Hemicellulose is usually present as a spent liquor,such as the prehydrolysis liquor of the prehydrolysis kraft dissolving pulp production process and the alkali extraction liquor of the cold caustic extraction of pulp fibers.Due to its dilute nature,hemicellulose needs to be dried for practical utilization,and this is challenging.In this study,cellulose and hemicellulose in a bleached bamboo kraft pulp were separated using an alkali extraction process.Hemicellulose obtained from the extraction liquor was dried by an ammonium carbonate-assisted drying process.The effects of drying time and drying temperature were determined.Structure of the hemicellulose obtained by the ammonium carbonate-assisted drying process was similar to that of original hemicellulose,as revealed by detailed Fourier transform infrared and X-ray diffraction analyses.The novel drying method was more energy efficient and required a shorter drying time than the conventional freeze drying method,and the excellent solubility in alkaline solutions favored the chemical modification of hemicellulose.The dried hemicellulose can be used as a renewable raw material for the preparation of hydrogels and other substances such as bioethanol/biochemicals and biodegradable films.展开更多
In order to investigate the effect of the relative motion of nano CaCO_(3)reinforced bamboo pulp fiber(BPF)/HDPE composite components on the mechanical performance,a comparative study was performed.BPF was treated by ...In order to investigate the effect of the relative motion of nano CaCO_(3)reinforced bamboo pulp fiber(BPF)/HDPE composite components on the mechanical performance,a comparative study was performed.BPF was treated by nano CaCO_(3)blending(BM)and impregnation modification(IM)technology.The composites were produced using hot press(HPMP),extrusion(EMP)and injection molding process(IMP).The physical morphology of BPF was similar at different manufacturing processes.Compared to the samples manufactured by HPMP,a decrease in the(specific)flexural strength of BPF/HDPE composites and an increase in those of composites treated by nano CaCO_(3)manufactured by EMP and IMP were observed.The injection molded composites exhibited the best values in the(specific)impact strength,(specific)tensile properties.IM had a greater effect on the rheological behavior of the composites than BM,and nano CaCO_(3)treatment most effectively affected the performance of the extrusion molded composites.展开更多
基金the National Key Research and Development Program of China(2017YFB0307900,2019YFC1905903)the National Natural Science Foundation of China(31700507)the Major Project on the Integration of Industry-Education-Research of Fujian Provincial Department of Science and Technology(2018H6003).
文摘Hemicellulose has a wide range of applications,including that as an emulsifier for the food industry and raw material for the synthesis of bioethanol/biochemicals and biodegradable films.Hemicellulose is usually present as a spent liquor,such as the prehydrolysis liquor of the prehydrolysis kraft dissolving pulp production process and the alkali extraction liquor of the cold caustic extraction of pulp fibers.Due to its dilute nature,hemicellulose needs to be dried for practical utilization,and this is challenging.In this study,cellulose and hemicellulose in a bleached bamboo kraft pulp were separated using an alkali extraction process.Hemicellulose obtained from the extraction liquor was dried by an ammonium carbonate-assisted drying process.The effects of drying time and drying temperature were determined.Structure of the hemicellulose obtained by the ammonium carbonate-assisted drying process was similar to that of original hemicellulose,as revealed by detailed Fourier transform infrared and X-ray diffraction analyses.The novel drying method was more energy efficient and required a shorter drying time than the conventional freeze drying method,and the excellent solubility in alkaline solutions favored the chemical modification of hemicellulose.The dried hemicellulose can be used as a renewable raw material for the preparation of hydrogels and other substances such as bioethanol/biochemicals and biodegradable films.
基金This study is financially supported by the Basic Research Operating Expenses Program of International Centre for Bamboo and Rattan(1632021002).
文摘In order to investigate the effect of the relative motion of nano CaCO_(3)reinforced bamboo pulp fiber(BPF)/HDPE composite components on the mechanical performance,a comparative study was performed.BPF was treated by nano CaCO_(3)blending(BM)and impregnation modification(IM)technology.The composites were produced using hot press(HPMP),extrusion(EMP)and injection molding process(IMP).The physical morphology of BPF was similar at different manufacturing processes.Compared to the samples manufactured by HPMP,a decrease in the(specific)flexural strength of BPF/HDPE composites and an increase in those of composites treated by nano CaCO_(3)manufactured by EMP and IMP were observed.The injection molded composites exhibited the best values in the(specific)impact strength,(specific)tensile properties.IM had a greater effect on the rheological behavior of the composites than BM,and nano CaCO_(3)treatment most effectively affected the performance of the extrusion molded composites.
