Combining the system of rapid collection of ambient particles and ion chromatography, the system of rapid collection of fine particles and ion chromatography (RCFP-IC) was established to automatically analyze on-lin...Combining the system of rapid collection of ambient particles and ion chromatography, the system of rapid collection of fine particles and ion chromatography (RCFP-IC) was established to automatically analyze on-line the concentrations of water-soluble ions in ambient particles. Here, the general scheme of RCFP-IC is described and its basic performance is tested. The detection limit of RCFP-IC for SO4^2-, NO3^-, NO2^-, Cl^- and F- is below 0.3μg m^-3. The collection efficiency of RCFP-IC increases rapidly with increasing sized particles. For particles larger than 300 nm, the collection efficiency approaches 100%. The precision of RCFP-IC is more than 90% over 28 repetitions. The response of RCFP-IC is very sensitive and no obvious cross-pollution is found during measurement. A comparison of RCFP-IC with an integrated filter measurement indicates that the measurement of RCFP-IC is comparable in both laboratory experiments and field observations. The results of the field experiment prove that RCFP-IC is an effective on-line monitoring system and is helpful in source apportionment and pollution episode monitoring.展开更多
Owing to the environmental protection potential and the desirable high performance capabilities,asphalt rubber(AR)and styrene-butadiene-styrene(SBS)modified asphalt have been widely used.However,the poor construction ...Owing to the environmental protection potential and the desirable high performance capabilities,asphalt rubber(AR)and styrene-butadiene-styrene(SBS)modified asphalt have been widely used.However,the poor construction workability and segregation issues of AR,along with the exorbitant cost of SBS modified asphalt,are of the serious problems that plague their application scope.Moreover,SBS/crumb rubber(CR)modified asphalt is gradually becoming widespread and it therefore becomes incumbent to find appropriate ways to mitigate the issues that may limit its use.As a consequence,it becomes crucial to analyze the interaction between CR and SBS modifiers in the composite mixture,as well as evaluate the influence of modifier dosage on the performance of the modified asphalt.This study presents a comprehensive review of the effects of SBS modifier,CR modifier and composite SBS/CR on the performance of modified asphalts.Macro analysis and micro analysis,including analysis on the conventional physical properties,are carried out.It can uncover the interaction between modifier and asphalt,which reveals how the modifiers influence the properties of modified asphalts.This study will serve as a source of invaluable information to researchers,engineers,and designers,informing them the development,potential and challenges of the CR,SBS and SBS/CR modified asphalts,the optimum contents to attain the best performance along with the mechanism involved.展开更多
基金This work was supported by the National Natural Science Foundation of China under Grant No. 40525016.
文摘Combining the system of rapid collection of ambient particles and ion chromatography, the system of rapid collection of fine particles and ion chromatography (RCFP-IC) was established to automatically analyze on-line the concentrations of water-soluble ions in ambient particles. Here, the general scheme of RCFP-IC is described and its basic performance is tested. The detection limit of RCFP-IC for SO4^2-, NO3^-, NO2^-, Cl^- and F- is below 0.3μg m^-3. The collection efficiency of RCFP-IC increases rapidly with increasing sized particles. For particles larger than 300 nm, the collection efficiency approaches 100%. The precision of RCFP-IC is more than 90% over 28 repetitions. The response of RCFP-IC is very sensitive and no obvious cross-pollution is found during measurement. A comparison of RCFP-IC with an integrated filter measurement indicates that the measurement of RCFP-IC is comparable in both laboratory experiments and field observations. The results of the field experiment prove that RCFP-IC is an effective on-line monitoring system and is helpful in source apportionment and pollution episode monitoring.
基金funded by Key Research and Development Project of Shaanxi Province(2022SF-328)the Science and Technology Project of Henan Department of Transportation(2020J-2-3)+1 种基金Science and Technology Project of Shaanxi Department of Transportation(No.19-10K,No.19-28K)Rising Tech Star Project of Shaanxi Department of Science and Technology(No.2019KJXX-035)。
文摘Owing to the environmental protection potential and the desirable high performance capabilities,asphalt rubber(AR)and styrene-butadiene-styrene(SBS)modified asphalt have been widely used.However,the poor construction workability and segregation issues of AR,along with the exorbitant cost of SBS modified asphalt,are of the serious problems that plague their application scope.Moreover,SBS/crumb rubber(CR)modified asphalt is gradually becoming widespread and it therefore becomes incumbent to find appropriate ways to mitigate the issues that may limit its use.As a consequence,it becomes crucial to analyze the interaction between CR and SBS modifiers in the composite mixture,as well as evaluate the influence of modifier dosage on the performance of the modified asphalt.This study presents a comprehensive review of the effects of SBS modifier,CR modifier and composite SBS/CR on the performance of modified asphalts.Macro analysis and micro analysis,including analysis on the conventional physical properties,are carried out.It can uncover the interaction between modifier and asphalt,which reveals how the modifiers influence the properties of modified asphalts.This study will serve as a source of invaluable information to researchers,engineers,and designers,informing them the development,potential and challenges of the CR,SBS and SBS/CR modified asphalts,the optimum contents to attain the best performance along with the mechanism involved.