The aim of this study was to determine the relationship between inter canine width (ICW) and inter alar width (IAW), inter commissural width (ICoW), and inter canthal distance (ICaD) in Bantu population. Materials and...The aim of this study was to determine the relationship between inter canine width (ICW) and inter alar width (IAW), inter commissural width (ICoW), and inter canthal distance (ICaD) in Bantu population. Materials and Methods: It was a pilot study included all participants who were aged at least 18 years, without a history of orthodontics treatment from Prosthodontics Department, Faculty of Dental Medicine, University of Kinshasa. The Ethics committee of the National Center of Research for Dental Sciences in DR Congo approved the study protocol (CNRSB 1504.218). The participants medical records were obtained from the interview and dental examination. Nature of the study was explained with participant information sheet, and an informed consent of all participants was obtained. The inclusion criteria were no missing maxillary and mandibular teeth, no diastema, and no anterior restorations, 18 years old before enrollment in the study. The exclusion criteria were inability to meet the above requirements, pregnancy, and refusal to participate in the study. The inter-canine width (ICW), inter alar width (IAW), inter canthal distance (ICaD) and inter-commissural width (ICoW) of each participant were measured with a digital Vernier caliper (Mitutoyo, UK Ltd.,) (0.01 mm) three times and the average value was recorded. The inter canthal distance (ICaD) was measured without applying pressure by bringing the recording parts of the caliper just in contact with the medial angle. The inter alar width (IAW) was marked with a fine marked pencil on the widest outer surface of the alae of the nose on either side or width. Those two points were measured without applying pressure by bringing the recording parts of the caliper just in contact with the outer surface. The participant was told to stop breathing shortly to avoid any change in shape of the nose. The inter-commissural width (ICoW) was determined by measuring the maxillary lip vermilion from commissure to commissure without the application of pressure on the tissue in the relaxed state. The inter-canine width (ICW) was measured indirectly using a dental floss. A dental floss was marked on one end prior to placement in the mouth. Using that point as reference, the dental floss was circumference along the curvature of the anterior dentition such that it passed along the contact point of all the teeth. The distal end of the canine teeth on both sides was then marked on the floss while it was stretched in the patients mouth. Floss was marked on both sides with the marker pencil. The distance between the two proximal contact points was measured and recorded. Data, analysis and validation were performed by the SPSS software (version 22.0, IBM SPSS Statistics, Chicago, IL, USA). Unpaired t-test was used, of Kolmogorov-Smirnov test. Analysis of variance (ANOVA) test was used to test for comparability between socio-demographic characteristics dental measurements. Pearsons correlation coefficients test was calculated to determine the relationship between facial and dental parameters. Significance was set at P 0.01. Results: Of 314 participants enrolled, 202 were included. The age ranged from 18 to 68 years, with a mean age of 40.62 12.99 years. Although the Pearsons correlation coefficients were negative. Ninety-three participants (46%) were men and one hundred and nine (54%) were women. The overall mean age was 40.62 12.99 years. Facial and dental measurements were greater in women than men with significant differences for ICW (p = 0.04). However, no significant difference was seen between men and women for IAW, ICaD and ICoW (p = 0.44, p = 0.23, p = 0.31 respectively). The correlation including Pearsons correlation coefficient and P-values for all participants is not demonstrated. Conclusion: Within the limitations of this study, the results suggest that IAW, ICaD and ICoW cannot be used as a preliminary method for determining the width of the maxillary for anterior teeth for edentulous patients.展开更多
Analysis of stock recruitment (SR) data is most often done by fitting various SR relationship curves to the data. Fish population dynamics data often have stochastic variations and measurement errors, which usually re...Analysis of stock recruitment (SR) data is most often done by fitting various SR relationship curves to the data. Fish population dynamics data often have stochastic variations and measurement errors, which usually result in a biased regression analysis. This paper presents a robust regression method, least median of squared orthogonal distance (LMD), which is insensitive to abnormal values in the dependent and independent variables in a regression analysis. Outliers that have significantly different variance from the rest of the data can be identified in a residual analysis. Then, the least squares (LS) method is applied to the SR data with defined outliers being down weighted. The application of LMD and LMD based Reweighted Least Squares (RLS) method to simulated and real fisheries SR data is explored.展开更多
Polychlorinated dibenzothiophenes(PCDTs) are classified as persistent organic pollutants in the environment,so the analysis of PCDTs by their gas chromatographic behaviors is of great significance.Quantitative struc...Polychlorinated dibenzothiophenes(PCDTs) are classified as persistent organic pollutants in the environment,so the analysis of PCDTs by their gas chromatographic behaviors is of great significance.Quantitative structure-retention relationship(QSRR) analysis is a useful technique capable of relating chromatographic retention time to the molecular structure.In this paper,a QSRR study of 37 PCDTs was carried out by using molecular electronegativity distance vector(MEDV) descriptors and multiple linear regression(MLR) and partial least-squares regression(PLS) methods.The correlation coefficient R of established MLR,PLS models,leave-one-out(LOO) cross-validation(CV),Q2ext were 0.9951,0.9942,0.9839(MLR) and 0.9925,0.9915,0.9833(PLS),respectively.Results showed that the model exhibited excellent estimate capability for internal sample set and good predictive capability for external sample set.By using MEDV descriptors,the QSRR model can provide a simple and rapid way to predict the gas-chromatographic retention indices of polychlorinated dibenzothiophenes in conditions of lacking standard samples or poor experimental conditions.展开更多
The peak ground acceleration (PGA), the volume of a sliding mass V, the height of a mountain HL and the slope angle θ of a mountain are four important parameters affecting the horizontal run-out distance of a lands...The peak ground acceleration (PGA), the volume of a sliding mass V, the height of a mountain HL and the slope angle θ of a mountain are four important parameters affecting the horizontal run-out distance of a landslide L. Correlations among them are studied statistically based on field investigations from 67 landslides triggered by the ground shaking and other factors during the Wenchuan earthquake, and then a prediction model for horizontal run-out distance L is developed in this study. This model gives due consideration to the implications of the above four parameters on the horizontal run-out distance L and the validity of the model is verified by the Donghekou and Magong Woqian landslides. At the same time, the advantages of the model are shown by comparing it with two other common prediction methods. The major findings drawn from the analyses and comparisons are: (1) an exponential relationship exists between L and log V, L and log HL, L and log PGA separately, but a negative exponential relationship exists between L and log tan0, which agrees with the statistical results; and (2) according to the analysis results of the relative relationship between the height of a mountain (H) and the place where the landslides occur, the probabilities at distances of2H/3-H, H/3-2H/3, and O-H/3 are 70.8%, 15.4%, and 13.8%, respectively, revealing that most landslides occurred at a distance of H/2-H. This prediction model can provide an effective technical support for the prevention and mitigation of landslide hazards.展开更多
Atoms in most organic molecules are often carbon,oxygen,nitrogen,sulfur,halogens,etc. Based on the three-dimensional structure of a molecule,a molecular structural characterization(MSC) method called improved molecu...Atoms in most organic molecules are often carbon,oxygen,nitrogen,sulfur,halogens,etc. Based on the three-dimensional structure of a molecule,a molecular structural characterization(MSC) method called improved molecular electronegativity-distance vector(I-MEDV) was developed. It was used to describe the structures of 37 compounds of styrax japonicus sieb flowers. Through multiple linear regression(MLR),a QSRR model was built up. The correlation coefficient(R1) of the model was 0.980. Then,4 vectors were selected to build another model through the method of stepwise multiple regression(SMR) ,and the correlation coefficient(R2) of the model was 0.975. Moreover,all the two models were evaluated by performing the crossvalidation with the leave-one-out(LOO) procedure and the correlation coefficients(Rcv) were 0.948 and 0.968,respectively. The results show that the I-MEDV could successfully describe the structures of organic compounds. The stability and predictability of the models were good.展开更多
The distance effect of the doped heteroatoms away from the catalytic centers has rarely been reported.In this work,we conducted density functional theory calculations to thoroughly investigate the influence of heteroa...The distance effect of the doped heteroatoms away from the catalytic centers has rarely been reported.In this work,we conducted density functional theory calculations to thoroughly investigate the influence of heteroatom(N,P,B,and S atoms)doping distance on the oxygen reduction reaction(ORR)activity of graphene-based FeN_(4)sites.We uncovered a Sabatier-like relationship between heteroatom doping distance and ORR activity of FeN_(4)sites.The nearest doping does not significantly improve and even block the ORR activity of FeN_(4)sites.Optimal ORR activity is achieved when the heteroatoms are 4-5Å(N,P,and S atoms)or 6-7Å(B atoms)away from the Fe atoms.Analysis of electronic structure indicates that distance effect can modulate the local chemical environment of Fe atoms,thereby account for the changes in ORR activity along with the doping distance and doping atoms.This study provides insights into the influence of heteroatom doping on the chemical environment of reaction active centers,and provides the theoretical guidance for controlling the doping distance of heteroatoms to achieve optimal catalytic activity and selectivity.展开更多
Based on the identical group as a pseudo atom instead of a typical atom, a novel modified molecular dis-tance-edge (MDE) vector μ was developed in our laboratory to characterize chemical structure of polychlorinated ...Based on the identical group as a pseudo atom instead of a typical atom, a novel modified molecular dis-tance-edge (MDE) vector μ was developed in our laboratory to characterize chemical structure of polychlorinated diben-zofurans (PCDFs) congeners and/or isomers. Quantitative structure-retention relationships (QSRRs) between the new VMDE parameters and gas chromatographic (GC) retention behavior of PCDFs were then generated by multiple linear regression (MLR) method for non-polar, moderately polar, and polar stationary phases. Four excellent models with high correlation coefficients, R=0.984-0.995, were proposed for non-polar columns (DB-5, SE-54, OV-101). For the moder-ately polar columns (OV-1701), the correlation coefficient of the developed good model is only 0.958. For the polar col-umns (SP-2300), the QSRR model is poor with R=0.884. Then cross validation with leave-one out of procedure (CV) is performed in high correlation with the non-polar (Rcv=992-0.974) and weakly polar (Rcv=921) columns and in little cor-relation (Rcv=0.834) with the polar columns. These results show that the new μ vector is suitable for describing the re-tention behaviors of PCDFs on non-polar and moderately polar stationary phases and not for the various gas chroma-tographic retention behaviors of PCDFs on the different po-larity-varying stationary phases.展开更多
文摘The aim of this study was to determine the relationship between inter canine width (ICW) and inter alar width (IAW), inter commissural width (ICoW), and inter canthal distance (ICaD) in Bantu population. Materials and Methods: It was a pilot study included all participants who were aged at least 18 years, without a history of orthodontics treatment from Prosthodontics Department, Faculty of Dental Medicine, University of Kinshasa. The Ethics committee of the National Center of Research for Dental Sciences in DR Congo approved the study protocol (CNRSB 1504.218). The participants medical records were obtained from the interview and dental examination. Nature of the study was explained with participant information sheet, and an informed consent of all participants was obtained. The inclusion criteria were no missing maxillary and mandibular teeth, no diastema, and no anterior restorations, 18 years old before enrollment in the study. The exclusion criteria were inability to meet the above requirements, pregnancy, and refusal to participate in the study. The inter-canine width (ICW), inter alar width (IAW), inter canthal distance (ICaD) and inter-commissural width (ICoW) of each participant were measured with a digital Vernier caliper (Mitutoyo, UK Ltd.,) (0.01 mm) three times and the average value was recorded. The inter canthal distance (ICaD) was measured without applying pressure by bringing the recording parts of the caliper just in contact with the medial angle. The inter alar width (IAW) was marked with a fine marked pencil on the widest outer surface of the alae of the nose on either side or width. Those two points were measured without applying pressure by bringing the recording parts of the caliper just in contact with the outer surface. The participant was told to stop breathing shortly to avoid any change in shape of the nose. The inter-commissural width (ICoW) was determined by measuring the maxillary lip vermilion from commissure to commissure without the application of pressure on the tissue in the relaxed state. The inter-canine width (ICW) was measured indirectly using a dental floss. A dental floss was marked on one end prior to placement in the mouth. Using that point as reference, the dental floss was circumference along the curvature of the anterior dentition such that it passed along the contact point of all the teeth. The distal end of the canine teeth on both sides was then marked on the floss while it was stretched in the patients mouth. Floss was marked on both sides with the marker pencil. The distance between the two proximal contact points was measured and recorded. Data, analysis and validation were performed by the SPSS software (version 22.0, IBM SPSS Statistics, Chicago, IL, USA). Unpaired t-test was used, of Kolmogorov-Smirnov test. Analysis of variance (ANOVA) test was used to test for comparability between socio-demographic characteristics dental measurements. Pearsons correlation coefficients test was calculated to determine the relationship between facial and dental parameters. Significance was set at P 0.01. Results: Of 314 participants enrolled, 202 were included. The age ranged from 18 to 68 years, with a mean age of 40.62 12.99 years. Although the Pearsons correlation coefficients were negative. Ninety-three participants (46%) were men and one hundred and nine (54%) were women. The overall mean age was 40.62 12.99 years. Facial and dental measurements were greater in women than men with significant differences for ICW (p = 0.04). However, no significant difference was seen between men and women for IAW, ICaD and ICoW (p = 0.44, p = 0.23, p = 0.31 respectively). The correlation including Pearsons correlation coefficient and P-values for all participants is not demonstrated. Conclusion: Within the limitations of this study, the results suggest that IAW, ICaD and ICoW cannot be used as a preliminary method for determining the width of the maxillary for anterior teeth for edentulous patients.
文摘Analysis of stock recruitment (SR) data is most often done by fitting various SR relationship curves to the data. Fish population dynamics data often have stochastic variations and measurement errors, which usually result in a biased regression analysis. This paper presents a robust regression method, least median of squared orthogonal distance (LMD), which is insensitive to abnormal values in the dependent and independent variables in a regression analysis. Outliers that have significantly different variance from the rest of the data can be identified in a residual analysis. Then, the least squares (LS) method is applied to the SR data with defined outliers being down weighted. The application of LMD and LMD based Reweighted Least Squares (RLS) method to simulated and real fisheries SR data is explored.
基金supported by the Foundation of Returned Scholars (Main Program) of Shanxi Province (200902)
文摘Polychlorinated dibenzothiophenes(PCDTs) are classified as persistent organic pollutants in the environment,so the analysis of PCDTs by their gas chromatographic behaviors is of great significance.Quantitative structure-retention relationship(QSRR) analysis is a useful technique capable of relating chromatographic retention time to the molecular structure.In this paper,a QSRR study of 37 PCDTs was carried out by using molecular electronegativity distance vector(MEDV) descriptors and multiple linear regression(MLR) and partial least-squares regression(PLS) methods.The correlation coefficient R of established MLR,PLS models,leave-one-out(LOO) cross-validation(CV),Q2ext were 0.9951,0.9942,0.9839(MLR) and 0.9925,0.9915,0.9833(PLS),respectively.Results showed that the model exhibited excellent estimate capability for internal sample set and good predictive capability for external sample set.By using MEDV descriptors,the QSRR model can provide a simple and rapid way to predict the gas-chromatographic retention indices of polychlorinated dibenzothiophenes in conditions of lacking standard samples or poor experimental conditions.
基金NSF of China under Contract No. 41030742NBRP of China (973 Program) under Grant No.2011CB013605Scientific Research Foundation of Graduate School of Southwest Jiaotong University
文摘The peak ground acceleration (PGA), the volume of a sliding mass V, the height of a mountain HL and the slope angle θ of a mountain are four important parameters affecting the horizontal run-out distance of a landslide L. Correlations among them are studied statistically based on field investigations from 67 landslides triggered by the ground shaking and other factors during the Wenchuan earthquake, and then a prediction model for horizontal run-out distance L is developed in this study. This model gives due consideration to the implications of the above four parameters on the horizontal run-out distance L and the validity of the model is verified by the Donghekou and Magong Woqian landslides. At the same time, the advantages of the model are shown by comparing it with two other common prediction methods. The major findings drawn from the analyses and comparisons are: (1) an exponential relationship exists between L and log V, L and log HL, L and log PGA separately, but a negative exponential relationship exists between L and log tan0, which agrees with the statistical results; and (2) according to the analysis results of the relative relationship between the height of a mountain (H) and the place where the landslides occur, the probabilities at distances of2H/3-H, H/3-2H/3, and O-H/3 are 70.8%, 15.4%, and 13.8%, respectively, revealing that most landslides occurred at a distance of H/2-H. This prediction model can provide an effective technical support for the prevention and mitigation of landslide hazards.
基金supported by the Youth Foundation of Education Bureau,Sichuan Province (09ZB036)Technology Bureau,Sichuan Province (2006j13-141)
文摘Atoms in most organic molecules are often carbon,oxygen,nitrogen,sulfur,halogens,etc. Based on the three-dimensional structure of a molecule,a molecular structural characterization(MSC) method called improved molecular electronegativity-distance vector(I-MEDV) was developed. It was used to describe the structures of 37 compounds of styrax japonicus sieb flowers. Through multiple linear regression(MLR),a QSRR model was built up. The correlation coefficient(R1) of the model was 0.980. Then,4 vectors were selected to build another model through the method of stepwise multiple regression(SMR) ,and the correlation coefficient(R2) of the model was 0.975. Moreover,all the two models were evaluated by performing the crossvalidation with the leave-one-out(LOO) procedure and the correlation coefficients(Rcv) were 0.948 and 0.968,respectively. The results show that the I-MEDV could successfully describe the structures of organic compounds. The stability and predictability of the models were good.
文摘The distance effect of the doped heteroatoms away from the catalytic centers has rarely been reported.In this work,we conducted density functional theory calculations to thoroughly investigate the influence of heteroatom(N,P,B,and S atoms)doping distance on the oxygen reduction reaction(ORR)activity of graphene-based FeN_(4)sites.We uncovered a Sabatier-like relationship between heteroatom doping distance and ORR activity of FeN_(4)sites.The nearest doping does not significantly improve and even block the ORR activity of FeN_(4)sites.Optimal ORR activity is achieved when the heteroatoms are 4-5Å(N,P,and S atoms)or 6-7Å(B atoms)away from the Fe atoms.Analysis of electronic structure indicates that distance effect can modulate the local chemical environment of Fe atoms,thereby account for the changes in ORR activity along with the doping distance and doping atoms.This study provides insights into the influence of heteroatom doping on the chemical environment of reaction active centers,and provides the theoretical guidance for controlling the doping distance of heteroatoms to achieve optimal catalytic activity and selectivity.
基金This work was supported by the Chunhui Project Fund of the Ministry of Education(Grant No.SCPF99-4-4+37)Fok Ying-Tung Educational Foundation(Grant No.FYTF98-7-6)+1 种基金Chongqing Applied Science Fund(Grant No,CASF01-3-6)Chongqing University ZYXT Innovation Fund(Grant No.CUIF03-5-6+04-10-10).
文摘Based on the identical group as a pseudo atom instead of a typical atom, a novel modified molecular dis-tance-edge (MDE) vector μ was developed in our laboratory to characterize chemical structure of polychlorinated diben-zofurans (PCDFs) congeners and/or isomers. Quantitative structure-retention relationships (QSRRs) between the new VMDE parameters and gas chromatographic (GC) retention behavior of PCDFs were then generated by multiple linear regression (MLR) method for non-polar, moderately polar, and polar stationary phases. Four excellent models with high correlation coefficients, R=0.984-0.995, were proposed for non-polar columns (DB-5, SE-54, OV-101). For the moder-ately polar columns (OV-1701), the correlation coefficient of the developed good model is only 0.958. For the polar col-umns (SP-2300), the QSRR model is poor with R=0.884. Then cross validation with leave-one out of procedure (CV) is performed in high correlation with the non-polar (Rcv=992-0.974) and weakly polar (Rcv=921) columns and in little cor-relation (Rcv=0.834) with the polar columns. These results show that the new μ vector is suitable for describing the re-tention behaviors of PCDFs on non-polar and moderately polar stationary phases and not for the various gas chroma-tographic retention behaviors of PCDFs on the different po-larity-varying stationary phases.