High efficiency,cost-effective and durable electrocatalysts are of pivotal importance in energy conversion and storage systems.The electro-oxidation of water to oxygen plays a crucial role in such energy conversion te...High efficiency,cost-effective and durable electrocatalysts are of pivotal importance in energy conversion and storage systems.The electro-oxidation of water to oxygen plays a crucial role in such energy conversion technologies.Herein,we report a robust method for the synthesis of a bimetallic alkoxide for efficient oxygen evolution reaction(OER)for alkaline electrolysis,which yields current density of 10 mA cm^(-2)at an overpotential of 215 mV in 0.1 M KOH electrolyte.The catalyst demonstrates an excellent durability for more than 540 h operation with negligible degradation in activity.Raman spectra revealed that the catalyst underwent structure reconstruction during OER,evolving into oxyhydroxide,which was the active site proceeding OER in alkaline electrolyte.In-situ synchrotron X-ray absorption experiment combined with density functional theory calculation suggests a lattice oxygen involved electrocatalytic reaction mechanism for the in-situ generated nickel–iron bimetal-oxyhydroxide catalyst.This mechanism together with the synergy between nickel and iron are responsible for the enhanced catalytic activity and durability.These findings provide promising strategies for the rational design of nonnoble metal OER catalysts.展开更多
Cu-Co bi-metal catalysts derived from CuO/LaCoO3 perovskite structure were prepared by one-step citrate complexing method, and the structure evolution reaction from CuO/LaCoO3 to Cu-Co2C/La202CO3 under 1-12 pretreatme...Cu-Co bi-metal catalysts derived from CuO/LaCoO3 perovskite structure were prepared by one-step citrate complexing method, and the structure evolution reaction from CuO/LaCoO3 to Cu-Co2C/La202CO3 under 1-12 pretreatment was investigated by techniques of XRD, TPR and TEM. The results suggest that a much higher dispersion of copper significantly enhanced the reduction of cobalt, and a stronger interaction between copper and cobalt ions in LaCoO3 particles led to the formation of bi-metallic Cu-Co particles in the reduced catalysts and the enrichment of Co on the surface of bimetallic particles. The prepared catalysts were highly active and selective for the alcohol synthesis from syngas due to the presence of copper-modified C02C species.展开更多
An orthogonal experiment scheme was designed to investigate the effects of the Cu content,compaction pressure,and sintering temperature on the microstructures and mechanical and thermal properties of(30−50)wt.%Cu/Inva...An orthogonal experiment scheme was designed to investigate the effects of the Cu content,compaction pressure,and sintering temperature on the microstructures and mechanical and thermal properties of(30−50)wt.%Cu/Invar bi-metal matrix composites fabricated via spark plasma sintering(SPS).The results indicated that as the Cu content increased from 30 to 50 wt.%,a continuous Cu network gradually appeared,and the density,thermal conductivity(TC)and coefficient of thermal expansion of the composites noticeably increased,but the tensile strength decreased.The increase in the sintering temperature promoted the Cu/Invar interface diffusion,leading to a reduction in the TC but an enhancement in the tensile strength of the composites.The compaction pressure comprehensively affected the thermal properties of the composites.The 50wt.%Cu/Invar composite sintered at 700℃ and 60 MPa had the highest TC(90.7 W/(m·K)),which was significantly higher than the TCs obtained for most of the previously reported Cu/Invar composites.展开更多
LaFeO3 perovskite supported Ni and Ni-Fe catalysts were prepared and applied to methanation reaction of syngas. Two preparation methods were employed. One was one-step citrate complexing method, and the other was a tw...LaFeO3 perovskite supported Ni and Ni-Fe catalysts were prepared and applied to methanation reaction of syngas. Two preparation methods were employed. One was one-step citrate complexing method, and the other was a two step method using citrate complexing method to produce LaFeO3 and followed by loading nickel oxide on it with impregnation. The structure evolution of the sample as prepared was investigated by XRD, TPR and TEM techniques. For the former, the chemical composites of the calcined sample are NiO-Fe2O3/LaFe1-xNixO3. After reduction and reaction of CO methanation, its composites convert to Fe-Ni@Ni/LaFeO3-La2O2CO3, in which Fe-Ni@Ni is metal particles in nano-size composed of nickel core and Fe-Ni alloy shell. For the latter, the chemical composites of the calcined sample are NiO/LaFeO3; and after reduction and reaction of CO methanation, its chemical composites change to Ni/LaFeO3. Ni/LaFeO3 catalyst is a little more active, while Fe-Ni@Ni/LaFeO3-La2O2CO3 is much more stable and shows very good resistance to carbon deposition. In this work it is aimed to show that the structure and composites of the catalysts can be tailored using perovskite-type oxide as precursor with different preparing method or preparing condition. Therefore, it is a promising route to prepare supported bi-metal catalysts in nano-size for a lot of metals with desired catalytic performances.展开更多
Two kinds of bi-metal composite parts (Sn-15%Pb and Pb-22%Sn bi-metal system, and Al-7%Si and SiCp/6061 MMC bi-metal system) were prepared by the strain-induced melt activated thixo-forging. The interfaces of the bi...Two kinds of bi-metal composite parts (Sn-15%Pb and Pb-22%Sn bi-metal system, and Al-7%Si and SiCp/6061 MMC bi-metal system) were prepared by the strain-induced melt activated thixo-forging. The interfaces of the bi-metal composites were observed by OM and SEM. The observations show that the semisolid metals keep independence during thixo-forging. The solid phases in the semisolid slurries maintain their original morphologies after thixo-forging. The liquid phases near the interface mix together and form a thin layer. The interfaces are bonded firmly with the metallurgical bonding. No oxide layers are found at the interfaces. Strengths of the interfaces were investigated by the micro-hardness test. The experimental results show that the composite interfaces have high strength. However, the agglomerated enhancing particles cause fine defect on the interface of the Al-7%Si and SiCr/6061 MMC bi-metal composite.展开更多
Bi-metal material consisting of spray-formed Al-22Si and ZL104 is a suitable candidate for applications in internal combustion engines. This research investigated the effects of surface treatment and appropriate gatin...Bi-metal material consisting of spray-formed Al-22Si and ZL104 is a suitable candidate for applications in internal combustion engines. This research investigated the effects of surface treatment and appropriate gating system on the microstructures and mechanical properties in evaluating the optimal strategy for producing high quality bi-metal materials. The bi-metal materials were prepared using ZL104 gravity casting by different pouring types around the spray-formed AI-22Si with varied surface treatments. The wettability between AI-22Si and ZL104 was significantly improved when Zn coating was used to remove the natural oxide layer. This research also obtained the improved interfacial microstructures and interracial bonding strength for materials when applying the appropriate pouring method. The hardness profiles of AI-22Si/ZL104 bi-metal were consistent with the observed microstructures. The average tensile strength of the bi-metal material with zinc coating is -42.3 MPa, which is much higher than that with oxide film at -10 MPa. The process presented is a promising and effective approach for developing materials in the automotive industry.展开更多
This study introduces an innovative theoretical model critical for predicting stress and strain distributions in Ti/Al bi-metal sheet production and its subsequent deep drawing process.Grounded in extensive mechanical...This study introduces an innovative theoretical model critical for predicting stress and strain distributions in Ti/Al bi-metal sheet production and its subsequent deep drawing process.Grounded in extensive mechanical and geometric analysis,the model facilitates manufacturing process optimization and the production of high-quality components.Finite Element Method(FEM)simulations are integrated to examine the significant effects of die geometric parameters on metal flow dynamics and susceptibility to material stress.The model's precision is enhanced by incorporating anisotropic material properties and cohesive zone models.A rigorous experimental framework validates the model,highlighting the practical utility of optimized parameters in Ti/Al bimetal component fabrication.Additionally,uniaxial tensile tests using the Video Image Correlation-3D(VIC-3D)system provide detailed insights into material deformation,elucidating stress distribution and metal flow in composite layers.Thus,the research presents a refined methodology for the efficient production of Ti/Al bi-metal components,offering valuable knowledge transferable to various materials and processing scenarios.The findings of this work are expected to make a significant impact on material engineering and mechanical manufacturing.展开更多
Bimetallic oxides are attractive anode materials for lithium-ion batteries(LIBs)due to their large theoretical capacity.However,the low conductivity,short cycle life,and poor rate capability are the bottlenecks for th...Bimetallic oxides are attractive anode materials for lithium-ion batteries(LIBs)due to their large theoretical capacity.However,the low conductivity,short cycle life,and poor rate capability are the bottlenecks for their further applications.To overcome above issues,the basket-like polymolybdate(NiP_(6)Mo_(18))and carbon nanotubes(CNTs)were uniformly embedded on the urchin-shaped CoNiO_(2)nanospheres to yield a ternary composites CoNiO_(2)@NiP_(6)Mo_(18)/CNTs via electrostatic adsorption.The multi-level morphology of urchin spinules accelerates the diffusion rate of Li^(+);CNT improves the conductivity and enhances cycle stability of the material;and heteropoly acid contributes more redox activity centres.Thus,CoNiO_(2)@NiP_(6)Mo_(18)/CNTs as an anode of LIBs exhibits a high initial capacity(1396.7 mA h g^(−1)at 0.1 A g^(−1)),long-term cycling stability(750.2 mA h g^(−1)after 300 cycles),and rate performance(450.3 mA h g^(−1)at 2 A g^(−1)),which are superior to reported metallic oxides anode of LIBs.The density functional theory(DFT)and kinetic mechanism suggest that CoNiO_(2)@NiP_(6)Mo_(18)/CNTs delivers an outstanding pseudocapacitance and rapid Li^(+)diffusion behaviors,which is due to the rich surface area of the urchin-like CoNiO_(2)with the uniform embeddedness of NiP_(6)Mo_(18)and CNTs.This study provides a new idea for optimizing the performance of bimetallic oxides and developing high-rate lithium-ion battery composites.展开更多
This paper examines the interface development between a single crystalline Ag matrix and core-shell AgnCom nanoclusters that have been deposited with energies varying between 0.25 eV and 1.5 eV per atom using computer...This paper examines the interface development between a single crystalline Ag matrix and core-shell AgnCom nanoclusters that have been deposited with energies varying between 0.25 eV and 1.5 eV per atom using computer modeling techniques. Clusters undergo deformation as a result of the slowing down;they may also become epitaxial with the substrate and maintain their core-shell structure. A detailed analysis of the effects of the cluster-surface interaction is conducted over a realistic size and energy range, and a model is created to show how clusters accumulate. It is discovered that both the silver shells and the cobalt cluster cores exhibit limited epitaxy with the substrate, and that the contact produced is only a few atomic layers thick. The effect is higher for Ag shells than for Co cores, and it is not very energy dependent.展开更多
在导弹类金属-介质复合目标电磁散射特性求解过程中,采用常规迭代求解方法存在难以收敛以及内迭代边界积分区域重复求解的问题。针对该问题,在传统有限元边界积分区域分解法(finite element boundary integral domain decomposition met...在导弹类金属-介质复合目标电磁散射特性求解过程中,采用常规迭代求解方法存在难以收敛以及内迭代边界积分区域重复求解的问题。针对该问题,在传统有限元边界积分区域分解法(finite element boundary integral domain decomposition method,FE-BI-DDM)的基础上,采用了更为灵活的多区多求解器的方法(multi domain multi solver method,MDMSM)。该方法对导弹类金属-介质复合目标中难以收敛的金属区域,使用快速直接求逆的方法求解,由于可以使用独立的网格模型进行电磁建模,避免了内迭代部分的模型重复建立过程,从而大幅减少了整体模型求解时间。实验结果表明:所提方法可以在相同计算精度的条件下,以不过多增加内存空间为前提,大幅缩短了导弹类目标的金属-介质复合模型的电磁求解时间。该方法为开展导弹类目标特性分析提供了一条可行的技术途径。展开更多
Seeking and developing efficient CO_(2)reduction reaction(CO_(2)RR)electrocatalysts is a hot topic in this era of global warming.Among material candidates for sustainable and cost-effective applications,metal sulfides...Seeking and developing efficient CO_(2)reduction reaction(CO_(2)RR)electrocatalysts is a hot topic in this era of global warming.Among material candidates for sustainable and cost-effective applications,metal sulfides have attracted attention as promising nature-inspired materials due to multiple adsorption sites which are enhanced by the covalent character of sulfur.This article summarizes the current status regarding the utilization and development of metal sulfide materials as CO_(2)RR electrocatalysts.First,the research background and basic principles of electrochemical CO_(2)RR are introduced.Next,an overview of the main obstacles to developing efficient CO_(2)RR electrocatalysts is presented.The section is followed by a summary of the empirical evidence supporting the application of metal sulfides as CO_(2)RR electrocatalysts beside nature-inspired motivation.The summary of synthesis methods of various metal sulfides is also presented.Furthermore,the paper also highlights the recent works on metal sulfide as efficient CO_(2)RR including the undertaking strategy on the activity enhancement,and finally,discusses the challenges and prospect of metal sulfides-based CO_(2)RR electrocatalysts.Despite recent efforts,metal sulfides remain relatively unexplored as materials for CO_(2)RR electrocatalytic applications.Therefore,this review aims to stimulate novel ideas and research for improved catalyst designs and functionality.展开更多
基金the staff at Beamline (BL08U1-A and BL11B)of the Shanghai Synchrotron Radiation Facility (SSRF)the support from the National Key Research&Development Program of China (2022YFB3803700)+2 种基金the National Natural Science Foundation of China (52171186)the support through the Overseas Outstanding Youth Fund and Shanghai Pujiang Talent Project (21PJ1408500)the financial support from the Center of Hydrogen Science,Shanghai Jiao Tong University。
文摘High efficiency,cost-effective and durable electrocatalysts are of pivotal importance in energy conversion and storage systems.The electro-oxidation of water to oxygen plays a crucial role in such energy conversion technologies.Herein,we report a robust method for the synthesis of a bimetallic alkoxide for efficient oxygen evolution reaction(OER)for alkaline electrolysis,which yields current density of 10 mA cm^(-2)at an overpotential of 215 mV in 0.1 M KOH electrolyte.The catalyst demonstrates an excellent durability for more than 540 h operation with negligible degradation in activity.Raman spectra revealed that the catalyst underwent structure reconstruction during OER,evolving into oxyhydroxide,which was the active site proceeding OER in alkaline electrolyte.In-situ synchrotron X-ray absorption experiment combined with density functional theory calculation suggests a lattice oxygen involved electrocatalytic reaction mechanism for the in-situ generated nickel–iron bimetal-oxyhydroxide catalyst.This mechanism together with the synergy between nickel and iron are responsible for the enhanced catalytic activity and durability.These findings provide promising strategies for the rational design of nonnoble metal OER catalysts.
基金supported by the Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Provincethe Ph.D.Programs Foundation of Liaocheng University(No.31805)the NSF of China(21263011,21376170)
文摘Cu-Co bi-metal catalysts derived from CuO/LaCoO3 perovskite structure were prepared by one-step citrate complexing method, and the structure evolution reaction from CuO/LaCoO3 to Cu-Co2C/La202CO3 under 1-12 pretreatment was investigated by techniques of XRD, TPR and TEM. The results suggest that a much higher dispersion of copper significantly enhanced the reduction of cobalt, and a stronger interaction between copper and cobalt ions in LaCoO3 particles led to the formation of bi-metallic Cu-Co particles in the reduced catalysts and the enrichment of Co on the surface of bimetallic particles. The prepared catalysts were highly active and selective for the alcohol synthesis from syngas due to the presence of copper-modified C02C species.
基金the International Science&Technology Cooperation Program of China(No.2014DFA50860).
文摘An orthogonal experiment scheme was designed to investigate the effects of the Cu content,compaction pressure,and sintering temperature on the microstructures and mechanical and thermal properties of(30−50)wt.%Cu/Invar bi-metal matrix composites fabricated via spark plasma sintering(SPS).The results indicated that as the Cu content increased from 30 to 50 wt.%,a continuous Cu network gradually appeared,and the density,thermal conductivity(TC)and coefficient of thermal expansion of the composites noticeably increased,but the tensile strength decreased.The increase in the sintering temperature promoted the Cu/Invar interface diffusion,leading to a reduction in the TC but an enhancement in the tensile strength of the composites.The compaction pressure comprehensively affected the thermal properties of the composites.The 50wt.%Cu/Invar composite sintered at 700℃ and 60 MPa had the highest TC(90.7 W/(m·K)),which was significantly higher than the TCs obtained for most of the previously reported Cu/Invar composites.
基金supported by the Financial support from the NSF of China(21066007)the NSF of Tianjin China(10JCZDJC23800)the NSF of Mongolia China(2009BS0203)
文摘LaFeO3 perovskite supported Ni and Ni-Fe catalysts were prepared and applied to methanation reaction of syngas. Two preparation methods were employed. One was one-step citrate complexing method, and the other was a two step method using citrate complexing method to produce LaFeO3 and followed by loading nickel oxide on it with impregnation. The structure evolution of the sample as prepared was investigated by XRD, TPR and TEM techniques. For the former, the chemical composites of the calcined sample are NiO-Fe2O3/LaFe1-xNixO3. After reduction and reaction of CO methanation, its composites convert to Fe-Ni@Ni/LaFeO3-La2O2CO3, in which Fe-Ni@Ni is metal particles in nano-size composed of nickel core and Fe-Ni alloy shell. For the latter, the chemical composites of the calcined sample are NiO/LaFeO3; and after reduction and reaction of CO methanation, its chemical composites change to Ni/LaFeO3. Ni/LaFeO3 catalyst is a little more active, while Fe-Ni@Ni/LaFeO3-La2O2CO3 is much more stable and shows very good resistance to carbon deposition. In this work it is aimed to show that the structure and composites of the catalysts can be tailored using perovskite-type oxide as precursor with different preparing method or preparing condition. Therefore, it is a promising route to prepare supported bi-metal catalysts in nano-size for a lot of metals with desired catalytic performances.
基金Project(1343-71333000469) supported by the Funding of Graduate Student Training of Central South University,China
文摘Two kinds of bi-metal composite parts (Sn-15%Pb and Pb-22%Sn bi-metal system, and Al-7%Si and SiCp/6061 MMC bi-metal system) were prepared by the strain-induced melt activated thixo-forging. The interfaces of the bi-metal composites were observed by OM and SEM. The observations show that the semisolid metals keep independence during thixo-forging. The solid phases in the semisolid slurries maintain their original morphologies after thixo-forging. The liquid phases near the interface mix together and form a thin layer. The interfaces are bonded firmly with the metallurgical bonding. No oxide layers are found at the interfaces. Strengths of the interfaces were investigated by the micro-hardness test. The experimental results show that the composite interfaces have high strength. However, the agglomerated enhancing particles cause fine defect on the interface of the Al-7%Si and SiCr/6061 MMC bi-metal composite.
基金financially supported by the National Natural Science Foundation of China(No.51375110)
文摘Bi-metal material consisting of spray-formed Al-22Si and ZL104 is a suitable candidate for applications in internal combustion engines. This research investigated the effects of surface treatment and appropriate gating system on the microstructures and mechanical properties in evaluating the optimal strategy for producing high quality bi-metal materials. The bi-metal materials were prepared using ZL104 gravity casting by different pouring types around the spray-formed AI-22Si with varied surface treatments. The wettability between AI-22Si and ZL104 was significantly improved when Zn coating was used to remove the natural oxide layer. This research also obtained the improved interfacial microstructures and interracial bonding strength for materials when applying the appropriate pouring method. The hardness profiles of AI-22Si/ZL104 bi-metal were consistent with the observed microstructures. The average tensile strength of the bi-metal material with zinc coating is -42.3 MPa, which is much higher than that with oxide film at -10 MPa. The process presented is a promising and effective approach for developing materials in the automotive industry.
基金supported by the National Natural Science Foundation of China(No.52005432,51674222)the Natural Science Foundation of Hebei Province of Iron and Steel Research(No.E2021203179)+1 种基金the Chinese Post-doctoral Science Foundation(No.2020M680904)the Foundation of Hebei Province Post-Doctoral Preferred Project(No.B2020003011)。
文摘This study introduces an innovative theoretical model critical for predicting stress and strain distributions in Ti/Al bi-metal sheet production and its subsequent deep drawing process.Grounded in extensive mechanical and geometric analysis,the model facilitates manufacturing process optimization and the production of high-quality components.Finite Element Method(FEM)simulations are integrated to examine the significant effects of die geometric parameters on metal flow dynamics and susceptibility to material stress.The model's precision is enhanced by incorporating anisotropic material properties and cohesive zone models.A rigorous experimental framework validates the model,highlighting the practical utility of optimized parameters in Ti/Al bimetal component fabrication.Additionally,uniaxial tensile tests using the Video Image Correlation-3D(VIC-3D)system provide detailed insights into material deformation,elucidating stress distribution and metal flow in composite layers.Thus,the research presents a refined methodology for the efficient production of Ti/Al bi-metal components,offering valuable knowledge transferable to various materials and processing scenarios.The findings of this work are expected to make a significant impact on material engineering and mechanical manufacturing.
基金supported by the National Science Foundation of China(22171061,21771046,and 22272143)the 2020 Central Government's Plan to Support the Talent Training Project of the Reform and Development Fund of Local Universities(2020GSP03)+1 种基金the Natural Science Foundation of Heilongjiang Province of China(ZD2021B002)the Fundamental Research Funds for the Central Universities(20720220009).
文摘Bimetallic oxides are attractive anode materials for lithium-ion batteries(LIBs)due to their large theoretical capacity.However,the low conductivity,short cycle life,and poor rate capability are the bottlenecks for their further applications.To overcome above issues,the basket-like polymolybdate(NiP_(6)Mo_(18))and carbon nanotubes(CNTs)were uniformly embedded on the urchin-shaped CoNiO_(2)nanospheres to yield a ternary composites CoNiO_(2)@NiP_(6)Mo_(18)/CNTs via electrostatic adsorption.The multi-level morphology of urchin spinules accelerates the diffusion rate of Li^(+);CNT improves the conductivity and enhances cycle stability of the material;and heteropoly acid contributes more redox activity centres.Thus,CoNiO_(2)@NiP_(6)Mo_(18)/CNTs as an anode of LIBs exhibits a high initial capacity(1396.7 mA h g^(−1)at 0.1 A g^(−1)),long-term cycling stability(750.2 mA h g^(−1)after 300 cycles),and rate performance(450.3 mA h g^(−1)at 2 A g^(−1)),which are superior to reported metallic oxides anode of LIBs.The density functional theory(DFT)and kinetic mechanism suggest that CoNiO_(2)@NiP_(6)Mo_(18)/CNTs delivers an outstanding pseudocapacitance and rapid Li^(+)diffusion behaviors,which is due to the rich surface area of the urchin-like CoNiO_(2)with the uniform embeddedness of NiP_(6)Mo_(18)and CNTs.This study provides a new idea for optimizing the performance of bimetallic oxides and developing high-rate lithium-ion battery composites.
文摘This paper examines the interface development between a single crystalline Ag matrix and core-shell AgnCom nanoclusters that have been deposited with energies varying between 0.25 eV and 1.5 eV per atom using computer modeling techniques. Clusters undergo deformation as a result of the slowing down;they may also become epitaxial with the substrate and maintain their core-shell structure. A detailed analysis of the effects of the cluster-surface interaction is conducted over a realistic size and energy range, and a model is created to show how clusters accumulate. It is discovered that both the silver shells and the cobalt cluster cores exhibit limited epitaxy with the substrate, and that the contact produced is only a few atomic layers thick. The effect is higher for Ag shells than for Co cores, and it is not very energy dependent.
文摘在导弹类金属-介质复合目标电磁散射特性求解过程中,采用常规迭代求解方法存在难以收敛以及内迭代边界积分区域重复求解的问题。针对该问题,在传统有限元边界积分区域分解法(finite element boundary integral domain decomposition method,FE-BI-DDM)的基础上,采用了更为灵活的多区多求解器的方法(multi domain multi solver method,MDMSM)。该方法对导弹类金属-介质复合目标中难以收敛的金属区域,使用快速直接求逆的方法求解,由于可以使用独立的网格模型进行电磁建模,避免了内迭代部分的模型重复建立过程,从而大幅减少了整体模型求解时间。实验结果表明:所提方法可以在相同计算精度的条件下,以不过多增加内存空间为前提,大幅缩短了导弹类目标的金属-介质复合模型的电磁求解时间。该方法为开展导弹类目标特性分析提供了一条可行的技术途径。
基金The present work was supported by JSPS KAKENHI(Grant number 18H05159)in Scientific Research on Innovative Areas“Innovations for Light Energy Conversion(I4 LEC)”from MEXT,Japan,and was also supported by the JST Strategic International Collaborative Research Program(SICORP),Japan(Grant number JPMJSC18H7)International Science and Technology Cooperation Program(Grant No.2017YFE0127800),China.
文摘Seeking and developing efficient CO_(2)reduction reaction(CO_(2)RR)electrocatalysts is a hot topic in this era of global warming.Among material candidates for sustainable and cost-effective applications,metal sulfides have attracted attention as promising nature-inspired materials due to multiple adsorption sites which are enhanced by the covalent character of sulfur.This article summarizes the current status regarding the utilization and development of metal sulfide materials as CO_(2)RR electrocatalysts.First,the research background and basic principles of electrochemical CO_(2)RR are introduced.Next,an overview of the main obstacles to developing efficient CO_(2)RR electrocatalysts is presented.The section is followed by a summary of the empirical evidence supporting the application of metal sulfides as CO_(2)RR electrocatalysts beside nature-inspired motivation.The summary of synthesis methods of various metal sulfides is also presented.Furthermore,the paper also highlights the recent works on metal sulfide as efficient CO_(2)RR including the undertaking strategy on the activity enhancement,and finally,discusses the challenges and prospect of metal sulfides-based CO_(2)RR electrocatalysts.Despite recent efforts,metal sulfides remain relatively unexplored as materials for CO_(2)RR electrocatalytic applications.Therefore,this review aims to stimulate novel ideas and research for improved catalyst designs and functionality.
基金The project was supported by National Key R&D Plan (2020YFA0210900)National Natural Science Foundation of China (21991090, 21991092,22272195, U22A20431)Youth Innovation Promotion Association of Chinese Academy of Sciences (2021172)。