Alloyed-type anode materials with high-energy density for lithium and sodium ion batteries attracted much attention of the researchers. However, substantial volume expansion of these materials in the devices during re...Alloyed-type anode materials with high-energy density for lithium and sodium ion batteries attracted much attention of the researchers. However, substantial volume expansion of these materials in the devices during repeated electrochemical process leads to fast capacity fading and hinders their further practical application. Nanotechnology could act as a useful tool to effectively address the issue. Herein, lotus-stalk Bi4Ge3O12 nanosheets vertically grown on the nickel foam (denoted as Bi4Ge3O12 NSs@NF) were prepared via a straight-forward solvothermal method. Benefiting from their three dimensional (3D) conductive framework and two dimensional (2D) lotus-stalk Bi4Ge3O12 nanosheet structure, as anode materials of lithium-ion batteries (LIBs) and sodium-ion batteries (NIBs), the electrochemical performances of Bi4Ge3O12 NSs@NF were greatly enhanced as a result of mitigating the huge volume variations during cycles. The Bi4Ge3O12 NSs@NF electrodes delivered a high reversible capacity of 1033.1 mAh/g for the first cycle and exhibited 68.6%capacity retention of after 88 cycles at 0.10 A/g in the voltage window of 0.01~3.0 V versus Li/Li+. In the test of NIBs, the lotus-stalk Bi4Ge3O12 composite electrodes still stored Na+as high as 332.3 mAh/g at 0.10 A/g over 100 sodiation/desodiation repeating cycles.展开更多
Ⅰ. INTRODUCTION Crystalline Bi4Ge2O12 （BGO） is one of the typical scintillation crystals, Bi3+ ions are its active centres. Amorphous bismuth germanite glasses containing higher bismuth have attracted great attenti...Ⅰ. INTRODUCTION Crystalline Bi4Ge2O12 （BGO） is one of the typical scintillation crystals, Bi3+ ions are its active centres. Amorphous bismuth germanite glasses containing higher bismuth have attracted great attention because of the scintillation property it展开更多
基金supported by the National Natural science Foundation of China (No. U1804138)the Science Foundation of Henan Province (No. 162300410209)+1 种基金the Key Scientific Research Project of High Schools in Henan Province (No. 17A480009)the Special Key Research Program of Henan Province (No. 182102210488)
文摘Alloyed-type anode materials with high-energy density for lithium and sodium ion batteries attracted much attention of the researchers. However, substantial volume expansion of these materials in the devices during repeated electrochemical process leads to fast capacity fading and hinders their further practical application. Nanotechnology could act as a useful tool to effectively address the issue. Herein, lotus-stalk Bi4Ge3O12 nanosheets vertically grown on the nickel foam (denoted as Bi4Ge3O12 NSs@NF) were prepared via a straight-forward solvothermal method. Benefiting from their three dimensional (3D) conductive framework and two dimensional (2D) lotus-stalk Bi4Ge3O12 nanosheet structure, as anode materials of lithium-ion batteries (LIBs) and sodium-ion batteries (NIBs), the electrochemical performances of Bi4Ge3O12 NSs@NF were greatly enhanced as a result of mitigating the huge volume variations during cycles. The Bi4Ge3O12 NSs@NF electrodes delivered a high reversible capacity of 1033.1 mAh/g for the first cycle and exhibited 68.6%capacity retention of after 88 cycles at 0.10 A/g in the voltage window of 0.01~3.0 V versus Li/Li+. In the test of NIBs, the lotus-stalk Bi4Ge3O12 composite electrodes still stored Na+as high as 332.3 mAh/g at 0.10 A/g over 100 sodiation/desodiation repeating cycles.
文摘Ⅰ. INTRODUCTION Crystalline Bi4Ge2O12 （BGO） is one of the typical scintillation crystals, Bi3+ ions are its active centres. Amorphous bismuth germanite glasses containing higher bismuth have attracted great attention because of the scintillation property it
