We investigate the dielectric and ferroelectric properties of Sr1-xBixTi1-xFex03 solid solutions （x =0, 0.05, 0.1, 0.15 and 0.2） together with their structures. Through the analysis of Rietveld refinement of powder ...We investigate the dielectric and ferroelectric properties of Sr1-xBixTi1-xFex03 solid solutions （x =0, 0.05, 0.1, 0.15 and 0.2） together with their structures. Through the analysis of Rietveld refinement of powder x-ray diffraction, a cubic structure in space group Pm3m is determined for all the compositions. An obvious dielectric relaxation peak differing from SrTiO3 is observed in the present ceramics. The peak temperature Tm increases with increasing x, and it approaches room temperature at x =0.2. The Vogel Fulcher law and Curie Weiss law fittings further confirm the relaxor ferroelectricity in the present ceramics.展开更多
Bismuth ferrite(BiFeO3)-based materials are multiferroic materials widely studied.This study reports that strong ferroelectricity and enhanced magnetic performance are simultaneously obtained in the quenched(1−x)BiFeO...Bismuth ferrite(BiFeO3)-based materials are multiferroic materials widely studied.This study reports that strong ferroelectricity and enhanced magnetic performance are simultaneously obtained in the quenched(1−x)BiFeO3−xBaTiO3(BFBT100x,x=0.2 and 0.3)ceramics.Quenching treatment can reduce the amount of defects and Fe2+ions and make the defect dipole in a random state,which is conducive to improving the ferroelectricity and magnetism.Compared with the conventional sintered samples,the quenched ceramics have higher remnant and saturation polarization.As for magnetism,the coercive field(Hc)of the quenched ceramics is smaller and the quenching treatment can increase the maximum magnetization by up to 15%.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 51332006,11274270,and 51272233
文摘We investigate the dielectric and ferroelectric properties of Sr1-xBixTi1-xFex03 solid solutions （x =0, 0.05, 0.1, 0.15 and 0.2） together with their structures. Through the analysis of Rietveld refinement of powder x-ray diffraction, a cubic structure in space group Pm3m is determined for all the compositions. An obvious dielectric relaxation peak differing from SrTiO3 is observed in the present ceramics. The peak temperature Tm increases with increasing x, and it approaches room temperature at x =0.2. The Vogel Fulcher law and Curie Weiss law fittings further confirm the relaxor ferroelectricity in the present ceramics.
基金This study was supported by the National Natural Science Foundation of China (51502054)the Postdoctoral Science Foundation of China (2014M551236)the Postdoctoral Science Foundation of Heilongjiang Province (LBH-Z14083).
文摘Bismuth ferrite(BiFeO3)-based materials are multiferroic materials widely studied.This study reports that strong ferroelectricity and enhanced magnetic performance are simultaneously obtained in the quenched(1−x)BiFeO3−xBaTiO3(BFBT100x,x=0.2 and 0.3)ceramics.Quenching treatment can reduce the amount of defects and Fe2+ions and make the defect dipole in a random state,which is conducive to improving the ferroelectricity and magnetism.Compared with the conventional sintered samples,the quenched ceramics have higher remnant and saturation polarization.As for magnetism,the coercive field(Hc)of the quenched ceramics is smaller and the quenching treatment can increase the maximum magnetization by up to 15%.
