Wearing helmetswhile riding electric bicycles can significantly reduce head injuries resulting fromtraffic accidents.To effectively monitor compliance,the utilization of target detection algorithms through traffic cam...Wearing helmetswhile riding electric bicycles can significantly reduce head injuries resulting fromtraffic accidents.To effectively monitor compliance,the utilization of target detection algorithms through traffic cameras plays a vital role in identifying helmet usage by electric bicycle riders and recognizing license plates on electric bicycles.However,manual enforcement by traffic police is time-consuming and labor-intensive.Traditional methods face challenges in accurately identifying small targets such as helmets and license plates using deep learning techniques.This paper proposes an enhanced model for detecting helmets and license plates on electric bicycles,addressing these challenges.The proposedmodel improves uponYOLOv8n by deepening the network structure,incorporating weighted connections,and introducing lightweight convolutional modules.These modifications aim to enhance the precision of small target recognition while reducing the model’s parameters,making it suitable for deployment on low-performance devices in real traffic scenarios.Experimental results demonstrate that the model achieves an mAP@0.5 of 91.8%,showing an 11.5%improvement over the baselinemodel,with a 16.2%reduction in parameters.Additionally,themodel achieves a frames per second(FPS)rate of 58,meeting the accuracy and speed requirements for detection in actual traffic scenarios.展开更多
In this study,a detailed analysis of the combustion behaviors of the lithium iron phosphate(LFP)and lithium manganese oxide(LMO)batteries used in electric bicycles was conducted.This research included quantitative mea...In this study,a detailed analysis of the combustion behaviors of the lithium iron phosphate(LFP)and lithium manganese oxide(LMO)batteries used in electric bicycles was conducted.This research included quantitative measurements of the combustion duration,flame height,combustion temperature,heat release rate,and total heat release.The results indicated that LMO batteries exhibited higher combustion temperatures of 600–700°C,flame heights of 70–75 cm,a significantly higher heat release rate of40.1 k W(12 Ah),and a total heat release of 1.04 MJ(12 Ah)compared to LFP batteries with the same capacity.Based on these experimental results,a normalized total heat release(NORTHR)parameter was proposed,demonstrating good universality for batteries with different capacities.Utilizing this parameter,quantitative calculations and optimization of the extinguishing agent dosage were conducted for fires involving these two types of batteries,and the method was validated by extinguishing fires for these two types of battery packs with water-based extinguishing fluids.展开更多
Objectives: The primary objective was to characterize the range of Knowledge, Attitude, and Practice (KAP) of Helmet use in children amongst parents to prevent head injuries and death. Methods: This is a cross-section...Objectives: The primary objective was to characterize the range of Knowledge, Attitude, and Practice (KAP) of Helmet use in children amongst parents to prevent head injuries and death. Methods: This is a cross-sectional study, done by online survey using a snowball sampling technique, the number of included responses were 386 parents (Male and female) living in Riyadh Aged 21 - 60 years old or above. Results: The study showed that there is a difference in Parents’ belief in the importance of helmet use while riding a Bicycle vs Motorcycle/Quad bike and that was affected by parents’ education level, almost all the people who answered the survey (76.7%) agree that it is important for their children to wear a helmet when riding both a Bicycle and a Motorcycle or Quadbike with a cumulative percentage of (93.8%). And almost all agreed on multiple approaches to help increase helmet use be it by forcing rental shops to give out helmets, forcing sellers to recommend the use of helmets, increasing awareness campaigns, and imposing fines for not wearing helmets. Conclusions: This study is the first to explore Family helmet use while riding Bicycles and Motorcycles/Quad bikes. Although Parent’s belief in the importance of helmet use for their children was high, it is clear that the level of practice is low. With that the risk of head injuries might be high, our findings suggest that safety interventions for increasing pediatric helmet use are needed to increase helmet use and reduce the risk of head injury and hospitalization.展开更多
In recent years,disorderly parking and difficult charging of electric bicycles have been challenges in urban management.The rapid growth of electric bicycles is in contradiction with the lack of dedicated parking spac...In recent years,disorderly parking and difficult charging of electric bicycles have been challenges in urban management.The rapid growth of electric bicycles is in contradiction with the lack of dedicated parking spaces and charging service facilities in towns and villages.To solve the issue of parking and charging electric bicycles in limited urban and rural spaces,prefabricated building technology is applied to the design of a multi-story electric bicycle parking lot.The multi-story prefabricated electric bicycle parking lot is utilized in urban and rural planning and design to upgrade parking facilities in old urban areas,land-constrained commercial areas,as well as counties,towns,and rural areas with inadequate municipal facilities.Multi-story prefabricated electric bicycle parking lots are the application exploration of industrial buildings,and promote the high-quality development planning and construction of towns and counties and villages.Compared with the single-story metal charging station,the multi-story assembled electric bicycle parking lot has the characteristics of integrating parking and charging,being more durable and safer in structure,accommodating a large number of vehicles,and improving the space utilization rate.展开更多
Drawing upon Donna Haraway’s cyborg theory,this paper argues that the bicycle can be conceived as a cyborg extension of body and identity which transcended its mechanical essence to become an integral co-partner for ...Drawing upon Donna Haraway’s cyborg theory,this paper argues that the bicycle can be conceived as a cyborg extension of body and identity which transcended its mechanical essence to become an integral co-partner for women involved in resistance activities in WWII.More specifically,the study explores how women used cycling during World War Ⅱ not only for mobility but as a profound expression of courage,endurance and solidarity which enabled them to overcome physical and symbolic barriers under totalitarian regimes.The bicycle emerges not only as a central co-agent but also actively co-creates the situations in which it emerges as a transformative force.Cycling acted as a catalyst for personal and collective empowerment,fostering new subjectivities while transcending physical and social limitations.This study sparks multidimensional discourse on how technological tools can co-create our societies and identities,offering insights into how bicycles can drive socio-political change,promote emancipation and foster inclusivity.展开更多
Aim To develop a concise method for the synthesis of bicyclic azasugar and thiosugar with novel scaffold. Methods The two primary hydroxyl groups of compound 1 were selectively protected with tosyl cloloride in pyridi...Aim To develop a concise method for the synthesis of bicyclic azasugar and thiosugar with novel scaffold. Methods The two primary hydroxyl groups of compound 1 were selectively protected with tosyl cloloride in pyridine, followed by ring-closure with sodium sulfide or primary amine to form the oxy-bridged bicyclic molecules in good yields. Results Two bicyclic azasugars and a thiosugar were produced from L-sorbose in several steps. Conclusion The described procedures provide an efficient method to synthesize bicyclic azasugar and thiosugar with novel scaffold as potential glycosidase inhibitors.展开更多
Background: Cycling as a means of transport contributes to public health in terms of increasing the physical activity behaviour and reducing air pollution. In comparison to walking, cycling-spe cific environmental cha...Background: Cycling as a means of transport contributes to public health in terms of increasing the physical activity behaviour and reducing air pollution. In comparison to walking, cycling-spe cific environmental characteristics have been less investigated. The aim of this study was to develop, based on geographic information systems (GIS) data, a bikeability index for a mid-sized European city, to examine the predictive validity of the index and to visualize the bicycle-friendliness of the city by creating a bikeability map. Methods: Using GIS data, we assessed the environmental characteristics of 278 bicycle trips in the city of Graz, Austria. Characteristics which differed significantly between the actually taken and shortest possible routes were used to form an additive bikeability index and the bikeability map for 100 m × 100 m cells. The relationship between the cycling behaviour and the bikeability index around the home environment was examined to assess the predictive validity of the index. Results: Three environmental components (cycling infrastructure, bicycle pathways and green areas) were positively related, and two components (main roads, and topography) were negatively related to the actually used route. These components formed the bikeability index, which was positively correlated with cycling behaviour (OR: 1.08, 95% CI 1.01 - 1.17). The final outcome is a high-resolution coloured map indicating the degree of bicycle-friendliness in the city of Graz. Conclusion: Mapping based on the bikeability index helps to visualize the bicycle-friendliness of an urban area. Therefore, it should be a useful tool for the planning as well as for the evaluation of the transport environments in cities.展开更多
Background: Cycling currently comprises only 1% of transport trips in the U.S. despite benefits for air pollution, traffic congestion, and improved public health. Methods: Building upon the Level of Traffic Stress (LT...Background: Cycling currently comprises only 1% of transport trips in the U.S. despite benefits for air pollution, traffic congestion, and improved public health. Methods: Building upon the Level of Traffic Stress (LTS) methodology, we assessed GPS trip data from utilitarian cyclists to understand route preferences and the level of low stress cycling connection between origins and destinations. GPS data were obtained from adult transport cyclists over multiple days. All bikeable road segments in the network were assigned an LTS score. The shortest paths between each origin and destination along bikeable roadways and along low stress (LTS 1 or 2) routes were calculated. Route trajectories were mapped to the LTS network, and the LTS and distances of observed, the shortest and low stress routes were compared. LTS maps and animations were developed to highlight where low stress connections were lacking. Results: There were 1038 unique cycling trips from 87 participants included in the analysis. An exclusively low stress route did not exist for 51% of trips. Low stress routes that were possible were, on average, 74% longer than the shortest possible path and 56% longer than the observed route. Observed routes were longer and lower stress than the shortest possible route. Conclusions: Results indicate that transport cyclists traveled beyond low stress residential areas and that low stress routes with acceptable detour distances were lacking. Cyclists appeared to weigh both route distance and quality and were willing to trade maximum directness for lower stress. GPS data provide additional information to support planning decisions to increase the impact of infrastructure investments on cycling mode share.展开更多
This paper investigates the passing events between electric bicycles and conventional bicycles and explores the relationships between passing events and traffic parameters in bicycle facilities.Three exclusive bicycle...This paper investigates the passing events between electric bicycles and conventional bicycles and explores the relationships between passing events and traffic parameters in bicycle facilities.Three exclusive bicycle paths in Nanjing, China,were observed with cameras.Then,the field data including vehicle number,velocity characteristics and passing event features were analyzed in detail.Data analysis and fitting reveal that the speed difference has little impact on the passing event number,as does the bicycle ratio.The Gaussian function can better describe the relationship between the passing event number and bicycle volume (density).The valid use level of bicycle path width influences the inflexion of the passing events-density fitting curve.The conclusions can be applied for estimating the passing events in mixed bicycle flows and for choosing a suitable width of separate bicycle path.展开更多
PI novel caged bicyclic phosphate flame retardant tri(1-oxo-2,6,7-trioxa-1-phosphabicyclo [2.2.2] octane-methyl) phosphate (Trimer) was synthesized from 1-oxo-4-hydroxymethyl-2,6,7-trioxa-1-phosphabicyclo [2.2.2] octa...PI novel caged bicyclic phosphate flame retardant tri(1-oxo-2,6,7-trioxa-1-phosphabicyclo [2.2.2] octane-methyl) phosphate (Trimer) was synthesized from 1-oxo-4-hydroxymethyl-2,6,7-trioxa-1-phosphabicyclo [2.2.2] octane (PEPA) and phosphorus oxychloride in this paper. Its structure was characterized by elemental analysis. FTIR, H-1 NMR. P-31 NMR and X-ray diffraction analysis.展开更多
Mobile information and communication technologies(MICTs) have fully penetrated everyday life in smart societies;this has greatly compressed time, space, and distance, and consequently, reshaped residents’ travel beha...Mobile information and communication technologies(MICTs) have fully penetrated everyday life in smart societies;this has greatly compressed time, space, and distance, and consequently, reshaped residents’ travel behaviour patterns. As a new mode of shared mobility, the sharing bicycle offers a variety of options for the daily travel of urban residents. Extant studies have mainly examined the travel characteristics and influencing factors of public bicycles with piles, while the travel patterns for sharing bicycles and their driving mechanisms have been largely ignored. Using one week’s travel data for Mobike, this study investigated the spatial and temporal distribution patterns of sharing bicycle travel behaviours in the central urban area of Guangzhou, China;furthermore, it identified the influences of built environment density factors on sharing bicycle travel behaviours based on the geographically weighted regression method. Obvious morning and evening peaks were observed in the sharing bicycle travel patterns for both weekdays and weekends. The old urban area, which had a high degree of mixed function, dense road networks, and cycling-friendly built environments, was the main travel area that attracted sharing bicycles on both weekdays and weekends. Furthermore, factors including the point of interest(POI) for the density of public transport stations, the functional mixing degree, and the density of residential POIs significantly affected residents’ travel behaviours. These findings could enrich discourse regarding shared mobility with a Chinese case characterised by rapidly developing MICTs and also provide references to local authorities for improving slow traffic environments.展开更多
To determine how bus stop design influences mixed traffic operation near Chinese bus stops,a new theoretical method was developed by using additive-conflict-flows procedure.The procedure was extended from homogeneous ...To determine how bus stop design influences mixed traffic operation near Chinese bus stops,a new theoretical method was developed by using additive-conflict-flows procedure.The procedure was extended from homogeneous traffic flow to mixed traffic flow.Based on the procedure and queuing theory,car capacity and speed models were proposed for three types of bus stops including curbside,bus bay and bicycle detour.The effects of various combinations of bus stop type,traffic volume,bus dwell time,and berth number on traffic operations were investigated.The results indicate that traffic volume,bus dwell time and berth number have negative effects on traffic operations for any type of bus stops.For different types of bus stops,at car volumes above approximately 200 vehicles per hour,the bus bay and bicycle detour designs provide more benefits than the curbside design.As traffic volume increases,the benefit firstly increases in uncongested conditions and then decreases in congested conditions.It reaches the maximum at car volumes nearly 1 100 vehicles per hour.The results can be used to aid in the selection of a preferred bus stop design for a given traffic volume in developing countries.展开更多
Sesquiterpanes are ubiquitous components of crude oils and ancient sediments.Liquid saturated hydrocarbons from simulated pyrolysis experiments on immature organic-rich mudstone collected from the Lower Cretaceous Hes...Sesquiterpanes are ubiquitous components of crude oils and ancient sediments.Liquid saturated hydrocarbons from simulated pyrolysis experiments on immature organic-rich mudstone collected from the Lower Cretaceous Hesigewula Sag were analyzed by gas chromatography-mass spectrometry(GC-MS).C14 bicyclic sesquiterpanes,namely,8β(H)-drimane,8β(H)-homodrimane,and 8 a(H)-homodrimane were detected and identified on basis of their diagnostic fragment ions(m/z123,179,193,and 207),and previously published mass spectra data,and these bicyclic sesquiterpanes presented relatively regular characteristics in their thermal evolution.The ratios 8β(H)-drimane/8β(H)-homodrimane,8β(H)-homodrimane/8 a(H)-homodrimane,and 8β(H)-drimane/8 a(H)-homodrimane all show a clear upward trend with increasing temperature below the temperature turning point.Thus,all these ratios can be used as evolution indexes of source rocks in the immature-lowmaturity stage.However,the last two ratios may be more suitable than the first ratio as valid parameters for measuring the extent of thermal evolution of organic matter in the immature-low-maturity stage because their change amplitude with increasing temperature is more obvious.展开更多
The safety and the fatigue comfort were compared between a domestic and a Japanese postal bicycle. Firstly, the fatigue comfort of these two kinds of bicycles was evaluated by surface electromyographic signal (sEMG) e...The safety and the fatigue comfort were compared between a domestic and a Japanese postal bicycle. Firstly, the fatigue comfort of these two kinds of bicycles was evaluated by surface electromyographic signal (sEMG) experiment, in which human lower limb muscle groups were research objects, and the average EMG (AEMG) index and median frequency (MF) were chosen as the evaluation indexes. Secondly, the safety of these two kinds of bicycle frames was analyzed and compared by using the finite element analysis. The results show that the riding fatigue comfort of the Japanese postal bicycle is better, and the Japanese postal bicycle frame is more safe and reasonable although both the postal bicycles meet the requirement for strength. Finally, based on the above analysis, the frame structure and related parameters of the domestic postal bicycle were improved with reference to the Japanese postal bicycle and biomechanics theory.展开更多
The atom-bond connectivity(ABC) index provides a good model for the stability of linear and branched alkanes as well as the strain energy of cycloalkanes,which is defined as ABC(G) =∑ uv∈E(G) √d u+dv-2 dudv,...The atom-bond connectivity(ABC) index provides a good model for the stability of linear and branched alkanes as well as the strain energy of cycloalkanes,which is defined as ABC(G) =∑ uv∈E(G) √d u+dv-2 dudv,where du denotes the degree of a vertex u in G.A chemical graph is a graph in which no vertex has degree greater than 4.In this paper,we obtain the sharp upper and lower bounds on ABC index of chemical bicyclic graphs.展开更多
With the development of technology and the change of market demands,the trend in middle and high grade bicycle manufacturing is developed toward small-volume,multi-species,and customer-oriented production.Therefore,hu...With the development of technology and the change of market demands,the trend in middle and high grade bicycle manufacturing is developed toward small-volume,multi-species,and customer-oriented production.Therefore,human element should be fully considered in design so that the bicycle has the best cycling performance for the specific rider.Currently,customized design is difficult to achieve since feature parameters of the rider are not included in the design.The design of bicycle frame is the most important in bicycle design.The relative positions among the saddle,handlebar and central axis are defined as the bicycle three-pivot,they are the main parameters in bicycle frame design.In conventional bicycle design,frame parameters are merely relevant to bicycle types.On the basis of the principles of biomechanics and ergonomics knowledge,this paper presents a design method for bicycle three-pivot considering feature parameters of the rider by dynamic simulation.Firstly,a dynamic model of rider-bicycle system is built for a special rider,and a serial of simulation experiments is designed by uniform test method.Then,a mathematical model is built between the three-pivot position and the square of lower limb muscle stress by using simulation and regression analysis of the rider-bicycle system.The optimal three-pivot position parameters are obtained by setting the minimal of the square of the lower limb muscle stress as the objective.Therefore,the optimal parameters are gained for the specific rider.Finally,various results are gained for different riders based on the same design process.The function between feature parameters of the rider and the optimum three-pivot position parameters is built by regression.Bicycle design considering biomechanics can be divided into three main steps:calculating the three-pivot position,designing the geometrical structure of the bicycle frame and analyzing frame strength,and selecting appropriate parts and assembling the bicycle.Bicycle design considering biomechanics changes the conventional bicycle design and realizes customized design by considering human element in the design process.展开更多
Ab initio molecular orbital calculations have been performed at Hartree-Fock (HF), second-order Mrller-Plesset (MP2), and hybrid density functional theory (DFT) B3LYP levels with 6-31G^** basis set to investig...Ab initio molecular orbital calculations have been performed at Hartree-Fock (HF), second-order Mrller-Plesset (MP2), and hybrid density functional theory (DFT) B3LYP levels with 6-31G^** basis set to investigate the low sensitive explosive trans-1,4,5,8-tetranitro-1,4,5,8- tetraazadecalin (TNAD) and its seven bicyclic isomers. Their molecular geometries, electronic structures, thermodynamic properties, and detonation performances were predicted and compared. The relationships between structures and various properties were discussed in detail. The calculated results agree well with the available experimental data, and suggest that some compounds may be novel potential candidates of high energy density materials (HEDMs) with performances better than TNT (2,4,6-trinitrotoluene) and similar to RDX (1,3,5-trinitro-1,3,5-triazacyclohexane).展开更多
基金supported by the Ningxia Key Research and Development Program(Talent Introduction Special Project)Project(2022YCZX0013)North Minzu University 2022 School-Level Scientific Research Platform“Digital Agriculture Enabling Ningxia Rural Revitalization Innovation Team”(2022PT_S10)+1 种基金Yinchuan City University-Enterprise Joint Innovation Project(2022XQZD009)Ningxia Key Research and Development Program(Key Project)Project(2023BDE02001).
文摘Wearing helmetswhile riding electric bicycles can significantly reduce head injuries resulting fromtraffic accidents.To effectively monitor compliance,the utilization of target detection algorithms through traffic cameras plays a vital role in identifying helmet usage by electric bicycle riders and recognizing license plates on electric bicycles.However,manual enforcement by traffic police is time-consuming and labor-intensive.Traditional methods face challenges in accurately identifying small targets such as helmets and license plates using deep learning techniques.This paper proposes an enhanced model for detecting helmets and license plates on electric bicycles,addressing these challenges.The proposedmodel improves uponYOLOv8n by deepening the network structure,incorporating weighted connections,and introducing lightweight convolutional modules.These modifications aim to enhance the precision of small target recognition while reducing the model’s parameters,making it suitable for deployment on low-performance devices in real traffic scenarios.Experimental results demonstrate that the model achieves an mAP@0.5 of 91.8%,showing an 11.5%improvement over the baselinemodel,with a 16.2%reduction in parameters.Additionally,themodel achieves a frames per second(FPS)rate of 58,meeting the accuracy and speed requirements for detection in actual traffic scenarios.
基金supported by the New Energy Vehicle Power Battery Life Cycle Testing and Verification Public Service Platform Project[2022-235-224]the Beijing Science and Technology Planning Project[Z221100005222004]+1 种基金the Key Technologies Research and Development Program[2021YFB2012504]the Beijing Goldenbridge Project[ZZ2023002]。
文摘In this study,a detailed analysis of the combustion behaviors of the lithium iron phosphate(LFP)and lithium manganese oxide(LMO)batteries used in electric bicycles was conducted.This research included quantitative measurements of the combustion duration,flame height,combustion temperature,heat release rate,and total heat release.The results indicated that LMO batteries exhibited higher combustion temperatures of 600–700°C,flame heights of 70–75 cm,a significantly higher heat release rate of40.1 k W(12 Ah),and a total heat release of 1.04 MJ(12 Ah)compared to LFP batteries with the same capacity.Based on these experimental results,a normalized total heat release(NORTHR)parameter was proposed,demonstrating good universality for batteries with different capacities.Utilizing this parameter,quantitative calculations and optimization of the extinguishing agent dosage were conducted for fires involving these two types of batteries,and the method was validated by extinguishing fires for these two types of battery packs with water-based extinguishing fluids.
文摘Objectives: The primary objective was to characterize the range of Knowledge, Attitude, and Practice (KAP) of Helmet use in children amongst parents to prevent head injuries and death. Methods: This is a cross-sectional study, done by online survey using a snowball sampling technique, the number of included responses were 386 parents (Male and female) living in Riyadh Aged 21 - 60 years old or above. Results: The study showed that there is a difference in Parents’ belief in the importance of helmet use while riding a Bicycle vs Motorcycle/Quad bike and that was affected by parents’ education level, almost all the people who answered the survey (76.7%) agree that it is important for their children to wear a helmet when riding both a Bicycle and a Motorcycle or Quadbike with a cumulative percentage of (93.8%). And almost all agreed on multiple approaches to help increase helmet use be it by forcing rental shops to give out helmets, forcing sellers to recommend the use of helmets, increasing awareness campaigns, and imposing fines for not wearing helmets. Conclusions: This study is the first to explore Family helmet use while riding Bicycles and Motorcycles/Quad bikes. Although Parent’s belief in the importance of helmet use for their children was high, it is clear that the level of practice is low. With that the risk of head injuries might be high, our findings suggest that safety interventions for increasing pediatric helmet use are needed to increase helmet use and reduce the risk of head injury and hospitalization.
文摘In recent years,disorderly parking and difficult charging of electric bicycles have been challenges in urban management.The rapid growth of electric bicycles is in contradiction with the lack of dedicated parking spaces and charging service facilities in towns and villages.To solve the issue of parking and charging electric bicycles in limited urban and rural spaces,prefabricated building technology is applied to the design of a multi-story electric bicycle parking lot.The multi-story prefabricated electric bicycle parking lot is utilized in urban and rural planning and design to upgrade parking facilities in old urban areas,land-constrained commercial areas,as well as counties,towns,and rural areas with inadequate municipal facilities.Multi-story prefabricated electric bicycle parking lots are the application exploration of industrial buildings,and promote the high-quality development planning and construction of towns and counties and villages.Compared with the single-story metal charging station,the multi-story assembled electric bicycle parking lot has the characteristics of integrating parking and charging,being more durable and safer in structure,accommodating a large number of vehicles,and improving the space utilization rate.
文摘Drawing upon Donna Haraway’s cyborg theory,this paper argues that the bicycle can be conceived as a cyborg extension of body and identity which transcended its mechanical essence to become an integral co-partner for women involved in resistance activities in WWII.More specifically,the study explores how women used cycling during World War Ⅱ not only for mobility but as a profound expression of courage,endurance and solidarity which enabled them to overcome physical and symbolic barriers under totalitarian regimes.The bicycle emerges not only as a central co-agent but also actively co-creates the situations in which it emerges as a transformative force.Cycling acted as a catalyst for personal and collective empowerment,fostering new subjectivities while transcending physical and social limitations.This study sparks multidimensional discourse on how technological tools can co-create our societies and identities,offering insights into how bicycles can drive socio-political change,promote emancipation and foster inclusivity.
基金We thank the National Science Foundation of China(NSFC,N0.20372003)for financial support.
文摘Aim To develop a concise method for the synthesis of bicyclic azasugar and thiosugar with novel scaffold. Methods The two primary hydroxyl groups of compound 1 were selectively protected with tosyl cloloride in pyridine, followed by ring-closure with sodium sulfide or primary amine to form the oxy-bridged bicyclic molecules in good yields. Results Two bicyclic azasugars and a thiosugar were produced from L-sorbose in several steps. Conclusion The described procedures provide an efficient method to synthesize bicyclic azasugar and thiosugar with novel scaffold as potential glycosidase inhibitors.
文摘Background: Cycling as a means of transport contributes to public health in terms of increasing the physical activity behaviour and reducing air pollution. In comparison to walking, cycling-spe cific environmental characteristics have been less investigated. The aim of this study was to develop, based on geographic information systems (GIS) data, a bikeability index for a mid-sized European city, to examine the predictive validity of the index and to visualize the bicycle-friendliness of the city by creating a bikeability map. Methods: Using GIS data, we assessed the environmental characteristics of 278 bicycle trips in the city of Graz, Austria. Characteristics which differed significantly between the actually taken and shortest possible routes were used to form an additive bikeability index and the bikeability map for 100 m × 100 m cells. The relationship between the cycling behaviour and the bikeability index around the home environment was examined to assess the predictive validity of the index. Results: Three environmental components (cycling infrastructure, bicycle pathways and green areas) were positively related, and two components (main roads, and topography) were negatively related to the actually used route. These components formed the bikeability index, which was positively correlated with cycling behaviour (OR: 1.08, 95% CI 1.01 - 1.17). The final outcome is a high-resolution coloured map indicating the degree of bicycle-friendliness in the city of Graz. Conclusion: Mapping based on the bikeability index helps to visualize the bicycle-friendliness of an urban area. Therefore, it should be a useful tool for the planning as well as for the evaluation of the transport environments in cities.
文摘Background: Cycling currently comprises only 1% of transport trips in the U.S. despite benefits for air pollution, traffic congestion, and improved public health. Methods: Building upon the Level of Traffic Stress (LTS) methodology, we assessed GPS trip data from utilitarian cyclists to understand route preferences and the level of low stress cycling connection between origins and destinations. GPS data were obtained from adult transport cyclists over multiple days. All bikeable road segments in the network were assigned an LTS score. The shortest paths between each origin and destination along bikeable roadways and along low stress (LTS 1 or 2) routes were calculated. Route trajectories were mapped to the LTS network, and the LTS and distances of observed, the shortest and low stress routes were compared. LTS maps and animations were developed to highlight where low stress connections were lacking. Results: There were 1038 unique cycling trips from 87 participants included in the analysis. An exclusively low stress route did not exist for 51% of trips. Low stress routes that were possible were, on average, 74% longer than the shortest possible path and 56% longer than the observed route. Observed routes were longer and lower stress than the shortest possible route. Conclusions: Results indicate that transport cyclists traveled beyond low stress residential areas and that low stress routes with acceptable detour distances were lacking. Cyclists appeared to weigh both route distance and quality and were willing to trade maximum directness for lower stress. GPS data provide additional information to support planning decisions to increase the impact of infrastructure investments on cycling mode share.
基金The National Natural Science Foundation of China(No.51238008,51408322)
文摘This paper investigates the passing events between electric bicycles and conventional bicycles and explores the relationships between passing events and traffic parameters in bicycle facilities.Three exclusive bicycle paths in Nanjing, China,were observed with cameras.Then,the field data including vehicle number,velocity characteristics and passing event features were analyzed in detail.Data analysis and fitting reveal that the speed difference has little impact on the passing event number,as does the bicycle ratio.The Gaussian function can better describe the relationship between the passing event number and bicycle volume (density).The valid use level of bicycle path width influences the inflexion of the passing events-density fitting curve.The conclusions can be applied for estimating the passing events in mixed bicycle flows and for choosing a suitable width of separate bicycle path.
文摘PI novel caged bicyclic phosphate flame retardant tri(1-oxo-2,6,7-trioxa-1-phosphabicyclo [2.2.2] octane-methyl) phosphate (Trimer) was synthesized from 1-oxo-4-hydroxymethyl-2,6,7-trioxa-1-phosphabicyclo [2.2.2] octane (PEPA) and phosphorus oxychloride in this paper. Its structure was characterized by elemental analysis. FTIR, H-1 NMR. P-31 NMR and X-ray diffraction analysis.
基金Under the auspices of National Natural Science Foundation of China(No.41801150,41571146,41801144)Natural Science Foundation of Guangdong Province(No.2018A030310392)+2 种基金Guangdong Planning Project of Philosophy and Social Science(No.GD17YGL01)Science and Technology Program of Guangzhou(No.201906010033)GDAS’(Guangdong Academy of Sciences)Project of Science and Technology Development(No.2020GDASYL-20200104007)。
文摘Mobile information and communication technologies(MICTs) have fully penetrated everyday life in smart societies;this has greatly compressed time, space, and distance, and consequently, reshaped residents’ travel behaviour patterns. As a new mode of shared mobility, the sharing bicycle offers a variety of options for the daily travel of urban residents. Extant studies have mainly examined the travel characteristics and influencing factors of public bicycles with piles, while the travel patterns for sharing bicycles and their driving mechanisms have been largely ignored. Using one week’s travel data for Mobike, this study investigated the spatial and temporal distribution patterns of sharing bicycle travel behaviours in the central urban area of Guangzhou, China;furthermore, it identified the influences of built environment density factors on sharing bicycle travel behaviours based on the geographically weighted regression method. Obvious morning and evening peaks were observed in the sharing bicycle travel patterns for both weekdays and weekends. The old urban area, which had a high degree of mixed function, dense road networks, and cycling-friendly built environments, was the main travel area that attracted sharing bicycles on both weekdays and weekends. Furthermore, factors including the point of interest(POI) for the density of public transport stations, the functional mixing degree, and the density of residential POIs significantly affected residents’ travel behaviours. These findings could enrich discourse regarding shared mobility with a Chinese case characterised by rapidly developing MICTs and also provide references to local authorities for improving slow traffic environments.
基金Project(2012CB725400) supported by the National Basic Research Program of ChinaProjects(70901005, 71071016, 71131001) supported by the National Natural Science Foundation of ChinaProject(2011JBM055) supported by the Fundamental Research Funds for the Central Universities of China
文摘To determine how bus stop design influences mixed traffic operation near Chinese bus stops,a new theoretical method was developed by using additive-conflict-flows procedure.The procedure was extended from homogeneous traffic flow to mixed traffic flow.Based on the procedure and queuing theory,car capacity and speed models were proposed for three types of bus stops including curbside,bus bay and bicycle detour.The effects of various combinations of bus stop type,traffic volume,bus dwell time,and berth number on traffic operations were investigated.The results indicate that traffic volume,bus dwell time and berth number have negative effects on traffic operations for any type of bus stops.For different types of bus stops,at car volumes above approximately 200 vehicles per hour,the bus bay and bicycle detour designs provide more benefits than the curbside design.As traffic volume increases,the benefit firstly increases in uncongested conditions and then decreases in congested conditions.It reaches the maximum at car volumes nearly 1 100 vehicles per hour.The results can be used to aid in the selection of a preferred bus stop design for a given traffic volume in developing countries.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41672117 and 41503034)the Hubei Provincial Natural Science Foundation of China (Project No. 2017CFA027)+1 种基金the Open Subject of Shandong Provincial Key Laboratory of Depositional Mineralization & Sedimentary Mineral (Baojun Liu Geoscience Science Foundation) (DMSM2017084)the Open Subject of the State Key Laboratory of Petroleum Resources and Prospecting (PRP/open-1509)
文摘Sesquiterpanes are ubiquitous components of crude oils and ancient sediments.Liquid saturated hydrocarbons from simulated pyrolysis experiments on immature organic-rich mudstone collected from the Lower Cretaceous Hesigewula Sag were analyzed by gas chromatography-mass spectrometry(GC-MS).C14 bicyclic sesquiterpanes,namely,8β(H)-drimane,8β(H)-homodrimane,and 8 a(H)-homodrimane were detected and identified on basis of their diagnostic fragment ions(m/z123,179,193,and 207),and previously published mass spectra data,and these bicyclic sesquiterpanes presented relatively regular characteristics in their thermal evolution.The ratios 8β(H)-drimane/8β(H)-homodrimane,8β(H)-homodrimane/8 a(H)-homodrimane,and 8β(H)-drimane/8 a(H)-homodrimane all show a clear upward trend with increasing temperature below the temperature turning point.Thus,all these ratios can be used as evolution indexes of source rocks in the immature-lowmaturity stage.However,the last two ratios may be more suitable than the first ratio as valid parameters for measuring the extent of thermal evolution of organic matter in the immature-low-maturity stage because their change amplitude with increasing temperature is more obvious.
基金Supported by Special Fund Project for Technology Innovation of Tianjin (No.10FDZDGX00500)Tianjin Product Quality Inspection Technology Research Institute
文摘The safety and the fatigue comfort were compared between a domestic and a Japanese postal bicycle. Firstly, the fatigue comfort of these two kinds of bicycles was evaluated by surface electromyographic signal (sEMG) experiment, in which human lower limb muscle groups were research objects, and the average EMG (AEMG) index and median frequency (MF) were chosen as the evaluation indexes. Secondly, the safety of these two kinds of bicycle frames was analyzed and compared by using the finite element analysis. The results show that the riding fatigue comfort of the Japanese postal bicycle is better, and the Japanese postal bicycle frame is more safe and reasonable although both the postal bicycles meet the requirement for strength. Finally, based on the above analysis, the frame structure and related parameters of the domestic postal bicycle were improved with reference to the Japanese postal bicycle and biomechanics theory.
基金Supported by the National Natural Science Foundation of China(11071272,10831001,11171279,11101087)the Young Talent Foundation of Fuzhou University(XRC-1154)
文摘The atom-bond connectivity(ABC) index provides a good model for the stability of linear and branched alkanes as well as the strain energy of cycloalkanes,which is defined as ABC(G) =∑ uv∈E(G) √d u+dv-2 dudv,where du denotes the degree of a vertex u in G.A chemical graph is a graph in which no vertex has degree greater than 4.In this paper,we obtain the sharp upper and lower bounds on ABC index of chemical bicyclic graphs.
基金supported by Tianjin Municipal Special Fund Project for Technology Innovation of China(Grant No.10FDZDGX00500),and Tianjin Municipal Key Laboratory of Advanced Manufacturing Technology and Equipment of Tianjin University of China
文摘With the development of technology and the change of market demands,the trend in middle and high grade bicycle manufacturing is developed toward small-volume,multi-species,and customer-oriented production.Therefore,human element should be fully considered in design so that the bicycle has the best cycling performance for the specific rider.Currently,customized design is difficult to achieve since feature parameters of the rider are not included in the design.The design of bicycle frame is the most important in bicycle design.The relative positions among the saddle,handlebar and central axis are defined as the bicycle three-pivot,they are the main parameters in bicycle frame design.In conventional bicycle design,frame parameters are merely relevant to bicycle types.On the basis of the principles of biomechanics and ergonomics knowledge,this paper presents a design method for bicycle three-pivot considering feature parameters of the rider by dynamic simulation.Firstly,a dynamic model of rider-bicycle system is built for a special rider,and a serial of simulation experiments is designed by uniform test method.Then,a mathematical model is built between the three-pivot position and the square of lower limb muscle stress by using simulation and regression analysis of the rider-bicycle system.The optimal three-pivot position parameters are obtained by setting the minimal of the square of the lower limb muscle stress as the objective.Therefore,the optimal parameters are gained for the specific rider.Finally,various results are gained for different riders based on the same design process.The function between feature parameters of the rider and the optimum three-pivot position parameters is built by regression.Bicycle design considering biomechanics can be divided into three main steps:calculating the three-pivot position,designing the geometrical structure of the bicycle frame and analyzing frame strength,and selecting appropriate parts and assembling the bicycle.Bicycle design considering biomechanics changes the conventional bicycle design and realizes customized design by considering human element in the design process.
基金The project was supported by NNSFC (Nos. 10576030 and 10576016) and the Innovation Project for Postgraduates in the Universities of Jiangsu Province (AD20116)
文摘Ab initio molecular orbital calculations have been performed at Hartree-Fock (HF), second-order Mrller-Plesset (MP2), and hybrid density functional theory (DFT) B3LYP levels with 6-31G^** basis set to investigate the low sensitive explosive trans-1,4,5,8-tetranitro-1,4,5,8- tetraazadecalin (TNAD) and its seven bicyclic isomers. Their molecular geometries, electronic structures, thermodynamic properties, and detonation performances were predicted and compared. The relationships between structures and various properties were discussed in detail. The calculated results agree well with the available experimental data, and suggest that some compounds may be novel potential candidates of high energy density materials (HEDMs) with performances better than TNT (2,4,6-trinitrotoluene) and similar to RDX (1,3,5-trinitro-1,3,5-triazacyclohexane).