Source and accumulation process of Jurassic biodegraded oil in the Eastern Junggar Basin,NW China

Biodegradation usually obscures or even radically alters the original characteristics of oil biomarkers.The mixing of oil from multiple sources makes each source difficult to trace.Identifying the source of biodegraded oil from multiple sources has always been a hard nut to crack.Rising to this challenge,in this study-we carried out a comprehensive investigation of biodegradation impacts,oil-source correlation,and oil charging history to trace the source and reveal the mixing process of biodegraded oil in the Toutunhe Formation(J_(2)t)in the eastern Junggar Basin,NW China.The oil of this area was biodegraded to different extent,consequently,many commonly used biomarker parameters(e.g.Pr/Ph,Pr/n C_(17))became less powerful for oil-source correlation.To address this problem,the resistance of many biomarkers to biodegradation was analyzed,and those of high bio resistance were selected to generate a more reliable oil-source correlation.The results revealed that biodegraded oil was a mixture of oil sourced from Lucaogou Formation(P_(2)l)and Xiaoquangou Formation(T_(2-3)xq).Core sample observation,microscopic fluorescent analysis and fluid inclusion analysis were combined to analyze comprehensively oil charging history.The analysis of accumulation process exhibited that the existing oil in J_(2)t was a mixture originated from the P_(2)l and T_(2-3)xq source rocks in two separate charging stages when it underwent a complicated process of charging,biodegradation,recharging and mixing.

Insulation System of Power Transformers Behavior Comparison of Mineral Oils and Natural Ester Dielectric Fluids

Paper deals with a comparison of selected properties of several vegetable oil representatives along their accelerated thermal ageing at the temperature of 90 ℃. These properties are compared to two widely used and commercially available mineral transformer oils. A combined insulating system （an oil-paper system） was created with the usage of mentioned oils for measurement purposes. Dissipation factor, capacity and volume resistance are characteristics measured along a thermal ageing of the oil-paper systems. Infrared spectroscopy was used as an additional method. After 1,000 hours of ageing, the dissipation factor of all systems based on vegetable oils did not exceed the value of 0.015. The volume resistance of systems containing mineral oils was approx, twice as high as the volume resistance of those with vegetable oils. The capacity on the other hand was slightly lower in the case of mineral oils application. An experiment also showed that the paper combined with the vegetable oil dries more quickly than in combination with the mineral oil. Infrared spectroscopy has not shown any expressive changes in the chemical structure of aU tested oils yet （up to 1,000 hours of ageing）.

严重生物降解原油GC-MS特征及油源对比

图牧吉油砂位于松辽盆地边缘,搞清它的油源对于该地区的油气勘探有着十分重要的意义.气相色谱-质谱分析表明,该样品受到了严重的生物降解,部分用于对比的甾、萜烷生标标志物受到了降解,使与之有关的参数值发生了变化,给油源对比带来了困难.……

Structure and Potential Application of Konjac Glucomannan Nano Microfibril Aerogel

An ultra-light and high porosity nano microfibril aerogel was prepared from konjac glucomannan（KGM） by the electrospinning and freeze-drying. The structure of aerogel was analyzed by scanning electron microscopy（SEM） and X-ray diffraction（XRD） while the density and compressive strength of the samples were studied separately. Results reveal that porous network structure of the KGM nano microfibril aerogel is constructed by intermolecular hydrogen bonds in random and interpenetrate way. The nano microfibril structure presents in the KGM aerogel,which is an important reason of its high density and compressive strength. There is a potential application for this unique nano microfibril aerogel in the absorption of biodegradation bacteria to solve problems in marine oil spill pollution.

Insight of unresolved complex mixtures of saturated hydrocarbons in heavy oil via GC×GC-TOFMS analysis

The saturated hydrocarbon fraction of a heavily biodegraded crude oil from Liaohe oilfield was analyzed by using comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOFMS). The "humps", which was termed as unresolved complex mixtures (UCMs) in conventional gas chromatographic analysis, was separated for identification of the individual compound. Main compounds of UCMs were identified according to the combined information of characteristics of GC×GC chromatogram and time-of-flight mass spectra. It's found that UCMs are mainly composed of great number of ring compounds with extremely low concentration. The ring compounds are separated according to their boiling point diversity in the first dimension column, then to their polarity or ring number variety in the second dimension column. In the sample there are two groups of UCMs, i.e., the first group compounds with boiling point lower that of C24 and the second group compounds with boiling point higher than that of C24. The first group of UCMs mainly consists of monocyclic, bicyclic and tricyclic ring compounds. The first group of UCMs is mainly composed of saturated hydrocarbons, in which the percentage of ring compounds with signal-to-noise ratio above 100 is about 75% of the total quantity of saturated hydrocarbon, while its mass is over 80% of the total saturated hydrocarbon. The second group of UCMs is mainly composed of tetracyclic and pentacyclic ring compounds, in which the percentage of UCM compounds with signal-to-noise ratio over 100 is about 17% of the total quantity of saturated hydrocarbon, and its mass is about 0.5% of the total saturated hydrocarbon. The results of this study are helpful for heavy oil developing and genesis mechanism understanding.